CN106804607A - A kind of bactericidal composition containing benziothiazolinone and thifluzamide and purposes - Google Patents

A kind of bactericidal composition containing benziothiazolinone and thifluzamide and purposes Download PDF

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Publication number
CN106804607A
CN106804607A CN201710130520.8A CN201710130520A CN106804607A CN 106804607 A CN106804607 A CN 106804607A CN 201710130520 A CN201710130520 A CN 201710130520A CN 106804607 A CN106804607 A CN 106804607A
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China
Prior art keywords
thifluzamide
benziothiazolinone
bactericidal composition
composition containing
suspending agent
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CN201710130520.8A
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Chinese (zh)
Inventor
王鹏
崔继承
段新新
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HUATE WESTERN SHAANXI SCIENCE AND TECHNOLOGY INDUSTRIAL Co Ltd
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HUATE WESTERN SHAANXI SCIENCE AND TECHNOLOGY INDUSTRIAL Co Ltd
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Priority to CN201710130520.8A priority Critical patent/CN106804607A/en
Publication of CN106804607A publication Critical patent/CN106804607A/en
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/02Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention relates to technical field of pesticide combination, a kind of bactericidal composition containing benziothiazolinone and thifluzamide is disclosed.The bactericidal composition active ingredient is benziothiazolinone and thifluzamide, and benziothiazolinone is 1 with the mass ratio of thifluzamide:40‑40:1, active ingredient gross mass accounts for 1% the 80% of whole preparation gross mass, and remaining is auxiliary element.The bactericidal composition can be configured to suspending agent, dispersible oil-suspending agent, wettable powder, water dispersible granules.Bactericidal composition of the present invention has significant synergistic function, is mainly used in preventing and treating banded sclerotial blight, damping-off.

Description

A kind of bactericidal composition containing benziothiazolinone and thifluzamide and purposes
Technical field
The present invention relates to technical field of pesticide combination, and in particular to a kind of Bactericidal composite containing benziothiazolinone and thifluzamide Thing, is mainly used in and prevents and treats banded sclerotial blight, damping-off.
Technical background
Benziothiazolinone is a kind of efficient, low toxicity, and broad-spectrum germicide, can destroy pathogen cell membrane protein and synthesis is System, so as to suppress pathogen breeding, disturbs pathogen cell metabolism, makes its physiologic derangement, causes pathogen dead.The change Compound is to bacterium, and fungus-caused multiple kinds of crops disease has good prevention effect, and fool proof to crops and environment.
Thifluzamide, belongs to thiazole amide bactericide, with strong Uptake and translocation and lasting effect long.Thifluzamide is amber Amber acid esters dehydrogenase inhibitor, due to fluorine-containing, its competitiveness is very strong in biochemical process, is difficult once being combined with substrate or enzyme Recover.The compound causes a disease to Rhizoctonia, Puccinia, Ustilago, Tilletia, corticium, nuclear cavity Pseudomonas etc. Fungi is active, especially has special efficacy to the fungus-caused disease of Basidiomycetes such as banded sclerotial blight, damping-off etc..
The banded sclerotial blight caused by Infection By Rhizoctonia Solani, damping-off etc., main harm leaf sheath, blade, invade stem when serious Stalk simultaneously spreads to fringe portion.Often result in grain not full, Empty grain rate increases, serious caused plant lodging is withered.Yield is received To influence, cause economic loss.
The content of the invention
It is an object of the invention to provide a kind of bactericidal composition containing benziothiazolinone and thifluzamide, synergistic effect is obvious, Prevent and treat banded sclerotial blight, damping-off effect is significant.In order to achieve the above object, the technical solution adopted by the present invention is:
A kind of matter of the bactericidal composition containing benziothiazolinone and thifluzamide, wherein active ingredient benziothiazolinone and thifluzamide Amount is than being 1:40‐40:1.
Further, active ingredient gross mass accounts for the 1%-80% of whole preparation gross mass, and remaining is auxiliary element.
The above-mentioned bactericidal composition containing benziothiazolinone and thifluzamide, the bactericidal composition can be processed into suspending agent, Dispersible oil-suspending agent, wettable powder, water dispersible granules.
The above-mentioned bactericidal composition containing benziothiazolinone and thifluzamide, when suspending agent is processed into, auxiliary element includes Dispersant, thickener, antifreezing agent, defoamer and water.
The above-mentioned bactericidal composition containing benziothiazolinone and thifluzamide, when be processed into dispersible oil-suspending agent when, auxiliary Composition includes solvent, antifreezing agent, emulsifying agent.
The above-mentioned bactericidal composition containing benziothiazolinone and thifluzamide, when wettable powder is processed into, auxiliary element Including wetting agent, dispersant, carrier.
The above-mentioned bactericidal composition containing benziothiazolinone and thifluzamide, when water dispersible granules are processed into, auxiliary element Including wetting agent, dispersant, binding agent, disintegrant.
The above dispersant is naphthalene sulfonate, lignosulfonates, polycarboxylate, cyclohexanone formaldehyde condensation products, alkyl Benzene sulfonate, APES, AEO, castor oil polyoxyethylene ether, AEO One or more in formaldehyde condensation products sulfate;
The above emulsifying agent is APES, styrylphenol polyoxyethylene ether, polyoxyethylene nonyl phenyl second Alkene ether, styrylphenol polyoxyethylene ether phosphate, aliphatic alcohol polyethenoxy ester, alkyl polyoxyethylene sulfate salt, phenethyl One or more in phenol polyethenoxy polyethenoxy ether;
The above antifreezing agent is ethylene glycol, propane diols, glycerine, one or more in urea;
The above thickener is xanthans, Arabic gum, aluminium-magnesium silicate, polyvinyl alcohol, carboxymethylcellulose calcium, Guar Glue, one or more in sodium alginate;
The above defoamer is organic silicone oil defoamer, C8-10 aliphatic alcohols compounds, in silicone defoamer one Plant or various.
The above solvent is solvent naphtha, methyl oleate, turpentine oil, methylated vegetable oil, soybean oil, castor oil, vegetable seed One or more in oily equal solvent;
The above wetting agent is lauryl sodium sulfate, calcium dodecyl benzene sulfonate, pull open powder, Tea Saponin, alkylnaphthalene One or more in the wetting agents such as sodium sulfonate;
The above binding agent is starch, and carboxymethylcellulose calcium, polyvinyl alcohol, PEG 8000, aluminium-magnesium silicate is organic One or more in bentonite;
The above disintegrant is sodium sulphate, ammonium sulfate, urea, calcium nitrate, one or more in magnesium nitrate;
The above filler is white carbon, urea, sodium sulphate, ammonium sulfate, kaolin, precipitated calcium carbonate, bentonite, diatom One or more in soil.
The present invention has found that benziothiazolinone and thifluzamide carry out compounded combination and there is obvious synergy to make by further investigation With preventing and treating banded sclerotial blight, damping-off effect is significant.
Specific embodiment
Inventor illustrates that benziothiazolinone and thifluzamide compounding are withered to line by Toxicity Determination and field control effectiveness test Disease, the synergistic effect of damping-off.
Preventive effect embodiment 1, the Toxicity Determination for preventing and treating rice sheath blight disease
Experimental technique is referred to《People's Republic of China's agricultural industry criteria NY/T1156.5-2006 agricultural chemicals indoor biological is surveyed Determine the part of test rule bactericide the 5th:Suppress Rhizoctonia solani Kuhn experiment Broad Bean Leaves method》.First by single dose and each mixture medicine Agent sets 9 different ratios.Potted plant from broad bean susceptible variety, clip same area, growing way suppresses, with petiolate blade, Put in culture dish, moisturizing is standby.Blade is fully infiltrated 5 seconds in the liquid for preparing in advance, unnecessary liquid, natural wind is drained After dry, by moisturizing culture after treatment mark.The one side that 5 millimeters of bacteria cakes of diameter have mycelia is inoculated in treatment blade with inoculator Centre.Often process 30 leaves.It is inoculated with 24 hours before chemicals treatment.It is placed in growth cabinet after inoculation, in temperature 26-28 degree, phase To being cultivated under conditions of humidity 80%-90%.Depending on blank incidence, each vaccination scab is recorded with kind of calliper long Degree and width, with length, average value wide represents lesion diameter (unit millimeter).
Prevention effect (%)=(blank lesion diameter-chemicals treatment lesion diameter)/blank lesion diameter leads to The linear regression analysis crossed between the niqueMin of preventive effect and the logarithm value of series concentration, obtains the EC50 values of each medicament, uses Sun Yun Abundant method calculates the co-toxicity coefficient (CTC) of mixture, and activity of the reagent agent to germ is evaluated with this.
The co-toxicity coefficient (CTC) >=120 of complex preparation shows as synergistic effect;Co-toxicity coefficient (CTC)≤80 shows as short of money Anti- effect;80 < co-toxicity coefficients (CTC) < 120 show as summation action.
The Toxicity Determination of the benziothiazolinone of table 1 and thifluzamide to rice sheath blight disease
Reagent agent Proportioning EC50(mg/L) Co-toxicity coefficient (CTC)
Benziothiazolinone (A) -- 1.35 --
Thifluzamide (B) -- 0.19 --
A:B 1:40 0.099 167.4
A:B 1:30 0.084 178.1
A:B 1:15 0.073 189.2
A:B 1:8 0.069 206.5
A:B 1:1 0.15 191.3
A:B 8:1 0.29 181.7
A:B 15:1 0.33 172.6
A:B 30:1 0.52 164.9
A:B 40:1 0.59 158.8
As shown in Table 1, benziothiazolinone and thifluzamide mixed ratio are 1:40~40:When 1, CTC is all higher than 120, shows Good synergistic effect.
Preventive effect embodiment 2, the indoor harmacological effect of preventing and treating cotton seedling blight are determined
Experimental technique
Experiment is using growth rate method (Plating).On aseptic operating platform, according to test process going out advance thawing Bacterium culture medium is quantitatively added in aseptic conical flask, is taken 5 milliliters of liquids successively from low concentration to high concentration and is added separately to equipped with 45 In the conical flask of the hot culture medium (40-45 degree) of milliliter, after shaking up, pour into rapidly in 90 millimeters of glass culture dish of diameter, each training Foster ware pours into 10 milliliters of band medicine culture medium.Horizontal positioned, is made flat board after cooling.5 repetitions of each concentration.Have with without medicament The treatment for imitating composition is blank.By cultured pathogen, aseptically with the sterilization punchers of 4 millimeters of diameter, Word colony edge steals bacteria cake, with inoculator by pure culture biscuits involvng inoculation in pastille flat board center, will have the one of mycelia downwards and culture Base is fitted, and covers ware lid.Culture in the constant temperature sterile culture case of 25-27 degree is placed on after treatment, is taken out after 2 days.Handed over using cross Fork method measures the colony diameter (unit millimeter) of each treatment respectively.
Prevention effect (%)=(blank lesion diameter-chemicals treatment lesion diameter)/blank lesion diameter leads to The linear regression analysis crossed between the niqueMin of preventive effect and the logarithm value of series concentration, obtains the EC50 values of each medicament, uses Sun Yun Abundant method calculates the co-toxicity coefficient (CTC) of mixture, and activity of the reagent agent to germ is evaluated with this.
The co-toxicity coefficient (CTC) >=120 of complex preparation shows as synergistic effect;Co-toxicity coefficient (CTC)≤80 shows as short of money Anti- effect;80 < co-toxicity coefficients (CTC) < 120 show as summation action.
The Toxicity Determination of the benziothiazolinone of table 2 and thifluzamide to cotton seedling blight
Reagent agent Proportioning EC50(mg/L) Co-toxicity coefficient (CTC)
Benziothiazolinone (A) -- 1.69 --
Thifluzamide (B) -- 0.17 --
A:B 1:40 0.112 166.2
A:B 1:30 0.095 177.6
A:B 1:15 0.082 188.3
A:B 1:8 0.074 205.1
A:B 1:1 0.16 190.5
A:B 8:1 0.32 180.4
A:B 15:1 0.39 171.7
A:B 30:1 0.56 163.3
A:B 40:1 0.61 157.2
As shown in Table 2, benziothiazolinone and thifluzamide mixed ratio are 1:40~40:When 1, CTC is all higher than 120, shows Good synergistic effect.
Preventive effect embodiment 3, field test prevents and treats rice sheath blight disease
Test method
Experiment is carried out in Hubei Jianli rice belt, and 15 square metres of plot area is repeated 4 times.Per cell diagonal, 5 points take Sample, every is investigated 0.1 square metre, record investigation total strain number, diseased plant number, sick series.
Control time and number of times
Experiment is investigated 4 times altogether, radix investigation before medicine, 7 days after first time medicine, is carried out within 15 days after 7 days and medicine after second medicine Investigation.
Dispenser formulation and method
Inventive composition formulation is suspending agent, and application method is spraying, and dosage is 30 liters/mu.
Drug effect computational methods
Grade scale:
0 grade:Complete stool is disease-free;
1 grade:Quaterfoil and its following leaf sheath, blade morbidity (being first piece leaf with sword-like leave);
3 grades:Third blade and its following leaf sheath, blade morbidity;
5 grades:Second blade and its following leaf sheath, blade morbidity;
7 grades:First blade and its following leaf sheath, blade morbidity;
9 grades:Sword-like leave blade and its following leaf sheath, blade morbidity;
Disease index=Σ (sick number of sheets * at different levels are with respect to value of series)/(investigation total number of sheets * 9) * 100
Prevention effect (%)=[1- (disease index after disease index * treatment region medicines before blank district medicine)/(blank pair According to disease index before disease index * treatment region medicines after area's medicine)] * 100
Table 3 respectively processes the effect for preventing and treating rice sheath blight disease
As shown in Table 3, benziothiazolinone and thifluzamide mixed ratio are 1:40~40:When 1, in the case where dosage is relatively low Prevention effect is significantly better than that comparison medicament, shows the effect of obvious compound synergic, can be as preventing and treating rice sheath blight disease The replacement of the thifluzamide suspending agent of common medicine 24% and upgrading medication.
Preventive effect embodiment 4, field test prevents and treats cotton seedling blight
Test method
Experiment is carried out in Hubei, 66.7 square metres of plot area, and often treatment is repeated 4 times.District's groups random alignment.Interval 7 days Spray 1 time, sprays 3 times altogether.
Control time and number of times
Experiment is investigated 4 times altogether, radix investigation before medicine, 7 days investigation preventive effects after each dispenser.
Dispenser formulation and method
Inventive composition formulation is suspending agent, and application method is spraying, and dosage is 30 liters/mu.
Drug effect computational methods
Investigation grade scale:
0 grade:Complete stool is disease-free.
1 grade:Rhizome base portion closely slightly shows scab or slightly changes colour, and upper blade is slightly wilted.
2 grades:Slightly now scab or the discoloration of rhizome base portion nearly 1/2 or 1/3, sick portion hangs contracting, the wilting of the blade of top 1/2.
3 grades:Rhizome base portion is all surround by scab, and sick portion hangs contracting, and complete stool is wilted, growing point bending.
4 grades:Complete stool is wilted, withered.
Disease index=Σ (diseased plant number * relative diseases value of series at different levels)/(the total diseased plant number * 4 of investigation) * 100
Prevention effect (%)=[(disease index after control disease index-treatment medicine)/(control disease index)] * 100
The prevention effect of the benziothiazolinone of table 4 and thifluzamide to cotton seedling blight
As shown in Table 4, benziothiazolinone and thifluzamide mixed ratio are 1:40~40:When 1, CTC is all higher than 120, shows Good synergistic effect, can be as the replacement of the hymexazol aqua of common medicine 15% of preventing and treating cotton seedling blight and upgrading medication.
Prepare the benziothiazolinone thifluzamide suspending agent of embodiment 1 27%
Benziothiazolinone 3%, thifluzamide 24%, polycarboxylate 2%, AEO formaldehyde condensation products sulfate 2%, ethylene glycol 4%, aluminium-magnesium silicate 0.8%, xanthans 0.18%, defoamer 0.5%, water supplies 100%.By polycarboxylate, AEO formaldehyde condensation products sulfate, ethylene glycol, aluminium-magnesium silicate, xanthans, defoamer, water, through high speed shear It is well mixed, benziothiazolinone is sequentially added, thifluzamide is sanded 2-3 hours in sand mill, makes particle diameter below 5 microns, and 27% Benziothiazolinone thifluzamide suspending agent.
Prepare the benziothiazolinone thifluzamide suspending agent of embodiment 2 33%
Benziothiazolinone 3%, thifluzamide 30%, polycarboxylate 4%, ethylene glycol 4%, aluminium-magnesium silicate 0.5%, xanthans 0.15%, defoamer 0.5%, water supplies 100%.By polycarboxylate, ethylene glycol, aluminium-magnesium silicate, xanthans, defoamer, water, warp High speed shear is well mixed, and sequentially adds benziothiazolinone, and thifluzamide is sanded 2-3 hours in sand mill, makes particle diameter at 5 microns Hereinafter, 33% benziothiazolinone thifluzamide suspending agent.
Prepare the benziothiazolinone thifluzamide of embodiment 3 20% and dispersible oil-suspending agent
Benziothiazolinone 10%, thifluzamide 10%, calcium dodecyl benzene sulfonate 4%, APES 6%, silicic acid Magnalium 1.5%, methyl oleate supplies 100%.By calcium dodecyl benzene sulfonate, APES, aluminium-magnesium silicate, oleic acid Methyl esters is well mixed through high speed shear, sequentially adds benziothiazolinone, and thifluzamide is sanded 2-3 hours in sand mill, particle diameter is existed Less than 5 microns, 20% benziothiazolinone thifluzamide dispersibles oil-suspending agent.
Prepare the benziothiazolinone thifluzamide of embodiment 4 35% and dispersible oil-suspending agent
Benziothiazolinone 15%, thifluzamide 20%, calcium dodecyl benzene sulfonate 3%, styrylphenol polyoxyethylene ether 7%, aluminium-magnesium silicate 1%, methyl oleate supplies 100%.By calcium dodecyl benzene sulfonate, styrylphenol polyoxyethylene ether, Aluminium-magnesium silicate, methyl oleate is well mixed through high speed shear, sequentially adds benziothiazolinone, and thifluzamide is sanded 2-3 in sand mill Hour, making particle diameter below 5 microns, 35% benziothiazolinone thifluzamide dispersibles oil-suspending agent.
Prepare the benziothiazolinone thifluzamide wettable powder of embodiment 5 22%
Benziothiazolinone 20%, thifluzamide 2%, lauryl sodium sulfate 2%, calcium lignosulfonate 5%, naphthalene sulfonate 4%, White carbon 4%, kaolin supplies 100%.Above-mentioned material is well mixed in mixer, mixed after being crushed through airslide disintegrating mill It is well mixed in conjunction machine, that is, 22% benziothiazolinone thifluzamide wettable powder is obtained.
Prepare the benziothiazolinone thifluzamide wettable powder of embodiment 6 50%
Benziothiazolinone 20%, thifluzamide 30%, lauryl sodium sulfate 4%, calcium lignosulfonate 6%, naphthalene sulfonate 3%, white carbon 2%, kaolin supplies 100%.Above-mentioned material is well mixed in mixer, after being crushed through airslide disintegrating mill It is well mixed in mixer, that is, 50% benziothiazolinone thifluzamide wettable powder is obtained.
Prepare the benziothiazolinone thifluzamide water dispersible granule of embodiment 7 54%
Benziothiazolinone 6%, thifluzamide 48%, lauryl sodium sulfate 3%, carboxylate 6%, ammonium sulfate 10%, corn forms sediment Powder 10%, precipitated calcium carbonate supplies 100%.Above-mentioned material is well mixed in mixer, mixes equal after airslide disintegrating mill It is even, be subsequently adding fluidized bed pelletizer or add water kneading after extruder grain, through drying, sampling analysis after screening obtains final product 54% thiophene Mould ketone thifluzamide water dispersible granule.
Prepare the benziothiazolinone thifluzamide water dispersible granule of embodiment 8 80%
Benziothiazolinone 30%, thifluzamide 50%, lauryl sodium sulfate 2%, carboxylate 4%, naphthalene sulfonate 6%, sulfuric acid Ammonium supplies 100%.Above-mentioned material is well mixed in mixer, is well mixed after airslide disintegrating mill, be subsequently adding fluidisation Extruder grain after bed comminutor or the kneading that adds water, through drying, sampling analysis after screening obtains final product 80% benziothiazolinone thifluzamide moisture Shot agent.

Claims (4)

1. a kind of bactericidal composition containing benziothiazolinone Yu thifluzamide, it is characterised in that:The active ingredient of the bactericidal composition It is that benziothiazolinone and thifluzamide, wherein active ingredient benziothiazolinone and the mass ratio of thifluzamide are 1:40‐40:1.
2. a kind of bactericidal composition containing benziothiazolinone Yu thifluzamide according to claim 1, it is characterised in that:Effectively Composition gross mass accounts for the 1%-80% of whole preparation gross mass, and remaining is auxiliary element.
3. a kind of bactericidal composition containing benziothiazolinone Yu thifluzamide according to claim 1, it is characterised in that:This is killed Bacteria composition can be processed into suspending agent, dispersible oil-suspending agent, wettable powder, water dispersible granules.
4. the composition according to claim 1,2 or 3 is used to prevent and treat banded sclerotial blight, damping-off.
CN201710130520.8A 2017-03-07 2017-03-07 A kind of bactericidal composition containing benziothiazolinone and thifluzamide and purposes Pending CN106804607A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109907056A (en) * 2019-03-21 2019-06-21 北京宇悦生物科技有限公司 Composition pesticide and its application

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101796955A (en) * 2009-12-31 2010-08-11 青岛星牌作物科学有限公司 Composite bactericidal composite and applications thereof
WO2012076634A1 (en) * 2010-12-08 2012-06-14 Basf Se Fungicidal mixtures comprising pyraclostrobin
CN105211073A (en) * 2015-08-31 2016-01-06 陕西西大华特科技实业有限公司 A kind of bactericidal composition containing benziothiazolinone and succinic acid Off hydrogen enzyme inhibitor, agricultural chemicals and application thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101796955A (en) * 2009-12-31 2010-08-11 青岛星牌作物科学有限公司 Composite bactericidal composite and applications thereof
WO2012076634A1 (en) * 2010-12-08 2012-06-14 Basf Se Fungicidal mixtures comprising pyraclostrobin
CN105211073A (en) * 2015-08-31 2016-01-06 陕西西大华特科技实业有限公司 A kind of bactericidal composition containing benziothiazolinone and succinic acid Off hydrogen enzyme inhibitor, agricultural chemicals and application thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109907056A (en) * 2019-03-21 2019-06-21 北京宇悦生物科技有限公司 Composition pesticide and its application

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