CN106924076B - 一种变色指甲油 - Google Patents
一种变色指甲油 Download PDFInfo
- Publication number
- CN106924076B CN106924076B CN201710179691.XA CN201710179691A CN106924076B CN 106924076 B CN106924076 B CN 106924076B CN 201710179691 A CN201710179691 A CN 201710179691A CN 106924076 B CN106924076 B CN 106924076B
- Authority
- CN
- China
- Prior art keywords
- parts
- color
- pigment
- nail polish
- mass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/11—Encapsulated compositions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/87—Polyurethanes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/88—Polyamides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q3/00—Manicure or pedicure preparations
- A61Q3/02—Nail coatings
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
- A61K2800/432—Direct dyes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
- A61K2800/438—Thermochromatic; Photochromic; Phototropic
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Cosmetics (AREA)
Abstract
本发明公开了一种变色指甲油,按质量份数计,该一种变色指甲油包括以下成分:硝化纤维8~20份;成膜剂10~25份;挥发性溶剂60~85份;可逆温变色料0.5~5份;可逆光变色料0.5~5份,具有变色、产生不同装饰样态的效果。
Description
技术领域
本发明涉及指甲美容领域,特别涉及一种变色指甲油。
背景技术
指甲油属于彩妆系列的产品,具有美化修饰指甲的作用,受到爱美人士的喜爱。申请公布号为CN102552059A、申请公布日为2012年7月11日的中国专利公开了一种低刺激指甲油,其包括溶剂、成膜剂、增稠悬浮剂、增塑剂。为使指甲油组成后可呈各种不同的颜色,可于其中添加入适量的颜料,使用者可以根据自身需求选择合适颜色的指甲油。
当指甲油被涂抹至指甲或趾甲上且干燥后,指甲油便牢固的与指甲或趾甲表面贴附,此时如果需要更换颜色则需要先以化学药剂将原先涂抹在指甲或趾甲上的指甲油擦拭干净,才可涂抹另一种颜色的指甲油来产生不同的装饰效果。在指甲油的实际使用过程中,同一指甲油对应单一的颜色会令使用者失去新鲜感,为产生不同的装饰样态使用者会购置多种不同样态的指甲油。而这种用不同色系的指甲油来产生不同装饰样态的方式,需要经常擦拭已涂抹的指甲油,对指甲或趾甲造成一定的损害。
发明内容
本发明的目的是提供一种变色指甲油,具有变色、产生不同装饰样态的效果。
本发明的上述技术目的是通过以下技术方案得以实现的:
一种变色指甲油,按质量份数计,包括以下成分:
硝化纤维8~20份;
成膜剂10~25份;
挥发性溶剂60~85份;
可逆温变色料0.5~5份;
可逆光变色料0.5~5份。
进一步优选为:所述可逆温变色料选用电子转移型有机化合物、重金属复盐络合物或液晶型可逆感温变色物中的一种或多种。
进一步优选为:所述可逆光变色料选用无机类光致变色材料、有机类光致变色材料中的一种或多种,所述无机类光致变色材料选用过渡金属氧化物或多金属氧酸盐中的一种或多种,所述有机类光致变色材料选用螺吡喃类、螺噁嗪类、偶氮苯类、二芳基乙烯类中的一种或多种。
进一步优选为:所述可逆温变色料和可逆光变色料外包裹有一层透明囊衣。
进一步优选为:所述透明囊衣包括固化剂和环氧树脂,所述固化剂选用聚酰胺或改性芳香胺中的一种或多种;按质量计,所述固化剂和环氧树脂的用量为1:0.5~3。
进一步优选为:所述透明囊衣的厚度为1~3μm。
进一步优选为:所述可逆温变色料和可逆光变色料外与透明囊衣之间通过高分子粘合剂粘合,所述高分子粘合剂选用混合树脂粘合剂或环氧树脂粘合剂中的一种或多种。
进一步优选为:按质量份数计,所述一种变色指甲油还包括0.5~2份的PAA。
进一步优选为:所述一种变色指甲油由如下方法制备得到:
(1)取PAA、可逆温变色料和可逆光变色料混合,加入水超声分散均匀,喷雾干燥得到干燥的颗粒;
(2)于干燥的颗粒上依次喷涂上高分子粘合剂和透明囊衣,得到色料微囊;
(3)于挥发性溶剂中加入色料微囊,分散均匀后依次加入硝化纤维、成膜剂和挥发性溶剂,分散均匀即得。
综上所述,本发明具有以下有益效果:
1、在低温弱光、低温强光、高温弱光和高温强光放置短时间内均出现明显的变色情况,且不同条件下的变色情况不同,具有变色、产生不同装饰样态的效果;
2、色料的损失率小,减少褪色的可能性,保持鲜艳的色彩。
具体实施方式
本具体实施例仅仅是对本发明的解释,其并不是对本发明的限制,本领域技术人员在阅读完本说明书后可以根据需要对本实施例做出没有创造性贡献的修改,但只要在本发明的保护范围内都受到专利法的保护。
实施例1:一种变色指甲油,其由如下方法制备得到:
(1)取PAA、可逆温变色料和可逆光变色料混合,加入水超声分散均匀,喷雾干燥得到干燥的颗粒;
(2)于干燥的颗粒上依次喷涂上高分子粘合剂和透明囊衣,得到色料微囊;
(3)于挥发性溶剂中加入色料微囊,分散均匀后依次加入硝化纤维、成膜剂和挥发性溶剂,分散均匀即得;
实施例1的配方如表1所示。
表1实施例1的配方
实施例2:一种变色指甲油,与实施例1的不同之处在于,实施例2的配方如表2所示。
表2实施例2的配方
实施例3:一种变色指甲油,与实施例1的不同之处在于,实施例3的配方如表3所示。
表3实施例3的配方
实施例4:一种变色指甲油,与实施例1的不同之处在于,可逆温变色料选用基本颜色为金红的感温变色颜料(电子转移型有机化合物),可逆光变色料选用螺噁嗪。
实施例5:一种变色指甲油,与实施例1的不同之处在于,可逆温变色料选用基本颜色为金黄的感温变色颜料(电子转移型有机化合物),可逆光变色料选用偶氮苯类。
实施例6:一种变色指甲油,与实施例1的不同之处在于,可逆温变色料选用基本颜色为橙红的感温变色颜料(电子转移型有机化合物),可逆光变色料选用二芳基乙烯类。
实施例7:一种变色指甲油,与实施例1的不同之处在于,未添加高分子粘合剂。
实施例8:一种变色指甲油,与实施例1的不同之处在于,未添加PAA。
实施例9:一种变色指甲油,其由如下方法制备得到:
取3质量份的基本颜色为桃红的感温变色颜料和3质量份的可逆光变色料(WO3:MoO3的质量比为1:1)混合,分散均匀后依次加入15质量份的硝化纤维、15质量份的聚甲基丙烯酸和75质量份的挥发性溶剂(乙酸乙酯、异丙醇、甲苯的体积比为3:2:0.5),分散均匀即得。
使用评价
(1)试验样品:实施例1-9的一种变色指甲油。
(2)试验内容:将试验样品均匀涂抹于指甲上,分别于低温弱光、低温强光、高温弱光和高温强光下放置5s,观察其变色情况。在这里,低温指的是3~20℃(本次实验的低温温度为5℃),高温指的是25~35℃(本次实验的高温温度为35℃),弱光指的是未开灯但能看清指甲颜色的室内,强光指的是强光下(本次实验在强太阳照射下进行)。
(3)试验结果:实施例1-9在低温弱光、低温强光、高温弱光和高温强光放置5s内均出现明显的变色情况,且在这四个条件下至少有3个不同的颜色,其中指甲上的指尖和指根部的颜色也稍有区别,其呈逐渐变化的状态。
稳定性测试
(1)试验样品:实施例1-9的一种变色指甲油。
(2)试验内容:于多个标记的玻璃瓶内分别加入2g测试样品,将玻璃瓶密封处理,分别放置在0℃/0%RH、25℃/40%RH和40℃/75%RH放置30d、90d和360d;放置后借助HPLC检测其色料含量的变化量(与放置0d相比,测试前均进行烘干除溶剂处理);每个测试样品在每个放置条件下平行试验3次,试验结果取平均值。
(3)试验结果:检测结果如表4-6所示。实施例1-6具有较好的稳定性,减少色料损失的可能性。
表4稳定性测试结果(0℃/0%RH)
表5稳定性测试结果(25℃/40%RH)
表6稳定性测试结果(40℃/75%RH)
Claims (1)
1.一种变色指甲油,其特征在于,按质量份数计,包括以下成分:
硝化纤维8~20份;
成膜剂10~25份;
挥发性溶剂60~85份;
可逆温变色料0.5~5份;
可逆光变色料0.5~5份,其中:
所述硝化 纤维的质量份数为15份,
所述成膜剂为聚甲基丙烯酸,质量份数为15份,
所述挥发性溶剂为体积比为3:2:0.5的乙酸乙酯、异丙醇和甲苯,质量份数为75份;
所述可逆温变色料为电子转移型有机化合物的桃红温感变色颜料,质量份数为3份;
所述可逆光变色料为质量比为1:1的WO3:MoO3 ,质量份数为3份;
所述变色指甲油还包含透明囊衣,所述透明囊衣为质量比为1:1.5的聚酰胺和环氧树脂,质量份数为4份;
所述变色指甲油还包含高分子粘合剂,所述高分子粘合剂为混合树脂粘合剂,质量份数为0.4份;
所述变色指甲油还包含PAA,质量份数为1份,
其中所述一种变色指甲油由如下方法制备得到:
(1)取PAA、可逆温变色料和可逆光变色料混合,加入水超声分散均匀,喷雾干燥得到干燥的颗粒;
(2)于干燥的颗粒上依次喷涂上高分子粘合剂和透明囊衣,得到色料微囊;
(3)于挥发性溶剂中加入色料微囊,分散均匀后依次加入硝化纤维、成膜剂和挥发性溶剂,分散均匀即得。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710179691.XA CN106924076B (zh) | 2017-03-23 | 2017-03-23 | 一种变色指甲油 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710179691.XA CN106924076B (zh) | 2017-03-23 | 2017-03-23 | 一种变色指甲油 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN106924076A CN106924076A (zh) | 2017-07-07 |
CN106924076B true CN106924076B (zh) | 2020-08-28 |
Family
ID=59426399
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201710179691.XA Active CN106924076B (zh) | 2017-03-23 | 2017-03-23 | 一种变色指甲油 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN106924076B (zh) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108714113B (zh) * | 2018-06-02 | 2021-08-17 | 浙江莱凡化妆品有限公司 | 一种印花甲油及其制备工艺和使用方法 |
CN110151573A (zh) * | 2019-07-10 | 2019-08-23 | 中山市美源化妆品有限公司 | 一种变色指甲油及其制造方法 |
CN110693755A (zh) * | 2019-11-25 | 2020-01-17 | 金华市科维思日化有限公司 | 一种新型安全环保的光变指甲油 |
CN112263531B (zh) * | 2020-11-11 | 2022-01-18 | 浙江利美化妆品有限公司 | 一种温感变色的粘贴式腮红及其制备方法 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20010086939A (ko) * | 2000-03-04 | 2001-09-15 | 장익수 | 열변색성 잉크제, 지조 (指爪) 래커 및 사용방법 |
US20090069467A1 (en) * | 2005-04-21 | 2009-03-12 | Gloria Ruiz Gomez | Pigment formulations |
CN103099741A (zh) * | 2011-11-14 | 2013-05-15 | 天津孚信科技有限公司 | 一种光致变色指甲油 |
-
2017
- 2017-03-23 CN CN201710179691.XA patent/CN106924076B/zh active Active
Also Published As
Publication number | Publication date |
---|---|
CN106924076A (zh) | 2017-07-07 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN106924076B (zh) | 一种变色指甲油 | |
CA1075842A (en) | Process for priming and compositions therefor | |
CN110997070A (zh) | 变色组合物 | |
WO2010041891A3 (ko) | 식물의 꽃잎 염색용 조성물 및 그 염색방법과 이에 의해 염색된 꽃잎을 구비한 식물 | |
JP5116046B2 (ja) | 温度/光量によって変色する花を製造する方法 | |
CN103396725A (zh) | 仿真铜涂料及其生产工艺 | |
CN110628268A (zh) | 一种温变油墨及其制备方法 | |
WO2015184172A1 (en) | System and method for application of chromic compositions | |
NO319249B1 (no) | Fremgangsmate for paforing av et tosjiktsbelegg | |
US20150328138A1 (en) | Hair clue | |
DE602005023902D1 (de) | System und verfahren zum färben von lacken und dekorativen beschichtungen und entsprechende betätigungsvorrichtung | |
KR20120123853A (ko) | 온도 감응형 매니큐어 조성물 및 그 제조방법 | |
WO1993018098A1 (en) | Thermochromic nail composition | |
CN107100014A (zh) | 一种彩色皮膜布及其制备方法 | |
CN103254747B (zh) | 高着色性醇酸漆料及其应用 | |
WO2000000551A1 (en) | Painting medium for artists | |
KR20100028369A (ko) | 온도/광량에 따라 색깔이 변하고 메세지가 나타나는 꽃을 제조하는 방법 | |
JP2013226374A (ja) | アクセサリー玩具セット | |
Tarhan | An Artist's Guide to Reversibly Color Changing Paints and Pigments | |
RU2086720C1 (ru) | Композиция и способ поверхностного крашения полиолефинов | |
CN116650352A (zh) | 一种可水洗褪色的环保型指甲油及其制备方法 | |
RU2029774C1 (ru) | Состав для крашения натуральной кожи | |
RU96102285A (ru) | Способ получения покрытия | |
JPH0536720Y2 (zh) | ||
JP3224982B2 (ja) | 草木染め用塗布液および草木染めによる木材への着色・塗装方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |