CN106854470A - A kind of fatty acid calcium of improved soil and its composition of derivative - Google Patents
A kind of fatty acid calcium of improved soil and its composition of derivative Download PDFInfo
- Publication number
- CN106854470A CN106854470A CN201510899198.6A CN201510899198A CN106854470A CN 106854470 A CN106854470 A CN 106854470A CN 201510899198 A CN201510899198 A CN 201510899198A CN 106854470 A CN106854470 A CN 106854470A
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- China
- Prior art keywords
- calcium
- composition
- derivative
- ester
- salt
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K17/00—Soil-conditioning materials or soil-stabilising materials
- C09K17/14—Soil-conditioning materials or soil-stabilising materials containing organic compounds only
- C09K17/18—Prepolymers; Macromolecular compounds
- C09K17/32—Prepolymers; Macromolecular compounds of natural origin, e.g. cellulosic materials
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2101/00—Agricultural use
Abstract
The present invention relates to aliphatic acid, their ester, their salt or derivative or their mixture and combinations thereof and inorganic calcium or organocalcium compound react that generation fatty acid calcium is made in the case where pH value is 2.0-3.3 with improvement rehabilitating soil structure, promote plant growth, strengthen the new application composition of plant resistance to environment stress.
Description
Technical field
The present invention relates to aliphatic acid, their ester, their salt or derivative or their mixture and combinations thereof with
Inorganic calcium or organocalcium compound react that generation fatty acid calcium is made in the case where pH value is 2.0-3.3 with improvement rehabilitating soil knot
Structure, promotes plant growth, strengthens the new application composition of plant resistance to environment stress, belongs to microbiology, chemistry and agricultural technology field, relates to
And microbiology, chemistry and biochemistry etc..
Background technology
With the development and the expansion of the agrochemical fertilizer scope of application of chemical industry, the quantity and kind of chemical fertilizer is not all
It is disconnected to increase, present world Fertilizer total output（As active ingredients）More than 30,000,000 tons.It is long-term due to chemical pesticide and chemical fertilizer
It is a large amount of to apply, serious Soil Environmental Pollution has been brought, and the hardened of soil is result in, drastically influence the life of crops
It is long.Many countries have all put into substantial contribution research and development and can substitute or reduce chemical pesticide and the novel formulation of chemical fertilizer, to protect
Hold the sustainable development of agricultural production.
The Soil Environmental Pollution that chemical fertilizer is caused is even more serious in China.Average every mu of China applies 21.9 kilograms of chemical fertilizer, far
Higher than the average level in the world（8 kilograms every mu）, it is 2.6 times of the U.S., 2.5 times of European Union.Since the seventies in last century, in
The Cultivated-land Fertility of state occurs in that and is decreased obviously that the national soil organism is average less than 1%.Corresponding to be, domestic chemical fertilizer is used
Amount and its growth rate are surprising, Three major grain cropsNitrogenous fertilizer, phosphate fertilizer,Potash fertilizerUtilization rate be only 33%, 24% and 42%.
Although a large amount of inputs of chemical fertilizer have ensured the stabilization of China's grain security, but at the same time, harm also begins to manifest,
Soil starts hardened.It is hardened to make less able, the influence crop root growth of soil conservation moisture, nutrient, reduce and make produce
Amount.Additionally, excessive fertilization also creates soil acidification, the field of some excessive applied nitrogens is compared with the normal field in side,
Can almost be described with " No kernels or seeds are gathered, as in a year of scarcity ".The change of soil makes peasant feel uneasy, in many places, in order to keep yield,
What peasants can do is exactly to apply a little chemical fertilizer again more, can increase production and but be increasingly difficult to, and the soil texture is worse and worse.
Aliphatic acid is largely to be present in the compound that nature has bioactivity, aliphatic acid, their ester, their salt
Or derivative or their mixture are had been widely used in fields such as food, chemical industry.Present invention discover that aliphatic acid it is especially short
Chain fatty acid, their ester, their salt or derivative or their mixture and calcium reaction generation with improved soil knot
Structure, promotes the effect of plant growth.
Aliphatic acid of the invention, their ester, their salt or derivative or their mixture and inorganic calcium or organic
Calcium compound reacts generation fatty acid calcium in the case where pH value is 2.0-3.3, by fatty acid calcium and following any one or more composition
It is combined before being administered to target site or when target site is administered to, a kind of anion sulfate or sulphonate surface are lived
Property agent, one or more spices, one or more sugar, one or more inorganic compound is by having that 0.1-95% is mixed
Improvement rehabilitating soil structure, promotes plant growth, and enhancing plant resistance to environment stress aspect shows unexpected multiple effect, and this is first
Before be not report.
More particularly composition of the invention is not only in coordinate plant growth development, enhancing plant resistance to environment stress and preventing and treating plant
Disease and insect pest aspect show unexpected multiple effect, and have combination to make us pleased because composition contains spices
Happy fragrance.
More it is advanced be the composition components that the present invention is selected be it is environment amenable, can be using this composition
Realize promoting soil improvement, promote plant growth, while increasing crop yield, energy-saving and emission-reduction, reduce it is a large amount of apply chemical fertilizer and
Pollution of the agricultural chemicals to agricultural product and environment.
More outstanding is that composition of the invention can also effectively suppress to endanger pest and disease damage of root system of plant etc. in soil.
The content of the invention
The technical problem to be solved
The purpose of the present invention one be to provide one or more aliphatic acid of following formula, their ester, their salt or derivative or it
Mixture：
And/or
X is H, C in formula1-C31Alkyl or alkenyl, 2- hydroxyethyls, the combination of 2- hydroxypropyls or these groups is more highly preferred to
It is the C of short chain1-C4Alkyl or alkenyl；Y is H, C1-C4Alkyl or alkenyl, metal or nonmetalloid or group, or these groups
Combination；Z is H, OH, C1-C4Alkyl or alkenyl, the derivative of alkoxylate, metal or nonmetalloid or group, or these
The combination of group；By the aliphatic acid containing above formula structure, their ester, their salt or derivative or their mixture and nothing
Machine calcium or organocalcium compound react generation fatty acid calcium in the case where pH value is 2.0-3.3, by fatty acid calcium with it is following any one
Or Multiple components are being combined before being administered to target site or when target site is administered to, a kind of anion sulfate or sulphur
Acid salt surfactant, one or more spices, one or more sugar, one or more inorganic compound is pressed for one or more
The composition that 0.1-95% is mixed.The proper combination that this preparation is made obtains efficient synergy, this collaboration
Effect shows that amount ratio calcium oxide containing calcium composition or the consumption of calcium sulfate are substantially reduced, and improved soil structure effect
Fruit significantly increases, and composition also has promotion plant growth and enhancing plant resistance to environment stress, prevents and treats the aspects such as soil-borne disease and is anticipated
Unimaginable effect.
The purpose of the present invention two is composition of the invention containing savory, and this is never have in current fertilizer and agricultural chemicals
's.
The purpose of the present invention three is that the application method of composition can be that composition is passed through into sprinkling during plant growth,
The modes such as pouring root, pouring are manured into soil without injury plant.
The object of the present invention is achieved like this.
Technical scheme
Those skilled in the art know that aliphatic acid is largely to be present in the compound that nature has bioactivity.In U.S.
State's patent 3, in 983,214, Misato et al. highlight sucrose fatty acid ester prevention fungal disease activity, United States Patent (USP) 4,
In 771,571, Obrero et al. describes the effect that fatty acid surfactant prevents and treats pineapple disease, and Kabera et al. is in U.S.
Disinfecting food additive in state's patent 4,002,775 to 1-2 mono laurates polyester composition proposes claim.At other
Also the anti-microbial effect of many aliphatic acid and its derivative has been published in the periodical and the book of professional society delivered.Although such as
This, the Valid concentration of aliphatic acid and its derivative is very narrow, does not have effect in low concentration, and plant is then injured when concentration is high
（United States Patent (USP) 5,366,995,6,103,768）, meanwhile, some soap can promote it again while a kind of disease is prevented and treated
The generation of its disease（Chase, A.R., L.S.Osborne（1983）Plase Disease67:1021-1-1023）.Savage
Et al. propose not produce in United States Patent (USP) 6,136,856 phytotoxicity again can effective controlling plant diseases C7-C20Long-chain
The valid density of aliphatic acid and its derivative is 0.1-2% w/v.Although inorganic calcium such as calcium oxide or calcium sulfate change in soil
The effect shown in good, but because consumption is big, in-convenience in use and being unable to large-area applications.
Novelty of the invention is that by aliphatic acid, their ester or has their salt and its derivative and inorganic calcium
Machine calcium compound pH value be 2.0-3.3 under react generation fatty acid calcium, by fatty acid calcium with it is following any one or more into
Point being combined before being administered to target site or when target site is administered to, a kind of anion sulfate or sulphonate surface
Activating agent, one or more spices, one or more sugar, one or more inorganic compound is by fitting that 0.1-95% is mixed
Preferably combine and obtain efficient synergy, this synergy shows amount ratio calcium oxide or calcium sulfate containing calcium composition
Consumption substantially reduce, and improved soil structure effect is significant enhancing, composition also have promote plant growth and enhancing
Plant resistance to environment stress, prevents and treats the effect of soil-borne disease.Another innovative point of the invention also resides in composition of the invention and contains savory,
This never has in current fertilizer and agricultural chemicals.And the optimum pH of composition is 2.0-3.3, this is being previously not report
What road was crossed.The pH of the soap of the controlling plant diseases that Savage et al. is proposed in United States Patent (USP) 6,130,768 is 7.4-
7.8。
Main method of the invention is by aliphatic acid, their salt or derivative or their mixture and inorganic calcium or has
Machine calcium compound pH value be 2.0-3.3 under react generation fatty acid calcium, by fatty acid calcium with it is following any one or more into
Point being combined before being administered to target site or when target site is administered to, a kind of anion sulfate or sulphonate surface
Activating agent, one or more spices, one or more sugar, the tool that one or more inorganic compound is mixed by 0.1-95%
There is improved soil structure, promote plant growth, strengthen plant resistance to environment stress, prevent and treat the composition of plant soil-borne diseases multiple effect, lead to
Cross the synergy between composition, make composition with the aliphatic acid of low concentration, their ester, their salt or derivative or they
The calcium of mixture and low consumption just obtains improved soil, promotes plant growth, improves plant products, prevents and treats plant soil borne disease
The remarkable result of insect pest.
The aliphatic acid, their ester, their salt or derivative or their mixture are included but is not limited to from C1
To C31Saturated or undersaturated aliphatic acid, their ester, their salt or derivative, it is more preferred to C1-C4Short chain
Aliphatic acid, their ester, their salt or derivative, such as acetic acid, butyric acid, vinyl acetate etc..
Described inorganic calcium or organic calcium including but not limited to calcium gluconae, calcium lactate, calcium citrate, calcium carbonate,
Calcium sulfate, calcium chloride, calcium hydroxide, calcium oxide etc..Described sugar is including but not limited to monose, disaccharide and oligosaccharide such as Portugal
Grape sugar, sucrose, shitosan, trehalose etc., it is more preferred to oligosaccharide.
Described sugar is including but not limited to monose, disaccharide and oligosaccharide such as glucose, sucrose, shitosan, trehalose
Deng.Described inorganic or organic compound is included but is not limited to containing calcium, magnesium, silicon, potassium, boron, aluminium, manganese, zinc, iron, copper and/or
The inorganic or organic salt of sodium, such as sulfate, hydrochloride, nitrate, carbonate, silicate, salicylate etc..Described is natural
Produce or artificial synthesized high molecular polymer includes but is not limited to cellulose, methylcellulose, starch etc..
Described spices includes but is not limited to terpenes, aromatics, aliphatic category, nitrogenous, sulfur-bearing, heterocycle and condensed ring class
And musk ambrette class etc., such as different ocimenum, allyl heptanoate, amphene, carvacrol, β-carypohyllene, geraniol acetate is fragrant
Thatch alcohol isobutyrate, lemongrass base nitrile, citronellyl propionate, cyclohexyl ethyl acetate, capraldehyde, cetone gamma, acetic acid is fragrant
Leaf ester, geranyl formate, geranyl isobutyrate, spiceleaf ester group nitrile, (R)-4-isopropenyl-1-methyl-1-cyclohexene, sodium ester in acetic acid, menthyl acetate, methyl is recklessly
Green pepper powder, methyl nonyl acetaldehyde, neryl acetate, nonyl acetate, aldehyde C-9, octanal, terpinolene, terpinyl acetate etc..
These compositions easily can have been bought by commercial sources.The aliphatic acid of selection, their ester, their salt spread out
Biological and polysaccharide can also be obtained using known method from plant, animal in marine organisms or microorganism.
Implementation steps of the invention are：
The preparation of the composition of example 1.
Take calcium sulfate 10g and be added in the acetic acid aqueous solutions of 500ml 2% reaction at 60 DEG C and be made fatty acid calcium in 24 hours, add
0.5 gram of shitosan, 0.1 gram of geranyl fat, 3 grams of fatty alcohol sulphuric acid sodium salt, 0.5 gram of Coconut Fatty Acid Monoethanolamide, Methyl cellulose
0.3 gram of element, stirs, and is made the composition of the fatty acid calcium of improved soil of the invention.
The effect of the composition improved soil of example 2.
Take composition and be diluted with water 100 times, the uniform soil for pouring plantation garlic is spaced 7 days 1 time, and soil is determined after pouring 2 times
Structure change.15 kilograms of calcium oxide is spread fertilizer over the fields for every mu in control plot before planting garlic, and composition significantly improves soil than control
Structure.
Claims (7)
1. the composition of a kind of fatty acid calcium of improved soil and its derivative, it is characterised in that under said composition is by including
The compound method for stating step is prepared：
1) aliphatic acid, their ester, their salt or the derivative of one or more following formula containing 0.01-99.9999% are selected
Thing or their mixture：
And/or
X is H, C in formula1-C31Alkyl or alkenyl, 2- hydroxyethyls, the combination of 2- hydroxypropyls or these groups is more highly preferred to
It is the C of short chain1-C4Alkyl or alkenyl；
Y is H, C1-C4Alkyl or alkenyl, metal or nonmetalloid or group, or these groups combination；
Z is H, OH, C1-C4Alkyl or alkenyl, the derivative of alkoxylate, metal or nonmetalloid or group, or these groups
Combination；
2) by step 1) aliphatic acid, their ester, their salt or derivative or their mixture and inorganic calcium or have
Machine calcium compound pH value be 2.0-3.3 under react generation fatty acid calcium, by fatty acid calcium with it is following any one or more into
Point being combined before being administered to target site or when target site is administered to, a kind of anion sulfate or sulphonate surface
Activating agent, one or more spices, one or more sugar, one or more inorganic compound presses 0.1-95% one or more
Be mixed with improvement rehabilitating soil structure, promote plant growth, enhancing plant resistance to environment stress and preventing and treating soil-borne disease insect pest group
Compound.
2. composition as claimed in claim 1, it is characterised in that described aliphatic acid, their ester, their salt or derivative
Thing is included but is not limited to：From C1To C31Saturated or undersaturated aliphatic acid, their ester, their salt or derivative, more
To be preferably C1-C4SCFA, their ester, their salt or derivative, such as acetic acid, butyric acid, vinyl acetate
Deng.
3. composition as claimed in claim 1, it is characterised in that described inorganic calcium or organic calcium are including but not limited to Portugal
Grape Calciofon, calcium lactate, calcium citrate, calcium carbonate, calcium sulfate, calcium chloride, calcium hydroxide, calcium oxide etc..
4. composition as claimed in claim 1, it is characterised in that described sugar including but not limited to monose, disaccharide and low
Glycan such as glucose, sucrose, shitosan, trehalose etc., it is more preferred to oligosaccharide.
5. composition as claimed in claim 1, it is characterised in that described inorganic or organic compound is included but is not limited to
Containing calcium, magnesium, silicon, potassium, boron, aluminium, manganese, zinc, iron, the inorganic or organic salt of copper and/or sodium, such as sulfate, hydrochloride, nitric acid
Salt, carbonate, silicate, salicylate etc..
6. composition as claimed in claim 1, it is characterised in that described naturally-produced or artificial synthesized polyphosphazene polymer
Compound includes but is not limited to cellulose, methylcellulose, starch etc..
7. composition as claimed in claim 1, it is characterised in that described spices includes but is not limited to terpenes, fragrance
Class, aliphatic category, nitrogenous, sulfur-bearing, heterocycle and condensed ring class and musk ambrette class etc., such as different ocimenum, allyl heptanoate, camphane
Alkene, carvacrol, β-carypohyllene, geraniol acetate, citronellyl isobutyrate, lemongrass base nitrile, citronellyl propionate, ethyl cyclohexyl
Base ethyl ester, capraldehyde, cetone gamma, geranyl acetate, geranyl formate, geranyl isobutyrate, spiceleaf ester group nitrile, d-
Limonene, sodium ester in acetic acid, menthyl acetate, methyl pepper powder, methyl nonyl acetaldehyde, neryl acetate, nonyl acetate, nonyl
Aldehyde, octanal, terpinolene, terpinyl acetate etc..
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510899198.6A CN106854470A (en) | 2015-12-09 | 2015-12-09 | A kind of fatty acid calcium of improved soil and its composition of derivative |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510899198.6A CN106854470A (en) | 2015-12-09 | 2015-12-09 | A kind of fatty acid calcium of improved soil and its composition of derivative |
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| Publication Number | Publication Date |
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| CN106854470A true CN106854470A (en) | 2017-06-16 |
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|---|---|---|---|
| CN201510899198.6A Pending CN106854470A (en) | 2015-12-09 | 2015-12-09 | A kind of fatty acid calcium of improved soil and its composition of derivative |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117778276A (en) * | 2024-02-23 | 2024-03-29 | 四川省农业农村厅植物保护站 | Biocontrol microbial inoculum for preventing and treating soil-borne diseases of ginger, preparation method and cultivation method |
| CN117778276B (en) * | 2024-02-23 | 2024-05-10 | 四川省农业农村厅植物保护站 | Biocontrol microbial inoculum for preventing and treating soil-borne diseases of ginger, preparation method and cultivation method |
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| CN101637156B (en) * | 2008-07-30 | 2014-01-29 | 黄永 | Composite of fatty acids and derivatives thereof |
| CN104628486A (en) * | 2015-02-13 | 2015-05-20 | 冉令波 | Preparation method for liquid organic calcium fertilizer |
-
2015
- 2015-12-09 CN CN201510899198.6A patent/CN106854470A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101637156B (en) * | 2008-07-30 | 2014-01-29 | 黄永 | Composite of fatty acids and derivatives thereof |
| CN104628486A (en) * | 2015-02-13 | 2015-05-20 | 冉令波 | Preparation method for liquid organic calcium fertilizer |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117778276A (en) * | 2024-02-23 | 2024-03-29 | 四川省农业农村厅植物保护站 | Biocontrol microbial inoculum for preventing and treating soil-borne diseases of ginger, preparation method and cultivation method |
| CN117778276B (en) * | 2024-02-23 | 2024-05-10 | 四川省农业农村厅植物保护站 | Biocontrol microbial inoculum for preventing and treating soil-borne diseases of ginger, preparation method and cultivation method |
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| PB01 | Publication | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20180314 Address after: 611731 Chengdu Mold Industrial Park, No. 199, Chengdu high tech Zone, Sichuan Province Applicant after: Chengdu top biological Polytron Technologies Inc Address before: 611731 B1, No. 199, West Avenue, hi-tech West District, Chengdu, Sichuan Applicant before: Huang Yong |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170616 |
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| RJ01 | Rejection of invention patent application after publication |