CN106833348A - 具有夜光效果的胶膜涂层及其制备方法 - Google Patents

具有夜光效果的胶膜涂层及其制备方法 Download PDF

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CN106833348A
CN106833348A CN201710104406.8A CN201710104406A CN106833348A CN 106833348 A CN106833348 A CN 106833348A CN 201710104406 A CN201710104406 A CN 201710104406A CN 106833348 A CN106833348 A CN 106833348A
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耿佃勇
荆晓东
董伟
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Abstract

本发明涉及一种具有夜光效果的胶膜涂层及其制备方法，属于有机高分子合成技术领域。所述的胶膜涂层由以下重量份数的原料制成：异氰酸酯55～75份，聚醚多元醇40～45份，聚四氢呋喃醚二醇55～60份，5％氢氧化钾水溶液2.5～4份，二乙醇胺1～1.5份，二羟甲基丁酸3～7份，消泡剂1.1～1.7份，去离子水130～150份，乙酸乙酯80～130份，乙二胺15～20份；所述制备方法是先将聚醚多元醇、聚四氢呋喃醚二醇和异氰酸酯进行反应，再依次加入二羟甲基丁酸、二乙醇胺反应，然后加入乙酸乙酯、5％氢氧化钾水溶液、消泡剂、去离子水和乙二胺进行乳化，减压蒸馏后得到产品。本发明的胶膜涂层为水性乳液，使用过程中对环境和人体无害，耐水，耐摩擦，不会随意析出夜光剂。

Description

具有夜光效果的胶膜涂层及其制备方法
技术领域
本发明涉及一种具有夜光效果的胶膜涂层及其制备方法，属于有机高分子合成技术领域。
背景技术
当今，具有夜光效果的生活用品越来越受到年轻人的青睐，如鞋子，耳机等，这些都成了时尚的代表性元素，年轻人喜欢在生活用品中涂上一层夜光涂层来彰显其个性。但是，现有的具有夜光效果的涂料存在使用不方便、操作困难的问题，且荧光粉也易从涂层中析出，不环保，也会危害人体生命健康。
发明内容
本发明的目的是提供一种具有夜光效果的胶膜涂层，具有适用方便、化学性质稳定、不会随意析出夜光剂的特点，本发明同时提供其制备方法。
本发明所述的具有夜光效果的胶膜涂层，由以下重量份数的原料制成：
其中：
所述的聚醚多元醇的相对分子质量为300～2500，官能度为1.5～2.5，优选由淄博德信联邦化学工业有限公司生产的DDL-1000。
所述的异氰酸酯为六亚甲基二异氰酸酯。
所述的聚四氢呋喃醚二醇的平均相对分子质量为300～2500，官能度为1.5～3.2，优选由拜耳公司生产的PTEMG1000。
所述的消泡剂的型号为DF-8205/879。
本发明所述的具有夜光效果的胶膜涂层的制备方法，包括以下步骤：
(1)将聚醚多元醇和聚四氢呋喃醚二醇加入到反应瓶中进行混合，升温，真空脱水后降温；
(2)向反应瓶中加入异氰酸酯进行反应，反应完成后降温，然后加入二羟甲基丁酸搅拌反应，得到预聚物，降温；
(3)向预聚物中加入二乙醇胺搅拌反应，冷却至室温，得到预聚体；
(4)向预聚体中加入乙酸乙酯，搅拌均匀，滴加5％氢氧化钾水溶液，加入消泡剂、去离子水和乙二胺，乳化后得到水性聚氨酯溶液，减压蒸馏后去除所有乙酸乙酯，得到具有夜光效果的胶膜涂层。
其中，优选地技术方案如下：
步骤(1)中升温温度为100～120℃，真空脱水时间为1.8～2.2h，降温温度为20～40℃。
步骤(2)中加入异氰酸酯进行反应时的反应温度为90～105℃，反应时间为1.5～2h，反应完成后降温至63～67℃；加入二羟甲基丁酸进行反应时的反应温度为80～85℃，反应时间为1.5～2h，降温至60～65℃。
步骤(2)中预聚物的NCO质量分数为2.5～4％。
步骤(3)中反应温度为80～85℃，反应时间为1.5～2h。
步骤(4)中滴加5％氢氧化钾水溶液后搅拌1～1.5h，乳化时间为90～150min，乳化温度为15～25℃。
本发明有益效果如下：
(1)本发明的具有夜光效果的胶膜涂层为水性乳液，使用过程中对环境和人体无害；
(2)使用方便，化学性质稳定，耐水，耐摩擦，不会随意析出夜光剂；
(3)操作简单，干燥时间快，可以被用于DIY。
具体实施方式
以下结合实施例对本发明做进一步描述。
实施例1
具有夜光效果的胶膜涂层，由以下重量份数的原料制成：
制备方法，包括以下步骤：
(1)将DDL-1000和PTEMG1000加入到反应瓶中进行混合，升温至100～120℃，真空脱水1.8～2.2h后降温至20～40℃；
(2)向反应瓶中加入六亚甲基二异氰酸酯进行反应，反应温度为90～105℃，反应时间为1.5～2h反应完成后降温至63～67℃，然后加入二羟甲基丁酸搅拌反应，反应温度为80～85℃，反应时间为1.5～2h，得到预聚物，降温至60～65℃；
(3)向预聚物中加入二乙醇胺搅拌反应，反应温度为80～85℃，反应时间为1.5～2h，冷却至室温后得到预聚体；
(4)向预聚体中加入乙酸乙酯，搅拌均匀，滴加5％氢氧化钾水溶液后搅拌1～1.5h，加入DF-8205、去离子水和乙二胺，乳化后得到水性聚氨酯溶液，乳化时间为90～150min，减压蒸馏后去除所有乙酸乙酯，得到具有夜光效果的胶膜涂层。
实施例2
具有夜光效果的胶膜涂层，由以下重量份数的原料制成：
制备方法同实施例1。
实施例3
具有夜光效果的胶膜涂层，由以下重量份数的原料制成：
制备方法同实施例1。

Claims (10)

1.一种具有夜光效果的胶膜涂层，其特征在于：由以下重量份数的原料制成：
所述聚醚多元醇的相对分子质量为300～2500，官能度为1.5～2.5。
2.根据权利要求1所述的具有夜光效果的胶膜涂层，其特征在于：异氰酸酯为六亚甲基二异氰酸酯。
3.根据权利要求1所述的具有夜光效果的胶膜涂层，其特征在于：聚四氢呋喃醚二醇的平均相对分子质量为300～2500，官能度为1.5～3.2。
4.根据权利要求1所述的具有夜光效果的胶膜涂层，其特征在于：消泡剂的型号为DF-8205/879。
5.一种权利要求1-4任一所述的具有夜光效果的胶膜涂层的制备方法，其特征在于：包括以下步骤：
(1)将聚醚多元醇和聚四氢呋喃醚二醇加入到反应瓶中进行混合，升温，真空脱水后降温；
(2)向反应瓶中加入异氰酸酯进行反应，反应完成后降温，然后加入二羟甲基丁酸搅拌反应，得到预聚物，降温；
(3)向预聚物中加入二乙醇胺搅拌反应，冷却至室温，得到预聚体；
(4)向预聚体中加入乙酸乙酯，搅拌均匀，滴加5％氢氧化钾水溶液，加入消泡剂、去离子水和乙二胺，乳化后得到水性聚氨酯溶液，减压蒸馏后去除所有乙酸乙酯，得到具有夜光效果的胶膜涂层。
6.根据权利要求5所述的具有夜光效果的胶膜涂层的制备方法，其特征在于：步骤(1)中升温温度为100～120℃，真空脱水时间为1.8～2.2h，降温温度为20～40℃。
7.根据权利要求5所述的具有夜光效果的胶膜涂层的制备方法，其特征在于：步骤(2)中加入异氰酸酯进行反应时的反应温度为90～105℃，反应时间为1.5～2h，反应完成后降温至63～67℃；加入二羟甲基丁酸进行反应时的反应温度为80～85℃，反应时间为1.5～2h，降温至60～65℃。
8.根据权利要求5所述的具有夜光效果的胶膜涂层的制备方法，其特征在于：步骤(2)中预聚物的NCO质量分数为2.5～4％。
9.根据权利要求5所述的具有夜光效果的胶膜涂层的制备方法，其特征在于：步骤(3)中反应温度为80～85℃，反应时间为1.5～2h。
10.根据权利要求5所述的具有夜光效果的胶膜涂层的制备方法，其特征在于：步骤(4)中滴加5％氢氧化钾水溶液后搅拌1～1.5h，乳化时间为90～150min。
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115612128A (zh) * 2022-10-26 2023-01-17 江苏华缘高科股份有限公司 一种多功能夜光水性聚氨酯复合板材及其制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103450440A (zh) * 2013-09-03 2013-12-18 山东天庆科技发展有限公司 一种水性聚氨酯树脂及其制备方法
CN104194610A (zh) * 2014-09-11 2014-12-10 北京东方雨虹防水技术股份有限公司 一种自交联型单组份聚氨酯防水涂料
CN104387547A (zh) * 2014-11-19 2015-03-04 上海华峰新材料研发科技有限公司 水性聚氨酯树脂及其制备方法和应用
CN106188476A (zh) * 2016-07-21 2016-12-07 淄博德信联邦化学工业有限公司 油墨用水性聚氨酯及其制备方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103450440A (zh) * 2013-09-03 2013-12-18 山东天庆科技发展有限公司 一种水性聚氨酯树脂及其制备方法
CN104194610A (zh) * 2014-09-11 2014-12-10 北京东方雨虹防水技术股份有限公司 一种自交联型单组份聚氨酯防水涂料
CN104387547A (zh) * 2014-11-19 2015-03-04 上海华峰新材料研发科技有限公司 水性聚氨酯树脂及其制备方法和应用
CN106188476A (zh) * 2016-07-21 2016-12-07 淄博德信联邦化学工业有限公司 油墨用水性聚氨酯及其制备方法

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
胡飞燕等: "《涂料基础配方与工艺》", 30 June 2013, 东华大学出版社 *
马兴元等: "《合成革化学与工艺学》", 30 November 2015, 中国轻工业出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115612128A (zh) * 2022-10-26 2023-01-17 江苏华缘高科股份有限公司 一种多功能夜光水性聚氨酯复合板材及其制备方法
CN115612128B (zh) * 2022-10-26 2023-08-29 江苏华缘高科股份有限公司 一种多功能夜光水性聚氨酯复合板材及其制备方法

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Application publication date: 20170613