CN106830351A - A kind of bio-stimulant repaired for river course, lake, landscape water body and its preparation method and application - Google Patents

A kind of bio-stimulant repaired for river course, lake, landscape water body and its preparation method and application Download PDF

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Publication number
CN106830351A
CN106830351A CN201710004673.8A CN201710004673A CN106830351A CN 106830351 A CN106830351 A CN 106830351A CN 201710004673 A CN201710004673 A CN 201710004673A CN 106830351 A CN106830351 A CN 106830351A
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stimulant
bio
water body
vitamin
application
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CN201710004673.8A
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Chinese (zh)
Inventor
唐晓声
邹权
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Guangda Environmental Restoration (Jiangsu) Co., Ltd.
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Suntime Environmental Remediation Co Ltd
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Priority to CN201710004673.8A priority Critical patent/CN106830351A/en
Publication of CN106830351A publication Critical patent/CN106830351A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/34Biological treatment of water, waste water, or sewage characterised by the microorganisms used
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/105Phosphorus compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/007Contaminated open waterways, rivers, lakes or ponds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment
    • C02F2305/06Nutrients for stimulating the growth of microorganisms
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

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  • Life Sciences & Earth Sciences (AREA)
  • Microbiology (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Micro-Organisms Or Cultivation Processes Thereof (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

This application discloses a kind of bio-stimulant repaired for river course, lake, landscape water body, including following mass percent component:30 50% amino acid, 10 30% vitamins, 10 30% organic acids, 5 15% inorganic salts, 1 5% trace element, 1 5% hormone, 1 5% purine, 1 5% pyrimidine.Bio-stimulant is prepared when using in proportion, and its solution is added in staying water, add concentration for 1 5g/m3.The bio-stimulant can promote microorganism to be grown in poor environment rapid, high volume, form good zoogloea, so as to improve the efficiency of microbial degradation organic pollution, improve water body treatment effect.

Description

A kind of bio-stimulant repaired for river course, lake, landscape water body and its preparation side Method and application
Technical field
The application belongs to environment remediation technical field, and river course, lake, landscape water body are used for more specifically to one kind Bio-stimulant of reparation and its preparation method and application.
Background technology
River course, lake, landscape water are the Main River Systems in city, with urbanization process quickening and industrial or agricultural it is swift and violent Development, city function is stronger and stronger, and water pollution is also severe all the more.A large amount of undressed municipal refuse, industrial wastewater, lifes Sewage living, contaminated soil and atmospheric fallout are continually drained in river course, lake and landscape water, cause the serious of water body Pollution, and threaten the health of the mankind.
Although water body has certain self purification, when the total emission volumn of pollutant has exceeded it from net capacity, water body Original state then can not be voluntarily returned to, the whole environmental system appearance of water body is unbalance, and pollutant increases, and causes some with this Pollutant is material, the preponderant algae amount reproduction in energy source, aquatic ecosystem is seriously damaged, and causes water body Eutrophication.If without cut-out external source pollution in time, the pollutant in water body is cumulative, and aerobic microbiological will largely disappear Oxygen in water consumption body, makes water body change into anaerobic condition, causes anaerobic bacteria amount reproduction, organic matter corruption, decomposition, hair Ferment, is converted into the malodoring substances such as ammonia nitrogen, humus, hydrogen sulfide, methane and mercaptan.OUR is more than during this process causes water body Reoxygenation speed, causes the foul smell of anaerobic environment, generation to escape the water surface, and the heavy metal such as iron, manganese is reduced in water, with the sulphur shape in water Into compounds such as ferrous sulfides, the suspended particulate of a large amount of negatively charged colloids for having adsorbed FeS, MnS is formed, make water body blackening, become It is smelly.
For the improvement that above-mentioned river course, lake, the black foul sewage of landscape water body contaminate, current most efficient method is that biology in situ is repaiied Recovering technology.Microorganism in situ is added using the indigenous microorganism or external source in water body repair polluted-water with efficient, low cost Advantage.The growth and metabolism of microorganism need carbon source, nitrogen source, energy, growth factor, inorganic salts and the big nutriment of water six. But serious nutrient imbalance and environmental hypoxia has occurred in the contaminated water body overwhelming majority, and contain suppression beneficial microbe The toxicant of growth, is unfavorable for the growth metabolism of indigenous microorganism.The change of nutritional condition can change to a certain extent Influence of the environmental factor to growth of microorganism, it is especially true for local microenvironment, such as biochemical system of sewage disposal.
Therefore, in order to overcome the drawbacks described above existing for prior art, spy proposes the application.
The content of the invention
The first purpose of the application is, there is provided a kind of bio-stimulant repaired for river course, lake, landscape water body. The bio-stimulant can stimulate the breeding of the aerobic beneficial bacterium in water body, improve the oxidative decomposition capacity of microbe, And toxicity of the chemical residue to microorganism can be shielded, so as to improve the impact resistance of water body system and the stability of operation.
To achieve these goals, the application is adopted the following technical scheme that:
A kind of bio-stimulant repaired for river course, lake, landscape water body, it is characterised in that described bioactivation Agent includes the component of following mass percent:
Preferably, described amino acid is one or more in histidine, leucine, threonine and glutamic acid;It is described Vitamin be the B B-complex of vitamin B1, vitamin B12 and biotin, preferably described vitamin is vitamin B1, The mass ratio of vitamin B12 and biotin is 1-2:1-2:1-2.
Preferably, described organic acid is citric acid and butanedioic acid, or sodium citrate and sodium succinate, and preferably described has Machine acid is 1-2 for the mass ratio of citric acid and butanedioic acid:The mixture or sodium citrate of 1-2 and the mass ratio of sodium succinate are 1-2:The mixture of 1-2.
Preferably, described inorganic salts are KH2PO4、K2HPO4、MgCl2、CaCl2And NaCl, preferably described inorganic salts are KH2PO4、K2HPO4、MgCl2、CaCl2It is 1-2 with the mass ratio of NaCl:1-2:1-2:1-2:The mixture of 1-2;Described is micro Element is FeSO4、CuSO4、ZnSO4、MnCl2、CoCl2And Na2MoO4, FeSO4、CuSO4、ZnSO4、MnCl2、CoCl2With Na2MoO4Mass ratio be 1-2:1-2:1-2:1-2:1-2:The mixture of 1-2;Described hormone is auxin, gibberellin, thin One or more in born of the same parents' mitogen.
The second purpose of the application is, there is provided a kind of bio-stimulant repaired for river course, lake, landscape water body Preparation method.The preparation method is simple to operation.
To achieve these goals, the application is adopted the following technical scheme that:
5th, a kind of life repaired for river course, lake, landscape water body in a kind of 1-4 such as claim as described in any one The preparation method of thing activator, it is characterised in that the preparation method comprises the following steps:
(1) according to following components and mass percent dispensing:
(2) step (1) each component is mixed, is well mixed it, that is, obtain described bio-stimulant.
The third purpose of the application is, there is provided a kind of bio-stimulant is being carried out during river course, lake, landscape water body repair Application.
To achieve these goals, the application is adopted the following technical scheme that:
A kind of application of bio-stimulant in river course, lake, landscape water body reparation is carried out.
Preferably, the application is comprised the following specific steps that:
A, distilled water is added to be dissolved the bio-stimulant, stirring makes it fully dissolve activation, obtains bioactivation Agent concentration is the mother liquor of 40-60g/L;
B, the mother liquor high-pressure sprayer obtained by step A is uniformly sprayed on the water surface of staying water, or uses water under high pressure Pump is squeezed into the bed mud of staying water so that the concentration of bio-stimulant described in staying water is 1-5g/m3
Preferably, in step A, in the mother liquor, the concentration of bio-stimulant is 50g/L.
Preferably, in step B, the concentration of the bio-stimulant is 3-5g/m3
Preferably, in step A, the time of stirring is 20-40 minutes, and the speed of stirring is 500-1000 revs/min.
The actual conditions of the renewal rate of pollutional load and water body according to water body determine the user of bio-stimulant Case, bio-stimulant processes the final concentration of 1-5g/m of water body3If rate of water exchange is fast, can be secondary in weekly or daily supplement one Thing activator.If pollutional load is big, processed with reference to aeration as needed.
The beneficial effect that the application can be produced includes:
To bio-stimulant described herein is added in water body, there is improvement well to water body system.Bio-stimulant The breeding of the aerobic beneficial bacterium in water body can be stimulated, the oxidative decomposition capacity of microbe is improved, and chemistry can be shielded Residue is to the toxicity of microorganism, so as to improve the impact resistance of system and the stability of operation.
Bio-stimulant in the application includes amino acid, vitamin, mineral matter, organic acid, hormone.Wherein amino acid and Vitamin belongs to growth factor, and Main Function is to participate in metabolism as the prothetic group or coenzyme of enzyme.Organic acid can be used as nutrition The nutriments such as the transport agent of material, complexing trace element, nitrogen, phosphorus are absorbed by the micro-organisms, and are greatly enhanced the utilization of nutrition Rate, while organic acid is also a kind of nutriment of promotion growth of microorganism, sufficient nutrition can increase the activity of microorganism And diversity, multiple-microorganism is more effectively cooperateed with and play a role, more thoroughly degradation of contaminant, and improve the anti-ripple of system Dynamic property.Hormone can promote microorganism to be grown in poor environment rapid, high volume, good zoogloea be formed, so as to improve micro- life The efficiency of thing degradable organic pollutant, improves wastewater treatment efficiency.Meanwhile, it is various that bio-stimulant can also increase microbial species Property, by extending food chain and improving the cycle efficieny of food chain, multiple-microorganism is more effectively cooperateed with and play a role, it is more thorough Bottom ground degradation of contaminant, and improve system resistance to overload shock ability.Amino acid 30- in bio-stimulant provided herein 50%;Vitamin 10-30%;Organic acid 10-30%;Inorganic salts 5-15%;Micro- 1-5%;Hormone 1-5%;Purine 1- 5%;Under the collocation of pyrimidine 1-5%, exactly each component and content, each component collaboration is had an effect in the bioactivator, so that Reach the optimum efficiency of water process.
It is exceeded caused for the nutriment such as Organic Pollution and nitrogen phosphorus in river course, lake, landscape water body in the application Water pollution phenomenon, biology in situ reparation is carried out using bio-stimulant, bio-stimulant can make the soil in weak tendency originally Microorganism tachyauxesis breeding is write, accelerates the degraded of pollutant in water body, using simple, dosage is small, without external microorganism, Nonpoisonous, non-environmental-pollution, it is not necessary to huge and complicated plant equipment, without construction of structures, to surrounding environment also without secondary pollution, And certain biological prosthetic effect can be reached, it is particularly suitable for the in-situ immobilization of landscape water body.Compared with traditional administering method, River course, lake, the black smelly of landscape water body, eutrophication can be in a short time eliminated, recovers its self-purification capacity.
Specific embodiment
With reference to embodiment in detail the application is described in detail, but the application is not limited to these embodiments.
Unless otherwise instructed, the raw material in embodiments herein is bought by commercial sources.
Embodiment 1
Pudong New Area, Shanghai pond, about 500 square metres of area receives surrounding Sewage Pollution for a long time, and the depth of water is average It is 2 meters (being free of sediment layer) that water surface has house refuse and branch fallen leaves floating, water turbidity in dirty-green, and has smelly raw meat Taste.For the polluted-water, it is first according to table 1 and prepares bio-stimulant.
(1) compound method of bio-stimulant
The formula of the bio-stimulant of table 1
Said components are mixed, as bio-stimulant.
(2) application of bio-stimulant
Bio-stimulant 3kg is taken, plus distilled water 60L is dissolved, and stirs 30min, fully dissolving activation, compound concentration is The bio-stimulant mother liquor of 50g/L.Bio-stimulant mother liquor high-pressure sprayer is uniformly sprayed on the water surface of staying water. The final concentration of 3g/m that bio-stimulant is added3
(3) application effect of bio-stimulant
Water remediation is carried out using bio-stimulant, after two weeks, water body index is shown in Table 2.Wherein, before dissolved oxygen DO is by repairing 3.01mg/L increase to 3.94mg/L, it is seen that bio-stimulant can promote the growth of aerobic microbiological, and enhancing water body is answered Oxygen function, so that more effectively degradation of organic substances pollution.NH3- N is reduced to 0.87mg/L by preprosthetic 17.58mg/L, removal Rate reaches 95.05%, illustrates bio-stimulant to NH3The degradation effect highly significant of-N.Total nitrogen is also reduced to from 17.94mg/L 8.16mg/L, clearance is up to 54.52%.Meanwhile, bio-stimulant also has a certain degree of drop to the COD and total phosphorus of polluted-water Solution, clearance respectively reaches 29.53% and 22.22%.
The bio-stimulant of table 2 repairs water body result
The urban industry of embodiment 2, domestic pollution river course
Pudong New Area, Shanghai river course, total length about 3km, 2 meters of depth of water average out to (is free of sediment layer).It is long-term dirty by industry Water and Sewage Pollution, water surface have house refuse and algae to float, water turbidity.Water sampling carries out reality in laboratory Test.For the polluted-water, it is first according to table 3 and prepares bio-stimulant.
(1) compound method of bio-stimulant
The formula of the bio-stimulant of table 3
Said components are mixed, as bio-stimulant.
(2) application of bio-stimulant
Bio-stimulant 10g is taken, plus distilled water 200mL is dissolved, and stirs 30min, fully dissolving activation, compound concentration It is the bio-stimulant mother liquor of 50g/L.By in bio-stimulant mother liquor addition staying water.The end that bio-stimulant is added is dense It is 5g/m to spend3
(3) application effect of bio-stimulant
Water remediation is carried out using bio-stimulant, after two weeks, water body index is shown in Table 4.Wherein, before dissolved oxygen DO is by repairing 4.16mg/L increase to 5.33mg/L, it is seen that bio-stimulant can promote the growth of aerobic microbiological, and enhancing water body is answered Oxygen function, so that more effectively degradation of organic substances pollution.NH3- N is reduced to 0.66mg/L by preprosthetic 7.50mg/L, removal Rate reaches 91.20%, illustrates bio-stimulant to NH3The degradation effect highly significant of-N.Total nitrogen is also reduced to from 7.83mg/L 4.19mg/L, clearance is up to 46.49%.Meanwhile, bio-stimulant also has a certain degree of drop to the COD and total phosphorus of polluted-water Solution, clearance respectively reaches 41.22% and 50.00%.
The bio-stimulant of table 4 repairs water body result
The above, is only several embodiments of the application, any type of limitation is not done to the application, although this Shen Please disclosed as above with preferred embodiment, but and be not used to limit the application, any those skilled in the art are not taking off In the range of technical scheme, make a little variation using the technology contents of the disclosure above or modification is equal to Effect case study on implementation, belongs in the range of technical scheme.

Claims (10)

1. it is a kind of for river course, lake, landscape water body repair bio-stimulant, it is characterised in that described bio-stimulant Component including following mass percent:
2. bio-stimulant according to claim 1, it is characterised in that described amino acid is histidine, leucine, Soviet Union One or more in propylhomoserin and glutamic acid;Described vitamin is the compound dimension of vitamin B1, vitamin B12 and biotin Raw element;It is preferred that described vitamin is 1-2 for the mass ratio of vitamin B1, vitamin B12 and biotin:1-2:1-2's is compound Vitamin.
3. bio-stimulant according to claim 1 and 2, it is characterised in that described organic acid is citric acid and amber Acid, or sodium citrate and sodium succinate;It is preferred that described organic acid is 1-2 for the mass ratio of citric acid and butanedioic acid:1-2's is mixed Compound or sodium citrate and sodium succinate mass ratio are 1-2:The mixture of 1-2.
4. bio-stimulant according to claim 1 and 2, it is characterised in that described inorganic salts are KH2PO4、K2HPO4、 MgCl2、CaCl2With the mixture of NaCl;It is preferred that described inorganic salts are KH2PO4、K2HPO4、MgCl2、CaCl2With the matter of NaCl Amount is than being 1-2:1-2:1-2:1-2:The mixture of 1-2;Described trace element is FeSO4、CuSO4、ZnSO4、MnCl2、CoCl2 And Na2MoO4Mixture;It is preferred that described trace element is FeSO4、CuSO4、ZnSO4、MnCl2、CoCl2And Na2MoO4Quality Than being 1-2:1-2:1-2:1-2:1-2:The mixture of 1-2;Described hormone is in auxin, gibberellin, the basic element of cell division One or more.
5. a kind of biology repaired for river course, lake, landscape water body in a kind of 1-4 such as claim as described in any one swashs The preparation method of agent living, it is characterised in that the preparation method comprises the following steps:
(1) according to following components and mass percent dispensing:
(2) step (1) each component is mixed, is well mixed it, that is, obtain described bio-stimulant.
6. bio-stimulant in a kind of 1-4 such as claim as described in any one and made according to the method for claim 5 Application of the standby bio-stimulant in river course, lake, landscape water body reparation is carried out.
7. application according to claim 6, it is characterised in that the application is comprised the following specific steps that:
A, distilled water is added to be dissolved the bio-stimulant, stirring makes it fully dissolve activation, obtains bio-stimulant dense Spend the mother liquor for 40-60g/L;
B, the mother liquor high-pressure sprayer obtained by step A is uniformly sprayed on the water surface of staying water, or is beaten with high-pressure hydraulic pump In entering the bed mud of staying water so that the concentration of bio-stimulant described in staying water is 1-5g/m3
8. application according to claim 7, it is characterised in that in step A, in the mother liquor, the concentration of bio-stimulant It is 50g/L.
9. application according to claim 7, it is characterised in that in step B, the concentration of the bio-stimulant is 3-5g/ m3
10. application according to claim 7, it is characterised in that in step A, the time of stirring is 20-40 minutes, stirring Speed be 500-1000 revs/min.
CN201710004673.8A 2017-01-04 2017-01-04 A kind of bio-stimulant repaired for river course, lake, landscape water body and its preparation method and application Pending CN106830351A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109160617A (en) * 2018-09-30 2019-01-08 广西走山农牧开发有限公司 The method that water supports plantation sustained release improvement water quality
CN109319946A (en) * 2018-10-30 2019-02-12 深圳大学 A kind of microorganism growth stimulant and preparation method thereof
CN115231715A (en) * 2022-05-27 2022-10-25 湖州中恒园林建设有限公司 Microbial activator

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CN102515364A (en) * 2011-11-03 2012-06-27 袁磊 Broad-spectrum bio-energizer for industrial wastewater treatment and preparation method thereof
CN102815794A (en) * 2012-08-28 2012-12-12 环境保护部华南环境科学研究所 Composite bio-energizer used for in-situ ecological remediation of polluted river sediment
CN106256773A (en) * 2016-08-09 2016-12-28 湖北凌卓生物工程有限公司 A kind of Biostimulation agent rapidly promoting microbial reproduction

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CN102438453A (en) * 2009-04-07 2012-05-02 塔明克股份有限公司 Plant growth regulator additive
CN101591070B (en) * 2009-05-21 2011-07-20 东莞圣源环保科技有限公司 Method for restoring ecology in water body in lake
CN101974569A (en) * 2010-11-01 2011-02-16 黄虹寓 Method for preparing biofuel ethanol by using liquefied cell culture solution
CN102515364A (en) * 2011-11-03 2012-06-27 袁磊 Broad-spectrum bio-energizer for industrial wastewater treatment and preparation method thereof
CN102815794A (en) * 2012-08-28 2012-12-12 环境保护部华南环境科学研究所 Composite bio-energizer used for in-situ ecological remediation of polluted river sediment
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109160617A (en) * 2018-09-30 2019-01-08 广西走山农牧开发有限公司 The method that water supports plantation sustained release improvement water quality
CN109319946A (en) * 2018-10-30 2019-02-12 深圳大学 A kind of microorganism growth stimulant and preparation method thereof
CN115231715A (en) * 2022-05-27 2022-10-25 湖州中恒园林建设有限公司 Microbial activator

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