CN106882466A - 一种夜间易辨识瓦楞纸箱 - Google Patents

一种夜间易辨识瓦楞纸箱 Download PDF

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CN106882466A
CN106882466A CN201710228967.9A CN201710228967A CN106882466A CN 106882466 A CN106882466 A CN 106882466A CN 201710228967 A CN201710228967 A CN 201710228967A CN 106882466 A CN106882466 A CN 106882466A
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杜威
陶香君
郭杰
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Chuzhou Cigarette Materials Factory
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Abstract

本发明公开了一种夜间易辨识瓦楞纸箱，包括瓦楞纸板组成的箱体，该瓦楞纸板从外到内依次为面纸、瓦楞纸和内纸，面纸的表面复合一层阻燃薄膜，薄膜上层用自发光涂料喷涂发光标志，该自发光涂料由以下质量百分数原料组成：环氧树脂60‑70％，蓄光型发光材料10‑30％，分散剂0.5‑1％，防沉剂1‑3％，消泡剂0.1‑0.5％,有机溶剂15‑25％,固化剂5‑10％。本发明在纸箱表面复合阻燃薄膜，可以起到防火的作用，同时为了进一步提高安全措施，特别对于易燃易爆产品的包装，本发明利用自发光涂料，在纸箱的表面喷涂有夜间发光标志，该标志在夜间易辨认，减少了危险的发生。

Description

一种夜间易辨识瓦楞纸箱
技术领域
本发明属于纸箱制造领域，涉及一种夜间易辨识瓦楞纸箱。
背景技术
瓦楞纸箱是由瓦楞纸板制成的刚性纸质容器，半个多世纪以来，瓦楞纸箱以其优越的使用性能和良好的加工性能逐渐取代了木箱等运输包装容器，成为运输包装的主力军，它除了保护商品、便于仓储、运输之外，还起到美化商品，宣传商品的作用，瓦楞纸箱属于绿色环保产品，它利于环保，利于装卸运输。
蓄光材料是一种长余辉磷光材料，俗称夜光粉，是指在受到太阳光、荧光灯和其他人工光源，特别是紫外线激发时吸收能量，并将吸收的能量转化为可见光，在激发停止后可在夜间发光。
现有技术制备的瓦楞纸箱在包装危险产品时，有警示标志，易于辨认，但是该标志在夜间无法辨认，特别对于易燃易爆的产品，在夜间容易造成危险的发生，因此，应用于瓦楞纸箱的夜间易辨识警示标志，成为研究的重点。
发明内容
为了解决瓦楞纸箱夜间易辨识问题，本发明提供了一种夜间易辨识瓦楞纸箱，该纸箱表面复合阻燃薄膜，可以起到防火的作用，同时为了进一步提高安全措施，特别对于易燃易爆产品的包装，本发明利用自发光涂料，在纸箱的表面喷涂有夜间发光标志，该标志在夜间易辨认，减少了危险的发生。
本发明的目的可以通过以下技术方案实现：
一种夜间易辨识瓦楞纸箱，包括瓦楞纸板组成的箱体，该瓦楞纸板从外到内依次为面纸、瓦楞纸和内纸，面纸的表面复合一层阻燃薄膜，薄膜上层用自发光涂料喷涂发光标志，该自发光涂料由以下质量百分数原料组成：环氧树脂60-70％，蓄光型发光材料10-30％，分散剂0.5-1％，防沉剂1-3％，消泡剂0.1-0.5％,有机溶剂15-25％,固化剂5-10％；
所述自发光涂料制备过程如下：先将环氧树脂放入有机溶剂中分散均匀，在低搅拌速度下依次加入分散剂、防沉剂、消泡剂，混合均匀后，将蓄光型发光材料慢慢加入叶轮搅起的漩涡中，加完后，提高叶轮转速，直到蓄光型发光材料均匀分散到溶液中，然后快速加入固化剂，分散均匀后即可制得自发光涂料。
所述环氧树脂为双酚A环氧树脂或双酚F环氧树脂。
所述分散剂为聚丙烯酸铵盐、聚磷酸盐或聚羧酸盐中的一种；防沉剂为气相二氧化硅；有机溶剂为丁醇、正丁醇或二甲苯中的一种；固化剂为乙二胺、己二胺或乙醇胺中的一种。
所述蓄光型发光材料为碱土铝酸盐体系、碱土硅酸盐体系或碱土硫化锌体系中的一种。
所述阻燃薄膜成膜过程为：将1-1.5kg的氧化淀粉加入到7-9kg的水中，加热到60℃，搅拌均匀后加入15-25g硼砂和10-15g纳米氢氧化铝，搅拌半小时后得到胶体，通过涂布机，将胶体均匀的涂布在瓦楞纸板表面，用压光机压光，其中纳米氢氧化铝的粒径大小为10-20nm，比表面积为200-300m2/g。
本发明的有益效果：
(1)本发明在纸箱表面复合一层阻燃薄膜，对纸箱有一定的防火作用。
(2)本发明应用自发光涂料在瓦楞纸箱的阻燃薄膜表面喷涂警示标志，该涂料中含有蓄光材料，在夜间可以自行发光，特别对于易燃易爆的物品，在包装的瓦楞纸箱表面喷头警示标识后，在夜间可以给人以警示，进一步防止危险的发生。
具体实施方式
下面将结合实施例对本发明的技术方案进行清楚、完整地描述，显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其它实施例，都属于本发明保护的范围。
实施例1：
一种夜间易辨识瓦楞纸箱，包括瓦楞纸板组成的箱体，该瓦楞纸板从外到内依次为面纸、瓦楞纸和内纸，面纸的表面复合一层阻燃薄膜，薄膜上层用自发光涂料喷涂发光标志；
所述阻燃薄膜成膜过程为：将1kg的氧化淀粉加入到7kg的水中，加热到60℃，搅拌均匀后加入15g硼砂和10g纳米氢氧化铝，搅拌半小时后得到胶体，通过涂布机，将胶体均匀的涂布在瓦楞纸板表面，用压光机压光；
所述自发光涂料制备过程如下：先将6kgE44-双酚A环氧树脂放入1.5kg丁醇溶液中分散均匀，在低搅拌速度下依次加入50g聚丙烯酸铵盐、0.1kg气相二氧化硅、10g消泡剂，混合均匀后，将1kg碱土铝酸盐体系蓄光型发光材料慢慢加入叶轮搅起的漩涡中，加完后，提高叶轮转速，直到蓄光型发光材料均匀分散到溶液中，然后快速加入0.5kg乙二胺，分散均匀后即可制得自发光涂料。
实施例2：
一种夜间易辨识瓦楞纸箱，包括瓦楞纸板组成的箱体，该瓦楞纸板从外到内依次为面纸、瓦楞纸和内纸，面纸的表面复合一层阻燃薄膜，薄膜上层用自发光涂料喷涂发光标志；
所述阻燃薄膜成膜过程为：将1.2kg的氧化淀粉加入到8kg的水中，加热到60℃，搅拌均匀后加入17g硼砂和12g纳米氢氧化铝，搅拌半小时后得到胶体，通过涂布机，将胶体均匀的涂布在瓦楞纸板表面，用压光机压光；
所述自发光涂料制备过程如下：先将6.5kgE51-双酚A环氧树脂放入2kg二甲苯溶液中分散均匀，在低搅拌速度下依次加入80g聚磷酸盐、0.2kg气相二氧化硅、30g消泡剂，混合均匀后，将2kg碱土硅酸盐体系蓄光型发光材料慢慢加入叶轮搅起的漩涡中，加完后，提高叶轮转速，直到蓄光型发光材料均匀分散到溶液中，然后快速加入0.7kg己二胺，分散均匀后即可制得自发光涂料。
实施例3：
一种夜间易辨识瓦楞纸箱，包括瓦楞纸板组成的箱体，该瓦楞纸板从外到内依次为面纸、瓦楞纸和内纸，面纸的表面复合一层阻燃薄膜，薄膜上层用自发光涂料喷涂发光标志；
所述阻燃薄膜成膜过程为：将1.3kg的氧化淀粉加入到8kg的水中，加热到60℃，搅拌均匀后加入23g硼砂和14g纳米氢氧化铝，搅拌半小时后得到胶体，通过涂布机，将胶体均匀的涂布在瓦楞纸板表面，用压光机压光；
所述自发光涂料制备过程如下：先将6kg双酚F环氧树脂放入2.3kg正丁醇溶液中分散均匀，在低搅拌速度下依次加入90g聚羧酸盐、0.3kg气相二氧化硅、40g消泡剂，混合均匀后，将3kg碱土硫化锌体系蓄光型发光材料慢慢加入叶轮搅起的漩涡中，加完后，提高叶轮转速，直到蓄光型发光材料均匀分散到溶液中，然后快速加入1kg乙醇胺，分散均匀后即可制得自发光涂料。
实施例4：
一种夜间易辨识瓦楞纸箱，包括瓦楞纸板组成的箱体，该瓦楞纸板从外到内依次为面纸、瓦楞纸和内纸，面纸的表面复合一层阻燃薄膜，薄膜上层用自发光涂料喷涂发光标志；
所述阻燃薄膜成膜过程为：将1.5kg的氧化淀粉加入到9kg的水中，加热到60℃，搅拌均匀后加入25g硼砂和15g纳米氢氧化铝，搅拌半小时后得到胶体，通过涂布机，将胶体均匀的涂布在瓦楞纸板表面，用压光机压光；
所述自发光涂料制备过程如下：先将7kg双酚F环氧树脂放入2.5kg正丁醇溶液中分散均匀，在低搅拌速度下依次加入100g聚羧酸盐、0.3kg气相二氧化硅、50g消泡剂，混合均匀后，将3kg碱土硫化锌体系蓄光型发光材料慢慢加入叶轮搅起的漩涡中，加完后，提高叶轮转速，直到蓄光型发光材料均匀分散到溶液中，然后快速加入1kg乙醇胺，分散均匀后即可制得自发光涂料。
制备夜间易辨识瓦楞纸板的工艺如下：取复合阻燃膜后的瓦楞纸板，将自发光涂料置于气喷枪中，在瓦楞纸板阻燃薄膜表面喷涂防火标志，然后在烘箱中烘干。
以上公开的本发明优选实施例只是用于帮助阐述本发明。优选实施例并没有详尽叙述所有的细节，也不限制该发明仅为所述的具体实施方式。显然，根据本说明书的内容，可作很多的修改和变化。本说明书选取并具体描述这些实施例，是为了更好地解释本发明的原理和实际应用，从而使所属技术领域技术人员能很好地理解和利用本发明。本发明仅受权利要求书及其全部范围和等效物的限制。

Claims (6)

1.一种夜间易辨识瓦楞纸箱，包括瓦楞纸板组成的箱体，该瓦楞纸板从外到内依次为面纸、瓦楞纸和内纸，其特征在于，面纸的表面复合一层阻燃薄膜，薄膜上层用自发光涂料喷涂发光标志，该自发光涂料由以下质量百分数原料组成：环氧树脂60-70％，蓄光型发光材料10-30％，分散剂0.5-1％，防沉剂1-3％，消泡剂0.1-0.5％,有机溶剂15-25％,固化剂5-10％；
所述自发光涂料制备过程如下：先将环氧树脂放入有机溶剂中分散均匀，在低搅拌速度下依次加入分散剂、防沉剂、消泡剂，混合均匀后，将蓄光型发光材料慢慢加入叶轮搅起的漩涡中，加完后，提高叶轮转速，直到蓄光型发光材料均匀分散到溶液中，然后快速加入固化剂，分散均匀后即可制得自发光涂料。
2.根据权利要求1所述的一种夜间易辨识瓦楞纸箱，其特征在于，所述环氧树脂为双酚A环氧树脂或双酚F环氧树脂。
3.根据权利要求1所述的一种夜间易辨识瓦楞纸箱，其特征在于，所述分散剂为聚丙烯酸铵盐、聚磷酸盐或聚羧酸盐中的一种；防沉剂为气相二氧化硅；有机溶剂为丁醇、正丁醇或二甲苯中的一种；固化剂为乙二胺、己二胺或乙醇胺中的一种。
4.根据权利要求1所述的一种夜间易辨识瓦楞纸箱，其特征在于，所述蓄光型发光材料为碱土铝酸盐体系、碱土硅酸盐体系或碱土硫化锌体系中的一种。
5.根据权利要求1所述的一种夜间易辨识瓦楞纸箱，其特征在于，所述阻燃薄膜成膜过程为：将1-1.5kg的氧化淀粉加入到7-9kg的水中，加热到60℃，搅拌均匀后加入15-25g硼砂和10-15g纳米氢氧化铝，搅拌半小时后得到胶体，通过涂布机，将胶体均匀的涂布在瓦楞纸板表面，用压光机压光。
6.根据权利要求5所述的阻燃薄膜制备过程，其特征在于，所述纳米氢氧化铝为阻燃剂，粒径大小为10-20nm，比表面积为200-300m2/g。
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