CN106928770A - A kind of environmental protection is used for offset ink without phenol resin oil and preparation method - Google Patents
A kind of environmental protection is used for offset ink without phenol resin oil and preparation method Download PDFInfo
- Publication number
- CN106928770A CN106928770A CN201511024713.2A CN201511024713A CN106928770A CN 106928770 A CN106928770 A CN 106928770A CN 201511024713 A CN201511024713 A CN 201511024713A CN 106928770 A CN106928770 A CN 106928770A
- Authority
- CN
- China
- Prior art keywords
- phenol resin
- oil
- environmental protection
- offset ink
- qualified
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/104—Polyesters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/06—Printing inks based on fatty oils
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Phenolic Resins Or Amino Resins (AREA)
Abstract
The present invention disclose that a kind of environmental protection is used for offset ink to belong to resinon production technical field without phenol resin oil and preparation method, and it is formulated each material composition and weight percentage is：Without phenol resin 35-50, vegetable oil 20-30, mineral oil 20-40, catalyst 0.5-1, auxiliary agent 0.15-0.2, while it is used for offset ink without phenol resin oil preparation method that a kind of environmental protection is also disclosed.The beneficial effects of the invention are as follows：Aldehydes matter and formaldehyde are not used in manufacturing process, meet the requirement that environmentally friendly offset ink is used to reach resinon properties, the proportioning of Reasonable adjustment vegetable oil, reach resinon property indices requirement, strict control holding temperature, soaking time, to ensure the gloss of this programme resinon and the set speed of post-production ink.
Description
Technical field
The invention belongs to resinon production technical field, more particularly, to the environmentally friendly nothing used for offset ink of one kind
Phenol resin oil and preparation method.
Background technology
In the prior art, resinon used for offset ink is main with rosin modified phenolic resin and vegetable oil
Reaction, adds mineral oil and forms rosin modified phenolic resin oil after reaction, introduce in the process
Aldehydes matter and formaldehyde.
Phenolic compound is a kind of prototype matter poisonous substance, has toxic action to all living individuals, can be made
Protein coagulating, so there is strong bactericidal action, during its aqueous solution easily causes whole body very by skin
Poison；Its steam is sucked by respiratory tract, bigger to nervous system damage.Suck for concentration phenol steam for a long time
Or the water that phenol is polluted can cause chronic accumulation to be poisoned；Suction high-concentration phenol steams or phenol liquid or a large amount of phenol
Liquid is splashed can cause acute poisoning on skin.Chronic carbdism is common vomiting, suffer from diarrhoea, lose the appetite,
Dizzy, anaemia and various nerveous system illnesss.
Another reactant formaldehyde is more highly toxic material, in China's toxic chemical priority acccess control name
Formaldehyde is in second on list.Formaldehyde has been defined as carcinogenic and has caused deformed material by the World Health Organization,
It is generally acknowledged allergen, is also one of potential strong mutagen.Lot of documents is recorded, formaldehyde
With strong carcinogenic and promotion canceration effect.Influence of the formaldehyde to health is mainly manifested in smell
The aspects such as exception, stimulation, allergy, abnormal pulmonary function, dysfunction of liver.
So, operator and later stage ink are manufactured conventional resins technique and ink user has necessarily
Harm, do not meet environmental protection development requirement.
The content of the invention
In order to overcome the above-mentioned deficiencies of the prior art, it is an object of the invention to disclose a kind of environmentally friendly offset printing
Ink does not use aldehydes matter and formaldehyde with without phenol resin oil and preparation method in manufacturing process, with
Reach resinon properties and meet the requirement that environmentally friendly offset ink is used.
To achieve these goals, the present invention is realized using following technical scheme：
A kind of environmental protection is used for offset ink without phenol resin oil formula, it is characterised in that：Each material composition and weight
Measuring percentage composition is：Without phenol resin 35-50, vegetable oil 20-30, mineral oil 20-40, catalyst 0.5-1,
Auxiliary agent 0.15-0.2.
The vegetable oil includes soybean oil and linseed oil.
The auxiliary agent is antioxidant BHT.
The catalyst is lithium hydroxide.
A kind of environmental protection is used for offset ink without phenol resin oil formula, and each material composition and weight percentage are：
Without phenol resin 35-50, soybean oil 12-18, linseed oil 8-12, mineral oil 20-40, catalyst hydrogen-oxygen
Change lithium 0.5-1, antioxidant BHT 0.15-0.2.
A kind of environmental protection preparation method without phenol resin oil used for offset ink, it is characterised in that including following step
Suddenly：
1. reactant preheating is melted
Vegetable oil and catalyst are added in a kettle. according to the formula described in claim 1, in heating
When temperature is 160-170 DEG C, point 3-4 addition is without phenol resin, while temperature is risen to 180-200 DEG C,
The logical inert gas in surface, is stirred in temperature-rise period.
2. transesterification reaction
Reactor is warmed up to 220-225 DEG C, 30 minutes are incubated, sampling detection color and luster, until qualified.
3. test
Sampling detection release property, the data according to detection determine detection in every 20 minutes once, until qualified.
4. adjust
After release property detection is qualified, mineral oil, stirring 30 are added according to the formula described in claim 1
Minute, viscosity is detected, until it is qualified, auxiliary agent is added after viscosity is qualified, releasing is filtered and packaged.
The step 1. in temperature-rise period in the logical inert gas of surface institute be nitrogen.
The present invention has the advantages and positive effects that：
1. aldehydes matter and formaldehyde are not used in manufacturing process, to reach resinon properties satisfaction
The requirement that environmentally friendly offset ink is used.
2. the proportioning of Reasonable adjustment vegetable oil, and content of vegetable oil is properly increased, reduce mineral oil and contain
Amount, to ensure that this programme reaches the requirement of the performance indications such as release property, viscosity, acid number, color and luster.
3. strict control holding temperature, soaking time, with ensure this programme resinon gloss and after
Phase makes the set speed of ink.
Specific embodiment
With reference to specific embodiment explanation is further explained to of the invention.
It is used for offset ink without phenol resin oil formula that the present invention discloses a kind of environmental protection, it is characterised in that：Each thing
Matter component and weight percentage are：Without phenol resin 35-50, vegetable oil 20-30, mineral oil 20-40,
Catalyst 0.5-1, auxiliary agent 0.15-0.2.
The vegetable oil includes soybean oil and linseed oil.
The auxiliary agent is antioxidant BHT.
The catalyst is lithium hydroxide.
A kind of environmental protection is used for offset ink without phenol resin oil formula, and each material composition and weight percentage are：
Without phenol resin 35-50, soybean oil 12-18, linseed oil 8-12, mineral oil 20-40, catalyst hydrogen-oxygen
Change lithium 0.5-1, antioxidant BHT 0.15-0.2.
A kind of environmental protection preparation method without phenol resin oil used for offset ink, it is characterised in that including following step
Suddenly：
1. reactant preheating is melted
Vegetable oil and catalyst are added in a kettle. according to the formula described in claim 1, in heating
When temperature is 160-170 DEG C, point 3-4 addition is without phenol resin, while temperature is risen to 180-200 DEG C,
The logical inert gas in surface, is stirred in temperature-rise period.
2. transesterification reaction
Reactor is warmed up to 220-225 DEG C, 30 minutes are incubated, sampling detection color and luster, until qualified.
3. test
Sampling detection release property, the data according to detection determine detection in every 20 minutes once, until qualified.
4. adjust
After release property detection is qualified, mineral oil, stirring 30 are added according to the formula described in claim 1
Minute, viscosity is detected, until it is qualified, auxiliary agent is added after viscosity is qualified, releasing is filtered and packaged.
The step 1. in temperature-rise period in the logical inert gas of surface institute be nitrogen.
Time, order, the length of soaking time, the height of temperature fed during resinon is refined
The low performance to resinon has a significant impact：
Holding temperature is higher, the time is more long, the gloss of resinon is better, but post-production ink is consolidated
Speed slow；Conversely, holding temperature is lower, the time is shorter, the gloss of resinon is poorer, but the later stage
The set speed for making ink is fast, by many experiments, rational process route is finally determined, sternly
220-225 DEG C of lattice refining temperature, is incubated 30 minutes, and synthesis meets production requirement.
It is determined that suitable vegetable oil proportioning is also the emphasis of the technical program, in post-production ink formulations
There is suitable vegetable oil ratio, can be only achieved post-production ink property indices and print can be met
Brush requires that properly increase vegetable oil, reduction mineral oil also complies with environmental protection concept, by vegetable oil for several times
Making experiment and performance test, finally determine vegetable oil proportioning：Soybean oil 12-18, linseed oil
8-12, to reach the main technical requirements such as gloss, set.
Production method implements process：
Embodiment 1：
A kind of environmental protection is used for offset ink without phenol resin oil formula, and each material composition and weight percentage are：
Without phenol resin 35-50, vegetable oil 20-30, mineral oil 20-40, catalyst 0.5-1, auxiliary agent 0.15-0.2.
Embodiment 2：
A kind of environmental protection is used for offset ink without phenol resin oil formula, and each material composition and weight percentage are：
Without phenol resin 35-50, soybean oil 12-18, linseed oil 8-12, mineral oil 20-40, catalyst hydrogen-oxygen
Change lithium 0.5-1, antioxidant BHT 0.15-0.2.
Embodiment 3：
A kind of environmental protection preparation method without phenol resin oil used for offset ink, according to step 1. by soybean oil 180
Kilogram, linseed oil 120 kg is added in reactor, adds 7 kilograms of lithium hydroxide, in heating temperature
Spend for 160-170 DEG C when, add without 400 kilograms of phenol resin, while temperature is risen into 180-200 points for 3 times
DEG C, the logical nitrogen in surface, is stirred in temperature-rise period；
Reactor is 2. warmed up to 220-225 DEG C according to step, 30 minutes are incubated, sampling detection until
Color and luster #≤15；
Detection release property is 3. sampled according to step, the data according to detection determine detection in every 20 minutes once,
Until release property >=2.5ml/2g；
According to step 4. release property detection it is qualified after, by 250 kilograms of addition reactors of mineral oil, stir
Mix 30 minutes, detect viscosity, until viscosity is 30000mpa.s/25 DEG C, added after viscosity is qualified anti-
1.5 kilograms of oxidant BHT, releasing is filtered and packaged.
The embodiment performance indications reach：Viscosity：30000mpa.s/25 DEG C, release property >=2.5ml/2g,
Acid number≤15mgKOH/g, color and luster #≤15 are qualified products.
Embodiment 4：
A kind of environmental protection preparation method without phenol resin oil used for offset ink, according to step 1. by soybean oil 140
Kilogram, in 100 kilograms of addition reactors of linseed oil, 8 kilograms of lithium hydroxide is added, in heating temperature
Spend for 160-170 DEG C when, add without 450 kilograms of phenol resin, while temperature is risen into 180-200 points for 4 times
DEG C, the logical nitrogen in surface, is stirred in temperature-rise period；
Reactor is 2. warmed up to 220-225 DEG C according to step, 30 minutes are incubated, sampling detection until
Color and luster #≤15；
Detection release property is 3. sampled according to step, the data according to detection determine detection in every 20 minutes once,
Until release property >=2.5ml/2g；
According to step 4. release property detection it is qualified after, by 300 kilograms of addition reactors of mineral oil, stir
Mix 30 minutes, detect viscosity, until viscosity is 35000mpa.s/25 DEG C, added after viscosity is qualified anti-
1.8 kilograms of oxidant BHT, releasing is filtered and packaged.
The embodiment performance indications reach：Viscosity：35000mpa.s/25 DEG C, release property >=2.5ml/2g,
Acid number≤15mgKOH/g, color and luster #≤15 are qualified products.
Embodiment 5：
A kind of environmental protection preparation method without phenol resin oil used for offset ink, according to step 1. by soybean oil 120
Kilogram, in 150 kilograms of addition reactors of linseed oil, 5 kilograms of lithium hydroxide is added, in heating temperature
Spend for 160-170 DEG C when, add without 500 kilograms of phenol resin, while temperature is risen into 180-200 points for 4 times
DEG C, the logical nitrogen in surface, is stirred in temperature-rise period；
Reactor is 2. warmed up to 220-225 DEG C according to step, 30 minutes are incubated, sampling detection until
Color and luster #≤15；
Detection release property is 3. sampled according to step, the data according to detection determine detection in every 20 minutes once,
Until release property >=2.5ml/2g；
According to step 4. release property detection it is qualified after, by 280 kilograms of addition reactors of mineral oil, stir
Mix 30 minutes, detect viscosity, until viscosity is 25000mpa.s/25 DEG C, added after viscosity is qualified anti-
2 kilograms of oxidant BHT, releasing is filtered and packaged.
The embodiment performance indications reach：Viscosity：25000mpa.s/25 DEG C, release property >=2.5ml/2g,
Acid number≤15mgKOH/g, color and luster #≤15 are qualified products.
5 embodiments of the invention have been described in detail above, but the content is only the present invention
Preferred embodiment, it is impossible to be considered as limiting practical range of the invention.It is all according to the present patent application
Impartial change that scope is made with improve etc., all should still belong within patent covering scope of the invention.
Claims (7)
1. a kind of environmental protection is used for offset ink without phenol resin oil formula, it is characterised in that：Each material composition and
Weight percentage is：Without phenol resin 35-50, vegetable oil 20-30, mineral oil 20-40, catalyst
0.5-1, auxiliary agent 0.15-0.2.
2. environmental protection according to claim 1 is used for offset ink without phenol resin oil formula, and its feature exists
In：The vegetable oil includes soybean oil and linseed oil.
3. environmental protection according to claim 2 is used for offset ink without phenol resin oil formula, and its feature exists
In：The auxiliary agent is antioxidant BHT.
4. environmental protection according to claim 3 is used for offset ink without phenol resin oil formula, and its feature exists
In：The catalyst is lithium hydroxide.
5. environmental protection according to claim 4 is used for offset ink without phenol resin oil formula, and its feature exists
In：Each material composition and weight percentage are：Without phenol resin 35-50, soybean oil 12-18, flax
Oily 8-12, mineral oil 20-40, catalyst lithium hydroxide 0.5-1, antioxidant BHT 0.15-0.2.
6. a kind of environmental protection it is used for offset ink without phenol resin oil preparation method, it is characterised in that including as follows
Step：
1. reactant preheating is melted
Vegetable oil and catalyst are added in a kettle. according to the formula described in claim 1, in heating
When temperature is 160-170 DEG C, point 3-4 addition is without phenol resin, while temperature is risen to 180-200 DEG C,
The logical inert gas in surface, is stirred in temperature-rise period.
2. transesterification reaction
Reactor is warmed up to 220-225 DEG C, 30 minutes are incubated, sampling detection color and luster, until qualified.
3. test
Sampling detection release property, the data according to detection determine detection in every 20 minutes once, until qualified.
4. adjust
After release property detection is qualified, mineral oil, stirring 30 are added according to the formula described in claim 1
Minute, viscosity is detected, until it is qualified, auxiliary agent is added after viscosity is qualified, releasing is filtered and packaged.
7. environmental protection according to claim 6 it is used for offset ink without phenol resin oil preparation method, its
It is characterised by：Step 1. in temperature-rise period in the logical inert gas of surface institute be nitrogen.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511024713.2A CN106928770A (en) | 2015-12-29 | 2015-12-29 | A kind of environmental protection is used for offset ink without phenol resin oil and preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511024713.2A CN106928770A (en) | 2015-12-29 | 2015-12-29 | A kind of environmental protection is used for offset ink without phenol resin oil and preparation method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106928770A true CN106928770A (en) | 2017-07-07 |
Family
ID=59441773
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201511024713.2A Pending CN106928770A (en) | 2015-12-29 | 2015-12-29 | A kind of environmental protection is used for offset ink without phenol resin oil and preparation method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106928770A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102226059A (en) * | 2011-05-10 | 2011-10-26 | 天津市天宁树脂有限公司 | Phenol-free resin for offset printing ink and preparation method thereof |
| CN103865328A (en) * | 2012-12-07 | 2014-06-18 | 天津安光油墨厂 | Formula, preparation technology and application of gummy oil |
-
2015
- 2015-12-29 CN CN201511024713.2A patent/CN106928770A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102226059A (en) * | 2011-05-10 | 2011-10-26 | 天津市天宁树脂有限公司 | Phenol-free resin for offset printing ink and preparation method thereof |
| CN103865328A (en) * | 2012-12-07 | 2014-06-18 | 天津安光油墨厂 | Formula, preparation technology and application of gummy oil |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106893530A (en) | Senior water-proof adhesive | |
| CN102226059B (en) | Phenol-free resin for offset printing ink and preparation method thereof | |
| CN103992466B (en) | A kind of planographic ink rosen polyester resin and synthetic method thereof | |
| CN104194715A (en) | Formula and preparation process of instant organic silicon adhesive | |
| CN103361176B (en) | Aroma compound | |
| CN108558608A (en) | A kind of method of the nickel-base material Catalytic lignin selectivity hydrogenolysis of basic zirconium phosphate load | |
| CN102863477B (en) | Method for extracting plant polyphenol from walnut shells by using ionic liquid | |
| CN101935434A (en) | Preparation method of phenolic resins | |
| CN105968945A (en) | Connecting material composition for ink printing and preparation method thereof | |
| CN106928770A (en) | A kind of environmental protection is used for offset ink without phenol resin oil and preparation method | |
| CN102676116A (en) | Environment-friendly livestock depilatory paste and preparing method thereof | |
| CN105038895B (en) | A kind of safety and environmental protection fuel and preparation method thereof | |
| CN105085981B (en) | A kind of rubber adhesion promotor and its preparation method and application | |
| CN107022435A (en) | A kind of health wine and preparation method thereof | |
| CN104877437A (en) | Antimicrobial environment-friendly offset printing ink and preparation method thereof | |
| CN106928769A (en) | A kind of environmentally friendly offset gloss ink low VOC binders and preparation method | |
| CN101544857A (en) | Offset printing ink solvent and preparation method thereof | |
| CN106188617B (en) | A kind of cashew nut phenolic group ether type plasticizer and its synthetic method and application | |
| CN104356328B (en) | Preparation method of soybean oil rosin combined chemical modified phenolic resin and modified phenolic resin | |
| CN103483163B (en) | A kind of novel process being directly isomerizated into isoeugenol by clove leaf oil | |
| CN105461872A (en) | Light-colored cardanol resin and preparation method thereof | |
| CN105732963A (en) | Phenol-free resin for offset printing ink | |
| CN102766373A (en) | Environment-friendly anti-dryer and preparation method thereof | |
| CN102911604A (en) | Preparation method of rosin resin capable of being dissolved by low-concentration ammonia water | |
| CN107629546A (en) | A kind of VOC free offset printing environment-friendly ink binder and preparation method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170707 |