CN106818784A - A kind of bactericidal composition containing 2-cyano-3-amino-3-phenylancryic acetate and benziothiazolinone - Google Patents
A kind of bactericidal composition containing 2-cyano-3-amino-3-phenylancryic acetate and benziothiazolinone Download PDFInfo
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- CN106818784A CN106818784A CN201710049149.2A CN201710049149A CN106818784A CN 106818784 A CN106818784 A CN 106818784A CN 201710049149 A CN201710049149 A CN 201710049149A CN 106818784 A CN106818784 A CN 106818784A
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- benziothiazolinone
- cyano
- amino
- phenylancryic acetate
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
Abstract
The invention discloses a kind of bactericidal composition containing 2-cyano-3-amino-3-phenylancryic acetate and benziothiazolinone, active ingredient is made up of 2-cyano-3-amino-3-phenylancryic acetate and benziothiazolinone, and 2-cyano-3-amino-3-phenylancryic acetate and benziothiazolinone weight ratio in the composition are 100:1~1:1, percentage by weight is 0.1%~85% to the weight summation of 2-cyano-3-amino-3-phenylancryic acetate and benziothiazolinone in the composition；There is significant synergistic function after 2-cyano-3-amino-3-phenylancryic acetate and benziothiazolinone compounding, wheat scab excellent is prevented and treated, the lasting period is long, to wheat safety, Pesticide use amount can be reduced, reduce use cost, mitigate the pollution to environment, delay the drug-fast generation of pathogen, increase the Pesticide use life-span.
Description
Technical field
The present invention relates to pesticide complex composition and its application field, specifically with 2-cyano-3-amino-3-phenylancryic acetate and benziothiazolinone to have
The binary complex of effect active component compounding, is mainly used in the preventing and treating of disease on crops.
Background technology
2-cyano-3-amino-3-phenylancryic acetate, belongs to cyanoacrylate bactericide, with the spy such as efficient, micro- poison, low-residual, environmentally friendly
Point, to having protection and therapeutic action by the microbial all kinds of plant diseases of reaping hook, can be applied to preventing and treating reaping hook microbial small
Wheat head blight, cotton wilt, bakanae disease of rice, watermelon blight etc..
Benziothiazolinone, belongs to isothiazole heterocyclic compound, is a kind of efficient, low toxicity, broad-spectrum germicide, and its mechanism of action is：
Reacted with bacterium, the anion binding of the surface of cell membrane of mould or with sulfydryl, the synthesis system of destruction protein and cell membrane,
So as to suppress bacterium, mould breeding, pathogen cell metabolism is disturbed, make its physiologic derangement, cause pathogen dead.The change
Compound has good preventing and treating to diseases such as the rot on crops, canker, anthracnose, scab, leaf spot, downy mildew
Effect, and it is fool proof to crops.
The long-time of agricultural chemicals single variety is continuously used, and easily produces resistance risk and consumption to increase risk, and then increase
Cost and carrying capacity of environment, and the compounded combination with notable synergistic function is gone out by the compound screening of different pesticide species
Thing, can not only reduce Pesticide use amount, reduce use cost, reduce resistance risk, moreover it is possible to reduce potential environmental risk, increase
The Pesticide use life-span.
The present inventor during research 2-cyano-3-amino-3-phenylancryic acetate and benziothiazolinone compounded formula, surprisingly 2-cyano-3-amino-3-phenylancryic acetate
Compounded with benziothiazolinone, there is significant Synergistic to make the head blight on wheat in the range of certain compound proportion
With after further study, completing the present invention.
The content of the invention
It is an object of the invention to provide a kind of component rationally, obvious synergy, bactericidal effect is outstanding, the lasting period
Long, drug cost is low, and pathogen can be delayed to develop immunity to drugs, and to the pesticide sterilizing composite of Crop securify.
Another object of the present invention is to provide a kind of bactericidal composition preparation formulation containing 2-cyano-3-amino-3-phenylancryic acetate and benziothiazolinone.
It is still another object of the present invention to provide purposes of the above-mentioned bactericidal composition in head blight on preventing and treating wheat.
Technical scheme：A kind of bactericidal composition containing 2-cyano-3-amino-3-phenylancryic acetate and benziothiazolinone, active ingredient is by cyanogen alkene
Bacterium ester and benziothiazolinone are constituted, and 2-cyano-3-amino-3-phenylancryic acetate and benziothiazolinone weight ratio in the composition are 100:1~1:1,2-cyano-3-amino-3-phenylancryic acetate and thiophene
Percentage by weight is 0.1%~85% to the weight summation of mould ketone in the composition, and remaining is that can agriculturally receive and allow to make
Insecticides adjuvant.
Further, 2-cyano-3-amino-3-phenylancryic acetate and benziothiazolinone preferred weight portion rate in the composition are 35:1.
Bactericidal composition of the present invention can be prepared into suitable agricultural production any formulation for using, and relatively good formulation has
Suspending agent, dispersible oil-suspending agent, aqueous emulsion, microemulsion, water dispersible granules, ultra low volume liquids etc..
Compared with prior art, the advantage of the invention is that：
1st, 2-cyano-3-amino-3-phenylancryic acetate and benziothiazolinone compounding have significant synergistic function, are used alone than single dose and significantly improved
To the prevention effect of disease on crops.
2nd, 2-cyano-3-amino-3-phenylancryic acetate and benziothiazolinone two kinds of active components are compounded, and reduce Pesticide use amount, reduce use cost, are subtracted
The light pollution to environment.
3rd, 2-cyano-3-amino-3-phenylancryic acetate and benziothiazolinone two kinds of active components are compounded, and the mechanism of action is different, and action site increases, and delays
Pathogen drug-fast generation, increased the service life of agricultural chemicals.
Specific embodiment
Essence for a better understanding of the present invention, is described further with reference to embodiment to present disclosure,
But limitation of the present invention can not be considered as, it is as described below to be only used for explaining the present invention, for without departing from spirit of the invention and principle
Modification, replacement or the improvement made, belong to the scope of protection of present invention.
In various application forms prepared by bactericidal composition of the present invention, in addition to effective active composition, also including in agricultural chemicals
Allow to use and the various auxiliary elements of acceptable.
Auxiliary element in suspending agent has：It is the optional freely double naphthalenesulfonate formaldehyde condensation compounds of dispersant, polycarboxylate, wooden
Plain sulfonate, alkyl naphthalene formaldehyde condensate sulfonates, alkylphenol-polyethenoxy base ether phosphate, alkylphenol-polyethenoxy base ether sulphur
Hydrochlorate, phenethyl phenol polyoxyethylene groups ether phosphate, alkyl polyoxyethylene ether sulfonate, polyoxyethylene polyoxypropylene base ether block
The mixing of one or more in copolymer, pull open powder, alkylpolyoxyethylene phosphate；The optional polyethers freely of wetting agent
Modified polyorganosiloxanes, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulfate, phenethyl phenol polyoxyethylene groups ether phosphoric acid
Ester, alkyl sulfate, alkylsulfonate, alkylnaphthalene sulfonate, alkyl phenol formaldehyde resin polyoxyethylene ether, triphenoethyl benzene phenol gather
The mixing of one or more in oxypropylene polyoxyethylene block polymers；The optional Arabic gum freely of thickener, xanthans, carboxylic
Methylcellulose, polyvinyl alcohol, gaseous silicon oxide, Magnesiumaluminumsilicate, carboxyethyl cellulose, carboxy-propyl cellulose, PAA,
The mixing of one or more in polyvinylpyrrolidone, Sodium Polyacrylate, polyvinyl acetate, bentonite, white carbon；Anti-corrosion
One or more mixed in the optional KF88 of Kathon CG freely of agent, formaldehyde, benzoic acid, Sodium Benzoate, potassium sorbate, OIT
Close；The optional silicone oil freely of defoamer, silicone compound, C10-20Saturated fat acids compound, C8-10Aliphatic alcohols, hexanol,
The mixing of one or more in butanol, octanol；The optional glycerine freely-ether diglycol of antifreezing agent, methyl propylene diglycol,
The mixing of one or more in ethylene glycol, propane diols, glycerine, urea；Water is deionized water.
The auxiliary element dispersibled in oil-suspending agent has：The optional block copolymers of EO-PO freely of dispersant, polycarboxylate,
One kind in lignosulfonates, alkylnaphthalene sulfonate, TERSPERSE 2020 (Huntsman Corporation of U.S. HUNTSMAN products)
Or several mixing；Optional BY freely (castor oil polyoxyethylene ether) series emulsifying agent (BY-110, BY-125, the BY- of emulsifying agent
140), Nongru-700 # (common names：Alkyl phenol formaldehyde resin polyoxyethylene ether), agriculture breast 2201, this disk -60# (common names：Sorb
Alcohol acid anhydride monostearate), Tween-60 # (common names：Sorbitan monostearate APEO), agriculture breast 1601# it is (logical
With name：Phenethyl phenol polyoxyethylene poly-oxygen propylene aether), the one kind in TERSPERSE 4894 (Huntsman Corporation of U.S. product)
Or several mixing；Thickener may be selected from such as one or more in organobentonite, white carbon, polyvinyl alcohol, aluminium-magnesium silicate
Mixing；The mixing of one or more in the optional ethylene glycol freely of antifreezing agent, propane diols, glycerine, urea, sodium chloride；Point
The optional turpentine-based vegetable oil freely of dispersion media, methyl oleate, soybean oil, peanut oil, mineral oil, the solvent naphtha (trade mark：S-150、S-
180th, S-200), the mixing of one or more in formicester palm oil.
Auxiliary element in aqueous emulsion has：The optional ethylene oxide adduct freely of emulsifying agent, NPE phosphorus
Acid esters, triphenoethyl benzene phenol polyethenoxy ether phosphate, Nongru-700 # (common names：Alkyl phenol formaldehyde resin polyoxyethylene ether),
Agriculture breast 2201#, this disk -60# (common names：Span60), Tween-60 # (common names：Polyoxyethylene sorbitan mountain
Pears alcohol stearate), TX-10 (common names：Octyl phenol polyoxyethylene (10) ether), agriculture breast 1601# (common names：Triphenoethyl benzene
Phenol polyoxyethylene polyoxypropylene block polymer), agriculture breast 600#, the mixing of one or more in agriculture breast 400#；Solvent is optional
Ethanol, normal propyl alcohol, isopropanol, butanol, isobutanol, sec-Butyl Acetate, ethylene glycol monoethyl ether, dimethylbenzene, trimethylbenzene, first freely
Benzene, cyclohexanone, the solvent naphtha (trade mark：S-150, S-180, S-200) in the mixing of one or more；The optional ring freely of stabilizer
In oxygen soybean oil, epoxidized linseed oil, pentaerythrite, xylitol, 2,6 di tert butyl 4 methyl phenol, butylated hydroxy anisole
The mixing of one or more；One kind or several in the optional ethylene glycol freely of antifreezing agent, propane diols, glycerine, urea, sodium chloride
The mixing planted；One kind in the optional cellulose ether freely of thickener, xanthans, polyvinyl alcohol, organobentonite, aluminium-magnesium silicate or
Several mixing；The optional silicone oil freely of defoamer, silicone compound, C10-20Saturated fat acids compound, C8-10Fatty alcohol
The mixing of one or more in class, hexanol, butanol, octanol；In the optional formaldehyde freely of preservative, benzoic acid, Sodium Benzoate
The mixing of one or more, water is deionized water.
Auxiliary element in microemulsion has：The optional calcium dodecyl benzene sulfonate freely (agriculture breast 500#) of emulsifying agent, agriculture breast
700#, agriculture breast 2201#, this disk-60#, polysorbate60-#, TX-10, agriculture breast 1601# (common names：Phenethyl phenol polyoxyethylene gathers
Oxypropylene ether), agriculture breast 600#, the mixing of one or more in agriculture breast 400#；The optional methyl alcohol freely of assistant for emulsifying agent, isopropanol,
The mixing of one or more in n-butanol, ethanol；The optional dimethylbenzene freely of solvent, cyclohexanone, the solvent naphtha (trade mark：S-150、
S-180, S-200), mineral oil, turpentine-based vegetable oil, turpentine oil, methyl oleate, one or more mixed in sec-butyl acetate
Close；The mixing of one or more in the optional ethylene glycol freely of antifreezing agent, propane diols, glycerine, urea, sodium chloride；Defoamer
Optional silicone oil freely, silicone compound, C10-20Saturated fat acids compound, C8-10Aliphatic alcohols, hexanol, butanol, octanol
In the mixing of one or more；One kind in the optional epoxidized soybean oil freely of stabilizer, triphenyl phosphite, epoxychloropropane
Or several mixing；Water is deionized water.
Auxiliary element in water dispersible granules has：The optional sodium lignin sulfonate freely of dispersant, polycarboxylic acid salt, laruyl alcohol
Polyoxyethylene groups ether sodium sulfate, alkyl naphthalene formaldehyde condensate sulfonates, alkyl polyoxyethylene ether sulfonate, alkylphenol-polyethenoxy
In base ether formaldehyde condensation products, polyoxyethylene polyoxypropylene base ether block copolymers, alkylpolyoxyethylene phosphate one
Plant or several mixing；The optional neopelex freely of wetting agent, pull open powder, alkyl phenol formaldehyde resin polyoxyethylene ether
The mixing of one or more in sulfate, alkylphenol-polyethenoxy base ether, Nonyl pheno base ether；Disintegrant may be selected from
Such as the mixing of one or more in ammonium sulfate, sodium sulphate, polyvinylpyrrolidone, starch and its derivative, bentonite；Filler
Optional kaolin freely, diatomite, precipitated calcium carbonate, white carbon, attapulgite, cornstarch, sepiolite, calcite, silica,
The mixing of one or more in pyrophyllite, xylitol, montmorillonite, potter's clay.
Auxiliary element in ultra low volume liquids has：The optional AEO freely of surfactant, alkyl phenol
APEO, alkylaryl polyoxyethylene polyoxypropylene ether again, APES phosphate, phenethyl phenol polyoxyethylene
In ether phosphate, alkylaryl polyoxyethylene polyoxypropylene ether again phosphate, castor oil polyoxyethylene ether, calcium dodecyl benzene sulfonate
The mixing of one or more；One or more in the optional azone freely of bleeding agent, thiophene ketone, fast penetrant T, isophorone
Mixing；The mixing of one or more in the optional gibberellic acid freely of poisoning palliative, study on brassinolide, compound sodium nitrophenolate；Solvent
Optional ethylo benzene freely, trimethylbenzene, soybean oil, rapeseed oil, corn oil, loose base oil, methyl oleate, ethyl oleate, methyl alcohol, second
In alcohol, acetone, N,N-dimethylformamide, DMAC N,N' dimethyl acetamide, ethylene glycol, propane diols, glycerine, isooctanol, n-octyl alcohol
The mixing of one or more.
The production technology of the various application forms of bactericidal composition belongs to existing known technology, will not be repeated here.
Embodiment one：36% 2-cyano-3-amino-3-phenylancryic acetate benziothiazolinone suspending agent
Following material is weight percentage：2-cyano-3-amino-3-phenylancryic acetate 35%, benziothiazolinone 1%, double naphthalenesulfonate formaldehyde condensation compounds
10%th, triphenoethyl benzene phenol polyoxyethylene polyoxypropylene block polymer 5%, PAA 2%, Kathon CG KF88 0.5%, C10-20
Saturated fat acids compound 0.5%, glycerine 2%, deionized water supply 100%.Above-mentioned material is mixed in proportion, through height
Speed shearing is uniformly dispersed, be sanded in sand mill after, you can 36% 2-cyano-3-amino-3-phenylancryic acetate benziothiazolinone suspending agent is obtained.
Embodiment two：11% 2-cyano-3-amino-3-phenylancryic acetate benziothiazolinone dispersibles oil-suspending agent
Following material is weight percentage：2-cyano-3-amino-3-phenylancryic acetate 10%, benziothiazolinone 1%, alkylnaphthalene sulfonate 7%, agriculture breast
1601#10%, white carbon 2%, ethylene glycol 3%, methyl oleate supply 100%.Above-mentioned material is mixed in proportion, is cut through high speed
Cut after being uniformly dispersed, being sanded in sand mill, you can 11% 2-cyano-3-amino-3-phenylancryic acetate benziothiazolinone is obtained and dispersibles oil-suspending agent.
Embodiment three：51% 2-cyano-3-amino-3-phenylancryic acetate benziothiazolinone aqueous emulsion
Following material is weight percentage：2-cyano-3-amino-3-phenylancryic acetate 50%, benziothiazolinone 1%, thermally coupled distillation columns
10%th, dimethylbenzene 5%, the solvent naphtha (trade mark：S-150) 10%, butylated hydroxy anisole 1%, glycerine 2%, xanthans
2.5%th, C10-20Saturated fat acids compound 0.2%, benzoic acid 0.5%, deionized water supply 100%.Above-mentioned material is pressed
Ratio mix, through high shear agitation it is uniform after, you can be obtained 51% 2-cyano-3-amino-3-phenylancryic acetate benziothiazolinone aqueous emulsion.
Example IV：41% 2-cyano-3-amino-3-phenylancryic acetate benziothiazolinone microemulsion
Following material is weight percentage：2-cyano-3-amino-3-phenylancryic acetate 40%, benziothiazolinone 1%, agriculture breast 600#5%, agriculture breast 400#
5%th, isopropanol 3%, dimethylbenzene 5%, the solvent naphtha (trade mark：S-180) 10%, ethylene glycol 2%, silicone oil 0.3%, epoxidized soybean oil
2%th, deionized water supplies 100%.Above-mentioned material is mixed in proportion, through high shear agitation it is uniform after, you can be obtained 41%
2-cyano-3-amino-3-phenylancryic acetate benziothiazolinone microemulsion.
Embodiment five：66% 2-cyano-3-amino-3-phenylancryic acetate benziothiazolinone water dispersion granule
Following material is weight percentage：2-cyano-3-amino-3-phenylancryic acetate 65%, benziothiazolinone 1%, alkyl naphthalene formaldehyde condensate sulfonates
10%th, alkylphenol-polyethenoxy base ether 5%, starch 5%, diatomite supplies 100%.Above-mentioned material is mixed in proportion, through gas
Stream be pulverized and mixed uniformly, mediate granulation, dry screening after, can be prepared by 66% 2-cyano-3-amino-3-phenylancryic acetate benziothiazolinone water dispersion granule.
Embodiment six：21% 2-cyano-3-amino-3-phenylancryic acetate benziothiazolinone ultra low volume liquids
Following material is weight percentage：2-cyano-3-amino-3-phenylancryic acetate 20%, benziothiazolinone 1%, APES 15%, ten
Dialkyl benzene sulfonic acids calcium 10%, isophorone 2%, brassin lactones 0.02%, ethylo benzene 5%, N,N-dimethylformamide
10%th, soybean oil complements to 100%.Above-mentioned material is mixed in proportion, after stirring, you can 21% cyanogen alkene bacterium is obtained
Ester benziothiazolinone ultra low volume liquids.
Embodiment seven：The Toxicity Determination experiment of 2-cyano-3-amino-3-phenylancryic acetate and benziothiazolinone compounding to wheat scab pathogen
Test method：With reference to《Farm-chemical indoor determination test rule NY/T1156.2-2006》, using Plating.
Statistical analysis is carried out with DPS statistical analysis softwares, the EC of each medicament is calculated50, and mixture is calculated according to the abundant methods of Sun Yun
Co-toxicity coefficient (CTC values), co-toxicity coefficient (CTC) >=120 shows as synergistic effect；Co-toxicity coefficient (CTC)≤80 shows as short of money
Anti- effect；80 ＜ co-toxicity coefficients (CTC) ＜ 120 show as summation action.
Table 1,2-cyano-3-amino-3-phenylancryic acetate and benziothiazolinone compound the Toxicity Determination to wheat scab pathogen
As it can be seen from table 1 2-cyano-3-amino-3-phenylancryic acetate and benziothiazolinone are 100:1~1:It is malicious altogether when being compounded in the range of 1 (by weight)
Coefficient (CTC) is all higher than 120, illustrates to show synergistic function to wheat scab pathogen；2-cyano-3-amino-3-phenylancryic acetate and benziothiazolinone
80:1~10:When being compounded in the range of 1 (by weight), synergistic function is more notable, and co-toxicity coefficient (CTC) is 200
More than；2-cyano-3-amino-3-phenylancryic acetate and benziothiazolinone are with 35:1 (by weight) compounding, synergistic function is the most notable, and co-toxicity coefficient (CTC) reaches
It is 278.40 to maximum.It can be seen that, 2-cyano-3-amino-3-phenylancryic acetate and benziothiazolinone compounding have reasonability and feasibility.
Embodiment eight：2-cyano-3-amino-3-phenylancryic acetate and benziothiazolinone complex composition preparation prevent and treat the field test of wheat scab
In wheat scab early stage dispenser, per 7d dispensers 1 time, dispenser 2 times altogether.State of an illness radix, the 2nd are investigated before dispenser
A situation arises for 14d investigation disease after secondary dispenser, counts disease index, calculates preventive effect.
Table 2,2-cyano-3-amino-3-phenylancryic acetate and benziothiazolinone complex composition preparation prevent and treat the field test of wheat scab
From table 2 it can be seen that each 2-cyano-3-amino-3-phenylancryic acetate and benziothiazolinone complex composition preparation wheat scab is shown it is excellent
Different prevention effect, preventive effect is more than 80%, hence it is evident that be used alone higher than each single dose, especially (the 36% cyanogen alkene of embodiment one
Bacterium ester benziothiazolinone suspending agent) preventive effect of wheat scab is more protruded, preventive effect is up to more than 90%.Simultaneously in pilot survey
Do not find that each metrafenone and 2-cyano-3-amino-3-phenylancryic acetate complex composition preparation produce poisoning to wheat in journey.
In sum, the complex composition of a kind of 2-cyano-3-amino-3-phenylancryic acetate-containing of the present invention and benziothiazolinone, synergistic function
Significantly, it is used alone compared to each single dose and improves preventive effect, can effectively prevent and treat the head blight on wheat, the lasting period is long, wheat is pacified
Entirely, increase production obvious, be worth the popularization and application in agricultural production.
Claims (7)
1. a kind of bactericidal composition containing 2-cyano-3-amino-3-phenylancryic acetate and benziothiazolinone, it is characterised in that：Active ingredient is by 2-cyano-3-amino-3-phenylancryic acetate and thiophene
Mould ketone composition, 2-cyano-3-amino-3-phenylancryic acetate and benziothiazolinone weight ratio in the composition are 100:1~1:1.
2. a kind of bactericidal composition containing 2-cyano-3-amino-3-phenylancryic acetate and benziothiazolinone according to claim 1, it is characterised in that：Cyanogen alkene
Percentage by weight is 0.1%~85% to the weight summation of bacterium ester and benziothiazolinone in the composition.
3. a kind of bactericidal composition containing 2-cyano-3-amino-3-phenylancryic acetate and benziothiazolinone according to claim 1, it is characterised in that：Cyanogen alkene
Percentage by weight is 11% to the weight summation of bacterium ester and benziothiazolinone in the composition.
4. a kind of bactericidal composition containing 2-cyano-3-amino-3-phenylancryic acetate and benziothiazolinone according to claim 1, it is characterised in that：Cyanogen alkene
Bacterium ester and benziothiazolinone weight ratio in the composition are 80:1~10:1.
5. a kind of bactericidal composition containing 2-cyano-3-amino-3-phenylancryic acetate and benziothiazolinone according to claim 1, it is characterised in that：Cyanogen alkene
Bacterium ester and benziothiazolinone weight ratio in the composition are 35:1.
6. a kind of bactericidal composition containing 2-cyano-3-amino-3-phenylancryic acetate and benziothiazolinone according to claim 1, it is characterised in that：It is described
The formulation of bactericidal composition is suspending agent, dispersibles oil-suspending agent, aqueous emulsion, microemulsion, water dispersible granules or ultra-low volume liquid
Agent.
7. a kind of bactericidal composition containing 2-cyano-3-amino-3-phenylancryic acetate and benziothiazolinone described in claim 1 is in head blight on preventing and treating wheat
Purposes.
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| CN109303060A (en) * | 2018-12-06 | 2019-02-05 | 陕西西大华特科技实业有限公司 | A kind of combination germicide and application containing benziothiazolinone and pyraoxystrobin |
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