CN106833063A - A kind of wet type electrostatic precipitator vinylite - Google Patents
A kind of wet type electrostatic precipitator vinylite Download PDFInfo
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- CN106833063A CN106833063A CN201611243406.8A CN201611243406A CN106833063A CN 106833063 A CN106833063 A CN 106833063A CN 201611243406 A CN201611243406 A CN 201611243406A CN 106833063 A CN106833063 A CN 106833063A
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- parts
- electrostatic precipitator
- wet type
- type electrostatic
- vinylite
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
Abstract
The present invention relates to technical field of macromolecules, and in particular to a kind of wet type electrostatic precipitator vinylite.Meter includes by weight：35 38 parts of o-cresol formaldehyde epoxy resin, 69 parts of polyurethane modified epoxy resin, 13 parts of butyl ether benzoguanamine resin, 13 15 parts of methacrylic acid, 15 18 parts of acrylic acid, 89 parts of fumaric acid, 11 13 parts of maleic anhydride, 0.5 1 parts of tri-phenyl-ethyl phosphonium bromide, 0.6 08 parts of hydroquinones, 38 42 parts of styrene, 8 parts of fire retardant, 38 parts of phenolic aldehyde compounding ingredient.Product prepared by the present invention, is a kind of vinylite suitable for wet type electrostatic precipitator, its good insulation preformance, with excellent mechanical property, can be worked in the larger environment of humidity for a long time, with good antiseptic property and fire resistance, can admirably meet the requirement of wet type electrostatic precipitator.
Description
Technical field
The present invention relates to technical field of macromolecules, and in particular to a kind of wet type electrostatic precipitator vinylite.
Background technology
Unsaturated polyester resin, is usually contracted by unsaturated dibasic acid dihydroxylic alcohols or monounsaturated dicarboxylic acid unsaturation dihydroxylic alcohols
The poly- chain macromolecule compound with ester bond and unsaturated double-bond.Generally, polyesterification polycondensation reaction be 190~
220 DEG C are carried out, until reaching expected acid number (or viscosity), after polyesterification contracting reaction terminates, a certain amount of second are added while hot
Alkenyl monomer, is made into sticky liquid, and such polymer solution is referred to as unsaturated polyester resin.
So far, unsaturated polyester (UP) (resin) matrix as matrices of composite material is substantially O-phthalic acid type both at home and abroad
(referred to as adjacent benzene-type), M-phthalic acid type (abbreviation metaphenylene), bisphenol A-type and vinyl ester type, halo unsaturated polyester resin
Deng.
Vinylite is vinyl ester resin, is a kind of epoxy resin and a kind of unsaturated monoacid containing ethylene linkage
Addition reaction product, and diluted through a kind of reactive monomer.Vinylite has good decay resistance, has asphalt mixtures modified by epoxy resin concurrently
The excellent mechanical property of fat and the good characteristic of unsaturated polyester resin normal temperature cure.The resin base made of vinylite is combined
Material, is widely used at aspects such as chemical anticorrosion, flue gas desulfurization, communications and transportation, electronic apparatus.
But the mechanical property of vinylite can not meet needs, traditional like product, its extension property is not excellent enough,
Influence its using effect.As reactivity is not high, insulating properties, antiseptic property and fire resistance are not enough.
The content of the invention
The invention aims to solve the above problems, there is provided a kind of wet type electrostatic precipitator vinylite.
In order to reach foregoing invention purpose, the present invention uses following technical scheme：
A kind of wet type electrostatic precipitator vinylite, by weight meter include：O-cresol formaldehyde epoxy resin 35-38
Part, polyurethane modified epoxy resin 6-9 parts, 1-3 parts of butyl ether benzoguanamine resin, methacrylic acid 13-15 parts, acrylic acid
15-18 parts, fumaric acid 8-9 parts, maleic anhydride 11-13 parts, tri-phenyl-ethyl phosphonium bromide 0.5-1 parts, hydroquinones 0.6-
08 part, styrene 38-42 parts, 8 parts of fire retardant, 3-8 parts of phenolic aldehyde compounding ingredient.
The present invention in order to meet requirement of the humidity compared with long-term work under overall situation, for wet type electrostatic precipitator to prior art
Improved, compounded using o-cresol formaldehyde epoxy resin, polyurethane modified epoxy resin, butyl ether benzoguanamine resin,
Fire retardant is added simultaneously, to meet actual requirement.In addition, mechanical property, anti-corrosion of the present invention using phenolic aldehyde compounding ingredient to product
Performance is improved, and it is possessed excellent mechanical property and is actually needed with meeting.
Preferably, meter includes by weight：35 parts of o-cresol formaldehyde epoxy resin, 9 parts of polyurethane modified epoxy resin, fourth
1 part of ether benzoguanamine resin, 15 parts of methacrylic acid, 15 parts of acrylic acid, 9 parts of fumaric acid, 11 parts of maleic anhydride, three
1 part of phenylethyl phosphonium bromide, 0.6 part of hydroquinones, 42 parts of styrene, 8 parts of fire retardant.
Preferably, meter includes by weight：38 parts of o-cresol formaldehyde epoxy resin, 6 parts of polyurethane modified epoxy resin, fourth
3 parts of ether benzoguanamine resin, 13 parts of methacrylic acid, 18 parts of acrylic acid, 8 parts of fumaric acid, 13 parts of maleic anhydride, three
0.5 part of phenylethyl phosphonium bromide, 08 part of hydroquinones, 38 parts of styrene, 8 parts of fire retardant.
Preferably, the phenolic aldehyde compounding ingredient is counted including urethanes 3-6 parts, citraconic acid dimethyl ester 5- by weight
7 parts, Methacrylamide 5-6 parts, 3-5 parts of dichloro base silane, dimethylformamide 0.8-1.5 parts, maleic acid 6
Part, ethyl acetate 1-2 parts, 4,4'- DADPS 0.5-2 parts.
Phenolic aldehyde compounding ingredient can improve bending strength and tensile strength, and keep preferable extension to a certain extent
Rate.
Preferably, the phenolic aldehyde compounding ingredient is counted including 3 parts of urethanes by weight, 7 parts of citraconic acid dimethyl ester,
5 parts of Methacrylamide, 5 parts of dichloro base silane, 0.8 part of dimethylformamide, 6 parts of maleic acid, ethyl acetate 2
Part, 4,4'- 0.5 part of DADPSs.
Preferably, the phenolic aldehyde compounding ingredient is counted including 6 parts of urethanes by weight, 5 parts of citraconic acid dimethyl ester,
6 parts of Methacrylamide, 3 parts of dichloro base silane, 1.5 parts of dimethylformamide, 6 parts of maleic acid, ethyl acetate 1
Part, 4,4'- 2 parts of DADPSs.
Preferably, also including ethyl cellulose 2-3 parts,
Preferably, also including titanate esters 2-4 parts.
Preferably, the titanate esters are butyl titanate or butyl titanate.
Product prepared by the present invention, is a kind of vinylite suitable for wet type electrostatic precipitator, its good insulation preformance, tool
There is excellent mechanical property, can be worked in the larger environment of humidity for a long time, with good antiseptic property and fire resistance,
The requirement of wet type electrostatic precipitator can admirably be met.
Specific embodiment
Explanation is further described to technical scheme below by specific embodiment.
If without specified otherwise, the raw material employed in embodiments of the invention is raw material commonly used in the art, implements
Method employed in example, is the conventional method of this area.
Embodiment 1：
A kind of wet type electrostatic precipitator vinylite, its formula is specific as follows：O-cresol formaldehyde epoxy resin 35kg, poly- ammonia
Ester modified epoxy resin 9kg, butyl ether benzoguanamine resin 1kg, methacrylic acid 15kg, acrylic acid 15kg, fumaric acid
9kg, maleic anhydride 11kg, tri-phenyl-ethyl phosphonium bromide 1kg, hydroquinones 0.6kg, styrene 42kg, fire retardant 8kg phenol
Aldehyde compounding ingredient 3kg；
Specifically, the ratio combination according to the following ratio of phenolic aldehyde compounding ingredient：6 parts of urethanes, 5 parts of citraconic acid dimethyl ester,
6 parts of Methacrylamide, 3 parts of dichloro base silane, 1.5 parts of dimethylformamide, 6 parts of maleic acid, ethyl acetate 1
Part, 4,4'- 2 parts of DADPSs.
Embodiment 2：
A kind of wet type electrostatic precipitator vinylite, its formula is specific as follows：O-cresol formaldehyde epoxy resin 38kg, poly- ammonia
Ester modified epoxy resin 6kg, butyl ether benzoguanamine resin 3kg, methacrylic acid 13kg, acrylic acid 18kg, fumaric acid
8kg, maleic anhydride 13kg, tri-phenyl-ethyl phosphonium bromide 0.5kg, hydroquinones 08kg, styrene 38kg, fire retardant 8kg,
Phenolic aldehyde compounding ingredient 8kg,
Specifically, the ratio combination according to the following ratio of phenolic aldehyde compounding ingredient：3 parts of urethanes, 7 parts of citraconic acid dimethyl ester,
5 parts of Methacrylamide, 5 parts of dichloro base silane, 0.8 part of dimethylformamide, 6 parts of maleic acid, ethyl acetate 2
Part, 4,4'- 0.5 part of DADPSs.
Embodiment 3：
On the basis of embodiment 1, ethyl cellulose 2kg is added, titanate esters 4kg, titanate esters are butyl titanate.
Embodiment 4：
On the basis of embodiment 2, ethyl cellulose 3kg is added, titanate esters 2kg, titanate esters are butyl titanate.
Compared with Example 1, its resistivity is improved, and specially resistivity improves 3- for embodiment 3 and embodiment 4
5%.Therefore, embodiment 3 and embodiment 4 possess more preferable insulating properties.
Embodiment described above is a kind of preferably scheme of the invention, not makees any formal to the present invention
Limitation, also has other variants and remodeling on the premise of without departing from the technical scheme described in claim.
Claims (9)
1. a kind of wet type electrostatic precipitator vinylite, it is characterised in that meter includes by weight：O-cresol formaldehyde asphalt mixtures modified by epoxy resin
Fat 35-38 parts, polyurethane modified epoxy resin 6-9 parts, 1-3 parts of butyl ether benzoguanamine resin, methacrylic acid 13-15
Part, acrylic acid 15-18 parts, fumaric acid 8-9 parts, maleic anhydride 11-13 parts, tri-phenyl-ethyl phosphonium bromide 0.5-1 parts, to benzene
Diphenol 0.6-08 parts, styrene 38-42 parts, 8 parts of fire retardant, 3-8 parts of phenolic aldehyde compounding ingredient.
2. a kind of wet type electrostatic precipitator vinylite according to claim 1, it is characterised in that count by weight
Including：35 parts of o-cresol formaldehyde epoxy resin, 9 parts of polyurethane modified epoxy resin, 1 part of butyl ether benzoguanamine resin, methyl
15 parts of acrylic acid, 15 parts of acrylic acid, 9 parts of fumaric acid, 11 parts of maleic anhydride, 1 part of tri-phenyl-ethyl phosphonium bromide, hydroquinones
0.6 part, 42 parts of styrene, 8 parts of fire retardant, 3 parts of phenolic aldehyde compounding ingredient.
3. a kind of wet type electrostatic precipitator vinylite according to claim 1, it is characterised in that count by weight
Including：38 parts of o-cresol formaldehyde epoxy resin, 6 parts of polyurethane modified epoxy resin, 3 parts of butyl ether benzoguanamine resin, methyl
13 parts of acrylic acid, 18 parts of acrylic acid, 8 parts of fumaric acid, 13 parts of maleic anhydride, 0.5 part of tri-phenyl-ethyl phosphonium bromide, to benzene two
08 part of phenol, 38 parts of styrene, 8 parts of fire retardant, 8 parts of phenolic aldehyde compounding ingredient.
4. a kind of wet type electrostatic precipitator vinylite according to claim 1,2 or 3, it is characterised in that the phenol
Aldehyde compounding ingredient is counted including urethanes 3-6 parts, 5-7 parts of citraconic acid dimethyl ester, Methacrylamide 5-6 by weight
Part, 3-5 parts of dichloro base silane, dimethylformamide 0.8-1.5 parts, 6 parts of maleic acid, ethyl acetate 1-2 parts, 4,
0.5-2 parts of 4'- DADPSs.
5. a kind of wet type electrostatic precipitator vinylite according to claim 4, it is characterised in that the phenolic aldehyde coordinates
Agent is counted including 3 parts of urethanes, 7 parts of citraconic acid dimethyl ester, 5 parts of Methacrylamide, dichlorophenyl by weight
5 parts of silane, 0.8 part of dimethylformamide, 6 parts of maleic acid, 2 parts of ethyl acetate, 4,4'- 0.5 part of DADPSs.
6. a kind of wet type electrostatic precipitator vinylite according to claim 4, it is characterised in that the phenolic aldehyde coordinates
Agent is counted including 6 parts of urethanes, 5 parts of citraconic acid dimethyl ester, 6 parts of Methacrylamide, dichlorophenyl by weight
3 parts of silane, 1.5 parts of dimethylformamide, 6 parts of maleic acid, 1 part of ethyl acetate, 4,4'- 2 parts of DADPSs.
7. a kind of wet type electrostatic precipitator vinylite according to claim 1, it is characterised in that also fine including ethyl
2-3 parts of element of dimension.
8. a kind of wet type electrostatic precipitator vinylite according to claim 1, it is characterised in that also including titanate esters
2-4 parts.
9. a kind of wet type electrostatic precipitator vinylite according to claim 8, it is characterised in that the titanate esters are
Butyl titanate or butyl titanate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611243406.8A CN106833063A (en) | 2016-12-29 | 2016-12-29 | A kind of wet type electrostatic precipitator vinylite |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611243406.8A CN106833063A (en) | 2016-12-29 | 2016-12-29 | A kind of wet type electrostatic precipitator vinylite |
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| Publication Number | Publication Date |
|---|---|
| CN106833063A true CN106833063A (en) | 2017-06-13 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611243406.8A Pending CN106833063A (en) | 2016-12-29 | 2016-12-29 | A kind of wet type electrostatic precipitator vinylite |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4480077A (en) * | 1982-10-12 | 1984-10-30 | Dow Chemical Co | Heat resistant vinyl ester resin composition |
| CN102604000A (en) * | 2012-03-26 | 2012-07-25 | 华东理工大学华昌聚合物有限公司 | Synthetic method and application of epoxy vinyl ester resin with high bromine content |
| CN103497287A (en) * | 2013-09-09 | 2014-01-08 | 华东理工大学华昌聚合物有限公司 | Synthetic technology of epoxy vinyl ester resin for SMC/BMC |
| CN103910855A (en) * | 2012-12-29 | 2014-07-09 | 常州华科聚合物股份有限公司 | Vinyl ester resin and preparation method thereof |
| CN105017729A (en) * | 2015-08-21 | 2015-11-04 | 永悦科技股份有限公司 | Synthetic method of efficient flame-retardant epoxy vinyl ester resin |
-
2016
- 2016-12-29 CN CN201611243406.8A patent/CN106833063A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4480077A (en) * | 1982-10-12 | 1984-10-30 | Dow Chemical Co | Heat resistant vinyl ester resin composition |
| CN102604000A (en) * | 2012-03-26 | 2012-07-25 | 华东理工大学华昌聚合物有限公司 | Synthetic method and application of epoxy vinyl ester resin with high bromine content |
| CN103910855A (en) * | 2012-12-29 | 2014-07-09 | 常州华科聚合物股份有限公司 | Vinyl ester resin and preparation method thereof |
| CN103497287A (en) * | 2013-09-09 | 2014-01-08 | 华东理工大学华昌聚合物有限公司 | Synthetic technology of epoxy vinyl ester resin for SMC/BMC |
| CN105017729A (en) * | 2015-08-21 | 2015-11-04 | 永悦科技股份有限公司 | Synthetic method of efficient flame-retardant epoxy vinyl ester resin |
Non-Patent Citations (2)
| Title |
|---|
| 张耀明等: "《玻璃纤维与矿物棉全书》", 31 March 2001, 化学工业出版社 * |
| 韩长日等: "《药物制造技术》", 31 March 2000, 科学技术文献出版社 * |
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Application publication date: 20170613 |