KR20030091127A - Ceramic ball produce aroma and far-infrared ray and their preparation method - Google Patents

Ceramic ball produce aroma and far-infrared ray and their preparation method Download PDF

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KR20030091127A
KR20030091127A KR1020020028567A KR20020028567A KR20030091127A KR 20030091127 A KR20030091127 A KR 20030091127A KR 1020020028567 A KR1020020028567 A KR 1020020028567A KR 20020028567 A KR20020028567 A KR 20020028567A KR 20030091127 A KR20030091127 A KR 20030091127A
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fragrance
natural
ceramic ball
minutes
ceramic
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Korean (ko)
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하윤식
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하윤식
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/14—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silica
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/32—Burning methods
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/0068—Ingredients with a function or property not provided for elsewhere in C04B2103/00
    • C04B2103/0097—Anion- and far-infrared-emitting materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/131—Inorganic additives

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Cosmetics (AREA)

Abstract

PURPOSE: Provided is a ceramic ball emitting a fragrance and far infrared rays, which improves water purification, stimulates blood circulation and metabolism and has deodorizing, nerve stabilizing and skin beauty-treating effects. CONSTITUTION: The ceramic ball is produced by the method comprising the steps of: mixing natural powder such as loess, jade, elvan and tourmalin or a synthetic far-infrared ray radiating material with an antibacterial ceramic powder such as an oyster shell powder, nano-silver and nano-copper, alone or a mixture of two or more materials, together with water, removing air in a pug mill or a compressor, forming into the shape of a ball in a cutter and a molder, and drying at 100-300 deg.C and optionally baking at 50-1000 deg.C to form a ceramic ball; preparing natural fragrance such as lavender, rose, peppermint or the like in the form of emulsion containing 5-50 wt% of the natural fragrance or a microcapsule containing 3-50 wt% of the natural fragrance; dipping the ceramic ball into a solution of the natural fragrance emulsion or microcapsule diluted at 10-100 wt%, stirring for about 5 minutes to 36 hours to adsorb the fragrance on the ceramic ball, and then drying at 25-130 deg.C for 10 seconds to 360 minutes and curing for 5 seconds to 30 minutes at 100-210 deg.C, or curing at 25-250 deg.C for 5 seconds to 600 minutes without drying in order to form the ceramic ball emitting fragrance and far infrared rays.

Description

향기와 원적외선을 발생하는 세라믹볼 및 그 제조방법{Ceramic ball produce aroma and far-infrared ray and their preparation method}Ceramic ball producing aroma and far-infrared ray and their preparation method

본 발명은 다량의 원적외선을 복사하는 향기나는 세라믹 볼의 제조에 관한 것으로서, 좀 더 상세하게는 다량의 원적외선을 복사하는 세라믹 볼을 제조한 후, 각종 치료효과를 발휘하는 천연향을 에멀젼화하거나 또는 마이크로캡슐화하여 세라믹 볼에 충분히 흡착시켜 건조함으로서 다양한 효과를 얻을 수 있는 향기나는 세라믹 볼의 제조에 관한 것이다.The present invention relates to the manufacture of a fragrant ceramic ball that radiates a large amount of far infrared rays, and more particularly to producing a ceramic ball that radiates a large amount of far infrared rays, and then emulsifying the natural fragrance exerting various therapeutic effects or The present invention relates to the manufacture of aromatic ceramic balls which can be microencapsulated and sufficiently adsorbed onto ceramic balls and dried.

종래의 세라믹 볼은 단순히 원적외선을 복사하는 특성에 따라 온 열치료기 또는 미용용 및 피부건강용으로 사용하거나 그렇지 않으면 다공성을 갖는 특성에 따라 정수용으로 사용되었다. 따라서 세라믹 볼의 사용에 따른 원적외선 효과를 짧은 시간에 확인하는 것은 어려울 수밖에 없었다.Conventional ceramic balls are simply used for heat treatment or cosmetic and skin health according to the property of radiating far-infrared rays or for water purification according to the property of porosity. Therefore, it was difficult to confirm the far-infrared effect of the use of ceramic balls in a short time.

따라서 본 발명은 이와 같은 종래의 문제점을 해결하기 위하여 발명한 것으로서, 본 발명의 목적은 다량의 원적외선 복사할 수 있는 소재로서 황토, 옥, 맥반석, 토르마린(전기석), 제올라이트, 벤토나이트, 일라이트, 운모류, 목화석, 거정석(페그마타이트), 근청석, 천기석(흑주석), 그리고 숯과 같은 천연물 분말이나 합성 원적외선 복사체 분말을 곤교린(소성굴패각 분말로부터 얻은 탄산칼슘), 나노 은, 나노 동, 나노 아연, 은 또는 동 또는 아연 함유 이산화티타늄, 은 또는 동 또는 아연 함유 등과 같은 항균성 세라믹스 분말을 단독으로 혹은 두 종류 이상을 서로 혼합하여 세라믹 볼을 제조한 뒤 각종 치료효과를 발휘하는 천연향을 에멀젼화하거나 또는 마이크로캡슐화하여 세라믹 볼에 충분히 흡착시킨 후 건조함으로서 그 효능을 극대화하고자 하였다.Therefore, the present invention is invented to solve such a conventional problem, the object of the present invention is a material capable of radiating a large amount of far-infrared, ocher, jade, ganban stone, tourmaline (tourmaline), zeolite, bentonite, illite, mica Gonguirin (calcium carbonate from plastic oyster shell powder), nano silver, nano copper, nano zinc, natural product powder such as charcoal, coarse stone (pegmatite), cordierite, celestial stone (black tin), and charcoal Emulsifying natural fragrances that have various therapeutic effects after producing ceramic balls alone or by mixing two or more types of antimicrobial ceramic powders such as silver, copper or zinc-containing titanium dioxide, silver or copper or zinc-containing Alternatively, microencapsulation is sufficiently adsorbed on ceramic balls and dried to maximize the efficacy. The.

도 1은 방향성 원적외선 세라믹 볼의 제조 공정도이다.1 is a manufacturing process diagram of a directional far infrared ceramic ball.

다량의 원적외선을 복사하기 위한 원적외선 복사체는 황토, 옥, 맥반석, 토르마린(전기석), 제올라이트, 벤토나이트, 일라이트, 운모류, 목화석, 거정석(페그마타이트), 근청석, 천기석(흑주석), 그리고 숯과 같은 천연물 분말이나 합성 원적외선 복사체 분말과 곤교린(소성굴패각 분말로부터 얻은 탄산칼슘), 나노 은, 나노 동, 은 또는 동 함유 이산화티타늄 등과 같은 항균성 세라믹스 분말을 단독으로 혹은 두 종류 이상을 배합기에서 서로 잘 혼합한 후 물을 첨가하여 충분히 배합하고서 토련기나 압축기에서 탈기한 후 커팅기와 성형기에서 볼을 성형한 뒤, 100∼300℃에서 건조만 하거나 또는 100∼300℃에서 건조 및 500∼1000℃의 소성 공정을 거쳐 세라믹 볼을 제조하였다.Far-infrared radiators for radiating large amounts of far-infrared radiation include ocher, jade, ganbanite, tourmaline, tourmaline, zeolite, bentonite, illite, mica, cotton fossil, megarite (pegmatite), cordierite, celestial stone (black tin), and charcoal The same natural or synthetic far-infrared radiation powder and antimicrobial ceramic powders such as gonkyorin (calcium carbonate obtained from calcined shell shell powder), nano silver, nano copper, silver or copper-containing titanium dioxide are used alone or in combination with each other in a blender. After mixing, the mixture is sufficiently mixed with water, degassed in a refining machine or a compressor, and the balls are formed in a cutter and a molding machine, and then dried at 100 to 300 ° C. or dried at 100 to 300 ° C. and a firing process of 500 to 1000 ° C. To prepare a ceramic ball through.

한편, 다양한 치료효과를 발휘하는 천연향은 에멀젼으로 제조하거나 또는 마이크로캡슐로 제조하였는데, 우선 에멀젼의 제조 공정을 살펴보면, 향료의 종류에 따라 알맞은 유화제를 선택하여 향료에 첨가하여 잘 교반한 후 물을 서서히 첨가하면서 유화하는 역상유화법으로 에멀젼을 제조하였으며, 마이크로캡슐의 경우에는 향료에 분산제를 첨가하고서 물을 넣으면서 잘 교반한 후 캡슐을 만드는 벽체를 첨가하여 가교반응을 통해 제조하였다.On the other hand, natural fragrances exhibiting various therapeutic effects were prepared in emulsions or microcapsules. First, in the process of preparing emulsions, a suitable emulsifier was selected according to the type of fragrance and added to the fragrance, followed by stirring. Emulsion was prepared by the reverse phase emulsification method to slowly emulsify, in the case of microcapsules were prepared by crosslinking reaction by adding a dispersant to the fragrance and stirring well while adding water and then adding a wall to make a capsule.

이렇게 제조한 세라믹 볼을 천연향 에멀젼 용액이나 마이크로캡슐 용액에 넣고 향의 종류에 따라 5분∼36시간 정도 잘 교반함으로서 충분히 천연향을 세라믹 볼에 흡착시킨 다음 25∼130℃에서 건조한 후 100∼210℃에서 경화시키거나 또는 건조없이 25∼250℃에서 경화시킴으로서 다량의 원적외선을 복사하는 향기나는 세라믹 볼을 제조하는 것을 특징으로 한다.Put the ceramic ball thus prepared in a natural fragrance emulsion solution or microcapsule solution and stir well for 5 minutes to 36 hours depending on the type of fragrance. It is characterized by producing a fragrant ceramic ball that radiates a large amount of far infrared rays by curing at 25 ° C. or without drying at 25 ° C.

그런데 천연향의 경우, 에멀젼은 향의 방출속도가 다소 빠르게 나타났으며, 마이크로캡술의 경우에는 3∼6개월 이상 지속적으로 향을 방출하는 특성을 보였다.However, in the case of natural fragrances, the release rate of the emulsion appeared somewhat faster, and in the case of microcapsule, it showed a characteristic of continuously emitting the fragrance for more than 3 to 6 months.

본 발명의 효과는 다량의 원적외선 복사에 의한 물의 활성으로 정화 및 정수 기능의 향상은 물론 많은 공극에 의한 각종 수중 이물질의 흡착 작용이 우수하여 필터작용이 양호함과 동시에 인체의 피로회복 및 혈액순환과 신진대사를 촉진시켜 생명활동을 원활하게 함으로서 항상 쾌적하고 건강한 컨디션을 유지시켜주고, 각종 치료효과를 발휘하는 천연향을 에멀젼화하거나 마이크로캡슐화하여 세라믹 볼에 흡착시킴으로서 공기청향 및 탈취효과, 신경안정효과, 정신집중력 향상, 성기능 향상, 그리고 피부질환치료 및 피부미용효과 등의 다양한 효과를 얻을 수 있다.The effect of the present invention is that the activity of water by a large amount of far-infrared radiation improves the purification and purification function, as well as the adsorption of various foreign substances in the water by a large number of pores, so that the filter action is good and the body's fatigue recovery and blood circulation and Promotes metabolism and facilitates vital activities to maintain a comfortable and healthy condition at all times, and emulsifies or microencapsulates natural fragrances that exert various therapeutic effects and adsorbs them on ceramic balls for air freshening, deodorizing and neurostable effects. In addition, various effects such as improving mental concentration, improving sexual function, and treating skin diseases and skin beauty can be obtained.

Claims (5)

황토, 옥, 맥반석, 토르마린(전기석), 제올라이트, 벤토나이트, 일라이트, 운모류, 목화석, 거정석(페그마타이트), 근청석, 천기석(흑주석), 그리고 숯과 같은 천연물 분말이나 합성 원적외선 복사체 분말과 곤교린(소성굴패각 분말로부터 얻은 탄산칼슘), 나노 은, 나노 동, 은 또는 동 함유 이산화티타늄 등과 같은 항균성 세라믹스 분말을 단독으로 혹은 두 종류 이상을 배합기에서 서로 잘 혼합한 후 물을 첨가하여 충분히 배합하고서 토련기나 압축기에서 탈기한 후 커팅기와 성형기에서 볼을 성형한 뒤, 100∼300℃의 건조 공정을 거쳐 세라믹볼을 제조하거나 또는 100∼300℃의 건조 및 500∼1000℃의 소성 공정을 거쳐 세라믹 볼을 제조하는 제 1과정과,Natural powders such as ocher, jade, elvanite, tourmaline (zeolite), zeolite, bentonite, illite, mica, cotton, macrorite (pegmatite), cordierite, sky stone (black tin), and charcoal, or synthetic far infrared radiant powder Antimicrobial ceramic powders such as Kyolin (calcium carbonate obtained from fired shell shell powder), nano silver, nano copper, silver or copper-containing titanium dioxide, alone or two or more are mixed well in a blender, and then mixed well by adding water. After degassing in a refining machine or a compressor, the balls are formed in a cutter and a molding machine, and then, the ceramic balls are manufactured through a drying process of 100 to 300 ° C., or the ceramic balls are subjected to a drying process of 100 to 300 ° C. and a firing process of 500 to 1000 ° C. The first process of manufacturing the, 다양한 치료효과를 발휘하기 위하여 라벤다, 장미, 박하, 베르가못, 제라늄 그리고 셀비어 등과 같은 천연향을 에멀젼으로 제조하거나 또는 마이크로캡슐로 제조하였다. 먼저 에멀젼의 제조 공정을 살펴보면, 향료의 종류에 따라 알맞은 유화제를 선택하여 향료에 첨가하여 잘 교반한 후 물을 서서히 첨가하면서 유화하는 역상유화법으로 천연향이 5∼50중량%인 에멀젼을 제조하였으며, 마이크로캡슐의 경우에는 향료에 분산제를 넣고 물을 첨가하면서 잘 교반한 후 캡슐을 만들기 위한 벽체를 첨가하고서 가교반응을 통해 천연향이 3∼50중량%인 마이크로 캡슐을 제조하는 제 2과정과,In order to exert various therapeutic effects, natural flavors such as lavender, rose, peppermint, bergamot, geranium, and selvia were prepared in emulsion or microcapsules. First, the emulsion manufacturing process, by selecting the appropriate emulsifier according to the type of fragrance added to the flavor and stirred well, the emulsion was prepared by the reverse phase emulsification method to emulsify with the addition of water gradually to prepare the emulsion with a natural flavor of 5 to 50% by weight. In the case of microcapsules, the second step of preparing a microcapsule having a natural flavor of 3 to 50% by weight through a crosslinking reaction by adding a dispersant to the fragrance, stirring it well while adding water, and adding a wall for making a capsule, 이렇게 제조한 세라믹 볼을 10∼100중량%로 묽힌 천연향 에멀젼 용액이나 마이크로캡슐 용액에 넣고 향의 종류에 따라 5분∼36시간 정도 잘 교반함으로서 충분히 천연향을 세라믹 볼에 흡착시킨 다음 25∼130℃에서 10초∼360분 정도 건조한 후 100∼210℃에서 5초∼30분 정도 경화시키거나 또는 건조없이 25∼250℃에서 5초∼600분 정도 경화시킴으로서 다량의 원적외선을 복사하는 향기나는 세라믹 볼을 제조하는 제 3과정으로 이루어진 것을 특징으로 하는 향기와 원적외선을 발생하는 세라믹 볼 및 그 제조방법.Put the ceramic ball thus prepared in a diluted natural flavor emulsion solution or microcapsule solution to 10 to 100% by weight, and stir well for 5 minutes to 36 hours depending on the type of flavor. Scented ceramic ball that radiates a large amount of far-infrared rays by drying for 10 seconds to 360 minutes at ℃ and curing for 5 seconds to 30 minutes at 100 to 210 ℃ or for 5 seconds to 600 minutes at 25 to 250 ℃ without drying Ceramic ball and a manufacturing method for producing a fragrance and far infrared rays, characterized in that consisting of a third process of manufacturing. 상기 제1항에서 세라믹볼은 황토, 옥, 맥반석, 토르마린(전기석), 제올라이트, 벤토나이트, 일라이트, 운모류, 목화석, 거정석(페그마타이트), 근청석, 천기석(흑주석), 그리고 숯과 같은 천연물 분말이나 합성 원적외선 복사체 분말과 곤교린(소성굴패각 분말로부터 얻은 탄산칼슘), 나노 은, 나노 동, 은 또는 동 함유 이산화티타늄 등과 같은 항균성 세라믹스 분말을 단독으로 혹은 두 종류 이상을 배합기에서 서로 잘 혼합한 후 물을 첨가하여 충분히 배합하고서 토련기나 압축기에서 탈기한 후 커팅기와 성형기에서 볼을 성형한 뒤, 100∼300℃의 건조 공정을 거쳐 세라믹볼을 제조하거나 또는 100∼300℃의 건조 및 500∼1000℃의 소성 공정을 거쳐 제조된 것을 특징으로하는 세라믹 볼.In claim 1, the ceramic ball is natural products such as ocher, jade, elvan, tourmaline, tourmaline, zeolite, bentonite, illite, mica, cotton, macrorite (pegmatite), cordierite, natural stone (black tin), and charcoal. Powders or synthetic far-infrared radiant powders and antimicrobial ceramic powders such as gonkyorin (calcium carbonate obtained from calcined shell shell powder), nano silver, nano copper, silver or copper-containing titanium dioxide, alone or in combination in a blender After mixing with water, the mixture is sufficiently mixed, degassed in a refining machine or a compressor, and the balls are formed in a cutter and a molding machine, and then ceramic balls are manufactured through a drying process at 100 to 300 ° C. or dried at 100 to 300 ° C. and 500 to 1000 ° C. Ceramic ball, characterized in that manufactured through a firing step of ℃. 상기 제1항에서 방향은 다양한 치료효과를 발휘하기 위하여 라벤다, 장미, 박하, 베르가못, 제라늄 그리고 셀비어 등과 같은 천연향을 에멀젼으로 제조하였는데, 에멀젼의 제조 공정을 살펴보면, 향료의 종류에 따라 알맞은 유화제로서 비이온 또는 음이온 계면활성제 또는 고분자 분산제를 선택하여 향료에 첨가하여 잘 교반한 후 물을 서서히 첨가하면서 유화하는 역상유화법으로 천연향이 5∼50중량%로 제조된 것을 특징으로 하는 천연향 에멀젼.In claim 1, the fragrance is a natural fragrance such as lavender, rose, peppermint, bergamot, geranium, and selvia in order to exert various therapeutic effects. Looking at the manufacturing process of the emulsion, a suitable emulsifier according to the type of fragrance The natural fragrance emulsion, characterized in that the natural flavor is prepared by 5 to 50% by weight in a reverse phase emulsification method by selecting a non-ionic or anionic surfactant or a polymer dispersant as an additive to the fragrance and stirring well and then slowly adding water. 상기 제1항에서 방향은 다양한 치료효과를 발휘하기 위하여 라벤다, 장미, 박하, 베르가못, 제라늄 그리고 셀비어 등과 같은 천연향을 마이크로캡슐로 제조하였는데, 마이크로캡슐의 경우에는 향료에 분산제를 넣고 물을 첨가하면서 잘 교반한 후 캡슐을 만들기 위한 벽체를 첨가하고서 가교반응을 통해 천연향이 3∼50중량%로 제조된 것을 특징으로 하는 천연향 마이크로 캡슐.In claim 1, the fragrance is a natural capsule such as lavender, rose, peppermint, bergamot, geranium, and selvia in order to exert various therapeutic effects. In the case of microcapsules, a dispersant is added to the perfume and water is added. Naturally flavored microcapsule, characterized in that the natural flavor is prepared by 3 to 50% by weight through a crosslinking reaction after adding the wall for making the capsule while stirring well. 상기 제1항에서 세라믹 볼을 10∼100중량%로 묽힌 천연향 에멀젼 용액이나 마이크로캡슐 용액에 넣고 향의 종류에 따라 5분∼36시간 정도 잘 교반함으로서 충분히 천연향을 세라믹 볼에 흡착시킨 다음 25∼130℃에서 10초∼360분 정도 건조한 후 100∼210℃에서 5초∼30분 정도 경화시키거나 또는 건조없이 25∼250℃에서 5초∼600분 정도 경화시킴으로서 제조되는 것을 특징으로 하는 다량의 원적외선을 복사하는 향기나는 세라믹 볼.After adhering the ceramic ball to the natural flavor emulsion solution or microcapsule solution diluted to 10 to 100% by weight and stirring well for 5 minutes to 36 hours depending on the type of the flavor, the natural flavor is sufficiently adsorbed onto the ceramic ball, and then 25 It is prepared by drying at ˜130 ° C. for 10 seconds to 360 minutes and curing at 100 to 210 ° C. for 5 seconds to 30 minutes, or curing at 25 to 250 ° C. for 5 seconds to 600 minutes without drying. Fragrant ceramic balls that radiate far infrared rays.
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KR100742503B1 (en) * 2006-03-23 2007-07-24 김영현 Process for manufacturing charcoal core containingliquid fertilizer for accelerating growth of tree
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KR100618075B1 (en) * 2003-08-07 2006-09-01 경상대학교산학협력단 Far infrared rays paint of functional the using loess and manufacture method thereof
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KR101419425B1 (en) * 2012-10-30 2014-07-14 주식회사 중앙환경기술 Manufacturing method of ceramic powder for removing heavy metals and water treatment method thereof
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KR20210112108A (en) * 2020-03-04 2021-09-14 주식회사 성현테크 Components for ceramic ball, manufacturing method of ceramic ball, and ceramic ball manufactured by the method
CN111418889A (en) * 2020-03-16 2020-07-17 云南中烟工业有限责任公司 Neroli oil capsule dry bead, preparation method thereof and application thereof in tobacco
KR20200075810A (en) * 2020-06-22 2020-06-26 홍상열 sulphur spring
WO2023234543A1 (en) * 2022-06-02 2023-12-07 주식회사 세라젬 Ceramic composition for thermal therapy

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