CN106830953A - 一种湿法高强耐碱耐火喷注料 - Google Patents

一种湿法高强耐碱耐火喷注料 Download PDF

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CN106830953A
CN106830953A CN201710085686.2A CN201710085686A CN106830953A CN 106830953 A CN106830953 A CN 106830953A CN 201710085686 A CN201710085686 A CN 201710085686A CN 106830953 A CN106830953 A CN 106830953A
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wet method
jetting material
resistant refractory
powder
strength alkali
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刘春乐
刘勇
程殿勇
徐彬
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Beijing Sea Jincheng Refractories Co Ltd
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Beijing Sea Jincheng Refractories Co Ltd
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Abstract

本发明公开了一种湿法高强耐碱耐火喷注料，按重量百分比计算，组成为：焦宝石40‑50%；莫来石颗粒10‑20%；板状刚玉细粉10‑15%；氧化铝微粉5‑10%；二氧化硅微粉3‑8%；纯铝酸钙水泥5‑10%；复合耐碱粉4‑8%；减水剂0.5‑2%；流平剂0.5‑2%；缓凝剂0.5‑1%；速凝剂0.5‑2%；防爆纤维0.2‑0.5%。本发明的有益效果：通过对现有技术中的喷注料组分进行改进，加高效减水剂和流平剂，使浇注料在极少的加水量下可以达到自流的效果，减少喷注过程中材料运输的困难的问题；经过泵送到枪口上，自流浇注料加入速凝剂使材料喷射到带有锚固钉的钢壳上能够紧密结合，加强喷注成型后喷涂层的强度，加入复合耐碱粉，加强喷注成型后喷涂层的耐碱性能。

Description

一种湿法高强耐碱耐火喷注料
技术领域
本发明涉及一种喷注料，具体来说，涉及一种湿法高强耐碱耐火喷注料。
背景技术
喷注料是利用气动工具以机械喷射方法施工的不定形耐火材料，在喷涂过程中水泥与骨料等组成材料反复连续冲击促使喷射出的物料压实，喷涂层具有较好的致密度和力学强度，在水泥生产线上被广泛使用，具体施工方法根据加水的顺序和用水量分为湿法、半干法和干法喷涂料三种。水泥生产线中预热器和窑头罩由于其处在高碱度及高温度的环境特性，浇注料很容易损坏，出现垮塌现象，而传统的用于湿法的喷注料由于其施工结构复杂，支模费时费力，施工材料运输困难，加水过多导致浇注体强度低下，难以满足预热器和窑头罩对浇注料的要求。
针对相关技术中的问题，目前尚未提出有效的解决方案。
发明内容
针对相关技术中的上述技术问题，本发明提出一种专门用于水泥窖生产线上预热器和窑头罩用的湿法高强耐碱耐火喷注料，能够满足预热器和窑头罩对浇注料的苛刻条件，在极少的加水量下既可以达到自流的效果，将浇注料喷射在带有锚固钉的钢壳上能够进别结合。
为实现上述技术目的，本发明的技术方案是这样实现的：
一种湿法高强耐碱耐火喷注料，其特征在于，按重量百分比计算，组成为：焦宝石40-50%；莫来石颗粒10-20%；板状刚玉细粉10-15%；氧化铝微粉5-10%；二氧化硅微粉3-8%；纯铝酸钙水泥5-10%；复合耐碱粉4-8%；减水剂0.5-2%；流平剂0.5-2%；缓凝剂0.5-1%；速凝剂0.5-2%；防爆纤维0.2-0.5%。
进一步地，按重量百分比计算，所述复合耐碱粉组成为：碳化硅10-20%、锆英砂10-20%、电熔镁砂60-80%。
进一步地，所述减水剂为萘系减水剂。
进一步地，所述缓凝剂为柠檬酸。
进一步地，按重量百分比计算，所述速凝剂组成为：铝氧熟料40%；碳酸钠40%；生石灰20%。
进一步地，焦宝石骨料粒度为1-5mm;莫来石颗粒粒度为1-5mm；板状刚玉细粉粒度为325目；氧化铝微粉粒度为1-3μm；二氧化硅微粉粒度为0.1-0.3μm；纯铝酸钙水泥比表面积5500g/cm2。
本发明所述的喷注料，尤其适合作为水泥窖生产线上预热器和窑头罩使用的湿法高强耐碱耐火喷注料。本发明选用焦宝石（也称为一级硬质粘土熟料）作为浇注料的骨料，要求Al2O3≥44%，Fe2O3<1.5%。焦宝石是一种优质硬质耐火粘土，成分稳定，质地均匀、结构致密，按重量百分比计算，用40-50%的焦宝石及10-20%的莫来石颗粒作为骨料，添加10-15%的板状刚玉细粉，制成的喷注料在使用过程中具有很高的强度。其中，板状刚玉是一种纯净的、不添加如MgO、B2O3等任何添加剂而烧成收缩彻底的烧结刚玉，具有结晶粗大、发育良好的α- Al2O3晶体结构，Al2O3的含量在99%以上。板片状晶体结构，气孔小且闭气孔较多而气孔率与电熔刚玉大体相当，纯度高，体积稳定性好，极小的重烧收缩。莫来石本身具有耐高温、热膨胀小河康化学侵蚀强等特点。采用焦宝石、莫来石颗粒作为喷注料骨料添加板状刚玉得出的成品喷注料韧性强，能够很好地提高成品的强度和抗冲刷性能，高温下抗氧化性能强，不易爆裂，能够显著提喷注料的高使用寿命。
纯铝酸钙水泥作为喷注料的促硬剂，掺加氧化铝微粉，在喷注料混合搅拌时，两种材料同时添加，可以保证喷注料在成型时保证有良好的流动性，在成型后限定的时间内，能使喷注料获得足够的强度。
加入高效减水剂和流平剂的作用是，使材料在极少的加水量可以达到自流效果。经过泵送到枪口上，自流浇注料加入速凝剂使材料喷射到带有锚固钉的钢壳上紧密结合。水的加入量为所述喷注料重量的6-8%左右。其中，高效减水剂与流平剂属于本领域常用试剂材料，可从商业途径获得。减水剂优选为萘系减水剂。
加入缓凝剂与促凝剂可以使喷注料在喷枪口均匀分散，喷到墙体上达到立刻凝固，或是不流淌的效果。其中，缓凝剂使喷注料在出喷枪口前不凝固并达到很好的流动。其中，促凝剂可以使浇注料从枪口喷射至带有锚固钉的钢壳上时，能够与钢壳紧密结合，成型后的浇注料强度高，不会发生垮塌现象。其中，缓凝剂与促凝剂属于本领域常用试剂材料，可从商业途径获得。缓凝剂优选为柠檬酸。本申请还提供一种具体的速凝剂组成：铝氧熟料40%；碳酸钠40%；生石灰20%。
加入复合耐碱粉的作用是，加强喷注料喷注成型后的耐碱性能。按重量百分比计算，所述复合耐碱粉组成为：碳化硅10-20%、锆英砂10-20%、电熔镁砂60-80%。
本发明的有益效果：通过对现有技术中的喷注料组分进行改进，加高效减水剂和流平剂，使浇注料在极少的加水量下可以达到自流的效果，减少喷注过程中材料运输的困难的问题；经过泵送到枪口上，自流浇注料加入速凝剂使材料喷射到带有锚固钉的钢壳上能够紧密结合，加强喷注成型后喷涂层的强度，加入复合耐碱粉，加强喷注成型后喷涂层的耐碱性能。
具体实施方式
以下结合具体实施例对本发明的湿法高强耐碱耐火喷注料作进一步的详细描述，其仅用于解释本发明，不用于限制本发明,本发明所涉及的具体原材料均可从商业途径获得：
实施例一：
焦宝石45Kg；莫来石颗粒15Kg；板状刚玉细粉12Kg；氧化铝微粉6Kg；二氧化硅微粉4Kg；纯铝酸钙水泥6Kg；复合耐碱粉6Kg；减水剂1.5Kg；流平剂1.5Kg；缓凝剂1Kg；速凝剂1.5Kg；防爆纤维0.5Kg。于搅拌设备中充分搅拌均匀后得到成品。
其中，原材料满足如下指标：焦宝石骨料粒度为1-5mm;莫来石颗粒粒度为1-5mm；板状刚玉细粉粒度为325目；氧化铝微粉粒度为1-3μm；二氧化硅微粉粒度为0.1-0.3μm；纯铝酸钙水泥比表面积5500g/cm2。
其中，复合耐碱粉共6Kg，碳化硅0.6Kg，锆英砂0.6Kg，电熔镁砂4.8Kg。
其中，减水剂共1.5Kg，为萘系减水剂。
其中，流平剂共1.5Kg。
其中，缓凝剂共1Kg，为柠檬酸。
其中，速凝剂共1.5Kg，铝氧熟料0.6Kg，碳酸钠0.6Kg，生石灰0.3Kg。
经测定，成品的物理性能满足：110℃×24h体积密度为：2.6g/cm3；110℃×24h抗折强度为：11.6MPa；1450℃×3h抗折强度为：14.5MPa；110℃×24h 耐压强度为：100.2MPa；1450℃×3h耐压强度为：135.1MPa。
实施例二：
焦宝石40Kg；莫来石颗粒18Kg；板状刚玉细粉13Kg；氧化铝微粉7Kg；二氧化硅微粉5Kg；纯铝酸钙水泥5Kg；复合耐碱粉7Kg；减水剂1.2Kg；流平剂1.2Kg；缓凝剂0.8Kg；速凝剂1.5Kg；防爆纤维0.3Kg。于搅拌设备中充分搅拌均匀后得到成品。
其中，原材料满足如下指标：焦宝石骨料粒度为1-5mm;莫来石颗粒粒度为1-5mm；板状刚玉细粉粒度为325目；氧化铝微粉粒度为1-3μm；二氧化硅微粉粒度为0.1-0.3μm；纯铝酸钙水泥比表面积5500g/cm2。
其中，复合耐碱粉共7Kg，碳化硅0.7Kg，锆英砂0.14Kg，电熔镁砂4.9Kg。
其中，减水剂共1.2Kg，为萘系减水剂。
其中，流平剂共1.2Kg。
其中，缓凝剂共0.8Kg，为柠檬酸。
其中，速凝剂共1.5Kg，铝氧熟料0.6Kg，碳酸钠0.6Kg，生石灰0.3Kg。经测定，成品的物理性能满足：110℃×24h体积密度为：2.55g/cm3；110℃×24h抗折强度为：11.2MPa；1450℃×3h抗折强度为：13.2MPa；110℃×24h 耐压强度为：91.2MPa；1450℃×3h耐压强度为：103.5MPa。
实施例三：
焦宝石50Kg；莫来石颗粒11Kg；板状刚玉细粉11Kg；氧化铝微粉8Kg；二氧化硅微粉3Kg；纯铝酸钙水泥9Kg；复合耐碱粉4Kg；减水剂0.8Kg；流平剂1.3Kg；缓凝剂0.8Kg；速凝剂0.8Kg；防爆纤维0.3Kg。于搅拌设备中充分搅拌均匀后得到成品。
其中，原材料满足如下指标：焦宝石骨料粒度为1-5mm;莫来石颗粒粒度为1-5mm；板状刚玉细粉粒度为325目；氧化铝微粉粒度为1-3μm；二氧化硅微粉粒度为0.1-0.3μm；纯铝酸钙水泥比表面积5500g/cm2。
其中，复合耐碱粉共4Kg，碳化硅0.8Kg，锆英砂0.8Kg，电熔镁砂2.4Kg。
其中，减水剂共0.8Kg，为萘系减水剂。
其中，流平剂共1.3Kg。
其中，缓凝剂共0.8Kg，为柠檬酸。
其中，速凝剂共0.8Kg，铝氧熟料0.32Kg，碳酸钠0.32Kg，生石灰0.16Kg。经测定，成品的物理性能满足：110℃×24h体积密度为：2.63g/cm3；110℃×24h抗折强度为：13.5MPa；1450℃×3h抗折强度为：15.3MPa；110℃×24h 耐压强度为：132.2MPa；1450℃×3h耐压强度为：146.3MPa。

Claims (6)

1.一种湿法高强耐碱耐火喷注料，其特征在于，按重量百分比计算，组成为：焦宝石40-50%；莫来石颗粒10-20%；板状刚玉细粉10-15%；氧化铝微粉5-10%；二氧化硅微粉3-8%；纯铝酸钙水泥5-10%；复合耐碱粉4-8%；减水剂0.5-2%；流平剂0.5-2%；缓凝剂0.5-1%；速凝剂0.5-2%；防爆纤维0.2-0.5%。
2.根据权利要求1所述的一种湿法高强耐碱耐火喷注料，其特征在于，按重量百分比计算，所述复合耐碱粉组成为：碳化硅10-20%、锆英砂10-20%、电熔镁砂60-80%。
3.根据权利要求1所述的一种湿法高强耐碱耐火喷注料，其特征在于，所述减水剂为萘系减水剂。
4.根据权利要求1所述的一种湿法高强耐碱耐火喷注料，其特征在于，所述缓凝剂为柠檬酸。
5.根据权利要求1所述的一种湿法高强耐碱耐火喷注料，其特征在于，按重量百分比计算，所述速凝剂组成为：铝氧熟料40%；碳酸钠40%；生石灰20%。
6.根据权利要求1所述的一种湿法高强耐碱耐火喷注料，其特征在于，原材料的满足如下指标：焦宝石骨料粒度为1-5mm;莫来石颗粒粒度为1-5mm；板状刚玉细粉粒度为325目；氧化铝微粉粒度为1-3μm；二氧化硅微粉粒度为0.1-0.3μm；纯铝酸钙水泥比表面积5500g/cm2。
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107266087A (zh) * 2017-06-16 2017-10-20 傅修文 一种节能长寿命铁水溜槽及其制造方法
CN108083743A (zh) * 2018-01-31 2018-05-29 河南东大高温节能材料有限公司 一种室温固化型Al2O3-SiO2系无机高温粘结剂及其制备方法
CN109251008A (zh) * 2018-08-23 2019-01-22 安徽瑞泰新材料科技有限公司 一种高炉用高性能湿法喷涂料及其制备方法
CN109503135A (zh) * 2018-11-28 2019-03-22 江苏恒耐炉料集团有限公司 高强自流型防爆耐火浇注料
CN112351964A (zh) * 2018-07-06 2021-02-09 巴斯夫欧洲公司 用于可流动的耐火材料的组合物
CN113683426A (zh) * 2021-07-29 2021-11-23 浙江自立高温科技股份有限公司 一种免烧的高强度金属陶瓷复合材料及其制备方法和应用

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5930762A (ja) * 1982-08-10 1984-02-18 川崎炉材株式会社 キヤスタブル耐火物
CN102060549A (zh) * 2009-11-16 2011-05-18 中冶建筑研究总院有限公司 一种高炉热态维修用低回弹率喷涂料及其制备方法
CN102093064A (zh) * 2010-12-21 2011-06-15 北京联合荣大工程材料有限责任公司 一种高钢纤维含量的耐火喷涂料及喷涂方法
CN102690123A (zh) * 2012-04-27 2012-09-26 洛阳市科创耐火材料有限公司 一种快干防爆浇注料及其生产工艺
CN102718505A (zh) * 2011-03-31 2012-10-10 上海宝冶集团有限公司 高炉炉内造衬泵送湿法喷涂耐火组合物
CN103058686A (zh) * 2013-01-25 2013-04-24 苏州罗卡节能科技有限公司 中密度耐碱浇注料
CN103496994A (zh) * 2013-09-23 2014-01-08 宜兴市张泽浇注耐火材料有限公司 垃圾焚烧炉用耐火耐酸耐碱浇注料
CN104150929A (zh) * 2014-08-12 2014-11-19 秦皇岛中青冶金阀门有限公司 一种用于风口送风装置的耐火材料及其制作工艺
CN104211412A (zh) * 2014-08-25 2014-12-17 长兴鑫鼎耐火材料厂(普通合伙） 喷煤管预制砖及生产方法

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5930762A (ja) * 1982-08-10 1984-02-18 川崎炉材株式会社 キヤスタブル耐火物
CN102060549A (zh) * 2009-11-16 2011-05-18 中冶建筑研究总院有限公司 一种高炉热态维修用低回弹率喷涂料及其制备方法
CN102093064A (zh) * 2010-12-21 2011-06-15 北京联合荣大工程材料有限责任公司 一种高钢纤维含量的耐火喷涂料及喷涂方法
CN102718505A (zh) * 2011-03-31 2012-10-10 上海宝冶集团有限公司 高炉炉内造衬泵送湿法喷涂耐火组合物
CN102690123A (zh) * 2012-04-27 2012-09-26 洛阳市科创耐火材料有限公司 一种快干防爆浇注料及其生产工艺
CN103058686A (zh) * 2013-01-25 2013-04-24 苏州罗卡节能科技有限公司 中密度耐碱浇注料
CN103496994A (zh) * 2013-09-23 2014-01-08 宜兴市张泽浇注耐火材料有限公司 垃圾焚烧炉用耐火耐酸耐碱浇注料
CN104150929A (zh) * 2014-08-12 2014-11-19 秦皇岛中青冶金阀门有限公司 一种用于风口送风装置的耐火材料及其制作工艺
CN104211412A (zh) * 2014-08-25 2014-12-17 长兴鑫鼎耐火材料厂(普通合伙） 喷煤管预制砖及生产方法

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
夏寿荣等: "《最新混凝土外加剂生产配方精选400例》", 31 January 2014, 中国建材工业出版社 *
黄书谋等: "《第五届全国新型干法水泥生产技术交流会论文集》", 31 August 2003, 中国建材工业出版社 *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107266087A (zh) * 2017-06-16 2017-10-20 傅修文 一种节能长寿命铁水溜槽及其制造方法
CN107266087B (zh) * 2017-06-16 2020-07-14 山东鲁铭高温材料股份有限公司 一种节能长寿命铁水溜槽及其制造方法
CN108083743A (zh) * 2018-01-31 2018-05-29 河南东大高温节能材料有限公司 一种室温固化型Al2O3-SiO2系无机高温粘结剂及其制备方法
CN112351964A (zh) * 2018-07-06 2021-02-09 巴斯夫欧洲公司 用于可流动的耐火材料的组合物
CN109251008A (zh) * 2018-08-23 2019-01-22 安徽瑞泰新材料科技有限公司 一种高炉用高性能湿法喷涂料及其制备方法
CN109503135A (zh) * 2018-11-28 2019-03-22 江苏恒耐炉料集团有限公司 高强自流型防爆耐火浇注料
CN113683426A (zh) * 2021-07-29 2021-11-23 浙江自立高温科技股份有限公司 一种免烧的高强度金属陶瓷复合材料及其制备方法和应用

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