CN106830916B - 一种锰锌功率铁氧体材料及其元件制备方法 - Google Patents

一种锰锌功率铁氧体材料及其元件制备方法 Download PDF

Info

Publication number
CN106830916B
CN106830916B CN201611174772.2A CN201611174772A CN106830916B CN 106830916 B CN106830916 B CN 106830916B CN 201611174772 A CN201611174772 A CN 201611174772A CN 106830916 B CN106830916 B CN 106830916B
Authority
CN
China
Prior art keywords
blank
manganese
core element
magnetic core
ferrite material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201611174772.2A
Other languages
English (en)
Other versions
CN106830916A (zh
Inventor
王宏
曾伟鑫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangxi Sunshine Electronic Technology Co Ltd
Original Assignee
Jiangxi Sunshine Electronic Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangxi Sunshine Electronic Technology Co Ltd filed Critical Jiangxi Sunshine Electronic Technology Co Ltd
Priority to CN201611174772.2A priority Critical patent/CN106830916B/zh
Publication of CN106830916A publication Critical patent/CN106830916A/zh
Application granted granted Critical
Publication of CN106830916B publication Critical patent/CN106830916B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/26—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on ferrites
    • C04B35/2608—Compositions containing one or more ferrites of the group comprising manganese, zinc, nickel, copper or cobalt and one or more ferrites of the group comprising rare earth metals, alkali metals, alkaline earth metals or lead
    • C04B35/2633—Compositions containing one or more ferrites of the group comprising manganese, zinc, nickel, copper or cobalt and one or more ferrites of the group comprising rare earth metals, alkali metals, alkaline earth metals or lead containing barium, strontium or calcium
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/64—Burning or sintering processes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
    • H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
    • H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
    • H01F1/12—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
    • H01F1/34—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials non-metallic substances, e.g. ferrites
    • H01F1/342—Oxides
    • H01F1/344—Ferrites, e.g. having a cubic spinel structure (X2+O)(Y23+O3), e.g. magnetite Fe3O4
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3208—Calcium oxide or oxide-forming salts thereof, e.g. lime
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3224—Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
    • C04B2235/3225—Yttrium oxide or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3239—Vanadium oxides, vanadates or oxide forming salts thereof, e.g. magnesium vanadate
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3244—Zirconium oxides, zirconates, hafnium oxides, hafnates, or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3251—Niobium oxides, niobates, tantalum oxides, tantalates, or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3262—Manganese oxides, manganates, rhenium oxides or oxide-forming salts thereof, e.g. MnO
    • C04B2235/3263—Mn3O4
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3284—Zinc oxides, zincates, cadmium oxides, cadmiates, mercury oxides, mercurates or oxide forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/658—Atmosphere during thermal treatment
    • C04B2235/6583—Oxygen containing atmosphere, e.g. with changing oxygen pressures
    • C04B2235/6584—Oxygen containing atmosphere, e.g. with changing oxygen pressures at an oxygen percentage below that of air
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Power Engineering (AREA)
  • Soft Magnetic Materials (AREA)
  • Magnetic Ceramics (AREA)

Abstract

本发明公开了一种锰锌功率铁氧体材料及其元件制备方法，一种锰锌软磁铁氧体材料，该材料包括主料和辅料，所述主料按摩尔百分比包括：51.5～53.5mol%的Fe2O3、6.5～8.5mol%的ZnO以及余量的Mn3O4，所述辅料为助熔剂、改性剂或增韧剂，其按照所述软磁铁氧体材料的重量计包括：0.03～0.05wt% V2O5、0.01～0.03wt% Nb2O3、0.02～0.04wt% CaCO3、0.05～0.10wt% ZrO2、0.10～0.20wt% Y2O3，其有效提高了磁芯元件的机械强度和韧性。改善了软磁铁氧体磁芯元件的脆性，减少运输时的破损及器件自动化装配中的应用断裂问题。

Description

一种锰锌功率铁氧体材料及其元件制备方法
技术领域
本发明涉及属于氧化物磁性材料技术领域，尤其涉及一种锰锌功率铁氧体材料及其元件制备方法。
背景技术
软磁铁氧体材料作为电子信息产业的基础功能材料自二十世纪60年代研发成功以来，已经走过了材料创新、性能开发、工艺完善三个阶段，现已步入全面应用、提高阶段。近年来由于开关电源、射频通讯、抗电磁干扰、高清晰度电视、新型节能照明及环保等新兴产业的发展，加上家电产业及计算机、程控交换机等工业长盛不衰，世界软磁材料的应用范围及市场需求量一直保持高速增长，其中锰锌功率软磁铁氧体材料及其元件的用量最大，应用最广。
但是作为基础功能材料，铁氧体材料的元件脆性问题一直是行业难题。随着电子产品的小型化、扁平化和国内运输行业暴力作业问题，铁氧体磁芯元件破损客诉非常突出。同时，由于近几年人工成本大幅上升，很多电子企业都开始采用自动化磁芯元件装配设备。这都对铁氧体磁芯元件的机械强度和韧性提出了更高的要求。
发明内容
针对现有技术中存在的不足，本发明的目的是在于提供一种锰锌功率铁氧体材料及其元件制备方法，其有效提高了磁芯元件的机械强度和韧性。改善了软磁铁氧体磁芯元件的脆性，减少运输时的破损及器件自动化装配中的应用断裂问题。
为实现上述目的，本发明通过以下技术方案予以实现：
一种锰锌软磁铁氧体材料，该材料包括主料和辅料，所述主料按摩尔百分比包括：51.5～53.5mol%的Fe2O3、6.5～8.5mol%的ZnO以及余量的Mn3O4，所述辅料为助熔剂、改性剂或增韧剂，其按照所述软磁铁氧体材料的重量计包括：0.03～0.05wt%V2O5、0.01～0.03wt%Nb2O3、0.02～0.04wt% CaCO3、0.05～0.10wt% ZrO2、0.10～0.20wt%Y2O3。
一种锰锌软磁铁氧体材料的制备方法，该方法步骤如下：
（1）粉体制造：
A、配料：将主成分按比例分别加入球磨机，用氧化物湿法工艺进行均匀混合;
B、一次喷雾造粒：将球磨后搅拌均匀的混合料，加入喷雾塔内，进行喷雾造粒;
C、预烧：将喷雾好的一次料用回转窑在780℃～920℃的温度条件下预烧，预烧时间45～60min。预烧时用富氧环境，采用鼓风机向窑内通入空气，使主成分预合成并提高磁化度;
D、掺杂：将预烧料放入砂磨机中，并添加改性剂，进行砂磨，注意控制浆料粒度为1.2～1.6μm;
E、二次喷雾造粒：用喷雾干燥塔进行造粒，使颗粒目数分布在80～160目之间；
（2）冲压成型：
A、在坯件的上下压制方向边角设计倒角，角度范围可以在30度～45度，其目的在于提高坯件的成型密度和强度；
B、在坯件的侧面内外拐角设计工艺圆角，范围在R0.2～R0.65。其目的在于分散应力，改善磁芯元件强度，减少坯件及成品边角碰撞破损；
（3）低温烧结：
A、生坯烧结前，先在露天放置24～72小时，使坯件在空气中膨胀，释放其内部应力，并使坯件内部的颗粒自由舒展；
B、烧结时，采用1320～1350度，保温4～6小时；还原气氛O2含量3～5%，阻止ZnO挥发，使磁芯元件尽可能达到细晶、高密度的内部结构。
综上所述，本发明与现有技术相比，（1）有效提高锰锌功率软磁铁氧体材料及其磁芯元件的机械强度，增强韧性。（2）改善软磁铁氧体磁芯元件的脆性，减少运输时的破损及器件自动化装配中的应用断裂问题。（3）在提高磁芯元件高机械强度的同时，使锰锌功率软磁铁氧体材料具有良好的电磁性能，并保证磁芯元件的尺寸、外观。
具体实施方式
下面结合具体实施方式对发明作进一步的说明：
一种锰锌软磁铁氧体材料，该材料包括主料和辅料，所述主料按摩尔百分比包括：51.5～53.5mol%的Fe2O3、6.5～8.5mol%的ZnO以及余量的Mn3O4，所述辅料为助熔剂、改性剂或增韧剂，其按照所述软磁铁氧体材料的重量计包括：0.03～0.05wt%V2O5、0.01～0.03wt%Nb2O3、0.02～0.04wt% CaCO3、0.05～0.10wt% ZrO2、0.10～0.20wt%Y2O3。
一种如权利要求1所述的锰锌软磁铁氧体材料的制备方法，该方法步骤如下：
（1）粉体制造：
A、配料：将主成分按比例分别加入球磨机，用氧化物湿法工艺进行均匀混合;
B、一次喷雾造粒：将球磨后搅拌均匀的混合料，加入喷雾塔内，进行喷雾造粒;
C、预烧：将喷雾好的一次料用回转窑在780℃～920℃的温度条件下预烧，预烧时间45～60min。预烧时用富氧环境，采用鼓风机向窑内通入空气，使主成分预合成并提高磁化度;
D、掺杂：将预烧料放入砂磨机中，并添加改性剂，进行砂磨，注意控制浆料粒度为1.2～1.6μm;
E、二次喷雾造粒：用喷雾干燥塔进行造粒，使颗粒目数分布在80～160目之间；
（4）冲压成型：
A、在坯件的上下压制方向边角设计倒角，角度范围可以在30度～45度，其目的在于提高坯件的成型密度和强度；
B、在坯件的侧面内外拐角设计工艺圆角，范围在R0.2～R0.65。其目的在于分散应力，改善磁芯元件强度，减少坯件及成品边角碰撞破损；
（5）低温烧结：
A、生坯烧结前，先在露天放置24～72小时，使坯件在空气中膨胀，释放其内部应力，并使坯件内部的颗粒自由舒展；
B、烧结时，采用1320～1350度，保温4～6小时；还原气氛O2含量3～5%，阻止ZnO挥发，使磁芯元件尽可能达到细晶、高密度的内部结构。
实施例一：
一种锰锌软磁铁氧体材料的制备方法，该方法步骤如下：
（1）、粉体制造：
A、配料：将主成分分别加入球磨机用氧化物湿法工艺进行均匀混合，所述主成分由52.3%的Fe2O3、6.8mol%的ZnO以及余量的Mn3O4组成，主成分的含量为100mol%。
B、一次喷雾造粒：将球磨后搅拌均匀的混合料，加入喷雾塔内，进行喷雾造粒。
C、预烧：将喷雾好的一次料用回转窑在850℃的温度条件下预烧，预烧时间45min。预烧时用鼓风机向窑内通入空气，使主成分预合成，尽量提高磁化度。
D、掺杂：将预烧料放入砂磨机中，并添加改性剂，进行砂磨，注意控制浆料粒度为1.3μm。掺杂为0.05wt%V2O5、0.03wt% Nb2O3、0.03wt% CaCO3、0.05wt% ZrO2、0.15wt%Y2O3。
E、二次喷雾造粒：用喷雾干燥塔进行造粒，使颗粒目数分布在80～160目之间。
（2）、冲压成型：
以常规的EE16磁芯元件为例。
A、在坯件的上下压制方向边角设计倒角，角度范围30度。
B、在坯件的侧面内外拐角设计工艺圆角，范围在R0.35。
（3）、低温烧结：
A、生坯烧结前，先在露天放置48小时，使坯件在空气中膨胀，释放其内部应力，并使坯件内部的颗粒自由舒展。
B、烧结时，采用1320度，保温6小时；还原气氛，O2含量4%。阻止ZnO挥发，使磁芯元件尽可能达到细晶、高密度的内部结构。
通过上述实施例制得的锰锌功率软磁铁氧体材料的特性如下：
序号 技术指标名称 测试条件 技术指标
1 初始磁导率μi 25℃ 2400±10%
2 功率损耗Pv（mw/cm3） 100KHz，200mT 350（100℃）
3 饱和磁通密度Bs(mT) 25℃；100℃ 520；400
4 居里温度Tc（℃） \ ≥230
5 磁芯密度d(g/cm3) \ 5.0
通过上述实施例制得的锰锌功率软磁铁氧体磁芯元件EE16的机械强度对比如下：
Figure DEST_PATH_IMAGE002
由此可见，本发明其不仅有效提高锰锌功率软磁铁氧体材料及其磁芯元件的机械强度，增强韧性。且改善软磁铁氧体磁芯元件的脆性，减少运输时的破损及器件自动化装配中的应用断裂问题。还在提高磁芯元件高机械强度的同时，使锰锌功率软磁铁氧体材料具有良好的电磁性能，并保证磁芯元件的尺寸、外观。
对于本领域的技术人员来说，可根据以上技术方案以及构思，做出其他各种相应的改变以及变形，而所有的这些改变和变形都应该属于本发明权利要求的保护范围之内。

Claims (1)

1.一种锰锌软磁铁氧体材料的制备方法，包括主料和辅料，其特征在于，所述主料按摩尔百分比包括： 52.3mol%的Fe2O3、6.8mol%的ZnO以及余量的Mn3O4，所述辅料按照所述软磁铁氧体材料的重量计为： 0.05wt%V2O5、0.03wt% Nb2O3、0.03wt% CaCO3、0.05wt% ZrO2、0.15wt%Y2O3；
具体的制备方法步骤如下：
（1）粉体制造：
A、配料：将主成分按比例分别加入球磨机，用氧化物湿法工艺进行均匀混合;
B、一次喷雾造粒：将球磨后搅拌均匀的混合料，加入喷雾塔内，进行喷雾造粒；
C、预烧：将喷雾好的一次料用回转窑在780℃～920℃的温度条件下预烧，预烧时间45～60min；
预烧时用富氧环境，采用鼓风机向窑内通入空气，使主成分预合成并提高磁化度；
D、掺杂：将预烧料放入砂磨机中，并添加改性剂，进行砂磨，注意控制浆料粒度为1.2～1.6μm；
E、二次喷雾造粒：用喷雾干燥塔进行造粒，使颗粒目数分布在80～160目之间；
（2）冲压成型：
A、在坯件的上下压制方向边角设计倒角，角度范围为30度～45度，其目的在于提高坯件的成型密度和强度；
B、在坯件的侧面内外拐角设计工艺圆角，范围在R0.2～R0.65；
其目的在于分散应力，改善磁芯元件强度，减少坯件及成品边角碰撞破损；
（3）低温烧结：
A、生坯烧结前，先在露天放置24～72小时，使坯件在空气中膨胀，释放其内部应力，并使坯件内部的颗粒自由舒展；
B、烧结时，采用1320～1350度，保温4～6小时；还原气氛O2含量3～5%，阻止ZnO挥发，使磁芯元件尽可能达到细晶、高密度的内部结构。
CN201611174772.2A 2016-12-19 2016-12-19 一种锰锌功率铁氧体材料及其元件制备方法 Active CN106830916B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611174772.2A CN106830916B (zh) 2016-12-19 2016-12-19 一种锰锌功率铁氧体材料及其元件制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611174772.2A CN106830916B (zh) 2016-12-19 2016-12-19 一种锰锌功率铁氧体材料及其元件制备方法

Publications (2)

Publication Number Publication Date
CN106830916A CN106830916A (zh) 2017-06-13
CN106830916B true CN106830916B (zh) 2020-01-10

Family

ID=59140232

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611174772.2A Active CN106830916B (zh) 2016-12-19 2016-12-19 一种锰锌功率铁氧体材料及其元件制备方法

Country Status (1)

Country Link
CN (1) CN106830916B (zh)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107986773B (zh) * 2017-12-01 2021-02-26 常熟市三佳磁业有限公司 一种锰锌铁氧体球料
CN110767405B (zh) * 2019-09-24 2021-03-30 江西尚朋电子科技有限公司 一种高性能软磁材料及其元件制备方法
CN111128515B (zh) * 2020-01-04 2021-06-01 深圳感通科技有限公司 磁芯及含有该磁芯的共模电感器及共模电感器的制备工艺
CN112382456B (zh) * 2020-11-12 2022-02-22 南通三优佳磁业有限公司 一种混合动力汽车电源转换器用软磁铁氧体材料制备方法
CN113200741B (zh) * 2021-05-17 2021-12-07 湖北微硕新材料有限公司 一种5g应用低损耗软磁铁氧体材料及其制备方法
CN113620698B (zh) * 2021-09-03 2022-04-19 江西尚朋电子科技有限公司 一种高性能MnZn软磁铁氧体材料的制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103396111A (zh) * 2013-08-12 2013-11-20 江苏省晶石磁性材料与器件工程技术研究有限公司 一种高频宽温低损耗锰锌铁氧体及其制造工艺
CN103693952A (zh) * 2013-12-04 2014-04-02 江门安磁电子有限公司 一种超低损耗MnZn功率铁氧体材料的制造方法
CN104557007A (zh) * 2014-12-30 2015-04-29 天通控股股份有限公司 一种宽温低损耗功率锰锌铁氧体及其制备方法

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3024891B2 (ja) * 1993-08-17 2000-03-27 川崎製鉄株式会社 Ｍｎ−Ｚｎ系フェライトの製造方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103396111A (zh) * 2013-08-12 2013-11-20 江苏省晶石磁性材料与器件工程技术研究有限公司 一种高频宽温低损耗锰锌铁氧体及其制造工艺
CN103693952A (zh) * 2013-12-04 2014-04-02 江门安磁电子有限公司 一种超低损耗MnZn功率铁氧体材料的制造方法
CN104557007A (zh) * 2014-12-30 2015-04-29 天通控股股份有限公司 一种宽温低损耗功率锰锌铁氧体及其制备方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Y2O3掺杂对Mn-Zn铁氧体结构和磁学性能的影响;邢庆凯等;《第十六届全国高技术陶瓷学术年会摘要集》;20101022;第11页 *

Also Published As

Publication number Publication date
CN106830916A (zh) 2017-06-13

Similar Documents

Publication Publication Date Title
CN106830916B (zh) 一种锰锌功率铁氧体材料及其元件制备方法
CN107311637B (zh) 一种基于核壳结构晶粒制备低功率损耗锰锌铁氧体的方法
CN103664154B (zh) 高频高电阻率Li-Ti-Zn软磁铁氧体材料配方及工艺
CN103058643B (zh) 宽温高叠加低功耗Mn-Zn软磁铁氧体材料及制备方法
CN101404197B (zh) 一种锰锌软磁铁氧体材料及所得磁芯的制备方法
CN108275992B (zh) 宽温低功耗高磁导率锰锌铁氧体材料及其制备方法
CN107129291A (zh) 具有高频低温度系数低损耗MnZn软磁铁氧体材料及其制备方法
CN100368341C (zh) 频率特性优异的高磁导率锰锌系铁氧体及其制备方法
CN105097168A (zh) 一种添加稀土元素的磁芯材料
CN103342554A (zh) 一种宽频低损耗锰锌铁氧体磁性材料及其制备工艺
CN103626484B (zh) 一种宽温镍锌软磁铁氧体及其制备方法
CN110078488B (zh) 一种高Bs宽温低损耗软磁铁氧体材料及其制备方法
CN103613368B (zh) 一种氧化铝纯黑陶瓷材料
CN103524124A (zh) 一种高磁导率MnZn铁氧体材料的烧结方法
CN104072120A (zh) 一种高磁感锰锌铁氧体材料
CN108395233A (zh) 大功率低功耗高频变压器用锰锌铁氧体材料及制备方法
CN104072118A (zh) 一种锰锌铁氧体材料及其制备工艺
CN112694323A (zh) 一种宽温高Bs锰锌铁氧体磁性材料及其制备方法
CN112898008A (zh) 一种低损耗yig铁氧体及其制备方法
CN104817317A (zh) 一种柔性好不易损坏软磁铁氧体材料及其制备方法
CN110767405B (zh) 一种高性能软磁材料及其元件制备方法
CN105399411A (zh) 一种锰锌铁氧体低温烧结工艺
CN105551708A (zh) 一种增材制造磁芯以及使用该磁芯的磁性器件
CN103382102B (zh) 一种低温烧结镍锌铜软磁铁氧体材料及其制备方法
CN105330279A (zh) 一种宽频软磁铁氧体磁芯材料的制备方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
PE01 Entry into force of the registration of the contract for pledge of patent right
PE01 Entry into force of the registration of the contract for pledge of patent right

Denomination of invention: A manganese zinc power ferrite material and its component preparation method

Effective date of registration: 20230803

Granted publication date: 20200110

Pledgee: Industrial Commercial Bank of China Ltd. bronze drum branch

Pledgor: SUNSHINE ELECTRONIC TECHNOLOGY Co.,Ltd.

Registration number: Y2023980050919