CN106832794A - A kind of vinylite being easy to concrete binding - Google Patents
A kind of vinylite being easy to concrete binding Download PDFInfo
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- CN106832794A CN106832794A CN201611243655.7A CN201611243655A CN106832794A CN 106832794 A CN106832794 A CN 106832794A CN 201611243655 A CN201611243655 A CN 201611243655A CN 106832794 A CN106832794 A CN 106832794A
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- vinylite
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- epoxy resin
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
- C08L63/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/14—Polycondensates modified by chemical after-treatment
- C08G59/1433—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
- C08G59/1438—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds containing oxygen
- C08G59/1455—Monocarboxylic acids, anhydrides, halides, or low-molecular-weight esters thereof
- C08G59/1461—Unsaturated monoacids
- C08G59/1466—Acrylic or methacrylic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Emergency Medicine (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention relates to technical field of macromolecules, and in particular to a kind of vinylite being easy to concrete binding.Meter includes by weight：38 41 parts of bisphenol A formaldehyde epoxy resin, 57 parts of polyurethane modified epoxy resin, 69 parts of butyl alcohol etherified melamine-formaldehyde resin, 58 parts of methacrylic acid, 16 18 parts of acrylic acid, 12 15 parts of fumaric acid, 16 20 parts of maleic anhydride, 0.5 1 parts of tri-phenyl-ethyl phosphonium bromide, 0.6 0.9 parts of hydroquinones, 48 50 parts of styrene, 13 15 parts of itaconic anhydride, 38 parts of cohesion modifiers.Product prepared by the present invention, with excellent mechanical property, its tensile strength, bending strength and fracture elongation are superior to conventional vinyl resin, after it is constructed on concrete surface, can be with the pliability of itself and concrete binding, and combined with the silicon oxygen bond of concrete after hardening, to improve the caking property with concrete.
Description
Technical field
The present invention relates to technical field of macromolecules, and in particular to a kind of vinylite being easy to concrete binding.
Background technology
Unsaturated polyester resin, is usually contracted by unsaturated dibasic acid dihydroxylic alcohols or monounsaturated dicarboxylic acid unsaturation dihydroxylic alcohols
The poly- chain macromolecule compound with ester bond and unsaturated double-bond.Generally, polyesterification polycondensation reaction be 190~
220 DEG C are carried out, until reaching expected acid number (or viscosity), after polyesterification contracting reaction terminates, a certain amount of second are added while hot
Alkenyl monomer, is made into sticky liquid, and such polymer solution is referred to as unsaturated polyester resin.
So far, unsaturated polyester (UP) (resin) matrix as matrices of composite material is substantially O-phthalic acid type both at home and abroad
(referred to as adjacent benzene-type), M-phthalic acid type (abbreviation metaphenylene), bisphenol A-type and vinyl ester type, halo unsaturated polyester resin
Deng.
Vinylite is vinyl ester resin, is a kind of epoxy resin and a kind of unsaturated monoacid containing ethylene linkage
Addition reaction product, and diluted through a kind of reactive monomer.Vinylite has good decay resistance, has asphalt mixtures modified by epoxy resin concurrently
The excellent mechanical property of fat and the good characteristic of unsaturated polyester resin normal temperature cure.The resin base made of vinylite is combined
Material, is widely used at aspects such as chemical anticorrosion, flue gas desulfurization, communications and transportation, electronic apparatus.
Traditional vinylite is when with concrete combination, and durability is poor, and firmness is not enough, ultimately results in life-span drop
It is low.
The content of the invention
The invention aims to solve the above problems, there is provided a kind of vinylite being easy to concrete binding.
In order to reach foregoing invention purpose, the present invention uses following technical scheme：
A kind of vinylite being easy to concrete binding, by weight meter include：Bisphenol A formaldehyde epoxy resin
38-41 parts, polyurethane modified epoxy resin 5-7 parts, butyl alcohol etherified melamine-formaldehyde resin 6-9 parts, methacrylic acid 5-8
Part, it is acrylic acid 16-18 parts, fumaric acid 12-15 parts, maleic anhydride 16-20 parts, tri-phenyl-ethyl phosphonium bromide 0.5-1 parts, right
Benzenediol 0.6-0.9 parts, styrene 48-50 parts, itaconic anhydride 13-15 parts, cohesion modifiers 3-8 parts.
Traditional vinylite is not high enough with the adhesion strength of concrete, and the present invention is by by bisphenol A formaldehyde asphalt mixtures modified by epoxy resin
Fat, polyurethane modified epoxy resin, butyl alcohol etherified melamine-formaldehyde resin is compounded, and auxiliary is carried out with cohesion modifiers
After reaction, the vinylite higher with Concrete Bond Strength is prepared, so as to improve current vinylite not
Foot.By modified, application property of the vinylite on concrete is greatly improved, and can be possessed than conventional vinyl resin more
Long endurance.By prolonged aging, its adhesion strength will be higher by 20-30% than conventional vinyl resin.Bisphenol A formaldehyde
Epoxy resin, polyurethane modified epoxy resin, after butyl alcohol etherified melamine-formaldehyde resin is compounded, the vinyl tree of preparation
Fat pliability is improved, in the shrinkage factor reduction of concrete surface, caused by the contraction after avoiding resin and concrete binding
Molecule chain break, and then reduce the adhesion strength of the two.Cohesion modifiers are directed to polyurethane modified epoxy resin and butanol
Modifying agent after etherified melamine amine-formaldehyde resins compounding, the modifying agent can be by improving vinylite with silicon in concrete
Epoxide adhesion, the purpose of resin and concrete binding is improved so as to reach.
Further, meter includes by weight：38 parts of bisphenol A formaldehyde epoxy resin, polyurethane modified epoxy resin 7
Part, 6 parts of butyl alcohol etherified melamine-formaldehyde resin, 8 parts of methacrylic acid, 16 parts of acrylic acid, 15 parts of fumaric acid, maleic acid
16 parts of acid anhydride, 1 part of tri-phenyl-ethyl phosphonium bromide, 0.6 part of hydroquinones, 50 parts of styrene, 13 parts of itaconic anhydride, cohesion modifiers 8
Part.
Further, meter includes by weight：41 parts of bisphenol A formaldehyde epoxy resin, polyurethane modified epoxy resin 5
Part, 9 parts of butyl alcohol etherified melamine-formaldehyde resin, 5 parts of methacrylic acid, 18 parts of acrylic acid, 12 parts of fumaric acid, maleic acid
20 parts of acid anhydride, 0.5 part of tri-phenyl-ethyl phosphonium bromide, 0.9 part of hydroquinones, 48 parts of styrene, 15 parts of itaconic anhydride, cohesion modifiers
3 parts.
Further, the cohesion modifiers count by weight including：Cellulose acetate 2-5 parts, itaconic acid 8-12 parts,
Nano zine oxide 0.3-0.5 parts, cesium hydroxide 0.1-0.2 parts.
Further, the cohesion modifiers count by weight including：5 parts of cellulose acetate, 12 parts of itaconic acid, nanometer
0.5 part of zinc oxide, 0.1 part of cesium hydroxide.
Further, also including bonding built agent, bonding built agent includes methyl methacrylate 5-8 parts, ethylene glycol ethyl ethers
Ether acetate 3-4 parts, 4-6 parts of dichloro base silane, 4 parts of maleic acid, ethylene glycol 3-5 parts, N- bromo-succinimides
1-2 parts, 4,4'- DADPS 0.5-2 parts.
Bond built agent to be used to coordinate cohesion modifiers, further to improve the mechanical property of resin.
Further, bonding built agent includes 8 parts of methyl methacrylate, 3 parts of ethylene glycol ether acetate, dichloro
6 parts of base silane, 4 parts of maleic acid, 3 parts of ethylene glycol, 2 parts of N- bromo-succinimides, 4,4'- 0.5 part of DADPSs.
Further, also including nanometer titanium dioxide 1-2 parts.Nanometer titanium dioxide forms island space in vinylite,
Exist in the form of resin encirclement, promote resin to form network structure with the faying face of concrete, to improve cohesive force.
Product prepared by the present invention, with excellent mechanical property, its tensile strength, bending strength and fracture elongation
Conventional vinyl resin is superior to, after it is constructed on concrete surface, can be with the pliability of itself and concrete
Bond, and combined with the silicon oxygen bond of concrete after hardening, with improve and concrete caking property.
Specific embodiment
Explanation is further described to technical scheme below by specific embodiment.
If without specified otherwise, the raw material employed in embodiments of the invention is raw material commonly used in the art, implements
Method employed in example, is the conventional method of this area.
Embodiment 1：
A kind of vinylite being easy to concrete binding, its specific proportioning is as follows：Bisphenol A formaldehyde epoxy resin
38kg, polyurethane modified epoxy resin 7kg, butyl alcohol etherified melamine-formaldehyde resin 6kg, methacrylic acid 8kg, acrylic acid
16kg, fumaric acid 15kg, maleic anhydride 16kg, tri-phenyl-ethyl phosphonium bromide 1kg, hydroquinones 0.6kg, styrene
50kg, itaconic anhydride 13kg, cohesion modifiers 8kg.
The proportioning of cohesion modifiers is calculated as with weight kg numbers：Cellulose acetate 2kg, itaconic acid 8kg, nano zine oxide
0.3kg, cesium hydroxide 0.2kg.
Embodiment 2：
A kind of vinylite being easy to concrete binding, its specific proportioning is as follows：Bisphenol A formaldehyde epoxy resin
41kg, polyurethane modified epoxy resin 5kg, butyl alcohol etherified melamine-formaldehyde resin 9kg, methacrylic acid 5kg, acrylic acid
18kg, fumaric acid 12kg, maleic anhydride 20kg, tri-phenyl-ethyl phosphonium bromide 0.5kg, hydroquinones 0.9kg, styrene
48kg, itaconic anhydride 15kg, cohesion modifiers 3kg.
The proportioning of cohesion modifiers is calculated as with weight kg numbers：Cellulose acetate 5kg, itaconic acid 12kg, nano zine oxide
0.5kg, cesium hydroxide 0.1kg.
Embodiment 3：
Add nanometer titanium dioxide 2kg and bonding built agent some on the basis of embodiment 1, bonding built agent includes methyl
Methyl acrylate 5kg, ethylene glycol ether acetate 4kg, dichloro base silane 4kg, maleic acid 4kg, ethylene glycol 5kg,
N- bromo-succinimides 1kg, 4,4'- DADPS 2kg.
Embodiment 4：
Add nanometer titanium dioxide 1kg and bonding built agent some on the basis of embodiment 2, bonding built agent includes methyl
Methyl acrylate 8kg, ethylene glycol ether acetate 3kg, dichloro base silane 6kg, maleic acid 4kg, ethylene glycol 3kg,
N- bromo-succinimides 2kg, 4,4'- DADPS 0.5kg.
The product that embodiment 1-4 is prepared carries out performance test according to national standard, and test result is specific as follows：
Embodiment described above is a kind of preferably scheme of the invention, not makees any formal to the present invention
Limitation, also has other variants and remodeling on the premise of without departing from the technical scheme described in claim.
Claims (8)
1. a kind of vinylite being easy to concrete binding, it is characterised in that meter includes by weight：Bisphenol A formaldehyde
Epoxy resin 38-41 parts, polyurethane modified epoxy resin 5-7 parts, butyl alcohol etherified melamine-formaldehyde resin 6-9 parts, methyl-prop
Olefin(e) acid 5-8 parts, acrylic acid 16-18 parts, fumaric acid 12-15 parts, maleic anhydride 16-20 parts, tri-phenyl-ethyl phosphonium bromide
0.5-1 parts, hydroquinones 0.6-0.9 parts, styrene 48-50 parts, itaconic anhydride 13-15 parts, cohesion modifiers 3-8 parts.
2. a kind of vinylite being easy to concrete binding according to claim 1, it is characterised in that by weight
Number meter includes：38 parts of bisphenol A formaldehyde epoxy resin, 7 parts of polyurethane modified epoxy resin, butyl alcohol etherified melamine-formaldehyde resin
6 parts, 8 parts of methacrylic acid, 16 parts of acrylic acid, 15 parts of fumaric acid, 16 parts of maleic anhydride, 1 part of tri-phenyl-ethyl phosphonium bromide,
0.6 part of hydroquinones, 50 parts of styrene, 13 parts of itaconic anhydride, 8 parts of cohesion modifiers.
3. a kind of vinylite being easy to concrete binding according to claim 1, it is characterised in that by weight
Number meter includes：41 parts of bisphenol A formaldehyde epoxy resin, 5 parts of polyurethane modified epoxy resin, butyl alcohol etherified melamine-formaldehyde resin
9 parts, 5 parts of methacrylic acid, 18 parts of acrylic acid, 12 parts of fumaric acid, 20 parts of maleic anhydride, tri-phenyl-ethyl phosphonium bromide 0.5
Part, 0.9 part of hydroquinones, 48 parts of styrene, 15 parts of itaconic anhydride, 3 parts of cohesion modifiers.
4. a kind of vinylite being easy to concrete binding according to claim 1 or 2 or 3, it is characterised in that institute
State cohesion modifiers count by weight including：Cellulose acetate 2-5 parts, itaconic acid 8-12 parts, nano zine oxide 0.3-0.5
Part, cesium hydroxide 0.1-0.2 parts.
5. a kind of vinylite being easy to concrete binding according to claim 4, it is characterised in that the bonding
Modifying agent count by weight including：5 parts of cellulose acetate, 12 parts of itaconic acid, 0.5 part of nano zine oxide, cesium hydroxide 0.1
Part.
6. a kind of vinylite being easy to concrete binding according to claim 1, it is characterised in that also including viscous
Knot built agent, bonding built agent includes methyl methacrylate 5-8 parts, ethylene glycol ether acetate 3-4 parts, dichlorophenyl silicon
Alkane 4-6 parts, 4 parts of maleic acid, ethylene glycol 3-5 parts, 1-2 parts of N- bromo-succinimides, 4,4'- DADPS 0.5-
2 parts.
7. a kind of vinylite being easy to concrete binding according to claim 6, it is characterised in that bond compounding
Agent include 8 parts of methyl methacrylate, 3 parts of ethylene glycol ether acetate, 6 parts of dichloro base silane, 4 parts of maleic acid,
3 parts of ethylene glycol, 2 parts of N- bromo-succinimides, 4,4'- 0.5 part of DADPSs.
8. a kind of vinylite being easy to concrete binding according to claim 1, it is characterised in that also including receiving
1-2 parts of titanium dioxide of rice.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611243655.7A CN106832794A (en) | 2016-12-29 | 2016-12-29 | A kind of vinylite being easy to concrete binding |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611243655.7A CN106832794A (en) | 2016-12-29 | 2016-12-29 | A kind of vinylite being easy to concrete binding |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106832794A true CN106832794A (en) | 2017-06-13 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611243655.7A Pending CN106832794A (en) | 2016-12-29 | 2016-12-29 | A kind of vinylite being easy to concrete binding |
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| Country | Link |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1884422A (en) * | 2006-05-22 | 2006-12-27 | 中国科学院广州化学研究所 | Modified ethenyl resin grouting material and its preparation method and construction method |
| CN104878743A (en) * | 2015-03-24 | 2015-09-02 | 中交上海三航科学研究院有限公司 | Prestressed reinforced concrete pile foundation anticorrosive material for oceaneering and its construction method |
| CN105017729A (en) * | 2015-08-21 | 2015-11-04 | 永悦科技股份有限公司 | Synthetic method of efficient flame-retardant epoxy vinyl ester resin |
-
2016
- 2016-12-29 CN CN201611243655.7A patent/CN106832794A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1884422A (en) * | 2006-05-22 | 2006-12-27 | 中国科学院广州化学研究所 | Modified ethenyl resin grouting material and its preparation method and construction method |
| CN104878743A (en) * | 2015-03-24 | 2015-09-02 | 中交上海三航科学研究院有限公司 | Prestressed reinforced concrete pile foundation anticorrosive material for oceaneering and its construction method |
| CN105017729A (en) * | 2015-08-21 | 2015-11-04 | 永悦科技股份有限公司 | Synthetic method of efficient flame-retardant epoxy vinyl ester resin |
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Application publication date: 20170613 |