CN106832455A - Emulsion foaming sponge of sleep and preparation method thereof, application can be promoted - Google Patents
Emulsion foaming sponge of sleep and preparation method thereof, application can be promoted Download PDFInfo
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- CN106832455A CN106832455A CN201710107421.8A CN201710107421A CN106832455A CN 106832455 A CN106832455 A CN 106832455A CN 201710107421 A CN201710107421 A CN 201710107421A CN 106832455 A CN106832455 A CN 106832455A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
- C08L7/02—Latex
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47C—CHAIRS; SOFAS; BEDS
- A47C27/00—Spring, stuffed or fluid mattresses or cushions specially adapted for chairs, beds or sofas
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47G—HOUSEHOLD OR TABLE EQUIPMENT
- A47G9/00—Bed-covers; Counterpanes; Travelling rugs; Sleeping rugs; Sleeping bags; Pillows
- A47G9/10—Pillows
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47G—HOUSEHOLD OR TABLE EQUIPMENT
- A47G9/00—Bed-covers; Counterpanes; Travelling rugs; Sleeping rugs; Sleeping bags; Pillows
- A47G9/10—Pillows
- A47G2009/1018—Foam pillows
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/14—Applications used for foams
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Otolaryngology (AREA)
- Pulmonology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
The invention discloses emulsion foaming sponge that can promote sleep and preparation method thereof, application.The emulsion foaming sponge, its raw material includes following components according to mass parts：100 parts of Heveatexes, 0.5~3.0 part of vulcanizing agent, 0.5~3.0 part of foaming agent and 0.1~5.0 part of aromatic essential oil microcapsules.Pillow or mattress that emulsion foaming sponge of the invention is made, due to comprising aromatic essential oil microcapsules, aromatic essential oil composition can be sustained out such that it is able to promote calm nerves, ease off the pressure, console mood to promote sleep.
Description
Technical field
The present invention relates to the technical field of Natural Rubber Latex Products, in particular to the emulsion foaming sea that can promote sleep
Silk floss and preparation method thereof, application.
Background technology
In recent years, the bed of the increasingly enhancing with health perception, pillow, mattress etc is improved rapidly with living standards of the people
Bed linens industry is just welcoming booming spring.The selected pure natural latex juice of emulsion foaming foam pillow/mattress is refined and formed,
Production process is naturally environment friendly and pollution-free without poisonous and harmful substance；Itself has certain mite-proofing and antimicrobial ability；Its is cellular
Design can reach good air permeable effect, the heat that Quick diffusing human body is produced；Its unique soft touch and latex high resiliency
Body contour can be complied with, human vertebra is relied on, makes your vertebra into the optimal straight line without any burden, reach healthy peace
Steady comfortable sleep, it is deep to be liked by consumers in general as material is filled in bedding most hot in recent years.
At present on latex pillow/mattress research, a few patents report is had both at home and abroad, but to improve or improving sleep matter
The patent of amount is actually rare.Patent of invention CN105795810A provides a kind of preparation side with the pillow for improving the health care of sleep effect
Method, adds the materials such as magnetite, tea seed, cassia seed, cornu bubali wherein, with tranquilizing soporific, shortens time for falling asleep, reduction night
Between wake up operations, lifting sleep quality effect.Patent of invention CN105394990A can be improved the health care of sleep the invention discloses one kind
The method of the pillow of quality, it utilizes the drug effects such as Herba Cistanches, safflower, cucumber, tender Folium Pterocaryae to pass through pillow permeability
Design, during sleep head temperature the active ingredient of medicine in pillow is slowly discharged, by the aromatic odor volatilized after drug regimen
And the stimulation to head channels and collaterals, with reach feel at ease with fixed attention, regulation qi and blood, nourishing and suppressing Yang, improve sleep quality effect.And have
Be that the purpose for improving the health care of sleep is reached by designing.Utility model patent 200820059573.1 discloses a kind of latex health-care
The preparation of pillow, the hole of at least more than one extended along pillow length direction is offered on the both sides of pillow width,
Function rod is plugged with each hole.Described pillow upper surface is provided with some massage convex points.The function rod can have
There are various functions, to realize improving the health care of sleep effect of quality, the function rod can adjust the soft durometer of pillow, can scientifically rib
Shoulder protector and waist support, while the effect of also there is massage.The patent of utility model 03236550.0 discloses comfortable health care nano pillow,
Nano material is also using outside pillow-cases increases spatter property and hygiene, and prolonging longitudinal axis in the pillow of pillow has one
Meet the camber sleep groove of head part's physiological curve, quality, the generation of pre- preventing cervical spondylosis are improved the health care of sleep to greatest extent.
The content of the invention
In view of this, one aspect of the present invention is to provide a kind of emulsion foaming sponge, the pillow that the emulsion foaming sponge is made
Head or mattress have the fragrance ingredient of calm nerves, can promote sleep.
A kind of emulsion foaming sponge that can promote to sleep, its raw material includes following components according to mass parts：100 parts natural
Latex, 0.5~3.0 part of vulcanizing agent, 0.5~3.0 part of foaming agent and 0.1~5.0 part of aromatic essential oil microcapsules.
Further, its raw material also includes 0.5~2 part of coagulator according to mass parts.
Further, its raw material also includes 1.0~5.0 parts of foam stabilisers according to mass parts.
Further, its raw material also includes 0.5~2 part of latex stabilizer according to mass parts.
Further, its raw material also includes 1.0~5.0 portions of activating agents according to mass parts；
Preferably, its raw material also includes 0.5~2.5 part of accelerator according to mass parts；
Preferably, its raw material also includes 1.0~1.5 parts of age resistor according to mass parts；
Preferably, its raw material also includes 1.0~10 parts of fillers according to mass parts.
Further, it is Lavender, Rosa Damascana, sweet osmanthus essence to prepare the crude oil of the aromatic essential oil microcapsules
Oil, repeatedly lemon, essential oil, jasmine essential oil, bergamot oil, chamomile essential oil, Atlas cedar essential oil, nutmeg
Oil, oil of ginger, thyme linaloe oil, the one kind in cypress oil, orange oil and styrax essential oil or at least two kinds.
Further, the foaming agent is potassium oleate；
Preferably, the coagulator is sodium silicofluoride and ammonium sulfate；
Preferably, the mass ratio of the sodium silicofluoride and ammonium sulfate is 1：2；
Preferably, the foam stabiliser is gelatin；
Preferably, the stabilizer is potassium hydroxide；
Preferably, the activating agent is zinc oxide；
Preferably, the accelerator is accelerator ZDC；
Preferably, the age resistor is antideteriorant BHT 264；
Preferably, described filler is calcium carbonate.
Another aspect of the present invention is to provide a kind of preparation method of the emulsion foaming sponge that can promote sleep, by the preparation
Pillow or mattress that emulsion foaming sponge obtained by method is made, the fragrance ingredient with calm nerves can promote sleep.
A kind of preparation method of such as above-mentioned emulsion foaming sponge, comprises the following steps：
Component comprising Heveatex and vulcanizing agent is cured, obtains curing Heveatex；
To successively be foamed comprising foaming agent, aromatic essential oil microcapsules and the curing Heveatex, be sent out
Bubble presoma；
And, vulcanize the foaming presoma.
Further, the temperature of the vulcanization is 70~95 DEG C.
Pillow or mattress that emulsion foaming sponge of the invention is made, due to comprising aromatic essential oil microcapsules, can
It is sustained out aromatic essential oil composition such that it is able to promote calm nerves, ease off the pressure, console mood to promote sleep.
Specific embodiment
Unless otherwise defined, all technologies used herein and scientific terminology have and the common skill of art of the present invention
The identical implication that art personnel are generally understood that.When there is contradiction, the definition in this specification is defined.
Term as used herein：
" by ... prepare " it is synonymous with "comprising".Term "comprising" used herein, " including ", " having ", " containing "
Or its any other deformation, it is intended that cover including for non-exclusionism.For example, composition, step, method comprising listed elements,
Product or device are not necessarily limited to those key elements, and can be including not expressly listed other key elements or this kind of composition, step
Suddenly, method, product or the intrinsic key element of device.
Conjunction " by ... constitute " exclude any key element do not pointed out, step or component.If be used in claim,
This phrase will make claim be closed, it is not included the material in addition to the material that those are described, but relative
Except customary impurities.When phrase " by ... constitute " be rather than immediately following after theme in the clause that appears in claim main body
When, it is only limited to the key element described in the clause；Other key elements be not excluded as the overall claim it
Outward.
Equivalent, concentration or other values or parameter are excellent with scope, preferred scope or a series of upper limit preferred values and lower limit
During the Range Representation that choosing value is limited, this is appreciated that and specifically discloses by any range limit or preferred value and any scope
All scopes that any pairing of lower limit or preferred value is formed, regardless of whether whether the scope separately discloses.For example, when open
During scope " 1~5 ", described scope should be interpreted as including scope " 1~4 ", " 1~3 ", " 1~2 ", " 1~2 and 4~
5 ", " 1~3 and 5 " etc..When number range is described herein, unless otherwise indicated, otherwise the scope is intended to include its end
Value and all integers and fraction within the range.
" mass parts " refer to the basic measurement unit of the mass ratio relation for representing multiple components, and 1 part can represent arbitrary list
Position quality, can such as be expressed as 1g, may also indicate that 2.689g etc..If we say that the mass parts of component A are a parts, the matter of B component
Amount part is b parts, then it represents that the quality of component A and the mass ratio a of B component：b.Or, the quality for representing component A is aK, B groups
The quality divided is bK (K is Arbitrary Digit, represents multiplying factor).Can not misread, and unlike mass fraction, all components
Mass parts sum be not limited to 100 parts of limitation.
"and/or" is used to represent that one of illustrated situation or both may to occur, for example, A and/or B includes (A
And B) and (A or B)；
Additionally, the indefinite article " one kind " and " one " before key element of the present invention or component are to key element or the quantitative requirement of component
(i.e. occurrence number) unrestriction.Therefore " one " or " one kind " should be read as including one or at least one, and odd number
The key element or component of form also include plural form, unless the obvious purport of the quantity refers to singulative.
The emulsion foaming sponge that can promote to sleep of the invention, its raw material includes following components according to mass parts：100 parts of days
Right latex, 0.5~3.0 part of vulcanizing agent, 0.5~3.0 part of foaming agent and 0.1~5.0 part of aromatic essential oil microcapsules.Specifically
Ground, the mass parts of vulcanizing agent can for 0.50 part, 0.52 part, 0.55 part, 0.6 part, 0.8 part, 1 part, 1.5 parts, 1.8 parts, 2 parts,
2.5 parts, 2.8 parts or 3 parts etc.；The mass parts of foaming agent can for 0.50 part, 0.52 part, 0.55 part, 0.6 part, 0.8 part, 1 part,
1.5 parts, 1.8 parts, 2 parts, 2.5 parts, 2.8 parts or 3 parts etc.；The mass parts of aromatic essential oil microcapsules can for 0.1 part, 0.15
Part, 0.3 part, 0.5 part, 1 part, 2 parts, 2.5 parts, 3.0 parts, 4.0 parts, 4.5 parts, 4.8 parts or 5.0 parts etc..
It should be noted that 100 parts of Heveatex is that in terms of the dry glue of Heveatex, it is 60% typically to use concentration
Concentrated natural latex.Citing is got on very well, and 167 parts of dry rubber contents are 60% natural emulsion, and its Heveatex is exactly 100 parts.If former
Material latex concentration is too low, causes to coordinate the latex concentration for completing less than 52-55%, influences follow-up foam process quality, seriously
When sponge can be caused to collapse completely bubble.
Above-mentioned aromatic essential oil microcapsules are to make a kind of shell-core obtained by microencapsulation treatment to aromatic essential oil
(being capsule core with aromatic essential oil) composite.Herein, microencapsulation treatment is using natural or synthesis macromolecule material
Material, solid or liquid substance embedding are got up, and form the microencapsulation technology with semipermeable or sealing cyst membrane.Microcapsules skill
Art can improve the physical property of wrapped material, active component is come with external environment isolation, can effectively extend essential oil
Fragrance remaining time；With control release function, slow down fragrance rate of release；The stability of active component is improved, strengthens stability.It is micro-
The specific implementation of encapsulated treatment can use known technology, for example, refer to periodical literature " Xu Shitao, Zhang Hongjuan, Wei Jie
Deng the preparation and its perfuming cigarette evaluation of microcapsules Rosa Damascana, Yunnan University's journal (natural science edition), 2013 (S1):
293-295 ", or such as periodical literature " Zhang Li, the research of Lavender essential oil microcapsule technology, East China University of Science, 2005, China
Shanghai ", or " Liu Wanlong, complex coacervation prepares the research of Lavender essential oil microcapsule and its performance characterization, Shanghai such as periodical literature
Application technology institute, 2014, Chinese Shanghai ", or such as Chinese patent CN103861537A, CN 102746450A, be not limited in
This.
Above-mentioned aromatic essential oil microcapsules are with plants essential oil as core.In the present invention, aromatic essential oil microcapsules
It is the extraction distinctive aromatic substance of plant, is taken from herbal flower, leaf, root, bark, fruit, seed, resin etc. to steam
Evaporate, squeezing mode extract.Essential oil contains the composition of Antimicrobial preservative, there is antibacterial, antimicrobial and antivirus action, helps
In the immunologic function of enhancing body, various germs, the attack of virus are resisted in help, also capable of purifying air；Essential oil contains hormone, dimension
The compositions such as raw element, antibiotic, can provide soma with nutrition.The most important speciality of essential oil is smell, or simple and elegant pure and fresh, or virtue
Aromatic strongly fragrant, itself is a kind of active material, can stimulate the nervous system of human body, and the psychology and physiology to the mankind have well
Curative effect is acted on.Fragrance smell is acted in smell, and small aromatic molecules can more cause psychology and physiology on nervous centralis
The reaction of different levels, directly stimulates the secretion of pituitary gland, and ferment and hormone secretion etc., function in balanced body play U.S.
Hold the effect of skin care.Such as grape fruit has functions that the angry mood of control, and repeatedly perfume (or spice) contributes to treatment mental fatigue and nerve to decline
It is weak, fish pelargonium can balance phychology, slow down pressure, eliminate anxiety, lavender releive balance, decompression relax dormancy etc.,
It is numerous.Essential oil has without chemical pigment, without preservative, without mineral grease, without the chemical composition for causing allergy
The features such as, safety and environmental protection.
Herein, the plants essential oil (i.e. crude oil) of aromatic essential oil microcapsules can include Lavender, Rosa Damascana,
Osmanthus essential oil, repeatedly lemon, essential oil, jasmine essential oil, bergamot oil, chamomile essential oil, Atlas cedar essential oil, meat
Cardamom oil, oil of ginger, thyme linaloe oil, the one kind in cypress oil, orange oil and styrax essential oil or at least two kinds.
Above-mentioned vulcanizing agent can include sulphur or peroxide vulcanizing agent, preferably sulphur.Peroxide vulcanizing agent is for example
BIBP is ([double DCP (cumyl peroxide), BPMC (1,1- bis(t-butylperoxy) -3,3,5- trimethyl-cyclohexanes)
(tert-butylperoxyiso-propyl) benzene]), BCP (tert-butyl cumyl peroxide peroxide) etc..
Above-mentioned foaming agent is anionic surfactant, such as SDS, SDBS, AS, SAS, can also be non-ionic surface
Activating agent, such as OP-10, APG, TWEEN Series (polysorbate60, Tween 80), cationic surfactant such as glycine betaine, CPDB, miaow
Azoles type surfactant, or amphoteric surfactant, such as dodecyl ammonium propionic acid inner salt, the present invention are preferably oleic acid system
Row, such as potassium oleate, preferably ammonium oleate (ammonium oleate can be substituted by the mixture of potassium oleate and ammonium sulfate).
Used as emulsion foaming sponge of the invention, its raw material can also include 0.5~2 part of coagulator.The effect of coagulator
The foam produced by foaming agent is easy for be molded (as by mould), in order to follow-up vulcanization.Generally use slow gelling
Hair is used in combination with heat sensitization gelling process, to reach optimal gelatinization results, while reducing the consumption of gelling agent.Coagulator can be included
Sodium silicofluoride, ammonium sulfate, ammonium chloride, ammonium acetate, polyetheracetal, ethylene methyl aldehyde etc..Ammonium salts substances are produced with zinc oxide
Zinc ammonium complex ion is produced in the case of being heated and promotes foamed latex to be gelled.Preferably sodium silicofluoride is compounded with ammonium sulfate.Fluosilicic
The consumption of sour sodium is 0-1.0 parts, consumption 0-1.0 parts of ammonium sulfate, the optimum proportioning 1 of the two:2.Ammonium sulfate can not with zinc oxide
Add simultaneously, one of which must be added before solidification.
Used as emulsion foaming sponge of the invention, its raw material can also include 1.0~5.0 parts of foam stabilisers.Foam is steady
The effect for determining agent is that in foaming process, control system has appropriate surface tension, produces good bubble network structure.Bubble
Foam stabilizers can include gelatin, Arabic gum, synthetic gum tragacanth, polyacrylamide, polyacrylate, oxidation of alkyl dimethyl
Amine, n-dodecanol, lauramide, many saccharic acids, Stearyl Amine, triethanolamine, carboxymethylcellulose calcium etc., preferably gelatin.
Used as emulsion foaming sponge of the invention, its raw material can also include 0.5~2 part of latex stabilizer.Latex stabilization
The effect of agent is that Heveatex is stablized before foaming to avoid demulsification gelling.Latex stabilizer can include hydrogen-oxygen
Change potassium, ammoniacal liquor, Strong oxdiative sodium, sodium pyrophosphate, tertiary sodium phosphate etc..
Used as emulsion foaming sponge of the invention, its raw material can also include 1.0~5.0 portions of activating agents.Activating agent can be excellent
Elect zinc oxide as, certainly can also be known other forms, such as magnesia.
Used as emulsion foaming sponge of the invention, its raw material also includes 0.5~2.5 part of accelerator according to mass parts.Promote
Agent is preferably accelerator ZDC.Herein, the entitled zinc diethyl dithiocarbamate of accelerator ZDC chemistry, is also called accelerator
EZ.Accelerator can also be known other forms, such as captax.
Used as emulsion foaming sponge of the invention, its raw material also includes 1.0~1.5 parts of age resistor according to mass parts.It is anti-old
Agent is preferably antideteriorant BHT 264.Herein, antideteriorant BHT 264 is antioxidant 264, alias antioxidant 264,6- di-t-butyls pair
Cresols etc..
Used as emulsion foaming sponge of the invention, its raw material also includes 1.0~10 parts of fillers according to mass parts.Filler can be
Calcium carbonate, magnesium silicate, calcium silicates, white carbon etc., preferably calcium carbonate.
Except above-mentioned, dispersant can be also added certainly.Dispersant can include methylene sodium dinaphthalenesulfonate, sodium tripolyphosphate, gather
Vinyl alcohol etc..Consumption as dispersant can make conventional adjustment as needed.
The preparation method of the present invention such as above-mentioned emulsion foaming sponge, comprises the following steps：
Component comprising Heveatex and vulcanizing agent is cured, obtains curing Heveatex；
To successively be foamed comprising foaming agent, aromatic essential oil microcapsules and the curing Heveatex, be sent out
Bubble presoma；
And, vulcanize the foaming presoma.
The referring to property of time of above-mentioned curing is 2~5 days.The charging sequence of curing is not particularly limited.
After above-mentioned foaming is finished, coagulator can be added to insert sizing in mould.The temperature of sizing can be 40~50 DEG C.
Above-mentioned, the temperature of vulcanization is 70~95 DEG C.The time of vulcanization can as needed make conventional selection.
Below do not address part and be applied to prior art.
Embodiment 1
Step one, from the base material that concentrated natural latex is pillow or mattress.Heveatex is taken from Brazilian three leaves rubber
Gum juice.In terms of mass fraction, the concentrated natural latex that 1.0 parts of potassium hydroxide and 167 parts of dry rubber contents are 60% is mixed
Uniformly, 2.5 parts of sulphur are separately added into, 1.5 parts of accelerator ZDC, 1.5 parts of antideteriorant BHTs 264 are 100- using mixing speed
The mechanical agitation of 200rmp, is mixed at room temperature, stands curing 2 days after stirring at room temperature, stand-by.
Step 2,5.0 parts of aromatic essential oils of microencapsulations treatment of addition, the plant in above-mentioned mixing Heveatex
Essential oil is 1 comprising Lavender, chamomile essential oil, lemon, the ratio of sweet orange oil:1:1.Continuing after well mixed will
1.5 parts of ammonium sulfate, 2.5 parts of gelatin, 5.0 parts of calcium carbonate stir, and 1.5 parts of vegetable oil acid potassium are added, with the speed of 350rpm
Mechanical agitation produces foam and carries out even bubble treatment, is eventually adding 1.0 parts of sodium silicofluoride and 2.5 zinc oxide, will after stopping stirring
The foam implantation temperature of generation is 40-50 DEG C of pillow mould, when foam is full of in mould, closed die lid, in mould
There is gelling in the presence of gelling agent so as to solidifying and setting in foam.
Step 3, it is 90 DEG C of vaporium or hot air chamber by mould feeding temperature, sulphur occurs in the presence of heating power
Change or solidify, then mould is taken out from vaporium or hot air chamber, remove foam sponge block, cleaning, drying, required for cutting
Shape, be obtained containing lavender, chamomile, lemon, sweet orange mixing fragrance foamed latex foam pillow or mattress.
Embodiment 2
Step one, from the base material that concentrated natural latex is pillow or mattress.In terms of mass fraction, by 1.5 parts of hydroxides
Potassium mixes equal Uniform with the concentrated natural latex that 167 parts of dry rubber contents are 60%, is separately added into 2.0 parts of sulphur, 1.5 parts of accelerator
ZDC, 1.0 parts of antideteriorant BHTs 264, are the mechanical agitation of 100-200rmp using mixing speed, are mixed at room temperature, are stirred
Curing 2 days are stood after mixing uniformly at room temperature, it is stand-by；
Step 2, the treated aromatic essential oil of 4.5 parts of microencapsulations of addition, the plant in above-mentioned mixing Heveatex
Thing essential oil is 2 comprising Lavender, jasmine essential oil, Bergamot, the ratio of styrax essential oil:1:1：1.It is well mixed
After continue to stir in 1.0 parts of ammonium sulfate, 2.0 parts of gelatin, 5.0 parts of calcium carbonate, 1.5 parts of vegetable oil acid potassium is added, with 300-
The speed mechanical stirring of 350rpm produces foam and carries out even bubble treatment, is eventually adding 0.8 part and 2.5 parts oxidation of sodium silicofluoride
Zinc, the foam implantation temperature for stopping to be produced after stirring is 40-50 DEG C of pillow mould, when foam is full of in mould, is closed
There is gelling in the presence of gelling agent so as to solidifying and setting in die cover, the foam in mould；
Step 3, it is 90 DEG C of vaporium or hot air chamber by mould feeding temperature, sulphur occurs in the presence of heating power
Change or solidify, then mould is taken out from vaporium or hot air chamber, remove foam sponge block, cleaning, drying, required for cutting
Shape, be obtained containing lavender, Jasmine, bergamot, styrax mixed flavor foamed latex foam pillow or mattress.
Embodiment 3
Step one, from the base material that concentrated natural latex is pillow or mattress.In terms of mass fraction, by 1.5 parts of hydroxides
Potassium is well mixed with the concentrated natural latex that 167 parts of dry rubber contents are 60%, is separately added into 2.0 parts of sulphur, 2.0 parts of accelerator
ZDC, 1.5 parts of antideteriorant BHTs 264, are the mechanical agitation of 100-200rmp using mixing speed, are mixed at room temperature, are stirred
Curing 2 days are stood after mixing uniformly at room temperature, it is stand-by；
Step 2,3.0 parts of aromatic essential oils of microencapsulations treatment of addition, the fragrance in above-mentioned mixing Heveatex
Plants essential oil crude oil is pure Lavender.Continue 1.5 parts of ammonium sulfate, 2.0 parts of gelatin, 5.0 parts of calcium carbonate after well mixed
Stir, add 1.5 parts of vegetable oil acid potassium, produce foam and carry out at even bubble with the speed mechanical stirring of 300-350rpm
Reason, is eventually adding 1.0 parts and 1.5 parts zinc oxide of sodium silicofluoride, and the foam implantation temperature for stopping to be produced after stirring is 40-50 DEG C
Pillow mould, when foam is full of in mould, closed die lid, the foam in mould is gelled in the presence of gelling agent
So as to solidifying and setting；
Step 3, it is 90 DEG C of vaporium or hot air chamber by mould feeding temperature, sulphur occurs in the presence of heating power
Change or solidify, then mould is taken out from vaporium or hot air chamber, remove foam sponge block, cleaning, drying, required for cutting
Shape, is obtained foamed latex foam pillow or mattress containing Lavender fragrance.
Embodiment 4
Step one, from the base material that concentrated natural latex is pillow or mattress.In terms of mass fraction, by 0.5 part of hydroxide
Potassium mixes equal Uniform with the concentrated natural latex that 167 parts of dry rubber contents are 60%, is separately added into 0.5 part of sulphur, 0.5 part of accelerator
ZDC, 1.0 parts of antideteriorant BHTs 264, are the mechanical agitation of 100-200rmp using mixing speed, are mixed at room temperature, are stirred
Curing 2 days are stood after mixing uniformly at room temperature, it is stand-by；
Step 2, the treated aromatic essential oil of 0.1 part of microencapsulation of addition, the plant in above-mentioned mixing Heveatex
Thing essential oil is 2 comprising Lavender, jasmine essential oil, Bergamot, the ratio of styrax essential oil:1:1：1.It is well mixed
After continue to stir in 0.5 part of ammonium sulfate, 1.0 parts of gelatin, 1.0 parts of calcium carbonate, 0.5 part of vegetable oil acid potassium is added, with 300-
The speed mechanical stirring of 350rpm produces foam and carries out even bubble treatment, is eventually adding 0.5 part and 1.0 parts oxidation of sodium silicofluoride
Zinc, the foam implantation temperature for stopping to be produced after stirring is 40-50 DEG C of pillow mould, when foam is full of in mould, is closed
There is gelling in the presence of gelling agent so as to solidifying and setting in die cover, the foam in mould；
Step 3, it is 90 DEG C of vaporium or hot air chamber by mould feeding temperature, sulphur occurs in the presence of heating power
Change or solidify, then mould is taken out from vaporium or hot air chamber, remove foam sponge block, cleaning, drying, required for cutting
Shape, be obtained containing lavender, Jasmine, bergamot, styrax mixed flavor foamed latex foam pillow or mattress.
Embodiment 5
Step one, from the base material that concentrated natural latex is pillow or mattress.In terms of mass fraction, by 2.0 parts of hydroxides
Potassium mixes equal Uniform with the concentrated natural latex that 167 parts of dry rubber contents are 60%, is separately added into 3.0 parts of sulphur, 2.5 parts of accelerator
ZDC, 1.5 parts of antideteriorant BHTs 264, are the mechanical agitation of 100-200rmp using mixing speed, are mixed at room temperature, are stirred
Curing 2 days are stood after mixing uniformly at room temperature, it is stand-by；
Step 2, the treated aromatic essential oil of 5 parts of microencapsulations of addition, the plant in above-mentioned mixing Heveatex
Essential oil is 2 comprising Lavender, jasmine essential oil, Bergamot, the ratio of styrax essential oil:1:1：1.After well mixed
Continuation stirs 2.0 parts of ammonium sulfate, 5.0 parts of gelatin, 10 parts of calcium carbonate, 3.0 parts of vegetable oil acid potassium is added, with 300-
The speed mechanical stirring of 350rpm produces foam and carries out even bubble treatment, is eventually adding 2.0 parts and 5.0 parts oxidations of sodium silicofluoride
Zinc, the foam implantation temperature for stopping to be produced after stirring is 40-50 DEG C of pillow mould, when foam is full of in mould, is closed
There is gelling in the presence of gelling agent so as to solidifying and setting in die cover, the foam in mould；
Step 3, it is 90 DEG C of vaporium or hot air chamber by mould feeding temperature, sulphur occurs in the presence of heating power
Change or solidify, then mould is taken out from vaporium or hot air chamber, remove foam sponge block, cleaning, drying, required for cutting
Shape, be obtained containing lavender, Jasmine, bergamot, styrax mixed flavor foamed latex foam pillow or mattress.
Because the number range of each technological parameter involved in the present invention can not possibly all embody in the above-described embodiments,
As long as but those skilled in the art's envisioned any numerical value fallen into the above-mentioned number range completely can implement this
Invention, also includes any combination of occurrence in the range of some numerical value certainly.Herein, for the consideration of length, eliminate to
Go out the embodiment of occurrence in certain one or more number range, this disclosure for being not to be construed as technical scheme is not filled
Point.
Applicant states that the present invention illustrates detailed process equipment of the invention and technological process by above-described embodiment,
But the invention is not limited in above-mentioned detailed process equipment and technological process, that is, do not mean that the present invention has to rely on above-mentioned detailed
Process equipment and technological process could be implemented.Person of ordinary skill in the field it will be clearly understood that any improvement in the present invention,
Addition, concrete mode selection to the equivalence replacement and auxiliary element of each raw material of product of the present invention etc., falls in protection of the invention
In the range of.
Claims (10)
1. a kind of energy promotes the emulsion foaming sponge of sleep, it is characterised in that its raw material includes following components according to mass parts：
100 parts of Heveatexes, 0.5~3.0 part of vulcanizing agent, 0.5~3.0 part of foaming agent and 0.1~5.0 part of micro- glue of aromatic essential oil
Capsule.
2. emulsion foaming sponge according to claim 1, it is characterised in that its raw material also includes 0.5~2 according to mass parts
Part coagulator.
3. emulsion foaming sponge according to claim 2, it is characterised in that its raw material according to mass parts also comprising 1.0~
5.0 parts of foam stabilisers.
4. emulsion foaming sponge according to claim 3, it is characterised in that its raw material also includes 0.5~2 according to mass parts
Part latex stabilizer.
5. emulsion foaming sponge according to claim 4, it is characterised in that its raw material according to mass parts also comprising 1.0~
5.0 portions of activating agents；
Preferably, its raw material also includes 0.5~2.5 part of accelerator according to mass parts；
Preferably, its raw material also includes 1.0~1.5 parts of age resistor according to mass parts；
Preferably, its raw material also includes 1.0~10 parts of fillers according to mass parts.
6. emulsion foaming sponge according to claim 1, it is characterised in that prepare the aromatic essential oil microcapsules
Crude oil is Lavender, Rosa Damascana, osmanthus essential oil, repeatedly lemon, essential oil, jasmine essential oil, bergamot oil, ocean
Camomile essential oil, Atlas cedar essential oil, mace oil, oil of ginger, thyme linaloe oil, in cypress oil, orange oil and styrax essential oil
One kind or at least two kinds.
7. emulsion foaming sponge according to claim 5, it is characterised in that the foaming agent is potassium oleate；
Preferably, the coagulator is sodium silicofluoride and ammonium sulfate；
Preferably, the mass ratio of the sodium silicofluoride and ammonium sulfate is 1：2；
Preferably, the foam stabiliser is gelatin；
Preferably, the latex stabilizer is potassium hydroxide；
Preferably, the activating agent is zinc oxide；
Preferably, the accelerator is accelerator ZDC；
Preferably, the age resistor is antideteriorant BHT 264；
Preferably, described filler is calcium carbonate.
8. a kind of preparation method of the emulsion foaming sponge as described in claim 1~7 any one, it is characterised in that including with
Lower step：
Component comprising Heveatex and vulcanizing agent is cured, obtains curing Heveatex；
To successively be foamed comprising foaming agent, aromatic essential oil microcapsules and the curing Heveatex, before being foamed
Drive body；
And, vulcanize the foaming presoma.
9. preparation method according to claim 8, it is characterised in that the temperature of the vulcanization is 70~95 DEG C.
10. a kind of application of emulsion foaming sponge as claimed in claim 1, it is characterised in that it is used as to make pillow or mattress.
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| CN110982113B (en) * | 2019-12-25 | 2022-06-28 | 中国热带农业科学院橡胶研究所 | Aloe latex foaming product |
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