CN106898845A - A kind of metal-air batteries system and its quick start method - Google Patents

A kind of metal-air batteries system and its quick start method Download PDF

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Publication number
CN106898845A
CN106898845A CN201510960581.8A CN201510960581A CN106898845A CN 106898845 A CN106898845 A CN 106898845A CN 201510960581 A CN201510960581 A CN 201510960581A CN 106898845 A CN106898845 A CN 106898845A
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metal
storage unit
liquid storage
air batteries
electrolyte
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CN201510960581.8A
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CN106898845B (en
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孙公权
刘敏
王二东
高建新
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Dalian Institute of Chemical Physics of CAS
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Dalian Institute of Chemical Physics of CAS
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M12/00Hybrid cells; Manufacture thereof
    • H01M12/04Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type
    • H01M12/06Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04223Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04223Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells
    • H01M8/04268Heating of fuel cells during the start-up of the fuel cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04276Arrangements for managing the electrolyte stream, e.g. heat exchange
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Hybrid Cells (AREA)

Abstract

A kind of metal-air batteries system, including metal-air batteries group, liquid pump, heat exchanger and liquid storage unit;The inlet of the liquid pump is connected with liquid storage unit, and the liquid outlet of the liquid pump is connected with heat exchanger inlet, and heat exchanger leakage fluid dram is connected with the injecting electrolytic solution mouthful of metal-air batteries group;The electrolyte liquid outlet of the metal-air batteries group is connected with liquid storage unit, forms closed-loop path;The liquid storage unit inside has partition member;When the partition member is closed, two independent seal cavities are divided into inside liquid storage unit.Compared with prior art, metal-air batteries of the present invention have start battery simple, it is multi-functional that liquid storage unit integrates raw material storage, electrolyte quota, electrolyte storage etc., liquid storage unit is especially suitable under low temperature environment, rapid preparing electrolyte, prevent from dissolving heat leakage, help to be heated up to battery system, promote start battery.

Description

A kind of metal-air batteries system and its quick start method
Technical field
The present invention relates to metal-air batteries system, specifically a kind of aluminium, zinc equipped with liquid storage unit Deng metal-air batteries system;The invention further relates to the quick start method of the metal-air batteries.
Background technology
Metal-air batteries be it is a kind of use metal (such as aluminium, zinc) be anode fuel, oxygen work in air Be oxidant, alkali lye as electrolyte solution electrochemical reaction appts.The metal reserves such as China's aluminium, zinc are rich It is rich and cheap, therefore metal-air batteries are in China's communication power supply, field emergency power supply, power for illumination The numerous areas of the movable power source such as source and redundant electrical power have broad application prospects.To improve the business of battery Industry practical level, battery needs Operation and Maintenance convenient, possesses good environmental suitability, wherein, battery Low tempertaure storage, startup and runnability are restriction metal/air and other fuel cells and lithium ion batteries Common problem, with the decline of environment temperature, battery system difficulty in starting, capacity reduction uses difficult.
And when starting metal-air batteries, electrolyte need to be prepared, and because solid KOH has severe corrosive, and it is electric Solution liquid process for preparation needs stirring again, while can be with penetrating odor, if need to be using dissolving during low temperature environment Heat starts battery, then need that electrolyte is filled into battery pack rapidly, it is to avoid the loss of heat, this mistake Journey is cumbersome and has potential safety hazard.Thus, simplify battery application method, especially at low ambient temperatures, safely may be used That leans on carries out electrolyte quota, stores most important.
The content of the invention
The present invention regarding to the issue above, invents a kind of metal-air batteries, realize water or low concentration electrolyte with Solid KOH or supersaturated solution coexist storage, realize rapid preparing electrolyte, realize that battery is simple and quick and open It is dynamic.
A kind of metal-air batteries system, including metal-air batteries group, liquid pump, heat exchanger and liquid storage list Unit;The inlet of the liquid pump is connected with liquid storage unit, liquid outlet and the heat exchanger inlet phase of the liquid pump Even, heat exchanger leakage fluid dram is connected with the injecting electrolytic solution mouthful of metal-air batteries group;The metal/air electricity The electrolyte liquid outlet of pond group is connected with liquid storage unit, forms closed-loop path;The liquid storage unit inside has Partition member;When the partition member is closed, two independent annular seal spaces are divided into inside liquid storage unit Body a, seal cavity is used to store solid electrolyte or supersaturated electrolyte solution, another seal cavity For the undersaturated electrolyte solution of storage or water;When the partition member is opened, the liquid storage list Two individual cavities connection inside unit, for realizing the required electrolyte solution of metal-air batteries reaction It is automatic to prepare.
The liquid storage unit is barrel-like structure or cystic structures.
When the liquid storage unit be barrel-like structure when, the partition member can be platy structure, platy structure with Bucket wall inner surface is abutted by sealing gasket, and also including a pressing plate being connected with platy structure, pressing plate cuts with scissors with bucket wall Connect, spring is provided between pressing plate and bucket wall, a barrel pars intramuralis is fixed on by spring and pressing plate, while passing through bullet The action of partition member is realized in the gearing of spring and pressing plate, is coordinated with sealing gasket, so as to realize two in liquid storage unit The connection of individual individual cavity and cut-off.
When the liquid storage unit is tubbiness or cystic structures, the dividing plate can be cylindrical telescopic device, Liquid storage unit bucket wall is anchored on by band serrated helicoid device, band sealing gasket dividing plate is compressed in liquid storage unit and is connected Bottom is connect, liquid storage unit is separated into two individual cavities.
Injecting electrolytic solution mouthful and the liquid outlet of described metal-air batteries group can merge into a connector, Now battery pack is the system not circulated, and cell reaction is carried out by spout reservoir, then again by note Liquid mouthful carries out discharge opeing.
The partition member is valve, by the either on or off of the valve, realizes in liquid storage unit two solely The connection of vertical cavity and cut-off.
The liquid storage unit is the simultaneously alkaline-resisting plastics or alloy or rubber of high-low temperature resistant.
The plastics be ABS plastic, polyvinylchloride, polythene PE, polystyrene PS, nylon PA, Polyformaldehyde POM, polysulfones PSF, polyphenylene thioether PPS, in one kind;The alloy is stainless steel, titanium alloy In one kind;The rubber is the one kind in natural rubber, EPDM, silicon rubber, fluorubber.
The liquid storage unit is connected by spring with the housing of battery system, and in being provided with fixing lock on spring.
The quick start method of the metal-air batteries system, respectively at metal-air batteries liquid storage unit Two individual cavity internal memories contain the electrolyte solution of solid electrolyte, water or dilution;Will before activation system It is described the partition member is made solid electrolyte fast solutions in open mode, what its dissolving reaction was released Heat be used for for the metal-air batteries group heating, after solution formed electrolyte solution be the metal/ Electrolyte needed for air cell reaction.
The quick start method of the metal-air batteries system, respectively at metal-air batteries liquid storage unit Two individual cavity internal memories contain the electrolyte solution of solid electrolyte, water or dilution;Will before activation system It is described the partition member is in open mode, while releasing the fixing lock, it is in liquid storage part and shakes Dynamic state accelerates the dissolving of solid electrolyte, and its dissolving reaction liberated heat is used to be metal/air electricity Pond group heating, electrolyte of the electrolyte solution formed after solution for needed for metal-air batteries reaction.
Compared with prior art, metal-air batteries of the present invention have advantages below:
(1) start battery is simple, partition member is in open mode, you can to realize that electrolyte is fast Speed is prepared, and is easy to battery operated expansion;
(2) liquid storage unit integrates multi-functional, the letters such as raw material storage, electrolyte quota, electrolyte storage Change system accessories to prepare;
(3) liquid storage unit is especially suitable under low temperature environment, rapid preparing electrolyte, prevents from dissolving heat leakage, Help to be heated up to battery system, promote start battery.
Brief description of the drawings
Fig. 1 is metal-air batteries structural representation;
Fig. 2 is metal-air batteries liquid storage unit plank frame sectional view;
Fig. 3 is metal-air batteries liquid storage unit spiral expanding structure sectional view;
In figure, 1- battery packs, 2- liquid pumps, 3- heat exchangers, 4- liquid storage units, 6- dividing plates, 7- exhaust outlets, 8- bulkhead seal pads, 9- bulkhead seal grooves, 10- partition regulators, 11- liquid injections mouthful, 12- is circular flexible Post, 13- steam vents, 14- barrels of wall intercommunicating pore, 15- band sealing gasket dividing plates, 16- fluid injections/material mouth.
Fig. 4 is contrasted for the start battery time;
Fig. 5 is start battery temperature rise and discharge curve.
Specific embodiment
Metal-air battery described in Fig. 1 is by battery pack (1), liquid pump (2), heat exchanger (3), liquid storage unit (4), during system operation, the electrolyte in liquid storage unit (4) is injected heat exchanger (3) by liquid pump (2), Battery pack (1) is then injected into be electrochemically reacted.Heat exchanger (3) loop can be cut off during low-temperature working, Maintain system temperature balance.
Liquid storage unit described in Fig. 2 is separated into two individual cavities by dividing plate (6), when preparing electrolyte, start every Plate adjusting means (10), opens fixing lock, and dividing plate (6) is risen, while dividing plate middle part sealing gasket (8) Contacted with liquid storage unit (4) upper wall surface, the power and liquid storage unit (4) applied by partition regulator (10) Upper port is fitted close, and realizes top seal, the cavity connection of liquid storage unit (4) bottom two, water or low dense Degree solution flows to solid KOH or supersaturated electrolyte solution storage cavity due to liquid level difference, realizes that electrolyte is fast Speed is prepared.
When liquid storage unit described in Fig. 3 carries out electrolyte quota, sprue of outwarding winding (11) screw so that Circular telescopic mast (12) is active, and band sealing gasket dividing plate (15) is left a barrel wall intercommunicating pore (14), The individual cavity of liquid storage unit two is connected, while circular telescopic mast (12) can be constantly moved up and down, constantly disturbance Liquid storage unit (4) electrolyte inside, is well mixed electrolyte.
Embodiment 1
Battery system is aluminium alloy plate () using 24 cells in series compositions, wherein cell anode, Size is 180mm × 160mm × 2.5mm, cell cathode size is 200mm × 170mm × 2mm, Dan Chi Die opening is the KOH weak solutions for storing 2.2kgKOH solids and 6.3L in 2mm, the cavity of liquid storage unit two respectively (1.7kgKOH+105gNa2SnO3), the start battery time is partition regulator opening time, and electrolyte Dissolution time, is 1min,
As a comparison, using traditional electrolyte liquid making method, operating personnel wear rubber gloves, goggles, Mouth mask, during supersaturated KOH solution then entered into beaker, injects water, is stirred with stirring rod, treats KOH After dissolving, electrolyte solution is injected in battery pack by liquid injection port, the fluid injection time is 3.5min, Ran Houqi Dynamic system, total time contrast is as shown in Figure 4.
Embodiment 2
Two chambers store the KOH weak solutions of 2.2kgKOH solids and 6.3L respectively in battery liquid storage unit (1.7kgKOH+105gNa2SnO3), battery system is placed in -25 DEG C of environment and stands 2h, treats that system is cooled down completely Afterwards, outward winding sprue screw so that circular telescopic mast is active, make band sealing gasket dividing plate from The water opened in barrel wall intercommunicating pore liquid storage unit flows to solid KOH storage cavity, while can constantly move up and down Circular telescopic mast, constantly disturbance liquid storage unit electrolyte inside, is well mixed electrolyte, then will by liquid pump Electrolyte injects battery pack, and its system temperature rise and 1.5kW invariable power discharge curves are as shown in Figure 5.It is wherein real Line represents voltage, and dotted line represents temperature
As a comparison, same battery pack is placed in system, then using shown in comparative example 1, traditional electrolyte Liquid making method carries out electrolyte quota, is then injected into system, and start battery temperature rise and discharge curve are such as Shown in Fig. 5.

Claims (10)

1. a kind of metal-air batteries system, it is levied and is:Including metal-air batteries group, liquid pump, change Hot device and liquid storage unit;The inlet of the liquid pump is connected with liquid storage unit, the liquid outlet of the liquid pump with change Hot device inlet is connected, and heat exchanger leakage fluid dram is connected with the injecting electrolytic solution mouthful of metal-air batteries group;It is described The electrolyte liquid outlet of metal-air batteries group is connected with liquid storage unit, forms closed-loop path;The liquid storage list It is first internal with partition member;When the partition member is closed, two are divided into inside liquid storage unit solely Vertical seal cavity a, seal cavity is used to store solid electrolyte or supersaturated electrolyte solution, another Individual seal cavity is used for the undersaturated electrolyte solution of storage or water;When the partition member is opened, Two individual cavities connection inside the liquid storage unit, the electricity needed for for realizing metal-air batteries reaction Solve the automatic preparation of liquor.
2. metal-air batteries system as claimed in claim 1, it is characterised in that:The liquid storage unit is bucket Shape structure or cystic structures.
3. metal-air batteries system as claimed in claim 2, it is characterised in that:When the liquid storage unit is During barrel-like structure, the partition member can be platy structure, and platy structure passes through sealing gasket with bucket wall inner surface Abut, also including a pressing plate being connected with platy structure, pressing plate is hinged with bucket wall, is set between pressing plate and bucket wall There is spring, a barrel pars intramuralis is fixed on by spring and pressing plate, while realizing dividing by the gearing of spring and pressing plate Every the action of part, coordinate with sealing gasket, so as to realize in liquid storage unit two connections of individual cavity with every It is disconnected.
4. metal-air batteries system as claimed in claim 2, it is characterised in that:When the liquid storage unit is When tubbiness or cystic structures, the dividing plate can be cylindrical telescopic device, tight by band serrated helicoid device Liquid storage unit bucket wall is fixed in, band sealing gasket dividing plate is compressed in liquid storage unit connection bottom, by liquid storage unit point It is divided into two individual cavities;The injecting electrolytic solution mouthful of described metal-air batteries group is with liquid outlet and with flatly.
5. the metal-air batteries system as described in claim 1,3 or 4, it is characterised in that:The separation Part is valve, by the either on or off of the valve, realizes two connections of individual cavity in liquid storage unit With cut-off.
6. metal-air batteries system as claimed in claim 1, it is characterised in that:The liquid storage unit is resistance to High/low temperature simultaneously alkaline-resisting plastics or alloy or rubber.
7. metal-air batteries system as claimed in claim 6, it is characterised in that:The plastics are moulded for ABS Material, polyvinylchloride, polythene PE, polystyrene PS, nylon PA, polyformaldehyde POM, polysulfones PSF, One kind in polyphenylene thioether PPS;The alloy is the one kind in stainless steel, titanium alloy;The rubber is day One kind in right rubber, EPDM, silicon rubber, fluorubber.
8. metal-air batteries system as claimed in claim 1, it is characterised in that:The liquid storage unit passes through Spring is connected with the housing of battery system, and in being provided with fixing lock on spring.
9. the quick start method of metal-air batteries system as claimed in claim 1, it is characterised in that:Point Two individual cavity internal memories not in metal-air batteries liquid storage unit contain solid electrolyte or supersaturation electricity Electrolyte solution, the electrolyte solution or water of dilution;Before activation system by it is described make the partition member be in beat Open state makes solid electrolyte fast solutions, and its dissolving reaction liberated heat is used to be metal/air electricity Pond group heating, electrolyte of the electrolyte solution formed after solution for needed for metal-air batteries reaction.
10. the quick start method of metal-air batteries system as claimed in claim 9, it is characterised in that: Solid electrolyte or supersaturation are contained respectively at two individual cavity internal memories of metal-air batteries liquid storage unit Electrolyte solution, the electrolyte solution or water of dilution;The partition member is set to be in open shape before activation system State, while releasing the fixing lock, makes circular telescopic mast be in the dissolving that vibrating state accelerates solid electrolyte, Its dissolving reaction liberated heat is heated when being used for as the metal-air batteries group cold-starting, shape after solution Into electrolyte solution for the metal-air batteries reaction needed for electrolyte.
CN201510960581.8A 2015-12-18 2015-12-18 A kind of metal-air batteries system and its quick start method Active CN106898845B (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109921152A (en) * 2017-12-13 2019-06-21 中国科学院大连化学物理研究所 A kind of metal-air batteries system automatically configuring electrolyte
CN109921153A (en) * 2017-12-13 2019-06-21 中国科学院大连化学物理研究所 A kind of metal-air batteries system
CN110048195A (en) * 2019-04-23 2019-07-23 东莞市中航华讯卫星技术有限公司 From the metal-air battery system of liquid preparation type
CN110071307A (en) * 2019-04-29 2019-07-30 北京理工大学 A kind of metal-air battery system and vehicle
CN112310444A (en) * 2020-09-24 2021-02-02 合肥综合性国家科学中心能源研究院(安徽省能源实验室) Multifunctional metal fuel cell system
CN112670538A (en) * 2020-12-24 2021-04-16 郑州佛光发电设备有限公司 Multifunctional portable metal air power supply
CN117293341A (en) * 2023-11-24 2023-12-26 成都岷山绿氢能源有限公司 Fuel cell system for equalizing inlet temperature of fuel cell stack

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CN103296338A (en) * 2013-06-20 2013-09-11 北京西区码头商贸有限公司 Aluminum air fuel cell system
CN104362352A (en) * 2014-11-18 2015-02-18 曹梅君 Aluminum alloy air battery cathode structure
WO2015159286A1 (en) * 2014-04-13 2015-10-22 Phinergy Ltd. Safety method and system for liquid electrolyte battery

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CN103296338A (en) * 2013-06-20 2013-09-11 北京西区码头商贸有限公司 Aluminum air fuel cell system
WO2015159286A1 (en) * 2014-04-13 2015-10-22 Phinergy Ltd. Safety method and system for liquid electrolyte battery
CN104362352A (en) * 2014-11-18 2015-02-18 曹梅君 Aluminum alloy air battery cathode structure

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109921152B (en) * 2017-12-13 2021-05-14 中国科学院大连化学物理研究所 Metal/air battery system capable of automatically configuring electrolyte
CN109921153A (en) * 2017-12-13 2019-06-21 中国科学院大连化学物理研究所 A kind of metal-air batteries system
CN109921153B (en) * 2017-12-13 2020-06-30 中国科学院大连化学物理研究所 Metal/air battery system
CN109921152A (en) * 2017-12-13 2019-06-21 中国科学院大连化学物理研究所 A kind of metal-air batteries system automatically configuring electrolyte
CN110048195A (en) * 2019-04-23 2019-07-23 东莞市中航华讯卫星技术有限公司 From the metal-air battery system of liquid preparation type
CN110071307A (en) * 2019-04-29 2019-07-30 北京理工大学 A kind of metal-air battery system and vehicle
CN110071307B (en) * 2019-04-29 2021-01-01 北京理工大学 Metal-air battery system and vehicle
CN112310444A (en) * 2020-09-24 2021-02-02 合肥综合性国家科学中心能源研究院(安徽省能源实验室) Multifunctional metal fuel cell system
CN112310444B (en) * 2020-09-24 2022-02-11 合肥综合性国家科学中心能源研究院(安徽省能源实验室) Multifunctional metal fuel cell system
CN112670538A (en) * 2020-12-24 2021-04-16 郑州佛光发电设备有限公司 Multifunctional portable metal air power supply
CN112670538B (en) * 2020-12-24 2022-12-09 郑州佛光发电设备股份有限公司 Multifunctional portable metal air power supply
CN117293341A (en) * 2023-11-24 2023-12-26 成都岷山绿氢能源有限公司 Fuel cell system for equalizing inlet temperature of fuel cell stack
CN117293341B (en) * 2023-11-24 2024-01-26 成都岷山绿氢能源有限公司 Fuel cell system for equalizing inlet temperature of fuel cell stack

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