CN106802684B - Purple sweet potato pears compound fruit vinegar fermentation monitoring system and its method of work based on MAS - Google Patents
Purple sweet potato pears compound fruit vinegar fermentation monitoring system and its method of work based on MAS Download PDFInfo
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- G—PHYSICS
- G05—CONTROLLING; REGULATING
- G05D—SYSTEMS FOR CONTROLLING OR REGULATING NON-ELECTRIC VARIABLES
- G05D27/00—Simultaneous control of variables covered by two or more of main groups G05D1/00 - G05D25/00
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
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- G05B—CONTROL OR REGULATING SYSTEMS IN GENERAL; FUNCTIONAL ELEMENTS OF SUCH SYSTEMS; MONITORING OR TESTING ARRANGEMENTS FOR SUCH SYSTEMS OR ELEMENTS
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- G05B19/02—Programme-control systems electric
- G05B19/04—Programme control other than numerical control, i.e. in sequence controllers or logic controllers
- G05B19/042—Programme control other than numerical control, i.e. in sequence controllers or logic controllers using digital processors
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- G—PHYSICS
- G05—CONTROLLING; REGULATING
- G05B—CONTROL OR REGULATING SYSTEMS IN GENERAL; FUNCTIONAL ELEMENTS OF SUCH SYSTEMS; MONITORING OR TESTING ARRANGEMENTS FOR SUCH SYSTEMS OR ELEMENTS
- G05B2219/00—Program-control systems
- G05B2219/20—Pc systems
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Abstract
The invention discloses purple sweet potato pears compound fruit vinegar fermentation monitoring systems and its method of work based on MAS, are made of dsp processor, pretreatment Agent, fermentation process Agent, alarm unit Agent, Communication Agent, central monitor Agent;The dsp processor difference programming Control pretreatment Agent, fermentation process Agent, alarm unit Agent;The central monitor Agent is connected by Communication Agent with dsp processor interactive controlling.Purple sweet potato pears compound fruit vinegar fermentation monitoring system of the present invention based on MAS, the system uses multi-Agent control mode, each relatively independent work of Agent, automatically adjust and solve the subproblem that each Agent gives, greatly improve system work efficiency, it mutually communicates, coordinate, cooperate between each Agent, greatly improve system stability.
Description
Technical field
The invention belongs to technical field of biological fermentation, and in particular to the purple sweet potato pears compound fruit vinegar fermentation monitoring system based on MAS
System and its method of work.
Background technology
Fruit vinegar is using the leftover bits and pieces of fruit or Fruit quality as primary raw material, is brewed through alcoholic fermentation, acetic fermentation
A kind of excellent in flavor, health-care effect protrude acid condiment or beverage of new generation.With constantly carrying for people's living standard
Height, the healthcare function of fruit vinegar are also increasingly valued by people, and the research in relation to fruit vinegar technique is also increasingly subject to researcher
Favor.
During fermentation, the variable of major control is temperature, pH value and time in technique.Fruit vinegar fermentation object has time-varying
Property, time lag and its uncertainty, therefore be difficult to find or establish a certain exact mathematical model to carry out simulation and pre- observing and controlling
System.Fruit vinegar producer is controlled using conventional instrument, manually monitors various parameters mostly at present, and human factor is more, this control
Mode processed causes fruit vinegar quality unstable it is difficult to ensure that the correct execution of production technology, and fluctuation is big and is unfavorable for expanding regeneration
Production scale.In addition according to the monitor mode of wire communication, also there are access in radio maintenance cost height, the system expandability and shiftings
The problems such as dynamic poor performance.
The content of the invention
In order to solve the above technical problem, the present invention provides the purple sweet potato pears compound fruit vinegar fermentation monitoring system based on MAS, hairs
Fermentation tank includes:Pressure-resistant tank body 1, agitating device 2, mixture uniformity detector 3, oxygen transfer solenoid valve 4, oxygen concentration detection
Device 5, temperature sense chip 6, PH adjust liquid input solenoid valve 7, pH sensor 8, pressure reducing valve 9, pressure detector 10;It is described resistance to
Pressure tank body 1 is cylindrical structural;The agitating device 2 is arranged at pressure-resistant 1 middle part of tank body, 2 upper end of agitating device and pressure-resistant tank body 1
Upper cover dismantling connection;The mixture uniformity detector 3 is fixedly mounted on pressure-resistant 1 inner wall bottom of tank body;The oxygen conveying
Solenoid valve 4 is located at pressure-resistant 1 top of tank body, and oxygen transfer solenoid valve 4 passes through gas pipeline and pressure-resistant 1 through connection of tank body;It is described
Oxygen concentration detector 5 is arranged above pressure-resistant 1 inner wall of tank body, with the distance of pressure-resistant 1 upper cover of tank body 10cm~15cm it
Between;The temperature sense chip 6 is arranged in the middle part of pressure-resistant 1 inner wall of tank body;The PH adjusts liquid input 7 one end of solenoid valve and PH tune
Flow container through connection is saved, PH adjusts pressure-resistant 1 bottom of tank body of liquid input 7 other end through connection of solenoid valve;The pH sensor 8
Be fixedly mounted on pressure-resistant 1 inner wall of tank body, 8 lower part of pH sensor be equipped with lactic acid concn inductor, acetate concentration inductor,
Fruit acid concentration inductor, wherein lactic acid concn inductor, acetate concentration inductor, fruit acid concentration inductor are led respectively with controller
Line connects, and the distance of 1 upper cover of pH sensor 8 and pressure-resistant tank body is between 12cm~18cm;The pressure reducing valve 9 is arranged at pressure-resistant
1 top of tank body, pressure reducing valve 9 and pressure-resistant 1 through connection of tank body;The pressure detector 10 is fixedly mounted on pressure-resistant 1 top of tank body,
10 one end of pressure detector is insinuated into inside pressure-resistant tank body 1;
Controller includes:Dsp processor 100 pre-processes Agent101, fermentation process Agent102, alarm unit
Agent103, Communication Agent 104, central monitor Agent105;The dsp processor 100 distinguishes programming Control pretreatment
Agent101, fermentation process Agent102, alarm unit Agent103;The central monitor Agent105 passes through communication
Agent104 is connected with 100 interactive controlling of dsp processor.
Further, the pretreatment Agent101 is provided with the miscellaneous bacteria processing Agent101-1 that goes out, raw material automatic gauge
Agent101-2;Wherein, the miscellaneous bacteria processing Agent101-1 that goes out includes thermophilic digestion module and miscellaneous bacteria concentration detection module,
It monitors miscellaneous bacteria high temperature in fermentation tank in real time and eliminates situation;The raw material automatic gauge Agent101-2 includes computer metering mould
Type, accurate monitor fermentation raw material input quantity.
Further, the fermentation process Agent102 is provided with mixing control Agent102-1, oxygen conveying control
Agent102-2, temperature adjust Agent102-3, pH value adjustment Agent102-4, and pressure adjusts Agent102-5;Wherein, it is described
Mixing control Agent102-1 includes agitating device Controlling model, mixture uniformity detection module, the agitating device control
Agitating device 2 in simulation polygon control survey connection fermentation tank, the mixture uniformity detection module polygon control survey connection hair
Mixture uniformity detector 3 in fermentation tank;Oxygen conveying control agents 102-2 include oxygen concentration detection unit,
Oxygen conveys control unit, and the oxygen conveying control unit polygon control survey connects the oxygen transfer solenoid valve 4 on fermentation tank, institute
State the oxygen concentration detector 5 in oxygen concentration detection unit polygon control survey connection fermentation tank;The temperature adjusts Agent102-
3 are provided with temperature adjustment model, and the temperature adjustment model polygon control survey connects the temperature sense chip 6 in fermentation tank;It is described
PH value adjustment Agent102-4 includes pH value detection module, PH adjusts model, the pH value detection module polygon control survey connection
PH sensor 8 in fermentation tank, the PH that the PH is adjusted on model polygon control survey connection fermentation tank adjust liquid input solenoid valve
7;The pressure adjusts Agent102-5 and includes pressure detecting model, pressure adjusting model, the pressure detecting model conducting wire
Pressure detector 10 in control connection fermentation tank, the pressure adjust the pressure reducing valve 9 on model polygon control survey connection fermentation tank.
Further, the PH adjusts 7 rear end of liquid input solenoid valve and is provided with flowmeter.
Further, the temperature sense chip 6 is molded by high molecular material pressing mold, the composition of temperature sense chip 6 into
Divide and manufacturing process is as follows:
First, 6 constituent of temperature sense chip:
It counts in parts by weight, 67~127 parts of 8- acetyl group -7- hydroxy-4-methyl -2H-1- chromen-2-ones, 3- (3-
(bromo- (1,1- the biphenyl) -4- bases of 4-) -3- hydroxyl -1- phenylpropyls) 57~157 parts of -4- hydroxyl -2H-1- chromen-2-ones, 5,
97~217 parts of 7- dihydroxy -3- (4- hydroxyphenyls) -4H-1- benzopyran-4-ones, 2- benzoyls -1,2,3,6,7,11b- six
Hydrogen -4H- pyrazines simultaneously 17~57 parts of [2,1-a] isoquinolin -4- ketone, interior-hexahydro-8-hydroxy -2,6- methylene -2H- quinolizines -3
77~137 parts of (4H) -one, sub- -1,3 (the 2H)-diketone 37 of 2- (bis- bromo- 3- methylols -2 (1H)-quinoline subunits of AR-4-) -1H-~
77 parts, concentration be 27ppm~57ppm 57~117 parts of 6- bromomethyl -3,4- dihydro -2- methyl -4- oxoquinazolins, 1-
37~77 parts of (o- bromobenzyl) -6,7- methylenedioxy group -2- methyl -3,4- dihydro-isoquinolines salt compounded of iodine, N- Benzyl-N-methyls -3,4
117~147 parts of dimethoxy-phenylethylamine hydrobromate, 67~197 parts of crosslinking agent, (R)-N, N- diisopropyl -3- (2- hydroxyls -
5- aminomethyl phenyls) 47~117 parts of -3- phenylpropylamines hydrogen bromide salt, two [4- hydroxyls -3- [(2- hydroxyl -1- naphthalenes) azo]-N-
(3- methoxycarbonyl propyls) phenyl-sulfamide closes] 27~87 parts of sodium chromate, double [2- [[6- [(chloro- 6- methoxyl groups -1,3,5-triazines-of 4-
2- yls) amino] -1- hydroxyl -3- sulfo group -2- naphthalenes] azo] benzoic acid] close 47~137 parts of chromic acid disodium salt, 6- methyl -2-
[4- [[2- oxos -1- [[(4- sulfo group -1- naphthalenes) amino] carbonyl] propyl] azo] -3- sulfophenyls] -7- benzothiazole sulfonic acid
87~167 parts of trisodium salt;
The crosslinking agent is 1- (2- bromines bytyry)-pipecoline, N- (diphenyl methyl) -3- oxos butyramide, 2-
Any one in fluoro- 6- methyl benzonitriles;
2nd, the manufacturing process of temperature sense chip 6, comprises the steps of:
1st step:Ultra-pure water 1377~1647 part of the electrical conductivity for the μ S/cm of 2.27 μ S/cm~4.27 is added in a kettle,
Start reaction kettle in blender, rotating speed be 67rpm~127rpm, start heat pump, make reactor temperature rise to 47 DEG C~
77℃;Sequentially add 8- acetyl group -7- hydroxy-4-methyl -2H-1- chromen-2-ones, 3- (3- (4- bromo- (1,1- biphenyl) -
4- yls) -3- hydroxyl -1- phenylpropyls) -4- hydroxyl -2H-1- chromen-2-ones, 5,7- dihydroxy -3- (4- hydroxyphenyls) -4H-
1- benzopyran-4-ones, to being completely dissolved, it is 3.7~6.7 to adjust pH value for stirring, by agitator speed be adjusted to 137rpm~
257rpm, temperature is 97 DEG C~137 DEG C, when esterification 17~27 is small;
2nd step:Take 2- benzoyl -1,2,3,6,7,11b- hexahydro -4H- pyrazines simultaneously [2,1-a] isoquinolin -4- ketone, it is interior -
- 3 (4H) -one of hexahydro-8-hydroxy -2,6- methylene -2H- quinolizines crushes, and powder diameter is 527~1357 mesh;Add in 2-
- 1,3 (2H)-diketone of (bis- bromo- 3- methylols -2 (1H)-quinoline subunits of AR-4-) -1H- Asias are uniformly mixed, and are laid in pallet,
Tiling thickness is 37mm~57mm, uses the alpha ray spoke that dosage is 5.7MeV~14.7MeV for 3.7kGy~9.7kGy, energy
According to 67~147 minutes and the same dose of β x ray irradiation xs 57~137 minutes;
3rd step:The mixed-powder handled through the 2nd step is dissolved in 6- bromomethyl -3,4- dihydro -2- methyl -4- oxoquinazolins
In, reaction kettle is added in, agitator speed is 77rpm~187rpm, and temperature is 87 DEG C~167 DEG C, and starting vacuum pump makes reaction kettle
Vacuum degree reach 1.37MPa~1.87MPa, when keeping this state response 17~37 small;Pressure release is simultaneously passed through radon gas, makes reaction kettle
Interior pressure is 1.27MPa~1.67MPa, when heat preservation standing 27~37 is small;Agitator speed is promoted to 157rpm~297rpm, together
When reaction kettle pressure release to 0MPa;Sequentially add 1- (o- bromobenzyl) -6,7- methylenedioxy group -2- methyl -3,4- dihydro-isoquinoline iodine
After salt, N- Benzyl-N-methyl -3,4 dimethoxy-phenylethylamine hydrobromates are completely dissolved, add in crosslinking agent and be stirred so that
The hydrophilic lipophilic balance of reaction kettle solution is 5.7~8.7, when heat preservation standing 27~47 is small;
4th step:When agitator speed is 147rpm~227rpm, (R)-N, N- diisopropyl -3- (2- hydroxyls are sequentially added
Base -5- aminomethyl phenyls) -3- phenylpropylamines hydrogen bromide salt, two [4- hydroxyls -3- [(2- hydroxyl -1- naphthalenes) azo]-N- (3- methoxies
Propyl) phenyl-sulfamide close] sodium chromate, double [2- [[6- [(the chloro- 6- methoxyl groups -1,3,5- triazines -2- bases of 4-) amino] -1- hydroxyls
Base -3- sulfo group -2- naphthalenes] azo] benzoic acid] and close chromic acid disodium salt and 6- methyl -2- [4- [[2- oxos -1- [[(4- sulfo groups -
1- naphthalenes) amino] carbonyl] propyl] azo] -3- sulfophenyls] -7- benzothiazole sulfonic acid trisodium salts, reactor pressure is promoted, is made
It reaches 1.97MPa~2.77MPa, and temperature is 147 DEG C~267 DEG C, when polymerisation 17~27 is small;It will reaction after the completion of reaction
Pressure is down to 0MPa in kettle, is cooled to 27 DEG C~47 DEG C, and discharging enters molding press and can be prepared by temperature sense chip 6.
Further, the method for work for monitoring system of fermenting the invention also discloses the purple sweet potato pears compound fruit vinegar based on MAS,
This method includes following steps:
1st step:Staff carries out miscellaneous bacteria processing of going out by way of thermophilic digestion to fermentation tank, and going out, miscellaneous bacteria treats
Cheng Zhong, miscellaneous bacteria of going out processing Agent101-1 monitors miscellaneous bacteria high temperature in fermentation tank in real time and eliminates situation, when miscellaneous bacteria concentration detection module
When detecting that miscellaneous bacteria concentration is close to default value A in fermentation tank, miscellaneous bacteria of going out processing Agent101-1 sends signal, and raw material is automatic
Agent101-2 is measured to start to work;
2nd step:Computer metering model in raw material automatic gauge Agent101-2 is using high-precision measuring device, accurate measurement
Fermentation raw material input quantity;
3rd step:After fermentation raw material end of input, staff is by fermentation tank encapsulation process;Mixing control Agent102-1
In agitating device Controlling model start fermentation tank in agitating device 2, raw mixture in fermentation tank is mixed;
In whipping process, the mixture uniformity detector 3 in fermentation tank monitors the mixture uniformity in real time, when mixture is uniform
When degree detector 3 detects that the mixture uniformity in fermentation tank reaches default value X, mixture uniformity detector 3 will
Electric signal is sent to the mixture uniformity detection module in mixing control Agent102-1, and mixture uniformity detection module is anti-
Feedforward information to agitating device Controlling model, agitating device Controlling model stops agitating device 2;
4th step:During mixture carries out biological respinse in fermentation tank, the oxygen concentration being arranged in fermentation tank is visited
Device 5 is surveyed to monitor the oxygen concentration in fermentation tank in real time;When the oxygen concentration that oxygen concentration detector 5 is detected in fermentation tank is low
When default value B, the oxygen that electric signal is sent in oxygen conveying control agents 102-2 by oxygen concentration detector 5 is dense
Detection unit is spent, the oxygen transfer solenoid valve 4 on the oxygen conveying control unit opening fermentation tank of signal is received, until fermentation
Oxygen concentration in tank reaches default value B;
5th step:During mixture carries out biological respinse in fermentation tank, the temperature sense chip in fermentation tank
Temperature in 6 pairs of fermentation tanks monitors in real time;When the temperature that temperature sense chip 6 is detected in fermentation tank is less than default most
During low temperature T1, the temperature adjustment model for receiving feedback signal takes temperature-boosting measure;When temperature sense chip 6 detects fermentation
When temperature in tank is higher than the maximum temperature T2 of default, the temperature adjustment model for receiving feedback signal takes cooling to arrange
It applies;
6th step:During mixture carries out biological respinse in fermentation tank, the pH sensor 8 in fermentation tank is to hair
The pH value the real time measure of mixture in fermentation tank;When pH sensor 8 detect mixture pH value not default scope M1~
During M2, feedback signal is sent to the pH value detection module in pH value adjustment Agent102-4, pH value adjustment by pH sensor 8
The PH that PH in Agent102-4 is adjusted on model cootrol fermentation tank adjusts liquid input solenoid valve 7 and opens, until being mixed in fermentation tank
The pH value for closing object reaches default scope M1~M2;
7th step:During mixture carries out biological respinse in fermentation tank, the pressure detector 10 on fermentation tank
Pressure condition in monitoring fermentation tank in real time;When the pressure value that pressure detector 10 is detected in fermentation tank is higher than default value
Feedback signal is sent to pressure and adjusts pressure in Agent102-5 by P and during not less than default value 5%, pressure detector 10
Signal is passed to pressure and adjusts model by power detection model, pressure detecting model, and pressure adjusts model and opens subtracting on fermentation tank
Pressure valve 9, until the pressure value in fermentation tank is down to default value P;The pressure in fermentation tank is detected when pressure detector 10
When value is more than 15% higher than default value P, pressure adjusts Agent102-5 and sends information to alarm unit Agent103, reports
Alert unit Agent103 sends alarm signal, and dsp processor 100 takes urgent decompression measure.
Purple sweet potato pears compound fruit vinegar fermentation monitoring system disclosed by the invention based on MAS, the advantage is that:
(1) system uses multi-Agent control mode, and each relatively independent work of Agent, automatic adjustment and solution are each
The subproblem that Agent gives greatly improves system work efficiency, mutually communicates, coordinates, cooperates between each Agent, greatly improve
System stability;
(2) system uses multi-Agent control model, and flexible design is simple, has good modularity and autgmentability,
It extends convenient and efficient on the basis of original system, and does not influence original system stability;
(3) each Agent of the system solves alone subproblem, reduces system complexity, by question simplification, improves system solution
The certainly efficiency of problem, while also greatly reduce the totle drilling cost of system.
Purple sweet potato pears compound fruit vinegar fermentation monitoring system of the present invention based on MAS, the system are controlled using multi-Agent
Mode, each relatively independent work of Agent, automatically adjusts and solves the subproblem that each Agent gives, and greatly improves system work effect
Rate mutually communicates between each Agent, coordinates, cooperates, greatly improves system stability.
Description of the drawings
Fig. 1 is the heretofore described purple sweet potato pears compound fruit vinegar fermentation monitoring system fermentation tank schematic diagram based on MAS.
Fig. 2 is the heretofore described purple sweet potato pears compound fruit vinegar fermentation monitoring system controller schematic diagram based on MAS.
Fig. 3 is heretofore described temperature sense wafer material compression strength with usage time variation diagram.
In figure 1 above~Fig. 2, pressure-resistant tank body 1, agitating device 2, mixture uniformity detector 3, oxygen transfer solenoid valve
4, oxygen concentration detector 5, temperature sense chip 6, PH adjusting liquid input solenoid valves 7, pH sensor 8, pressure reducing valve 9, pressure
Detector 10, dsp processor 100 pre-process Agent101, miscellaneous bacteria of going out processing Agent101-1, raw material automatic gauge
Agent101-2, fermentation process Agent102, mixing control Agent102-1, oxygen conveying control agents 102-2, temperature tune
Agent102-3, pH value adjustment Agent102-4 are saved, pressure adjusts Agent102-5, alarm unit Agent103, communication
Agent104, central monitor Agent105.
Specific embodiment
With reference to the accompanying drawings and examples to the purple sweet potato pears compound fruit vinegar fermentation monitoring system provided by the invention based on MAS
It is further described.
As shown in Figure 1, it is that the heretofore described purple sweet potato pears compound fruit vinegar fermentation monitoring system fermentation tank based on MAS shows
It is intended to.As shown in Fig. 2, it is the heretofore described purple sweet potato pears compound fruit vinegar fermentation monitoring system controller signal based on MAS
Figure.Find out from Fig. 1 or Fig. 2, fermentation tank includes:Pressure-resistant tank body 1, agitating device 2, mixture uniformity detector 3, oxygen is defeated
Power transmission magnet valve 4, oxygen concentration detector 5, temperature sense chip 6, PH adjust liquid input solenoid valve 7, pH sensor 8, decompression
Valve 9, pressure detector 10;The pressure-resistant tank body 1 is cylindrical structural;The agitating device 2 is arranged at pressure-resistant 1 middle part of tank body,
2 upper end of agitating device and pressure-resistant 1 upper cover dismantling connection of tank body;The mixture uniformity detector 3 is fixedly mounted on autoclave
1 inner wall bottom of body;The oxygen transfer solenoid valve 4 is located at pressure-resistant 1 top of tank body, and oxygen transfer solenoid valve 4 passes through gas pipeline
With pressure-resistant 1 through connection of tank body;The oxygen concentration detector 5 is arranged above pressure-resistant 1 inner wall of tank body, with pressure-resistant tank body 1
The distance of upper cover is between 10cm~15cm;The temperature sense chip 6 is arranged in the middle part of pressure-resistant 1 inner wall of tank body;The PH tune
It saves liquid input 7 one end of solenoid valve and adjusts flow container through connection with PH, it is pressure-resistant that PH adjusts liquid input 7 other end through connection of solenoid valve
1 bottom of tank body;The pH sensor 8 is fixedly mounted on pressure-resistant 1 inner wall of tank body, and lactic acid is equipped in 8 lower part of pH sensor
Concentration inductor, acetate concentration inductor, fruit acid concentration inductor, wherein lactic acid concn inductor, acetate concentration inductor, fruit
Acid concentration inductor is connected respectively with controller conducting wire, and the distance of pH sensor 8 and pressure-resistant 1 upper cover of tank body is in 12cm~18cm
Between;The pressure reducing valve 9 is arranged at pressure-resistant 1 top of tank body, pressure reducing valve 9 and pressure-resistant 1 through connection of tank body;The pressure detector
10 are fixedly mounted on pressure-resistant 1 top of tank body, and 10 one end of pressure detector is insinuated into inside pressure-resistant tank body 1;
Controller includes:Dsp processor 100 pre-processes Agent101, fermentation process Agent102, alarm unit
Agent103, Communication Agent 104, central monitor Agent105;The dsp processor 100 distinguishes programming Control pretreatment
Agent101, fermentation process Agent102, alarm unit Agent103;The central monitor Agent105 passes through communication
Agent104 is connected with 100 interactive controlling of dsp processor.
Pretreatment Agent101 is provided with go out miscellaneous bacteria processing Agent101-1, raw material automatic gauge Agent101-2;Wherein,
The miscellaneous bacteria processing Agent101-1 that goes out includes thermophilic digestion module and miscellaneous bacteria concentration detection module, monitors in real time in fermentation tank
Miscellaneous bacteria high temperature eliminates situation;The raw material automatic gauge Agent101-2 includes computer metering model, and accurate monitor fermentation is former
Expect input quantity.
Fermentation process Agent102 is provided with mixing control Agent102-1, oxygen conveying control agents 102-2, temperature
Agent102-3, pH value adjustment Agent102-4 are adjusted, pressure adjusts Agent102-5;Wherein, the mixing control
Agent102-1 includes agitating device Controlling model, mixture uniformity detection module, and the agitating device Controlling model is led
Agitating device 2 in line traffic control connection fermentation tank, the mixture uniformity detection module polygon control survey are connected in fermentation tank
Mixture uniformity detector 3;The oxygen conveying control agents 102-2 includes oxygen concentration detection unit, oxygen conveying
Control unit, the oxygen conveying control unit polygon control survey connect the oxygen transfer solenoid valve 4 on fermentation tank, and the oxygen is dense
Spend the oxygen concentration detector 5 in detection unit polygon control survey connection fermentation tank;The temperature adjusts Agent102-3 and is provided with
Temperature adjustment model, the temperature adjustment model polygon control survey connect the temperature sense chip 6 in fermentation tank;The pH value adjustment
Agent102-4 includes pH value detection module, PH adjusts model, in the pH value detection module polygon control survey connection fermentation tank
PH sensor 8, the PH that the PH is adjusted on model polygon control survey connection fermentation tank adjusts liquid input solenoid valve 7;The pressure
Power adjusts Agent102-5 and includes pressure detecting model, pressure adjusting model, the pressure detecting model polygon control survey connection
Pressure detector 10 in fermentation tank, the pressure adjust the pressure reducing valve 9 on model polygon control survey connection fermentation tank.
PH adjusts 7 rear end of liquid input solenoid valve and is provided with flowmeter.
It is of the present invention based on MAS purple sweet potato pears compound fruit vinegar fermentation monitoring system the course of work be:
1st step:Staff carries out miscellaneous bacteria processing of going out by way of thermophilic digestion to fermentation tank, and going out, miscellaneous bacteria treats
Cheng Zhong, miscellaneous bacteria of going out processing Agent101-1 monitors miscellaneous bacteria high temperature in fermentation tank in real time and eliminates situation, when miscellaneous bacteria concentration detection module
When detecting that miscellaneous bacteria concentration is close to default value A in fermentation tank, miscellaneous bacteria of going out processing Agent101-1 sends signal, and raw material is automatic
Agent101-2 is measured to start to work;
2nd step:Computer metering model in raw material automatic gauge Agent101-2 is using high-precision measuring device, accurate measurement
Fermentation raw material input quantity;
3rd step:After fermentation raw material end of input, staff is by fermentation tank encapsulation process;Mixing control Agent102-1
In agitating device Controlling model start fermentation tank in agitating device 2, raw mixture in fermentation tank is mixed;
In whipping process, the mixture uniformity detector 3 in fermentation tank monitors the mixture uniformity in real time, when mixture is uniform
When degree detector 3 detects that the mixture uniformity in fermentation tank reaches default value X, mixture uniformity detector 3 will
Electric signal is sent to the mixture uniformity detection module in mixing control Agent102-1, and mixture uniformity detection module is anti-
Feedforward information to agitating device Controlling model, agitating device Controlling model stops agitating device 2;
4th step:During mixture carries out biological respinse in fermentation tank, the oxygen concentration being arranged in fermentation tank is visited
Device 5 is surveyed to monitor the oxygen concentration in fermentation tank in real time;When the oxygen concentration that oxygen concentration detector 5 is detected in fermentation tank is low
When default value B, the oxygen that electric signal is sent in oxygen conveying control agents 102-2 by oxygen concentration detector 5 is dense
Detection unit is spent, the oxygen transfer solenoid valve 4 on the oxygen conveying control unit opening fermentation tank of signal is received, until fermentation
Oxygen concentration in tank reaches default value B;
5th step:During mixture carries out biological respinse in fermentation tank, the temperature sense chip in fermentation tank
Temperature in 6 pairs of fermentation tanks monitors in real time;When the temperature that temperature sense chip 6 is detected in fermentation tank is less than default most
During low temperature T1, the temperature adjustment model for receiving feedback signal takes temperature-boosting measure;When temperature sense chip 6 detects fermentation
When temperature in tank is higher than the maximum temperature T2 of default, the temperature adjustment model for receiving feedback signal takes cooling to arrange
It applies;
6th step:During mixture carries out biological respinse in fermentation tank, the pH sensor 8 in fermentation tank is to hair
The pH value the real time measure of mixture in fermentation tank;When pH sensor 8 detect mixture pH value not default scope M1~
During M2, feedback signal is sent to the pH value detection module in pH value adjustment Agent102-4, pH value adjustment by pH sensor 8
The PH that PH in Agent102-4 is adjusted on model cootrol fermentation tank adjusts liquid input solenoid valve 7 and opens, until being mixed in fermentation tank
The pH value for closing object reaches default scope M1~M2;
7th step:During mixture carries out biological respinse in fermentation tank, the pressure detector 10 on fermentation tank
Pressure condition in monitoring fermentation tank in real time;When the pressure value that pressure detector 10 is detected in fermentation tank is higher than default value
Feedback signal is sent to pressure and adjusts pressure in Agent102-5 by P and during not less than default value 5%, pressure detector 10
Signal is passed to pressure and adjusts model by power detection model, pressure detecting model, and pressure adjusts model and opens subtracting on fermentation tank
Pressure valve 9, until the pressure value in fermentation tank is down to default value P;The pressure in fermentation tank is detected when pressure detector 10
When value is more than 15% higher than default value P, pressure adjusts Agent102-5 and sends information to alarm unit Agent103, reports
Alert unit Agent103 sends alarm signal, and dsp processor 100 takes urgent decompression measure.
Purple sweet potato pears compound fruit vinegar fermentation monitoring system of the present invention based on MAS, the system are controlled using multi-Agent
Mode, each relatively independent work of Agent, automatically adjusts and solves the subproblem that each Agent gives, and greatly improves system work effect
Rate mutually communicates between each Agent, coordinates, cooperates, greatly improves system stability.
It is the embodiment of the manufacturing process of temperature sense chip 6 of the present invention below, embodiment is in order to furtherly
Bright present disclosure, but should not be construed as limiting the invention.Without departing from the spirit and substance of the case in the present invention, it is right
The modification and replacement that the method for the present invention, step or condition are made, all belong to the scope of the present invention.
Unless otherwise specified, the conventional means that technological means used in embodiment is well known to those skilled in the art.
Embodiment 1
Temperature sense chip 6 of the present invention is manufactured according to following steps, and is counted in parts by weight:
1st step:1377 parts of the ultra-pure water that electrical conductivity is 2.27 μ S/cm is added in a kettle, starts stirring in reaction kettle
Device, rotating speed 67rpm start heat pump, reactor temperature are made to rise to 47 DEG C;Sequentially add 8- acetyl group -7- hydroxyls -4-
67 parts of methyl -2H-1- chromen-2-ones, 3- (3- (bromo- (1,1- the biphenyl) -4- bases of 4-) -3- hydroxyl -1- phenylpropyls) -4- hydroxyls
57 parts of base -2H-1- chromen-2-ones, 97 parts of 5,7- dihydroxy -3- (4- hydroxyphenyls) -4H-1- benzopyran-4-ones, stirring
To being completely dissolved, it is 3.7 to adjust pH value, agitator speed is adjusted to 137rpm, temperature is 97 DEG C, when esterification 17 is small;
2nd step:Take 2- benzoyl -1,2,3,6,7,11b- hexahydro -4H- pyrazines simultaneously [2,1-a] isoquinolin -4- ketone 17
Part, interior--3 77 parts of (4H) -one of hexahydro-8-hydroxy -2,6- methylene -2H- quinolizines crush, and powder diameter is 527 mesh;Add
Enter 2- (bis- bromo- 3- methylols -2 (1H)-quinoline subunits of AR-4-) -1H- indenes -1,3 (2H) -37 parts of diketone to be uniformly mixed, be laid in
In pallet, tiling thickness is 37mm, and the alpha ray that dosage is used to be 5.7MeV for 3.7kGy, energy irradiates 67 minutes and equal
The β x ray irradiation xs of dosage 57 minutes;
3rd step:6- bromomethyl -3,4- dihydro -2- methyl -4- is dissolved in through the mixed-powder that the 2nd step concentration for the treatment of is 27ppm
In 57 parts of oxoquinazolin, reaction kettle, agitator speed 77rpm are added in, temperature is 87 DEG C, and starting vacuum pump makes reaction kettle
Vacuum degree reaches 1.37MPa, when keeping this state response 17 small;Pressure release is simultaneously passed through radon gas, makes the reacting kettle inner pressure be
1.27MPa, when heat preservation standing 27 is small;Agitator speed is promoted to 157rpm, simultaneous reactions kettle pressure release to 0MPa;Sequentially add 1-
37 parts of (o- bromobenzyl) -6,7- methylenedioxy group -2- methyl -3,4- dihydro-isoquinolines salt compounded of iodine, -3,4 diformazan of N- Benzyl-N-methyls
After 117 parts of oxygroup phenyl ethylamine hydrobromate is completely dissolved, add in 67 parts of crosslinking agent be stirred so that reaction kettle solution it is hydrophilic
Lipophilic balance value is 5.7, when heat preservation standing 27 is small;
4th step:When agitator speed is 147rpm, (R)-N, N- diisopropyl -3- (2- hydroxy-5-methyls are sequentially added
Base phenyl) 47 parts of -3- phenylpropylamines hydrogen bromide salt, two [4- hydroxyls -3- [(2- hydroxyl -1- naphthalenes) azo]-N- (3- methoxies third
Base) phenyl-sulfamide close] 27 parts of sodium chromate, double [2- [[6- [(the chloro- 6- methoxyl groups -1,3,5- triazines -2- bases of 4-) amino] -1-
Hydroxyl -3- sulfo group -2- naphthalenes] azo] benzoic acid] close 47 parts of chromic acid disodium salt and 6- methyl -2- [4- [[2- oxo -1- [[(4-
Sulfo group -1- naphthalenes) amino] carbonyl] propyl] azo] -3- sulfophenyls] 87 parts of -7- benzothiazole sulfonic acid trisodium salt, promote reaction
Kettle pressure reaches 1.97MPa, and temperature is 147 DEG C, when polymerisation 17 is small;Reacting kettle inner pressure is dropped after the completion of reaction
To 0MPa, 27 DEG C are cooled to, discharging enters molding press and can be prepared by temperature sense chip 6;
The crosslinking agent is 1- (2- bromines bytyry)-pipecoline.
Embodiment 2
Temperature sense chip 6 of the present invention is manufactured according to following steps, and is counted in parts by weight:
1st step:1647 parts of the ultra-pure water that electrical conductivity is 4.27 μ S/cm is added in a kettle, starts stirring in reaction kettle
Device, rotating speed 127rpm start heat pump, reactor temperature are made to rise to 77 DEG C;Sequentially add 8- acetyl group -7- hydroxyls -
127 parts of 4- methyl -2H-1- chromen-2-ones, 3- (3- (bromo- (1,1- the biphenyl) -4- bases of 4-) -3- hydroxyl -1- phenylpropyls) -
157 parts of 4- hydroxyl -2H-1- chromen-2-ones, 5,7- dihydroxy -3- (4- hydroxyphenyls) -4H-1- benzopyran-4-ones 217
Part, to being completely dissolved, it is 6.7 to adjust pH value for stirring, agitator speed is adjusted to 257rpm, temperature is 137 DEG C, esterification 27
Hour;
2nd step:Take 2- benzoyl -1,2,3,6,7,11b- hexahydro -4H- pyrazines simultaneously [2,1-a] isoquinolin -4- ketone 57
Part, interior--3 137 parts of (4H) -one of hexahydro-8-hydroxy -2,6- methylene -2H- quinolizines crush, and powder diameter is 1357 mesh;
It adds in 2- (bis- bromo- 3- methylols -2 (1H)-quinoline subunits of AR-4-) -1H- indenes -1,3 (2H) -77 parts of diketone to be uniformly mixed, tiling
In in pallet, tiling thickness is 57mm, the alpha ray that dosage is used to be 14.7MeV for 9.7kGy, energy irradiate 147 minutes and
The same dose of β x ray irradiation xs 137 minutes;
3rd step:6- bromomethyl -3,4- dihydro -2- methyl -4- is dissolved in through the mixed-powder that the 2nd step concentration for the treatment of is 57ppm
In 117 parts of oxoquinazolin, reaction kettle, agitator speed 187rpm are added in, temperature is 167 DEG C, and starting vacuum pump makes reaction
The vacuum degree of kettle reaches 1.87MPa, when keeping this state response 37 small;Pressure release is simultaneously passed through radon gas, makes the reacting kettle inner pressure be
1.67MPa, when heat preservation standing 37 is small;Agitator speed is promoted to 297rpm, simultaneous reactions kettle pressure release to 0MPa;Sequentially add 1-
77 parts of (o- bromobenzyl) -6,7- methylenedioxy group -2- methyl -3,4- dihydro-isoquinolines salt compounded of iodine, -3,4 diformazan of N- Benzyl-N-methyls
After 147 parts of oxygroup phenyl ethylamine hydrobromate is completely dissolved, adds in 197 parts of crosslinking agent and be stirred so that the parent of reaction kettle solution
Hydrophile-lipophile balance value is 8.7, when heat preservation standing 47 is small;
4th step:When agitator speed is 227rpm, (R)-N, N- diisopropyl -3- (2- hydroxy-5-methyls are sequentially added
Base phenyl) 117 parts of -3- phenylpropylamines hydrogen bromide salt, two [4- hydroxyls -3- [(2- hydroxyl -1- naphthalenes) azo]-N- (3- methoxies third
Base) phenyl-sulfamide close] 87 parts of sodium chromate, double [2- [[6- [(the chloro- 6- methoxyl groups -1,3,5- triazines -2- bases of 4-) amino] -1-
Hydroxyl -3- sulfo group -2- naphthalenes] azo] benzoic acid] close 137 parts of chromic acid disodium salt and 6- methyl -2- [4- [[2- oxos -1-
[[(4- sulfo group -1- naphthalenes) amino] carbonyl] propyl] azo] -3- sulfophenyls] 167 parts of -7- benzothiazole sulfonic acid trisodium salt, it carries
Reactor pressure is risen, reaches 2.77MPa, temperature is 267 DEG C, when polymerisation 27 is small;It will be in reaction kettle after the completion of reaction
Pressure is down to 0MPa, is cooled to 47 DEG C, and discharging enters molding press and can be prepared by temperature sense chip 6;
The crosslinking agent is N- (diphenyl methyl) -3- oxo butyramides.
Embodiment 3
Temperature sense chip 6 of the present invention is manufactured according to following steps, and is counted in parts by weight:
1st step:1447 parts of the ultra-pure water that electrical conductivity is 3.27 μ S/cm is added in a kettle, starts stirring in reaction kettle
Device, rotating speed 97rpm start heat pump, reactor temperature are made to rise to 67 DEG C;Sequentially add 8- acetyl group -7- hydroxyls -4-
87 parts of methyl -2H-1- chromen-2-ones, 3- (3- (bromo- (1,1- the biphenyl) -4- bases of 4-) -3- hydroxyl -1- phenylpropyls) -4- hydroxyls
137 parts of base -2H-1- chromen-2-ones, 187 parts of 5,7- dihydroxy -3- (4- hydroxyphenyls) -4H-1- benzopyran-4-ones, are stirred
It mixes to being completely dissolved, it is 4.7 to adjust pH value, agitator speed is adjusted to 197rpm, temperature is 117 DEG C, when esterification 22 is small;
2nd step:Take 2- benzoyl -1,2,3,6,7,11b- hexahydro -4H- pyrazines simultaneously [2,1-a] isoquinolin -4- ketone 37
Part, interior--3 87 parts of (4H) -one of hexahydro-8-hydroxy -2,6- methylene -2H- quinolizines crush, and powder diameter is 957 mesh;Add
Enter 2- (bis- bromo- 3- methylols -2 (1H)-quinoline subunits of AR-4-) -1H- indenes -1,3 (2H) -57 parts of diketone to be uniformly mixed, be laid in
In pallet, tiling thickness is 47mm, and the alpha ray that dosage is used to be 9.7MeV for 6.7kGy, energy irradiates 117 minutes, Yi Jitong
Isodose β x ray irradiation xs 87 minutes;
3rd step:6- bromomethyl -3,4- dihydro -2- methyl -4- is dissolved in through the mixed-powder that the 2nd step concentration for the treatment of is 47ppm
In 77 parts of oxoquinazolin, reaction kettle, agitator speed 127rpm are added in, temperature is 137 DEG C, and starting vacuum pump makes reaction kettle
Vacuum degree reach 1.17MPa, when keeping this state response 27 small;Pressure release is simultaneously passed through radon gas, makes the reacting kettle inner pressure be
1.47MPa, when heat preservation standing 32 is small;Agitator speed is promoted to 197rpm, simultaneous reactions kettle pressure release to 0MPa;Sequentially add 1-
57 parts of (o- bromobenzyl) -6,7- methylenedioxy group -2- methyl -3,4- dihydro-isoquinolines salt compounded of iodine, -3,4 diformazan of N- Benzyl-N-methyls
After 127 parts of oxygroup phenyl ethylamine hydrobromate is completely dissolved, adds in 137 parts of crosslinking agent and be stirred so that the parent of reaction kettle solution
Hydrophile-lipophile balance value is 6.7, when heat preservation standing 37 is small;
4th step:When agitator speed is 177rpm, (R)-N, N- diisopropyl -3- (2- hydroxy-5-methyls are sequentially added
Base phenyl) 87 parts of -3- phenylpropylamines hydrogen bromide salt, two [4- hydroxyls -3- [(2- hydroxyl -1- naphthalenes) azo]-N- (3- methoxies third
Base) phenyl-sulfamide close] 67 parts of sodium chromate, double [2- [[6- [(the chloro- 6- methoxyl groups -1,3,5- triazines -2- bases of 4-) amino] -1-
Hydroxyl -3- sulfo group -2- naphthalenes] azo] benzoic acid] close 117 parts of chromic acid disodium salt and 6- methyl -2- [4- [[2- oxos -1-
[[(4- sulfo group -1- naphthalenes) amino] carbonyl] propyl] azo] -3- sulfophenyls] 147 parts of -7- benzothiazole sulfonic acid trisodium salt, it carries
Reactor pressure is risen, reaches 2.27MPa, temperature is 227 DEG C, when polymerisation 24 is small;It will be in reaction kettle after the completion of reaction
Pressure is down to 0MPa, is cooled to 37 DEG C, and discharging enters molding press and can be prepared by temperature sense chip 6;
The crosslinking agent is the fluoro- 6- methyl benzonitriles of 2-.
Reference examples
Reference examples are the temperature sense chip of certain commercially available brand.
Embodiment 4
Temperature sense chip described in temperature sense chip 6 and reference examples that Examples 1 to 3 prepares is used
Contrast on effect.The two reaction rate, corrosion resistant erosion degree, antioxygen rate, high pressure resistant degree are counted, the results are shown in Table 1.
As seen from Table 1, temperature sense chip 6 of the present invention, reaction rate, corrosion resistant erosion degree, antioxygen rate, resistance to height
The indexs such as pressure degree are superior to the product of prior art production.
In addition, as shown in figure 3, it is that 6 material compression strength of temperature sense chip of the present invention changes with usage time
Statistics.Find out in figure, temperature sense chip 6 used in Examples 1 to 3, material compression strength is with usage time variation degree
Significantly it is better than existing product.
Claims (1)
1. the purple sweet potato pears compound fruit vinegar fermentation monitoring system based on MAS, fermentation tank include:Pressure-resistant tank body(1), agitating device(2),
Mixture uniformity detector(3), oxygen transfer solenoid valve(4), oxygen concentration detector(5), temperature sense chip(6), PH
Adjust liquid input solenoid valve(7), pH sensor(8), pressure reducing valve(9), pressure detector(10);It is it is characterized in that, described resistance to
Press tank body(1)For cylindrical structural;The agitating device(2)It is arranged at pressure-resistant tank body(1)Middle part, agitating device(2)Upper end with
Pressure-resistant tank body(1)Upper cover dismantling connection;The mixture uniformity detector(3)It is fixedly mounted on pressure-resistant tank body(1)Inner wall bottom
Portion;The oxygen transfer solenoid valve(4)Positioned at pressure-resistant tank body(1)Top, oxygen transfer solenoid valve(4)By gas pipeline with it is resistance to
Press tank body(1)Through connection;The oxygen concentration detector(5)It is arranged at pressure-resistant tank body(1)Above inner wall, with pressure-resistant tank body
(1)The distance of upper cover is between 10cm~15cm;The temperature sense chip(6)It is arranged at pressure-resistant tank body(1)In the middle part of inner wall;Institute
It states PH and adjusts liquid input solenoid valve(7)One end adjusts flow container through connection with PH, and PH adjusts liquid input solenoid valve(7)The other end passes through
Lead to and connect pressure-resistant tank body(1)Bottom;The pH sensor(8)It is fixedly mounted on pressure-resistant tank body(1)On inner wall, detected in pH value
Device(8)Lower part be equipped with lactic acid concn inductor, acetate concentration inductor, fruit acid concentration inductor, wherein lactic acid concn inductor,
Acetate concentration inductor, fruit acid concentration inductor are connected respectively with controller conducting wire, pH sensor(8)With pressure-resistant tank body(1)
The distance of upper cover is between 12cm~18cm;The pressure reducing valve(9)It is arranged at pressure-resistant tank body(1)Top, pressure reducing valve(9)With it is pressure-resistant
Tank body(1)Through connection;The pressure detector(10)It is fixedly mounted on pressure-resistant tank body(1)Top, pressure detector(10)One
End is insinuated into pressure-resistant tank body(1)It is internal;
Controller includes:Dsp processor(100), pre-process Agent(101), fermentation process Agent(102), alarm unit
Agent(103), Communication Agent(104), central monitor Agent(105);The dsp processor(100)Programming Control respectively
Pre-process Agent(101), fermentation process Agent(102), alarm unit Agent(103);The central monitor Agent
(105)Pass through Communication Agent(104)With dsp processor(100)Interactive controlling connects;
The pretreatment Agent(101)It is provided with the miscellaneous bacteria processing Agent that goes out(101-1), raw material automatic gauge Agent(101-
2);Wherein, the miscellaneous bacteria processing Agent that goes out(101-1)Include thermophilic digestion module and miscellaneous bacteria concentration detection module, supervise in real time
It controls miscellaneous bacteria high temperature in fermentation tank and eliminates situation;The raw material automatic gauge Agent(101-2)Include computer metering model, essence
True monitor fermentation raw material input quantity;
The fermentation process Agent(102)It is provided with mixing control Agent(102-1), oxygen conveying control agents(102-
2), temperature adjusting Agent(102-3), pH value adjustment Agent(102-4), pressure adjusting Agent(102-5);Wherein, it is described to stir
Mix control agents(102-1)Include agitating device Controlling model, mixture uniformity detection module, the agitating device control
Agitating device in simulation polygon control survey connection fermentation tank(2), the mixture uniformity detection module polygon control survey connection
Mixture uniformity detector in fermentation tank(3);The oxygen conveys control agents(102-2)Include oxygen concentration inspection
Unit, oxygen conveying control unit are surveyed, the oxygen conveying control unit polygon control survey connects the oxygen conveying electricity on fermentation tank
Magnet valve(4), the oxygen concentration detector in oxygen concentration detection unit polygon control survey connection fermentation tank(5);The temperature
Adjust Agent(102-3)Temperature adjustment model is provided with, the temperature adjustment model polygon control survey connects the temperature in fermentation tank
Sense chip(6);The pH value adjustment Agent(102-4)Include pH value detection module, PH adjusts model, the pH value inspection
Survey the pH sensor in module polygon control survey connection fermentation tank(8), the PH adjusted on model polygon control survey connection fermentation tank
PH adjust liquid input solenoid valve(7);The pressure adjusts Agent(102-5)Include pressure detecting model, pressure adjusts mould
Type, the pressure detecting model polygon control survey connect the pressure detector in fermentation tank(10), the pressure adjusting model conducting wire
Pressure reducing valve on control connection fermentation tank(9);
The PH adjusts liquid input solenoid valve(7)Rear end is provided with flowmeter;
The temperature sense chip(6)It is molded by high molecular material pressing mold, temperature sense chip(6)Constituent and manufactured
Journey is as follows:
First, temperature sense chip(6)Constituent:
It counts in parts by weight, 67~127 parts of 8- acetyl group -7- hydroxy-4-methyl -2H-1- chromen-2-ones, 3- (3- (4-
Bromo- (1,1- biphenyl) -4- bases) -3- hydroxyl -1- phenylpropyls) 57~157 parts of -4- hydroxyl -2H-1- chromen-2-ones, 5,7-
97~217 parts of dihydroxy -3- (4- hydroxyphenyls) -4H-1- benzopyran-4-ones, 2- benzoyls -1,2,3,6,7,11b- six
Hydrogen -4H- pyrazines simultaneously 17~57 parts of [2,1-a] isoquinolin -4- ketone, interior-hexahydro-8-hydroxy -2,6- methylene -2H- quinolizines -3
77~137 parts of (4H) -one, sub- -1,3 (the 2H)-diketone 37~77 of bis- bromo- 3- methylols -2 (1H) of 2-AR-4--quinoline subunit -1H-
Part, concentration is 57~117 parts of 6- bromomethyl -3,4- dihydro -2- methyl -4- oxoquinazolins of the ppm of 27 ppm~57,1-
37~77 parts of (o- bromobenzyl) -6,7- methylenedioxy group -2- methyl -3,4- dihydro-isoquinolines salt compounded of iodine, N- Benzyl-N-methyls -3,4
117~147 parts of dimethoxy-phenylethylamine hydrobromate, 67~197 parts of crosslinking agent, (R)-N, N- diisopropyl -3- (2- hydroxyls -
5- aminomethyl phenyls) 47~117 parts of -3- phenylpropylamines hydrogen bromide salt, two [4- hydroxyls -3- [(2- hydroxyl -1- naphthalenes) azo]-N-
(3- methoxycarbonyl propyls) phenyl-sulfamide closes] 27~87 parts of sodium chromate, double [2- [[6- [(chloro- 6- methoxyl groups -1,3,5-triazines-of 4-
2- yls) amino] -1- hydroxyl -3- sulfo group -2- naphthalenes] azo] benzoic acid] close 47~137 parts of chromic acid disodium salt, 6- methyl -2-
[4- [[2- oxos -1- [[(4- sulfo group -1- naphthalenes) amino] carbonyl] propyl] azo] -3- sulfophenyls] -7- benzothiazole sulfonic acid
87~167 parts of trisodium salt;
The crosslinking agent is 1- (2- bromines bytyry)-pipecoline, N- (diphenyl methyl) -3- oxos butyramide, 2- are fluoro-
Any one in 6- methyl benzonitriles;
2nd, temperature sense chip(6)Manufacturing process, comprise the steps of:
1st step:Ultra-pure water 1377~1647 part of the electrical conductivity for the μ S/cm of 2.27 μ S/cm~4.27 is added in a kettle, is opened
Blender in dynamic reaction kettle, rotating speed are the rpm of 67 rpm~127, start heat pump, make reactor temperature rise to 47 DEG C~
77 ℃;Sequentially add 8- acetyl group -7- hydroxy-4-methyl -2H-1- chromen-2-ones, 3- (3- (bromo- (1, the 1- connection of 4-
Benzene) -4- bases) -3- hydroxyl -1- phenylpropyls) -4- hydroxyl -2H-1- chromen-2-ones, 5,7- dihydroxy -3- (4- hydroxyphenyls) -
4H-1- benzopyran-4-ones, to being completely dissolved, it is 3.7~6.7 to adjust pH value, and agitator speed is adjusted to 137 rpm for stirring
~257 rpm, temperature is 97 DEG C~137 DEG C, when esterification 17~27 is small;
2nd step:Take 2- benzoyl -1,2,3,6,7,11b- hexahydro -4H- pyrazines simultaneously [2,1-a] isoquinolin -4- ketone, interior-six
- 3 (4H) -one of hydrogen -8- hydroxyl -2,6- methylene -2H- quinolizines crushes, and powder diameter is 527~1357 mesh;Add in 2-
(bis- bromo- 3- methylols -2 (1H)-quinoline subunits of AR-4-) -1H- indenes -1,3 (2H)-diketone is uniformly mixed, is laid in pallet,
Tiling thickness is the mm of 37 mm~57, uses dosage as α that the kGy of 3.7 kGy~9.7, energy are the MeV of 5.7 MeV~14.7
X ray irradiation x 67~147 minutes and the same dose of β x ray irradiation xs 57~137 minutes;
3rd step:The mixed-powder handled through the 2nd step is dissolved in 6- bromomethyl -3,4- dihydro -2- methyl -4- oxoquinazolins, is added
Enter reaction kettle, agitator speed is the rpm of 77 rpm~187, and temperature is 87 DEG C~167 DEG C, and starting vacuum pump makes the true of reaction kettle
Reciprocal of duty cycle reaches the MPa of 1.37 MPa~1.87, when keeping this state response 17~37 small;Pressure release is simultaneously passed through radon gas, makes in reaction kettle
Pressure is the MPa of 1.27 MPa~1.67, heat preservation stand 27~37 it is small when;Agitator speed is promoted to the rpm of 157 rpm~297,
The pressure release of simultaneous reactions kettle is to 0MPa;Sequentially add 1- (o- bromobenzyl) -6,7- methylenedioxy group -2- methyl -3,4- dihydro-isoquinolines
After salt compounded of iodine, N- Benzyl-N-methyl -3,4 dimethoxy-phenylethylamine hydrobromates are completely dissolved, add in crosslinking agent and be stirred, make
The hydrophilic lipophilic balance for obtaining reaction kettle solution is 5.7~8.7, when heat preservation standing 27~47 is small;
4th step:When agitator speed is 147 rpm~227 rpm, (R)-N, N- diisopropyl -3- (2- hydroxyls are sequentially added
Base -5- aminomethyl phenyls) -3- phenylpropylamines hydrogen bromide salt, two [4- hydroxyls -3- [(2- hydroxyl -1- naphthalenes) azo]-N- (3- methoxies
Propyl) phenyl-sulfamide close] sodium chromate, double [2- [[6- [(the chloro- 6- methoxyl groups -1,3,5- triazines -2- bases of 4-) amino] -1- hydroxyls
Base -3- sulfo group -2- naphthalenes] azo] benzoic acid] and close chromic acid disodium salt and 6- methyl -2- [4- [[2- oxos -1- [[(4- sulfo groups -
1- naphthalenes) amino] carbonyl] propyl] azo] -3- sulfophenyls] -7- benzothiazole sulfonic acid trisodium salts, reactor pressure is promoted, is made
It reaches the MPa of 1.97 MPa~2.77, and temperature is 147 DEG C~267 DEG C, when polymerisation 17~27 is small;It will be anti-after the completion of reaction
Pressure in kettle is answered to be down to 0 MPa, is cooled to 27 DEG C~47 DEG C, discharging enters molding press and can be prepared by temperature sense chip(6);
The method of work of purple sweet potato pears compound fruit vinegar fermentation monitoring system based on MAS, this method include following steps:
1st step:Staff carries out miscellaneous bacteria processing of going out by way of thermophilic digestion to fermentation tank, in miscellaneous bacteria processing procedure of going out
In, miscellaneous bacteria of going out processing Agent(101-1)It monitors miscellaneous bacteria high temperature in fermentation tank in real time and eliminates situation, when miscellaneous bacteria concentration detection module
When detecting that miscellaneous bacteria concentration is close to default value A in fermentation tank, miscellaneous bacteria of going out processing Agent(101-1)Signal is sent, raw material is certainly
Dynamic metering Agent(101-2)It starts to work;
2nd step:Raw material automatic gauge Agent(101-2)In computer metering model using high-precision measuring device, accurate measurement hair
Ferment raw material input quantity;
3rd step:After fermentation raw material end of input, staff is by fermentation tank encapsulation process;Mixing control Agent(102-1)In
Agitating device Controlling model start fermentation tank in agitating device(2), raw mixture in fermentation tank is mixed;
In whipping process, the mixture uniformity detector in fermentation tank(3)The mixture uniformity is monitored in real time, when mixture is equal
Evenness detector(3)When detecting that the mixture uniformity in fermentation tank reaches default value X, mixture uniformity detector
(3)Electric signal is sent to mixing control Agent(102-1)Interior mixture uniformity detection module, the inspection of the mixture uniformity
Module feedback information is surveyed to agitating device Controlling model, agitating device Controlling model stops agitating device(2);
4th step:During mixture carries out biological respinse in fermentation tank, the oxygen concentration detector that is arranged in fermentation tank
(5)Oxygen concentration in fermentation tank is monitored in real time;When oxygen concentration detector(5)Detect that the oxygen concentration in fermentation tank is low
When default value B, oxygen concentration detector(5)Electric signal is sent to oxygen conveying control agents(102-2)In oxygen
Gas concentration detection unit receives the oxygen transfer solenoid valve on the oxygen conveying control unit opening fermentation tank of signal(4), directly
Oxygen concentration in fermentation tank reaches default value B;
5th step:During mixture carries out biological respinse in fermentation tank, the temperature sense chip in fermentation tank(6)
Temperature in fermentation tank is monitored in real time;When temperature sense chip(6)Detect the temperature in fermentation tank less than default
During minimum temperature T1, the temperature adjustment model for receiving feedback signal takes temperature-boosting measure;When temperature sense chip(6)It detects
When temperature in fermentation tank is higher than the maximum temperature T2 of default, the temperature adjustment model for receiving feedback signal takes cooling
Measure;
6th step:During mixture carries out biological respinse in fermentation tank, the pH sensor in fermentation tank(8)To fermentation
The pH value the real time measure of in-tank mixing object;Work as pH sensor(8)Detect mixture pH value not default scope M1~
During M2, pH sensor(8)Feedback signal is sent to pH value adjustment Agent(102-4)In pH value detection module, pH value tune
Save Agent(102-4)In PH adjust model cootrol fermentation tank on PH adjust liquid input solenoid valve(7)It opens, until fermentation
The pH value of in-tank mixing object reaches default scope M1~M2;
7th step:During mixture carries out biological respinse in fermentation tank, the pressure detector on fermentation tank(10)It is real
When monitor fermentation tank in pressure condition;Work as pressure detector(10)Detect that the pressure value in fermentation tank is higher than default value
P and during not less than default value 5%, pressure detector(10)Feedback signal is sent to pressure and adjusts Agent(102-5)In
Pressure detecting model, pressure detecting model by signal pass to pressure adjust model, pressure adjust model open fermentation tank on
Pressure reducing valve(9), until the pressure value in fermentation tank is down to default value P;Work as pressure detector(10)Detect fermentation tank
When interior pressure value is more than 15% higher than default value P, pressure adjusts Agent(102-5)Send information to alarm unit
Agent(103), alarm unit Agent(103)Send alarm signal, dsp processor(100)Take urgent decompression measure.
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