CN106928794A - A kind of heat discoloration coating and heat discoloration container - Google Patents
A kind of heat discoloration coating and heat discoloration container Download PDFInfo
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- CN106928794A CN106928794A CN201710065792.4A CN201710065792A CN106928794A CN 106928794 A CN106928794 A CN 106928794A CN 201710065792 A CN201710065792 A CN 201710065792A CN 106928794 A CN106928794 A CN 106928794A
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- heat discoloration
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47G—HOUSEHOLD OR TABLE EQUIPMENT
- A47G19/00—Table service
- A47G19/22—Drinking vessels or saucers used for table service
- A47G19/2205—Drinking glasses or vessels
- A47G19/2227—Drinking glasses or vessels with means for amusing or giving information to the user
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/26—Thermosensitive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
Abstract
The invention discloses a kind of heat discoloration coating and heat discoloration container, the heat discoloration coating includes the raw material of following mass parts：Water-base resin：100 parts；Thermochromism toner：10~50 parts；Common toner：10~50 parts；Dispersant：0.5~0.9 part；Defoamer：0.5~1 part；Adhesion promoter：1.5~2.5 parts；Water：20~50 parts.The heat discoloration container includes vessel, the protective clear layer for being arranged on the heat discoloration on vessel surface layer and being arranged on heat discoloration layer；Described heat discoloration layer is obtained by heat discoloration coating dry solidification；Described protective clear layer is obtained by clear dope dry solidification.Heat discoloration coating of the invention and heat discoloration container color change are abundant; diversified pattern can be set on container; preparation process is simple; heat discoloration layer and vessel are tightly combined; it is difficult for drop-off; and container outermost layer is provided with protective clear layer, it is ensured that the design and color of vessel surface is durable in use.
Description
Technical field
The present invention relates to a kind of heat discoloration coating and heat discoloration container.
Background technology
Heat discoloration coating is a kind of coating that can produce color change with temperature change, why can be changed colour, and is
Because heat discoloration coating the inside is added with thermochromism toner.Heat discoloration coating is commonly used to prepare color-changeable cup, also known as magic
Cup, is commonly divided into cold color-changeable cup and thermo-color cup.General cold color-changeable cup selects 7~17 DEG C of off-color materials of change, less than this
Individual temperature just changes colour；And thermo-color cup is general from 40 DEG C or so the off-color materials of change, just change colour higher than this temperature.At present
Color-changeable cup color change it is single, be typically only capable to by a kind of color（Black, red, Lan Dengse）Bleach（Background color is presented）, it is relatively more single
Adjust, it is interesting not high.
The content of the invention
It is an object of the invention to provide a kind of heat discoloration coating and heat discoloration container.
The technical solution used in the present invention is：
A kind of heat discoloration coating, including following mass parts raw material：
Water-base resin：100 parts；
Thermochromism toner：10~50 parts；
Common toner：10~50 parts；
Dispersant：0.5~0.9 part；
Defoamer：0.5~1 part；
Adhesion promoter：1.5~2.5 parts；
Water：20~50 parts.
The transition interval of described thermochromism toner is 5~25 DEG C.
The transition interval of described thermochromism toner is 35~65 DEG C.
Described water-base resin is waterborne acrylic paint, waterborne polyurethane resin, aqueous epoxy resins, aqueous amino
At least one in resin.
Described dispersant is at least one in anion surfactant, nonionic surfactant.
Described defoamer is at least one in modified polyorganosiloxane, modified polyalcohol, dimethicone.
Described adhesion promoter is silane coupler.
A kind of heat discoloration container, including vessel, be arranged on vessel surface heat discoloration layer and be arranged on
Protective clear layer on heat discoloration layer；Described heat discoloration layer is obtained by above-mentioned heat discoloration coating dry solidification；It is described
Protective clear layer obtained by clear dope dry solidification.
Patterned layer is additionally provided between described heat discoloration layer and protective clear layer.
Pattern is provided with described heat discoloration layer.
Described heat discoloration layer normal temperature is presented a kind of color, and temperature is less than 10 DEG C of presentations, second color.
Described heat discoloration layer normal temperature is presented a kind of color, and temperature is presented second color when being higher than 43 DEG C.
Described heat discoloration layer normal temperature is presented a kind of color, and temperature is higher than less than 10 DEG C of presentations, second color, temperature
The third color is presented at 43 DEG C.
The beneficial effects of the invention are as follows：
1）What heat discoloration coating of the invention was presented at normal temperatures is thermochromism toner and the redeployed face of common toner
Color, is adding hot water（Or cold water）Afterwards, thermochromism toner slowly bleach, thermochromism toner and common toner are mixed and
Color can also change constantly, until cup shows the color of common toner completely, color change is enriched, and can be widely used for system
The standby ceramic cup with heat discoloration characteristic, thermos cup, feeding bottle, decoration painting, decoration wallpaper etc.；
2）Heat discoloration container color change of the invention is enriched, and diversified pattern can be set, and preparation process is simple, temperature-sensitive becomes
Color coating and vessel are tightly combined, difficult for drop-off, and container outermost layer is provided with protective clear layer, it is ensured that container table
The design and color in face is durable in use, for a long time using colour-fast.
Specific embodiment
A kind of heat discoloration coating, including following mass parts raw material：
Water-base resin：100 parts；
Thermochromism toner：10~50 parts；
Common toner：10~50 parts；
Dispersant：0.5~0.9 part；
Defoamer：0.5~1 part；
Adhesion promoter：1.5~2.5 parts；
Water：20~50 parts.
Preferably, the transition interval of described thermochromism toner is 5~25 DEG C.
Preferably, the transition interval of described thermochromism toner is 35~65 DEG C.
Preferably, described water-base resin be waterborne acrylic paint, waterborne polyurethane resin, aqueous epoxy resins,
At least one in water-compatible amino resin.
Preferably, described dispersant is at least one in anion surfactant, nonionic surfactant.
Preferably, described defoamer is at least one in modified polyorganosiloxane, modified polyalcohol, dimethicone.
Preferably, described adhesion promoter is silane coupler.
It is further preferred that described adhesion promoter is at least one in vinyl silanes, epoxy radicals silicone hydride.
A kind of heat discoloration container, including vessel, be arranged on vessel surface heat discoloration layer and be arranged on
Protective clear layer on heat discoloration layer；Described heat discoloration layer is obtained by above-mentioned heat discoloration coating dry solidification；It is described
Protective clear layer obtained by clear dope dry solidification.
Preferably, patterned layer is additionally provided between described heat discoloration layer and protective clear layer.
Preferably, pattern is provided with described heat discoloration layer.
Preferably, the pattern in described heat discoloration layer is obtained by heat sublimation technique.
Preferably, described heat discoloration layer normal temperature is presented a kind of color, and temperature is less than 10 DEG C of presentations, second color.
Preferably, described heat discoloration layer normal temperature is presented a kind of color, and temperature is presented second color when being higher than 43 DEG C.
Preferably, described heat discoloration layer normal temperature is presented a kind of color, and temperature is less than 10 DEG C of presentations, second color, temperature
The third color is presented when degree is higher than 43 DEG C.
The preparation method of above-mentioned heat discoloration container is comprised the following steps：
1) vessel is cleaned up, re-dry removes surface moisture；
2) water-base resin, thermochromism toner, common toner, dispersant, defoamer and adhesion promoter are added into three-level ball
Grinding machine, is fully ground uniformly, adds water, obtains heat discoloration coating；
3) heat discoloration coating is sprayed on vessel surface, is dried, toasted, obtain heat discoloration layer；
4) patterned layer in layer of transparent protective layer or first thermal transfer is sprayed on heat discoloration layer and sprays layer of transparent protection again
Layer or first pass through heat sublimation technique by pattern be arranged on heat discoloration layer in spray layer of transparent protective layer again, obtain temperature-sensitive become
Color tolerance device.
Preferably, step 1）Described dry temperature is 80~100 DEG C, and drying time is 15~30 minutes.
Preferably, step 3）The temperature of described baking is 150~190 DEG C, and the time is 30~50 minutes.
The present invention is made further explanation and description with reference to specific embodiment.
Embodiment 1：
1）Whiteware cup is cleaned up, then 80 DEG C of dryings 30 minutes, remove surface moisture；
2）By waterborne acrylic paint, 43 degree of black color-change powder, common red toner（Nondiscolouring）, anion surface active
Agent, modified polyorganosiloxane and epoxy radicals silicone hydride add three-level ball mill, are fully ground uniformly, add water, are well mixed, and obtain
Heat discoloration coating；
3）Heat discoloration coating is sprayed on whiteware cup outer surface, is dried, 150 DEG C are toasted 50 minutes, obtain heat discoloration
Layer；
4）Layer of transparent protective layer is sprayed on heat discoloration layer, temperature-sensing color-changing cup is obtained.
Appearance is coffee color under temperature-sensing color-changing cup normal temperature manufactured in the present embodiment, can be slowly after the hot water that more than 50 DEG C of addition
Discoloration, ultimately becomes red, and cup reverts to coffee color after being cooled to normal temperature.
Embodiment 2：
1）Clear glass cup is cleaned up, then 100 DEG C of dryings 15 minutes, remove surface moisture；
2）By aqueous epoxy resins, 45 degree of dark blue color-change powder, common pink toner（Nondiscolouring）, anion surface active
Agent, modified polyalcohol and vinyl silanes add three-level ball mill, are fully ground uniformly, add water, are well mixed, and are felt
Warm allochroic paint；
3）Heat discoloration coating is sprayed on clear glass cup outer surface, is dried, 170 DEG C are toasted 40 minutes, obtain heat discoloration
Layer；
4）White marble paper water is transferred on heat discoloration layer, then sprays layer of transparent protective layer, obtain temperature-sensing color-changing cup.
Appearance is purple under temperature-sensing color-changing cup normal temperature manufactured in the present embodiment, it can be seen that white flowers paper pattern, adds 50 DEG C
Can slowly change colour after hot water above, ultimately become pink and white flowers paper pattern is constant, cup recovers after being cooled to normal temperature
Purple.
Embodiment 3：
1）Whiteware cup is cleaned up, then 90 DEG C of dryings 20 minutes, remove surface moisture；
2）By water-compatible amino resin, 43 degree of black color-change powder, common light blue toner（Nondiscolouring）, non-ionic surface active
Agent, dimethicone and epoxy radicals silicone hydride add three-level ball mill, are fully ground uniformly, add water, are well mixed, and are felt
Warm allochroic paint；
3）Heat discoloration coating is sprayed on whiteware cup outer surface, is dried, 190 DEG C are toasted 30 minutes, obtain heat discoloration
Layer；
4）By pattern thermal transfer on heat discoloration layer, then layer of transparent protective layer is sprayed, obtain temperature-sensing color-changing cup.
Appearance is black under temperature-sensing color-changing cup normal temperature manufactured in the present embodiment, can slowly be become after the hot water for adding more than 50 DEG C
Color, finally has thermally transferred pattern, the cup of light blue background, and cup reverts to black after being cooled to normal temperature.
Embodiment 4：
1）Clear glass cup is cleaned up, then 100 DEG C of dryings 15 minutes, remove surface moisture；
2）By water-compatible amino resin, 10 degree of black color-change powder, common light blue toner（Nondiscolouring）, non-ionic surface active
Agent, dimethicone and epoxy radicals silicone hydride add three-level ball mill, are fully ground uniformly, add water, are well mixed, and are felt
Warm allochroic paint；
3）Heat discoloration coating is sprayed on clear glass cup outer surface, is dried, 170 DEG C are toasted 45 minutes, obtain heat discoloration
Layer；
4）One layer of thermal transfer coating is sprayed on heat discoloration layer（It is transparent）, 180 DEG C are toasted about 30 minutes, then pattern in thermal transfer
Layer, obtains temperature-sensing color-changing cup.
Appearance is black under temperature-sensing color-changing cup normal temperature manufactured in the present embodiment, can slowly be become after the cold water for adding less than 5 DEG C
Color, finally has thermally transferred pattern, the cup of light blue background, and cup recovers to revert to black to normal temperature.
Embodiment 5：
1）Whiteware cup is cleaned up, then 100 DEG C of dryings 15 minutes, remove surface moisture；
2）By water-compatible amino resin, 10 degree of black color-change powder, 65 degree of red color-change powders, common pink toners（Nondiscolouring）、
Nonionic surfactant, dimethicone and epoxy radicals silicone hydride add three-level ball mill, are fully ground uniformly, add water,
It is well mixed, obtain heat discoloration coating；
3）Heat discoloration coating is sprayed on whiteware cup outer surface, is dried, 170 DEG C are toasted 45 minutes, obtain heat discoloration
Layer；
4）Layer of transparent protective layer is sprayed on heat discoloration layer, temperature-sensing color-changing cup is obtained.
Appearance is red under temperature-sensing color-changing cup normal temperature manufactured in the present embodiment, can be slowly after less than 5 DEG C of cold water is added
Become coffee-like, cup recovers to revert to red to normal temperature；Pink is slowly become after 65 DEG C of hot water are added, cup recovers
Red is reverted to after to normal temperature.
Above-described embodiment is the present invention preferably implementation method, but embodiments of the present invention are not by above-described embodiment
Limitation, it is other it is any without departing from Spirit Essence of the invention and the change, modification, replacement made under principle, combine, simplification,
Equivalent substitute mode is should be, is included within protection scope of the present invention.
Claims (10)
1. a kind of heat discoloration coating, it is characterised in that：Raw material including following mass parts：
Water-base resin：100 parts；
Thermochromism toner：10~50 parts；
Common toner：10~50 parts；
Dispersant：0.5~0.9 part；
Defoamer：0.5~1 part；
Adhesion promoter：1.5~2.5 parts；
Water：20~50 parts.
2. heat discoloration coating according to claim 1, it is characterised in that：The transition interval of described thermochromism toner
It is 5~25 DEG C.
3. heat discoloration coating according to claim 1, it is characterised in that：The transition interval of described thermochromism toner
It is 35~65 DEG C.
4. the heat discoloration coating according to any one in claims 1 to 3, it is characterised in that：Described water-base resin
It is at least one in waterborne acrylic paint, waterborne polyurethane resin, aqueous epoxy resins, water-compatible amino resin；It is described
Dispersant be at least one in anion surfactant, nonionic surfactant；Described defoamer is modified poly-
At least one in siloxanes, modified polyalcohol, dimethicone；Described adhesion promoter is silane coupler.
5. a kind of heat discoloration container, it is characterised in that：Including vessel, be arranged on vessel surface heat discoloration layer
With the protective clear layer being arranged on heat discoloration layer；Described heat discoloration layer is obtained by heat discoloration coating dry solidification；
Described protective clear layer is obtained by clear dope dry solidification.
6. heat discoloration container according to claim 5, it is characterised in that：Described heat discoloration layer and protective clear layer
Between be additionally provided with patterned layer.
7. heat discoloration container according to claim 5, it is characterised in that：Figure is provided with described heat discoloration layer
Case.
8. the heat discoloration container according to any one in claim 5~7, it is characterised in that：Described heat discoloration
Layer normal temperature is presented a kind of color, and temperature is less than 10 DEG C of presentations, second color.
9. the heat discoloration container according to any one in claim 5~7, it is characterised in that：Described heat discoloration
Layer normal temperature is presented a kind of color, and temperature is presented second color when being higher than 43 DEG C.
10. the heat discoloration container according to any one in claim 5~7, it is characterised in that：Described heat discoloration
Layer normal temperature is presented a kind of color, and temperature is presented the third color less than 10 DEG C of presentations, second color, temperature when being higher than 43 DEG C.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710065792.4A CN106928794A (en) | 2017-02-06 | 2017-02-06 | A kind of heat discoloration coating and heat discoloration container |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710065792.4A CN106928794A (en) | 2017-02-06 | 2017-02-06 | A kind of heat discoloration coating and heat discoloration container |
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Family
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| CN201710065792.4A Pending CN106928794A (en) | 2017-02-06 | 2017-02-06 | A kind of heat discoloration coating and heat discoloration container |
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| CN107353822A (en) * | 2017-07-27 | 2017-11-17 | 深圳市联星服装辅料有限公司 | A kind of water-based stoving paint and its baking finish process for clothes metal button |
| CN107474658A (en) * | 2017-08-16 | 2017-12-15 | 兰州科天新材料股份有限公司 | A kind of aqueous, environmental protective heat discoloration crackle paint and preparation method thereof |
| CN107502026A (en) * | 2017-08-24 | 2017-12-22 | 深圳金生缘文化发展有限公司 | A kind of heat discoloration technique for noble metal |
| CN107604684A (en) * | 2017-09-21 | 2018-01-19 | 江西省新天汇实业有限公司 | A kind of environment-friendly type discoloration packaging leather and preparation method thereof |
| CN108650344A (en) * | 2018-04-24 | 2018-10-12 | 深圳初上科技有限公司 | A kind of intelligent temp.-sensitive controlled color-change ceramic mobile phone shell |
| CN108690448A (en) * | 2018-02-26 | 2018-10-23 | 河北晨阳工贸集团有限公司 | A kind of medical instrument allochroic paint and its preparation method and application |
| CN108690436A (en) * | 2018-02-26 | 2018-10-23 | 河北晨阳工贸集团有限公司 | A kind of aqueous allochroic paint and preparation method thereof |
| CN108944227A (en) * | 2018-05-04 | 2018-12-07 | 广州市昌成陶瓷有限公司 | A kind of cold discoloration thermal transfer container |
| CN109295746A (en) * | 2017-07-24 | 2019-02-01 | 南通东屹高新纤维科技有限公司 | Fabric with temperature-sensing discoloration function |
| CN110367771A (en) * | 2019-07-08 | 2019-10-25 | 临泉县变色杯陶瓷制品有限公司 | A kind of ceramic health-preserving cup |
| CN110638288A (en) * | 2019-09-04 | 2020-01-03 | 江苏中盈玻璃科技有限公司 | Teapot with glass product having temperature sensing function |
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| CN117247731B (en) * | 2023-09-14 | 2024-05-10 | 佛山市三水顺能化工有限公司 | Temperature-sensitive color-changing aqueous color layer coating for electrochemical aluminum and preparation method thereof |
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| CN107604684A (en) * | 2017-09-21 | 2018-01-19 | 江西省新天汇实业有限公司 | A kind of environment-friendly type discoloration packaging leather and preparation method thereof |
| CN108690436A (en) * | 2018-02-26 | 2018-10-23 | 河北晨阳工贸集团有限公司 | A kind of aqueous allochroic paint and preparation method thereof |
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| CN108650344A (en) * | 2018-04-24 | 2018-10-12 | 深圳初上科技有限公司 | A kind of intelligent temp.-sensitive controlled color-change ceramic mobile phone shell |
| CN108944227A (en) * | 2018-05-04 | 2018-12-07 | 广州市昌成陶瓷有限公司 | A kind of cold discoloration thermal transfer container |
| CN110367771A (en) * | 2019-07-08 | 2019-10-25 | 临泉县变色杯陶瓷制品有限公司 | A kind of ceramic health-preserving cup |
| CN110638288A (en) * | 2019-09-04 | 2020-01-03 | 江苏中盈玻璃科技有限公司 | Teapot with glass product having temperature sensing function |
| CN112431042A (en) * | 2020-11-17 | 2021-03-02 | 山东大鲁阁织染工业有限公司 | Thermochromic fabric and production method thereof |
| CN117247731A (en) * | 2023-09-14 | 2023-12-19 | 佛山市三水顺能化工有限公司 | Temperature-sensitive color-changing aqueous color layer coating for electrochemical aluminum and preparation method thereof |
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Application publication date: 20170707 |