CN106795693A - 包括水性聚氨酯组合物的分散体和膜 - Google Patents
包括水性聚氨酯组合物的分散体和膜 Download PDFInfo
- Publication number
- CN106795693A CN106795693A CN201580030966.2A CN201580030966A CN106795693A CN 106795693 A CN106795693 A CN 106795693A CN 201580030966 A CN201580030966 A CN 201580030966A CN 106795693 A CN106795693 A CN 106795693A
- Authority
- CN
- China
- Prior art keywords
- product
- dispersion
- fiber array
- prepolymer
- dispersions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 35
- 239000006185 dispersion Substances 0.000 title claims description 86
- 239000004814 polyurethane Substances 0.000 title claims description 27
- 229920002635 polyurethane Polymers 0.000 title claims description 26
- 239000000835 fiber Substances 0.000 claims abstract description 47
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims description 31
- 239000000758 substrate Substances 0.000 claims description 19
- 229920003226 polyurethane urea Polymers 0.000 claims description 13
- 239000004094 surface-active agent Substances 0.000 claims description 9
- 150000002148 esters Chemical class 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 5
- 239000000080 wetting agent Substances 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 4
- 238000007493 shaping process Methods 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 2
- 229910021529 ammonia Inorganic materials 0.000 claims 1
- 238000003491 array Methods 0.000 claims 1
- 239000000047 product Substances 0.000 description 46
- -1 diol compound Chemical class 0.000 description 32
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 31
- 239000002904 solvent Substances 0.000 description 27
- 239000005056 polyisocyanate Substances 0.000 description 23
- 229920001228 polyisocyanate Polymers 0.000 description 23
- 150000005846 sugar alcohols Polymers 0.000 description 22
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 19
- 239000003153 chemical reaction reagent Substances 0.000 description 19
- 235000019441 ethanol Nutrition 0.000 description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 19
- 239000004744 fabric Substances 0.000 description 16
- 229920000642 polymer Polymers 0.000 description 16
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 15
- 239000000654 additive Substances 0.000 description 15
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 14
- 239000003795 chemical substances by application Substances 0.000 description 14
- 239000002253 acid Substances 0.000 description 12
- 150000001261 hydroxy acids Chemical group 0.000 description 12
- 230000000996 additive effect Effects 0.000 description 11
- 239000000463 material Substances 0.000 description 11
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 9
- 150000003839 salts Chemical class 0.000 description 9
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 8
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 8
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 7
- 230000008859 change Effects 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 239000003960 organic solvent Substances 0.000 description 7
- 229920005862 polyol Polymers 0.000 description 7
- 239000004970 Chain extender Substances 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000012736 aqueous medium Substances 0.000 description 6
- 125000005442 diisocyanate group Chemical group 0.000 description 6
- 229920001971 elastomer Polymers 0.000 description 6
- PSGAAPLEWMOORI-PEINSRQWSA-N medroxyprogesterone acetate Chemical compound C([C@@]12C)CC(=O)C=C1[C@@H](C)C[C@@H]1[C@@H]2CC[C@]2(C)[C@@](OC(C)=O)(C(C)=O)CC[C@H]21 PSGAAPLEWMOORI-PEINSRQWSA-N 0.000 description 6
- 150000003077 polyols Chemical class 0.000 description 6
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 5
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 5
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 5
- 150000001412 amines Chemical class 0.000 description 5
- 239000013530 defoamer Substances 0.000 description 5
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 5
- 239000004745 nonwoven fabric Substances 0.000 description 5
- 229920000515 polycarbonate Polymers 0.000 description 5
- 229920003009 polyurethane dispersion Polymers 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 239000008367 deionised water Substances 0.000 description 4
- 229910021641 deionized water Inorganic materials 0.000 description 4
- 150000002009 diols Chemical class 0.000 description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 4
- 239000012948 isocyanate Substances 0.000 description 4
- 239000002609 medium Substances 0.000 description 4
- 230000003472 neutralizing effect Effects 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- 229920000570 polyether Polymers 0.000 description 4
- ALVZNPYWJMLXKV-UHFFFAOYSA-N 1,9-Nonanediol Chemical class OCCCCCCCCCO ALVZNPYWJMLXKV-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 description 3
- AYDQIZKZTQHYIY-UHFFFAOYSA-N OC(=O)C1(C)CC(C(O)=O)=CC=C1 Chemical class OC(=O)C1(C)CC(C(O)=O)=CC=C1 AYDQIZKZTQHYIY-UHFFFAOYSA-N 0.000 description 3
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical class OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical class OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- FOTKYAAJKYLFFN-UHFFFAOYSA-N decane-1,10-diol Chemical class OCCCCCCCCCCO FOTKYAAJKYLFFN-UHFFFAOYSA-N 0.000 description 3
- 125000004427 diamine group Chemical group 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 230000009189 diving Effects 0.000 description 3
- GHLKSLMMWAKNBM-UHFFFAOYSA-N dodecane-1,12-diol Chemical class OCCCCCCCCCCCCO GHLKSLMMWAKNBM-UHFFFAOYSA-N 0.000 description 3
- 239000000806 elastomer Substances 0.000 description 3
- 238000007046 ethoxylation reaction Methods 0.000 description 3
- XPFVYQJUAUNWIW-UHFFFAOYSA-N furfuryl alcohol Chemical compound OCC1=CC=CO1 XPFVYQJUAUNWIW-UHFFFAOYSA-N 0.000 description 3
- 238000009940 knitting Methods 0.000 description 3
- 238000006386 neutralization reaction Methods 0.000 description 3
- DIVDFFZHCJEHGG-UHFFFAOYSA-N oxidopamine Chemical compound NCCC1=CC(O)=C(O)C=C1O DIVDFFZHCJEHGG-UHFFFAOYSA-N 0.000 description 3
- 239000004417 polycarbonate Substances 0.000 description 3
- 238000006068 polycondensation reaction Methods 0.000 description 3
- 229920000909 polytetrahydrofuran Polymers 0.000 description 3
- 150000003141 primary amines Chemical class 0.000 description 3
- 239000005060 rubber Substances 0.000 description 3
- 150000003335 secondary amines Chemical class 0.000 description 3
- 230000035807 sensation Effects 0.000 description 3
- 235000019615 sensations Nutrition 0.000 description 3
- 230000006641 stabilisation Effects 0.000 description 3
- 238000011105 stabilization Methods 0.000 description 3
- 238000006467 substitution reaction Methods 0.000 description 3
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 2
- 241001116389 Aloe Species 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- 239000004425 Makrolon Substances 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical group C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- JGFZNNIVVJXRND-UHFFFAOYSA-N N,N-Diisopropylethylamine (DIPEA) Chemical compound CCN(C(C)C)C(C)C JGFZNNIVVJXRND-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 239000002390 adhesive tape Substances 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 235000011399 aloe vera Nutrition 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 230000037396 body weight Effects 0.000 description 2
- 238000009954 braiding Methods 0.000 description 2
- RYYVLZVUVIJVGH-UHFFFAOYSA-N caffeine Chemical compound CN1C(=O)N(C)C(=O)C2=C1N=CN2C RYYVLZVUVIJVGH-UHFFFAOYSA-N 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 description 2
- 125000005265 dialkylamine group Chemical group 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 2
- 239000010408 film Substances 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 150000002334 glycols Chemical class 0.000 description 2
- SXCBDZAEHILGLM-UHFFFAOYSA-N heptane-1,7-diol Chemical class OCCCCCCCO SXCBDZAEHILGLM-UHFFFAOYSA-N 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- KPSSIOMAKSHJJG-UHFFFAOYSA-N neopentyl alcohol Chemical compound CC(C)(C)CO KPSSIOMAKSHJJG-UHFFFAOYSA-N 0.000 description 2
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- 239000012457 nonaqueous media Substances 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 229960003742 phenol Drugs 0.000 description 2
- DGTNSSLYPYDJGL-UHFFFAOYSA-N phenyl isocyanate Chemical compound O=C=NC1=CC=CC=C1 DGTNSSLYPYDJGL-UHFFFAOYSA-N 0.000 description 2
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical class OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 2
- KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 description 2
- 239000006254 rheological additive Substances 0.000 description 2
- 238000007151 ring opening polymerisation reaction Methods 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- 150000003512 tertiary amines Chemical class 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 description 1
- MTZUIIAIAKMWLI-UHFFFAOYSA-N 1,2-diisocyanatobenzene Chemical compound O=C=NC1=CC=CC=C1N=C=O MTZUIIAIAKMWLI-UHFFFAOYSA-N 0.000 description 1
- ZXHZWRZAWJVPIC-UHFFFAOYSA-N 1,2-diisocyanatonaphthalene Chemical compound C1=CC=CC2=C(N=C=O)C(N=C=O)=CC=C21 ZXHZWRZAWJVPIC-UHFFFAOYSA-N 0.000 description 1
- VZXPHDGHQXLXJC-UHFFFAOYSA-N 1,6-diisocyanato-5,6-dimethylheptane Chemical compound O=C=NC(C)(C)C(C)CCCCN=C=O VZXPHDGHQXLXJC-UHFFFAOYSA-N 0.000 description 1
- ZFPGARUNNKGOBB-UHFFFAOYSA-N 1-Ethyl-2-pyrrolidinone Chemical class CCN1CCCC1=O ZFPGARUNNKGOBB-UHFFFAOYSA-N 0.000 description 1
- PNXWPUCNFMVBBK-UHFFFAOYSA-M 1-dodecylpyridin-1-ium;bromide Chemical compound [Br-].CCCCCCCCCCCC[N+]1=CC=CC=C1 PNXWPUCNFMVBBK-UHFFFAOYSA-M 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidine Chemical class CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 description 1
- DDHUNHGZUHZNKB-UHFFFAOYSA-N 2,2-dimethylpropane-1,3-diamine Chemical compound NCC(C)(C)CN DDHUNHGZUHZNKB-UHFFFAOYSA-N 0.000 description 1
- 125000004825 2,2-dimethylpropylene group Chemical group [H]C([H])([H])C(C([H])([H])[H])(C([H])([H])[*:1])C([H])([H])[*:2] 0.000 description 1
- GTACSIONMHMRPD-UHFFFAOYSA-N 2-[4-[2-(benzenesulfonamido)ethylsulfanyl]-2,6-difluorophenoxy]acetamide Chemical compound C1=C(F)C(OCC(=O)N)=C(F)C=C1SCCNS(=O)(=O)C1=CC=CC=C1 GTACSIONMHMRPD-UHFFFAOYSA-N 0.000 description 1
- UXFQFBNBSPQBJW-UHFFFAOYSA-N 2-amino-2-methylpropane-1,3-diol Chemical compound OCC(N)(C)CO UXFQFBNBSPQBJW-UHFFFAOYSA-N 0.000 description 1
- BFSVOASYOCHEOV-UHFFFAOYSA-N 2-diethylaminoethanol Chemical compound CCN(CC)CCO BFSVOASYOCHEOV-UHFFFAOYSA-N 0.000 description 1
- VKZYRCUVDRFYEZ-UHFFFAOYSA-N 2-icosylpropanedioic acid Chemical compound CCCCCCCCCCCCCCCCCCCCC(C(O)=O)C(O)=O VKZYRCUVDRFYEZ-UHFFFAOYSA-N 0.000 description 1
- AIDLAEPHWROGFI-UHFFFAOYSA-N 2-methylbenzene-1,3-dicarboxylic acid Chemical class CC1=C(C(O)=O)C=CC=C1C(O)=O AIDLAEPHWROGFI-UHFFFAOYSA-N 0.000 description 1
- WMRCTEPOPAZMMN-UHFFFAOYSA-N 2-undecylpropanedioic acid Chemical compound CCCCCCCCCCCC(C(O)=O)C(O)=O WMRCTEPOPAZMMN-UHFFFAOYSA-N 0.000 description 1
- LJPCNSSTRWGCMZ-UHFFFAOYSA-N 3-methyloxolane Chemical class CC1CCOC1 LJPCNSSTRWGCMZ-UHFFFAOYSA-N 0.000 description 1
- FUFZNHHSSMCXCZ-UHFFFAOYSA-N 5-piperidin-4-yl-3-[3-(trifluoromethyl)phenyl]-1,2,4-oxadiazole Chemical compound FC(F)(F)C1=CC=CC(C=2N=C(ON=2)C2CCNCC2)=C1 FUFZNHHSSMCXCZ-UHFFFAOYSA-N 0.000 description 1
- 101710130081 Aspergillopepsin-1 Proteins 0.000 description 1
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical group [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 102100031007 Cytosolic non-specific dipeptidase Human genes 0.000 description 1
- XBPCUCUWBYBCDP-UHFFFAOYSA-N Dicyclohexylamine Chemical compound C1CCCCC1NC1CCCCC1 XBPCUCUWBYBCDP-UHFFFAOYSA-N 0.000 description 1
- 229920001174 Diethylhydroxylamine Polymers 0.000 description 1
- 239000001836 Dioctyl sodium sulphosuccinate Substances 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 101000585359 Homo sapiens Suppressor of tumorigenicity 20 protein Proteins 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical group ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 206010021639 Incontinence Diseases 0.000 description 1
- 229920006309 Invista Polymers 0.000 description 1
- LPHGQDQBBGAPDZ-UHFFFAOYSA-N Isocaffeine Natural products CN1C(=O)N(C)C(=O)C2=C1N(C)C=N2 LPHGQDQBBGAPDZ-UHFFFAOYSA-N 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- 208000007811 Latex Hypersensitivity Diseases 0.000 description 1
- 241000283986 Lepus Species 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 229920001730 Moisture cure polyurethane Polymers 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical class CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- JOOMLFKONHCLCJ-UHFFFAOYSA-N N-(trimethylsilyl)diethylamine Chemical compound CCN(CC)[Si](C)(C)C JOOMLFKONHCLCJ-UHFFFAOYSA-N 0.000 description 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
- IIGAAOXXRKTFAM-UHFFFAOYSA-N N=C=O.N=C=O.CC1=C(C)C(C)=C(C)C(C)=C1C Chemical group N=C=O.N=C=O.CC1=C(C)C(C)=C(C)C(C)=C1C IIGAAOXXRKTFAM-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 229920000305 Nylon 6,10 Polymers 0.000 description 1
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 1
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 244000082204 Phyllostachys viridis Species 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- 206010039251 Rubber sensitivity Diseases 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229920002334 Spandex Polymers 0.000 description 1
- 241000162337 Stolas Species 0.000 description 1
- 102100029860 Suppressor of tumorigenicity 20 protein Human genes 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 241000677635 Tuxedo Species 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- 229930003427 Vitamin E Natural products 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 239000001089 [(2R)-oxolan-2-yl]methanol Substances 0.000 description 1
- RDURTRDFNKIFKC-UHFFFAOYSA-N acetic acid;1-butoxypropan-2-ol Chemical class CC(O)=O.CCCCOCC(C)O RDURTRDFNKIFKC-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 208000026935 allergic disease Diseases 0.000 description 1
- 230000007815 allergy Effects 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 235000019568 aromas Nutrition 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 229960001948 caffeine Drugs 0.000 description 1
- VJEONQKOZGKCAK-UHFFFAOYSA-N caffeine Natural products CN1C(=O)N(C)C(=O)C2=C1C=CN2C VJEONQKOZGKCAK-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- FZFAMSAMCHXGEF-UHFFFAOYSA-N chloro formate Chemical compound ClOC=O FZFAMSAMCHXGEF-UHFFFAOYSA-N 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 239000002482 conductive additive Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000012936 correction and preventive action Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- VSSAZBXXNIABDN-UHFFFAOYSA-N cyclohexylmethanol Chemical compound OCC1CCCCC1 VSSAZBXXNIABDN-UHFFFAOYSA-N 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 239000008380 degradant Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- FVCOIAYSJZGECG-UHFFFAOYSA-N diethylhydroxylamine Chemical class CCN(O)CC FVCOIAYSJZGECG-UHFFFAOYSA-N 0.000 description 1
- UAOMVDZJSHZZME-UHFFFAOYSA-N diisopropylamine Chemical compound CC(C)NC(C)C UAOMVDZJSHZZME-UHFFFAOYSA-N 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005686 electrostatic field Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 244000144992 flock Species 0.000 description 1
- 239000006081 fluorescent whitening agent Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical group C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N hexane Substances CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 230000027555 hydrotropism Effects 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 150000002527 isonitriles Chemical class 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 201000005391 latex allergy Diseases 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- AGVKXDPPPSLISR-UHFFFAOYSA-N n-ethylcyclohexanamine Chemical class CCNC1CCCCC1 AGVKXDPPPSLISR-UHFFFAOYSA-N 0.000 description 1
- UYYCVBASZNFFRX-UHFFFAOYSA-N n-propan-2-ylcyclohexanamine Chemical class CC(C)NC1CCCCC1 UYYCVBASZNFFRX-UHFFFAOYSA-N 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 229960002715 nicotine Drugs 0.000 description 1
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical class CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000012766 organic filler Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- AHHWIHXENZJRFG-UHFFFAOYSA-N oxetane Chemical compound C1COC1 AHHWIHXENZJRFG-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- VDGJOQCBCPGFFD-UHFFFAOYSA-N oxygen(2-) silicon(4+) titanium(4+) Chemical group [Si+4].[O-2].[O-2].[Ti+4] VDGJOQCBCPGFFD-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 210000004417 patella Anatomy 0.000 description 1
- UWJJYHHHVWZFEP-UHFFFAOYSA-N pentane-1,1-diol Chemical compound CCCCC(O)O UWJJYHHHVWZFEP-UHFFFAOYSA-N 0.000 description 1
- 239000012782 phase change material Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000083 poly(allylamine) Polymers 0.000 description 1
- 229920000962 poly(amidoamine) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920005906 polyester polyol Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 150000003112 potassium compounds Chemical class 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 239000004627 regenerated cellulose Substances 0.000 description 1
- 238000007763 reverse roll coating Methods 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229920005573 silicon-containing polymer Polymers 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- RHHHGLCTQKINES-UHFFFAOYSA-M sodium;5-amino-2-methoxy-4-sulfobenzenesulfonate Chemical compound [Na+].COC1=CC(S(O)(=O)=O)=C(N)C=C1S([O-])(=O)=O RHHHGLCTQKINES-UHFFFAOYSA-M 0.000 description 1
- 239000004759 spandex Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000007655 standard test method Methods 0.000 description 1
- 229960005137 succinic acid Drugs 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- BSYVTEYKTMYBMK-UHFFFAOYSA-N tetrahydrofurfuryl alcohol Chemical compound OCC1CCCO1 BSYVTEYKTMYBMK-UHFFFAOYSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- MEYZYGMYMLNUHJ-UHFFFAOYSA-N tunicamycin Natural products CC(C)CCCCCCCCCC=CC(=O)NC1C(O)C(O)C(CC(O)C2OC(C(O)C2O)N3C=CC(=O)NC3=O)OC1OC4OC(CO)C(O)C(O)C4NC(=O)C MEYZYGMYMLNUHJ-UHFFFAOYSA-N 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/022—Non-woven fabric
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/02—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of definite length, i.e. discrete articles
- B29C41/08—Coating a former, core or other substrate by spraying or fluidisation, e.g. spraying powder
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/003—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts characterised by the matrix material, e.g. material composition or physical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/30—Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/40—Layered products comprising a layer of synthetic resin comprising polyurethanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/024—Woven fabric
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/026—Knitted fabric
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/08—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer the fibres or filaments of a layer being of different substances, e.g. conjugate fibres, mixture of different fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0838—Manufacture of polymers in the presence of non-reactive compounds
- C08G18/0842—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents
- C08G18/0861—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers
- C08G18/0866—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers the dispersing or dispersed phase being an aqueous medium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
- D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
- D06N7/0094—Fibrous material being coated on one surface with at least one layer of an inorganic material and at least one layer of a macromolecular material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2075/00—Use of PU, i.e. polyureas or polyurethanes or derivatives thereof, as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2913/00—Use of textile products or fabrics as mould materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/20—All layers being fibrous or filamentary
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/02—Coating on the layer surface on fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/26—Polymeric coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/02—Composition of the impregnated, bonded or embedded layer
- B32B2260/021—Fibrous or filamentary layer
- B32B2260/023—Two or more layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/04—Impregnation, embedding, or binder material
- B32B2260/046—Synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0207—Elastomeric fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0207—Elastomeric fibres
- B32B2262/0215—Thermoplastic elastomer fibers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0246—Acrylic resin fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0253—Polyolefin fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0261—Polyamide fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0276—Polyester fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/06—Vegetal fibres
- B32B2262/062—Cellulose fibres, e.g. cotton
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/06—Vegetal fibres
- B32B2262/062—Cellulose fibres, e.g. cotton
- B32B2262/065—Lignocellulosic fibres, e.g. jute, sisal, hemp, flax, bamboo
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/08—Animal fibres, e.g. hair, wool, silk
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/12—Conjugate fibres, e.g. core/sheath or side-by-side
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/724—Permeability to gases, adsorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2437/00—Clothing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2437/00—Clothing
- B32B2437/02—Gloves, shoes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2535/00—Medical equipment, e.g. bandage, prostheses or catheter
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2203/00—Macromolecular materials of the coating layers
- D06N2203/06—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06N2203/068—Polyurethanes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2205/00—Condition, form or state of the materials
- D06N2205/02—Dispersion
- D06N2205/023—Emulsion, aqueous dispersion, latex
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/10—Properties of the materials having mechanical properties
- D06N2209/103—Resistant to mechanical forces, e.g. shock, impact, puncture, flexion, shear, compression, tear
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/12—Permeability or impermeability properties
- D06N2209/121—Permeability to gases, adsorption
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
- D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
- D06N3/145—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes two or more layers of polyurethanes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/23907—Pile or nap type surface or component
- Y10T428/23943—Flock surface
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/23907—Pile or nap type surface or component
- Y10T428/23993—Composition of pile or adhesive
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Textile Engineering (AREA)
- Dispersion Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Mechanical Engineering (AREA)
- Composite Materials (AREA)
- Manufacturing & Machinery (AREA)
- Mathematical Physics (AREA)
- Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Reinforced Plastic Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Laminated Bodies (AREA)
Abstract
本发明涉及一种包含聚氨酯组合物和纤维阵列的制品，其中所述纤维阵列嵌入所述聚氨酯组合物中，使得所述纤维的一部分延伸超出所述成型制品的内表面和所述成型制品的外表面。
Description
技术领域
包括的是聚氨酯制品，其包括纤维或织物。这些可以是包括嵌入表面中的纤维阵列或浸渍有聚氨酯的织物的成型聚氨酯制品。使用聚氨酯分散体制备所述制品。
背景技术
已知乳胶或橡胶被用于各种成型制品，如手套、手指套等。然而，鉴于过敏，特别是对乳胶过敏的普遍存在，可能需要替代的聚合物。
发明内容
当包括在具有皮肤接触表面的衣服、成型制品或其它基底中时，聚氨酯组合物可能更适合替代天然胶乳或橡胶。理想地，聚氨酯将提供现有产品的柔性和弹性。
一些实施例提供包括聚氨酯组合物和纤维阵列的成型制品，其中所述纤维阵列嵌入聚氨酯组合物中，使得纤维的一部分延伸超出成型制品的内表面和成型制品的外表面。
一种合适的聚氨酯分散体包括作为以下物质的反应产物的聚合物：
（a）选自聚醚、聚酯、聚碳酸酯和其组合的至少一种多元醇，其中所述多元醇的数均分子量为600至4000；
（b）包含选自由芳香族二异氰酸酯、脂肪族二异氰酸酯、脂环族二异氰酸酯和其组合组成的群组的成员的多异氰酸酯；
（c）至少一种二醇化合物，其包含：（i）能够与多异氰酸酯反应的羟基，和（ii）在中和时能够形成盐的至少一个羧酸基团，其中所述至少一个羧酸基团不能与多异氰酸酯反应；
（d）中和剂；和
（e）扩链剂。还提供一种制备成型制品的方法。所述方法包括：
（a）提供具有制品接触表面的模具，其中所述制品接触表面包括表面活性剂或润湿剂；
（b）将内部纤维阵列施用到所述制品接触表面；
（c）将聚氨酯分散体施用到所述纤维阵列；
（d）将外部纤维阵列施用到所述分散体；
（e）干燥所述制品；
（f）从所述模具中移出所述制品。
还提供一种制备成型制品的方法。所述方法包括：
（a）提供具有制品接触表面的模具，其中所述制品接触表面包括表面活性剂或润湿剂；
（b）任选地将内部纤维阵列施用到所述制品接触表面，这可在仅外表面上需要纤维的情况下被排除；
（c）将聚氨酯分散体施用到所述纤维阵列；
（d）任选地将外部纤维阵列施用到分散体，这可在仅内表面上需要纤维的情况下被排除；
（e）干燥所述制品；
（f）从所述模具中移出所述制品。
还包括已经用聚氨酯脲组合物涂布和/或浸渍的制品。所述制品可以包括织物，例如非织造片材。非织造物可以是任何合适的非织造物，例如水刺或水力缠结的非织造物。
还提供包括聚氨酯脲组合物和纤维和/或织物阵列的制品，其可以是非织造物。聚氨酯脲组合物包括分散体，其可以施用于制品、基底、模具等。分散体可以包括一种包括聚合物的合适的聚氨酯分散体，聚合物是以下物质的反应产物：
（a）选自聚醚、聚酯、聚碳酸酯及其组合的至少一种多元醇，其中所述多元醇的数均分子量为600至4000；
（b）包含选自由芳香族二异氰酸酯、脂肪族二异氰酸酯、脂环族二异氰酸酯及其组合组成的群组的成员的多异氰酸酯，例如仅包括脂肪族二异氰酸酯的多异氰酸酯；
（c）至少一种二醇化合物，其包含：（i）能够与多异氰酸酯反应的羟基，和（ii）在中和时能够形成盐的至少一个羧酸基团，其中所述至少一个羧酸基团不能与多异氰酸酯反应；
（d）中和剂；和
（e）扩链剂。
在另一个实施例中是制备可用于成型制品的聚氨酯脲水性分散体的方法。稳定的分散体可以商业规模制备，包括大于约500加仑和大于约1000加仑的批次。
具体实施方式
可用于制备成型制品的水性聚氨酯分散体由特定的氨基甲酸酯预聚物提供，其也形成一些实施例的一个方面。
在一些实施例中，用于制备聚氨酯脲分散体的嵌段聚氨酯脲包括：a）数均分子量在500至5000（例如约600至4000和600至3500）的多元醇或多元醇共聚物或多元醇混合物，包括但不限于聚醚二醇、聚酯二醇、聚碳酸酯二醇、聚丁二烯二醇或其氢化衍生物，和羟基封端的聚二甲基硅氧烷；b）包括二异氰酸酯例如脂肪族二异氰酸酯、芳香族二异氰酸酯和脂环族二异氰酸酯的多异氰酸酯；和c）二醇化合物d，其包括：（i）能够与多异氰酸酯反应的羟基，和（ii）在中和时能够形成盐的至少一个羧酸基团，其中所述至少一个羧酸基团不能与多异氰酸酯反应；d）扩链剂，例如水或二胺扩链剂；和e）任选的一元醇或单胺，伯胺或仲胺，作为封端剂或链终止剂；和任选地具有至少三个伯或仲胺基团的有机化合物或聚合物。
一些实施例的氨基甲酸酯预聚物，也称为加帽的二醇类，在将预聚物分散在水中和链扩展之前，通常可概念化为多元醇、异氰酸酯和在中和之后能够成盐的化合物的反应产物。此类预聚物通常可以在一个或多个步骤中制备，使用或不使用可用于降低预聚物组合物的粘度的溶剂。
取决于预聚物是否溶解在将保留在分散体中的不易挥发的溶剂（例如NMP）中；溶解在挥发性溶剂如丙酮或甲基乙基酮（MEK）中，其随后可以除去；或分散在没有任何溶剂的水中；分散体制备方法在实践中可以分别分类为溶剂方法、丙酮方法或预聚物混合方法。预聚物混合方法具有环境和经济优点，并且可用于制备基本上没有添加溶剂的水性分散体。
在预聚物混合过程中，重要的是有或没有被溶剂稀释，预聚物的粘度足够低，以便被运输和分散在水中。一个实施例涉及衍生自此类预聚物的聚氨酯脲分散体，其满足所述粘度要求并且在预聚物或分散体中不具有任何有机溶剂。根据本发明，预聚物是多元醇、二异氰酸酯和二醇化合物的反应产物。
一些实施例是无溶剂、稳定的水性聚氨酯分散体，通过常规技术，其可以作为用于涂布、粘结和层压到基底的直接的粘合剂材料（即，不需要任何额外的粘合剂材料）被加工和施用。水性聚氨酯分散体可以提供：基本上无挥发性有机材料的排放；生产中可接受的固化时间；以及在成品和实际应用中良好的粘合强度、耐热性和拉伸/恢复性。
基底可以是许多不同织物或制品中的任何一种。
如本文所用，术语“分散体”是指其中分散相由细碎颗粒组成的体系，且连续相可以是液体、固体或气体。
如本文所用，术语“水性聚氨酯分散体”是指包含至少一种聚氨酯或聚氨酯脲聚合物或预聚物（例如本文所述的聚氨酯预聚物）的组合物，任选地包括溶剂，其已经分散在水性介质，例如水，包括去离子水中。
如本文所用，除非另有说明，否则术语“溶剂”是指非水性介质，其中非水性介质包括有机溶剂，包括挥发性有机溶剂（例如丙酮）和稍微有点挥发性的有机溶剂（例如N-甲基吡咯烷酮（NMP））。
如本文所用，术语“无溶剂”或“无溶剂体系”是指其中组合物或分散组分的主体没有溶解或分散在溶剂中的组合物或分散体。
如本文所用，术语“织物”意在包括任何针织、纺织或非织造材料。针织织物可以是平针织、圆形针织、经编、窄弹性或花边。纺织织物可以是任何结构，例如缎纹、斜纹、平织、牛津编织、篮形编织或窄弹性。非织造材料可以是熔喷、纺粘、湿法成网、梳理纤维类短纤维网等中的一种。
如本文所用，术语“硬纱”是指基本上是非弹性的纱线。
如本文所用，术语“衍生自”是指从另一物体形成物质。例如，膜或成型制品可以衍生自已经干燥的分散体。
由一些实施例的水性分散体铸造（cast）的膜的另一个优点是关于膜的感觉或触感。与硅橡胶或市售的热塑性膜相比，它们提供更柔软的感觉，同时保持所需的摩擦以减少运动，这对于皮肤接触应用是进一步的优点。此外，较低的弯曲模量赋予更好的悬垂性和织物手感。包含纤维阵列提供了对形成制品的膜的感觉的额外改进。
取决于聚氨酯或聚氨酯脲组合物作为分散体从本文所述的水性分散体施用时的期望效果，膜中聚合物的重均分子量可在约40,000至约250,000，包括约40,000至约150,000；约100,000至约150,000；和约120,000至约140,000内变化。
各种不同的纤维和纱线可以与一些实施例的制品（其可以是成型制品）一起使用。这些包括棉、羊毛、丙烯酸类、聚酰胺（尼龙）、聚酯、氨纶、再生纤维素、橡胶（天然或合成）、竹，丝绸、大豆、聚烯烃如聚乙烯或聚丙烯，其可以是或可以不是弹性体，或其组合。纤维可以是弹性的，例如弹性纤维或来自并排或偏心壳核横截面中的非弹性聚合物的弹性纤维。短纤维对于获得延伸超出制品表面的纤维阵列是最有用的。纤维可以称为短纤维。或者，短纤维可以称为絮屑（flock）。
以下更详细地描述聚氨酯组合物的组分：
多元醇类
适合作为用于制备根据本发明的氨基甲酸酯预聚物的原料的多元醇组分是数均分子量为约600至约3,500或约4,000的聚醚二醇、聚碳酸酯二醇和聚酯二醇。
可以使用的聚醚多元醇的实例包括具有两个或更多个羟基的那些二醇，来自环氧乙烷、环氧丙烷、三亚甲基氧化物、四氢呋喃和3-甲基四氢呋喃的开环聚合和/或共聚，或者来自在每个分子中具有小于12个碳原子的多元醇，优选二醇或二醇混合物，例如乙二醇、1,3-丙二醇、1,4-丁二醇、1,5-戊二醇、1,6-己二醇、新戊二醇、3-甲基-1,5-戊二醇、1,7-庚二醇、1,8-辛二醇、1,9-壬二醇、1,10-癸二醇和1,12-十二烷二醇的缩聚。线性双官能聚醚多元醇是优选的，并且分子量为约1,700至约2,100的聚（四亚甲基醚）二醇，例如官能度为2的Terathane®1800（Invista）在本发明中是特别优选的。
可以使用的聚酯多元醇的实例包括具有两个或更多个羟基的那些酯二醇，其通过脂肪族多元羧酸和多元醇或它们的混合物的缩聚制备，所述多元醇或它们的混合物具有每分子不超过12个碳原子的低分子量。合适的多元羧酸的实例是丙二酸、琥珀酸、戊二酸、己二酸、庚二酸、辛二酸、壬二酸、癸二酸、十一烷二羧酸和十二烷二羧酸。用于制备聚酯多元醇的合适的多元醇的实例是乙二醇、1,3-丙二醇、1,4-丁二醇、1,5-戊二醇、1,6-己二醇、新戊二醇、3-甲基-1,5-戊二醇、1,7-庚二醇、1,8-辛二醇、1,9-壬二醇、1,10-癸二醇和1,12-十二烷二醇。优选熔融温度为约5℃至约50℃的线性双官能聚酯多元醇。
可以使用的聚碳酸酯多元醇的实例包括具有两个或更多个羟基的那些碳酸酯二醇，其通过低分子量每分子具有不超过12个碳原子的光气、氯甲酸酯、碳酸二烷基酯或碳酸二烯丙酯和脂肪族多元醇或它们的混合物的缩聚制备。用于制备聚碳酸酯多元醇的合适的多元醇的实例是二甘醇、1,3-丙二醇、1,4-丁二醇、1,5-戊二醇、1,6-己二醇、新戊二醇、3-甲基-1,5-戊二醇、1,7-庚二醇、1,8-辛二醇、1,9-壬二醇、1,10-癸二醇和1,12-十二烷二醇。优选熔融温度为约5℃至约50℃的线性双官能聚碳酸酯多元醇。
多异氰酸酯类
合适的多异氰酸酯组分的实例包括二异氰酸酯如1,6-二异氰酸酯己烷、1,12-二异氰酸酯十二烷、异佛尔酮二异氰酸酯、三甲基-六亚甲基二异氰酸酯、1,5-二异氰酸酯-2-甲基戊烷、二异氰酸酯环己烷、亚甲基-双（4-环己基异氰酸酯）、四甲基二甲苯二异氰酸酯、双（异氰酸酯甲基）环己烷、甲苯二异氰酸酯、亚甲基双（4-苯基异氰酸酯）、亚苯基二异氰酸酯、二甲苯二异氰酸酯和此类二异氰酸酯的混合物。例如，二异氰酸酯可以是芳香族二异氰酸酯，例如亚苯基二异氰酸酯、甲苯二异氰酸酯（TDI）、亚二甲苯基二异氰酸酯、联苯二异氰酸酯、萘二异氰酸酯、二苯基甲烷二异氰酸酯（MDI）及其组合。
适合作为用于制备根据本发明的氨基甲酸酯预聚物的另一原料的多异氰酸酯组分可以是包含4,4'-亚甲基双（苯基异氰酸酯）和2,4'-亚甲基双（苯基异氰酸酯）的二苯基甲烷二异氰酸酯（MDI）的异构体混合物，其中4,4'-MDI与2,4'-MDI异构体之比的范围在约65:35至约35:65的范围内，优选约55:45至约45:55，并且更优选约50:50的范围内。合适的多异氰酸酯组分的实例包括Mondur® ML（Bayer）、Lupranate® MI（BASF）和Isonate®50O,P'（Dow Chemical）。
二醇类
适合作为用于制备根据本发明的氨基甲酸酯预聚物的其它原料的二醇化合物包括至少一种二醇化合物，其具有：（i）能够与多异氰酸酯反应的两个羟基；和（ii）在中和时能够形成盐并且不能与多异氰酸酯（b）反应的至少一种羧酸基团。具有羧酸基团的二醇化合物的典型实例包括2,2-二甲基丙酸（DMPA）、2,2-二甲基丁酸（2,2-dimethylobutanoicacid）、2,2-二甲基戊酸和DMPA引发的己内酯例如CAPA®HC 1060（Solvay）。在本发明中DMPA是优选的。
中和剂
将酸基团转化成盐基团的合适中和剂的实例包括：叔胺类（例如三乙胺、N,N-二乙基甲胺、N-甲基吗啉、N,N-二异丙基乙胺和三乙醇胺）和碱金属氢氧化物（例如锂、钠和钾的氢氧化物）。伯胺和/或仲胺类也可以用作酸基团的中和剂。中和度通常在酸基团的约60%至约140%之间，例如在约80%至约120%的范围内。
扩链剂
可用于本发明的扩链剂包括二胺扩链剂和水。有用的扩链剂的许多实例是本领域普通技术人员已知的。合适的二胺扩链剂的实例包括：1,2-乙二胺、1,4-丁二胺、1,6-六亚甲基二胺、1,12-十二烷二胺、1,2-丙二胺、2-甲基-1,5-戊二胺、1,4-环己烷二胺、4,4'-亚甲基-双（环己胺）、异佛尔酮二胺、2,2-二甲基-1,3-丙二胺、间四甲基二甲苯二胺和分子量小于500的Jeffamine®（Texaco）。当期望聚氨酯时，可以包括二醇扩链剂。
表面活性剂
合适的表面活性试剂（表面活性剂）的实例包括：阴离子、阳离子或非离子分散剂或表面活性剂，例如十二烷基硫酸钠、二辛基磺基琥珀酸钠、十二烷基苯磺酸钠、乙氧基化烷基酚类如乙氧基化壬基酚类和乙氧基化脂肪醇类、月桂基溴化吡啶鎓、聚醚磷酸酯类和磷酸酯类、改性醇-乙氧基化物类，及其组合。
封端剂
用于异氰酸酯基团的封端剂可以是单官能醇或单官能胺。封端剂可以在形成预聚物之前，形成预聚物期间或形成预聚物之后的任何时间加入，包括在将预聚物分散在水性介质如去离子水中之前和之后。在一些实施例中，封端剂是任选的，或可以被排除。在其它实施例中，以预聚物的重量计，封端剂可以约0.05%至约10.0%，包括约0.1%至约6.0%和约1.0%至约4.0%的量纳入。以最终分散体的重量计，封端剂可以以约0.01%至约6.0%，包括约0.05%至约3%和约0.1%至约1.0%的量存在。
封端剂的纳入允许控制分散体中聚合物的重均分子量以及提供对聚合物分子量分布的控制。封端剂提供此类控制的有效性取决于封端剂的类型和在制备分散体期间加入封端剂的时间。例如，可以在形成预聚物之前，期间或之后加入单官能醇。单官能醇封端剂也可以加入分散有预聚物的水性介质中，或在预聚物分散在水性介质中后立即加入。然而，当需要控制聚合物分子量和在最终分散体中的分子量分布时，如果加入单官能醇并且在分散之前作为预聚物的一部分反应，则单官能醇可能是最有效的。如果在分散预聚物期间或之后将单官能醇加入到水性介质中，则由于竞争性扩链反应，其在控制聚合物分子量方面的有效性将降低。
可用于本发明的单官能醇的实例包括选自由具有1至18个碳的脂肪族和脂环族伯和仲醇类、酚、取代的酚类、乙氧基化的烷基酚类和分子量小于约750，包括分子量小于500的乙氧基化的脂肪醇类、羟胺类，羟甲基和羟乙基取代的叔胺类，羟甲基和羟乙基取代的杂环化合物及其组合组成的群组的至少一个成员，包括糠醇、四氢糠醇、N-（2-羟乙基）琥珀酰亚胺、4-（2-羟乙基）吗啉、甲醇、乙醇、丁醇、新戊醇、己醇、环己醇、环己烷甲醇、苯甲醇、辛醇、十八烷醇、N,N-二乙基羟胺、2-（二乙基氨基）乙醇、2-二甲基氨基乙醇，和4-哌啶乙醇，及其组合。
当单官能胺化合物如单官能二烷基胺用作异氰酸酯基团的封端剂时，也可以在制备分散体期间的任何时候加入，期望地在预聚物分散体期间或之后将单官能胺封端剂加入水中。例如，可以在预聚物分散后立即将单官能胺封端剂加入水混合物中。
合适的单官能二烷基胺封端剂的实例包括：N,N-二乙胺、N-乙基-N-丙胺、N,N-二异丙胺、N-叔丁基-N-甲胺、N-叔丁基-N-苄基胺、N,N-二环己基胺、N-乙基-N-异丙基胺、N-叔丁基-N-异丙基胺、N-异丙基-N-环己基胺、N-乙基-N-环己基胺、N,N-二乙醇胺和2,2,6,6-四甲基哌啶。在水中分散之前，胺封端剂与预聚物的异氰酸酯基团的摩尔比通常应在约0.05至约0.50的范围内，例如约0.20至约0.40。催化剂可用于去封端反应。
任选地，在预聚物分散和加入封端剂后，可以向水性介质中加入每摩尔聚合物具有至少三个或更多个伯和/或仲氨基的至少一种聚合物组分（MW>约500）。合适的聚合物组分的实例包括聚乙烯亚胺、聚（乙烯基胺）、聚（烯丙基胺）和聚（酰胺基胺）树枝状聚合物及其组合。
其它添加剂
合适的消泡剂或去泡剂或泡沫控制剂的实例包括：Additive 65和Additive 62（来自Dow Corning的硅氧烷类添加剂），FoamStar® I 300（来自Cognis的矿物油类无硅去泡剂）和SurfynolTMDF 110L（来自Air Products&Chemicals的高分子量炔属二醇非离子表面活性剂）。
合适的流变改性剂的实例包括：疏水改性的乙氧基化氨基甲酸酯（HEUR）、疏水改性的碱溶胀性乳液（HASE）和疏水改性的羟乙基纤维素（HMHEC）。
可任选地包括在水性分散体或预聚物中的其它添加剂包括：抗氧化剂、UV稳定剂、着色剂、颜料、交联剂、相变材料（即，Outlast®，可从Outlast Technologies，Boulder，科罗拉多州商购）、抗微生物剂、矿物质（即铜）、微胶囊化的健康添加剂（即芦荟、维生素E凝胶、芦荟、海带、尼古丁、咖啡因、气味剂（scents）或熏香料（aromas））、纳米颗粒（即二氧化硅或碳）、碳酸钙、阻燃剂、防粘添加剂、耐氯降解添加剂、维生素、药物、香料（fragrances）、电传导添加剂和/或染料助剂。可以加入到预聚物或水性分散体中的其它添加剂包含粘合促进剂、抗静电剂、抗缩孔剂、抗爬行剂、荧光增白剂、聚结剂、导电添加剂、发光添加剂、流平剂、冻融稳定剂、润滑剂、有机和无机填料、防腐剂、增稠剂、热变色添加剂、驱虫剂和润湿剂。
可以在预聚物分散之前、期间或之后将任选的添加剂加入水性分散体中。
在预聚物混合过程中，预聚物可以通过在一个步骤中将原料即多元醇、多异氰酸酯和二醇化合物混合在一起并且通过在约50℃至约100℃的温度下反应足够时间直到所有羟基基本上被消耗并达到异氰酸酯基的所需%NCO。或者，所述预聚物可以两个步骤制备，首先使多元醇与过量的多异氰酸酯反应，然后与二醇化合物反应，直到实现预聚物的最终所需的%NCO。例如，%NCO可以在约1.3至约6.5的范围内，例如约1.8至约2.6。重要的是，不需要有机溶剂，但可以在反应之前、期间或之后与原料一起添加或混合。任选地，可以使用催化剂以促进预聚物形成。
在一些实施例中，预聚物包括多元醇、多异氰酸酯和二醇，它们组合在一起并且以预聚物的总重量计以以下重量百分比范围提供：
约34%至约89%的多元醇，包括约61%至约80%；
约10%至约59%的多异氰酸酯，包括约18%至约35%；和
约1.0%至约7.0%的二醇化合物，包括约2.0%至约4.0%。
单官能醇可以与预聚物一起纳入以控制完全分散体中的聚氨酯脲聚合物的重均分子量。
由多元醇、多异氰酸酯、二醇化合物和任选的封端剂如单官能醇制备的预聚物可具有低于约6000泊（包括低于约4,500泊）的体积粘度（存在或不存在溶剂），通过在40℃下的落球法测量。沿着聚合物链（来自二醇化合物）含有羧酸基团的这种预聚物可以用高速分散机分散到去离子水介质中，所述去离子水介质包括：至少一种中和剂，以与酸形成离子盐；至少一种表面活性剂（离子和/或非离子分散剂或表面活性剂）；和任选的至少一种扩链组分。或者，中和剂可以在分散到水性介质中之前与预聚物混合。可以在预聚物分散之前、期间或之后将至少一种消泡剂和/或去泡剂和/或至少一种流变改性剂加入到水性介质中。
聚氨酯水性分散体可具有宽范围的固体含量，这取决于分散体的所需最终用途。对于一些实施例的分散体的合适的固体含量的实例包括约10重量%至约50重量%，例如约30重量%至约45重量%。
聚氨酯水性分散体的粘度也可以在约10厘泊至约100,000厘泊的宽范围内变化，这取决于加工和应用要求。例如，在一个实施例中，粘度在约500厘泊至约30,000厘泊的范围内。可以通过使用适当量，例如以水性分散体的总重量计约0至约2.0重量%的增稠剂来改变粘度。
在溶剂法或丙酮法中，有机溶剂也可用于制备一些实施例的膜和分散体。有机溶剂通过溶解和稀释可以用于降低预聚物粘度和/或有助于具有羧酸基团例如2,2-二甲基丙酸（DMPA）的二醇化合物的固体颗粒的分散以提高分散质量。它还可以用于改善膜均匀性，例如减少涂布/成膜过程中的条纹和裂纹的目的。
为这些目的选择的溶剂对异氰酸酯基团基本上或完全不反应，在水中稳定，并且对DMPA、DMPA和三乙胺形成的盐和预聚物具有良好的溶解能力。合适的溶剂的实例包括N-甲基吡咯烷酮、N-乙基吡咯烷酮、二丙二醇二甲醚、丙二醇正丁醚乙酸酯、N,N-二甲基乙酰胺、N,N-二甲基甲酰胺、2-丙酮（丙酮）和2-丁酮（丁酮或MEK）。
在溶剂法中，加入到一些实施例的膜/分散体中的溶剂的量可以变化。当包括溶剂时，溶剂的合适范围包括小于分散体的50重量%的量。还可以使用较小的量，例如小于分散体重量的20重量%，小于分散体重量的10重量%，小于分散体重量的5重量%和小于分散体重量的3重量%。
在丙酮法中，在制备分散体之前，可以将较大量的溶剂加入到预聚物组合物中。或者，预聚物可以在溶剂中制备。在预聚物分散之后，例如在真空下，也可以从分散体中除去溶剂。
在制造过程的不同阶段有许多方式将有机溶剂引入分散体中，例如：
1）在聚合完成之后转移和分散预聚物之前，可以将溶剂加入到预聚物中并与其混合，当其分散在水中的同时，在含有主链中的羧酸基团（来自二醇化合物）和链端的异氰酸酯基团的稀释的预聚物被中和并且扩链。
2）可以加入溶剂并与其它成分如多元醇、多异氰酸酯和二醇化合物混合以在溶液中制备预聚物，然后在溶液中含有主链中的羧酸基团和链端的异氰酸酯基团的所述预聚物分散在水中并同时被中和并扩链。
3）溶剂可以在分散之前与二醇化合物的中和盐和中和剂一起加入，并与多元醇和多异氰酸酯混合，以制备预聚物。
4）溶剂可以与TEA混合，然后在分散之前加入到形成的预聚物中。
5）可以加入溶剂并与多元醇混合，然后在分散之前向溶液中的中和的预聚物中依次加入二醇化合物和中和剂，然后加入多异氰酸酯。
6）也可以从分散体中除去溶剂，特别是在丙酮法的情况下。
衍生自聚氨酯分散体的涂料、分散体、膜或成形制品可以是染色的或着色的，并且还可以用作设计元件。
用于施用一些实施例的聚氨酯脲组合物的方法和手段包括但不限于：辊涂（包括逆辊涂布）；使用金属工具或刀片（例如，将分散体倾倒在基底上，然后通过使用金属工具例如刀片将分散体散布在基底上而将分散体铸造成均匀的厚度）；喷雾（例如，使用泵喷雾瓶）；浸泡；涂漆；印刷；冲压；并且浸渍制品。这些方法可用于将分散体直接施用到基底上而不需要另外的粘合剂材料，并且如果需要额外的/更重的层，则可以重复。分散体可以施用于任何基底，包括模具或织物。织物可以包括用于涂布、粘结、层压和粘合目的，由合成、天然或合成/天然共混材料制成的针织物、纺织物或非织造物。
在加工期间（例如，通过空气干燥或使用烘箱），可以通过干燥除去分散体中的水。制品可以在任何合适的条件下固化。这可以包括高达约200℃的温度，例如约140℃至约200℃下持续包括约90秒至约120秒的任何合适的时间。
膜、溶液和分散体的厚度可以根据应用而变化。在成型制品的情况下，每层膜的最终厚度可以例如为约0.1密耳至约250密耳，例如约0.5密耳至约25密耳，包括约1密耳至约6密耳（1密耳=千分之一英寸）。合适厚度的其它实例包括约0.5密耳至约12密耳，约0.5至约10密耳和约1.5密耳至约9密耳。
可以以通过单位面积上的分散体的重量描述的任何合适的量将水性分散体施用到基底或模具上。所用的量可以例如为约2.5g/m2至约6.40kg/m2，例如约12.7-约635g/m2，包括约25.4-约152.4g/m2。
用于制备制品的方法可以包括首先提供施用有表面活性剂或润湿剂的合适的基底或模具。这之后是添加可通过任何合适的方法添加的纤维阵列。美国专利3,917,883描述了一种用于将纤维阵列提供到模具表面上的合适方法。这可以通过静电手段实现，使得纤维由于静电场的影响而相对于模具或基底基本垂直地定向。这些纤维可以以任何所需的方式提供。这可以包括基本均匀的分布或图案。当以这种方式取向时，纤维的端部可以延伸超出制品中固化/干燥的分散体的表面。
聚氨酯分散体可以通过任何合适的方法例如喷雾、涂漆、涂布等来添加。可以添加纤维或聚氨酯分散体的另外的层，随后是最后一层纤维阵列。可以包括任何合适数量的层，例如1至50层，这取决于所需的厚度和其它性质。
或者，纤维可以以另一种方式与分散体组合。这可以包括分散体与纤维的组合以提供可以成型的制品。它们的纤维也可制备成包括分散体的非织造织物，例如纺粘或熔融粘结织物。在制备中，纤维/分散体组合可以施用到基底例如带/输送带。
可以使用分散体和成形制品生产的终制品包括但不限于：服装，其包括任何类型的衣服或布料制品；针织手套；室内装饰品；发饰；床单；地毯和地毯背衬；输送带；医疗应用，如拉伸绷带；个人护理用品，包括失禁和女性卫生用品；和鞋类。
可以使用落入本发明范围内的分散体和成型制品生产的服装或衣服的实例包括但不限于：贴身衣、胸罩、内裤、内衣、泳装、成型裤、吊带裤、靴袜、睡衣、围裙、潜水衣、领带、毛巾、太空服、制服、帽子、衣帽带、汗带、皮带、运动服、外衣、雨衣、寒冷天气夹克、裤子、衬衫、裙子、短衫、男士和女士上衣、毛衣、胸衣、背心、短衬裤、袜子、膝盖高、连衣裙、短衫、围裙、无尾礼服、阿拉伯袍子（bisht）、黑纱袍（abaya）、头巾（hijab）、长袍（jilbab）、白袍（thoub）、罩袍（burka）、披风、服饰、潜水服、褶裥短裙（kilt）、和服、球衣（jerseys）、法衣、防护服、纱丽、布裙、裙子、鞋罩（spats）、面纱（stola）、套装、束身衣、宽外袍、紧身裤、毛巾、制服、面罩、潜水衣、医用压缩服装、绷带、西服衬里、腰带及其中的所有部件。
本发明的另一方面是包含成形制品和基底的制品，其中成形制品和基底附接以形成层压体，由此弹性层压体的摩擦系数大于单独基底的摩擦系数。其实例是具有包含水性聚氨酯分散体的涂层或膜的腰带，其防止衣服从另一衣服（诸如女衬衫或衬衫）的滑脱，或者防止腰带在衣服穿着者的皮肤上滑脱。
本发明的另一方面是包含聚氨酯脲组合物和基底的制品，其中成形制品的模量沿制品的长度或者宽度变化。例如，基底（如织物）可以用两英尺（61cm）的聚氨酯脲组合物（如一英寸（2.5 cm）宽的胶带）处理。可以通过沿着一英寸宽的胶带的长度涂布三个两英寸（5cm）×一英寸的片段以形成复合结构来施用附加的粘合剂层。
由水性聚氨酯分散体形成的制品可以具有以下性质：
- 在约0至10%，例如约0至5%，典型地约0至约3%的伸长率下定型，
-伸长率为约400至约800%
-韧度为约0.5至约3Mpa，
-透气率为至少约0至约0.5cfm或更高，和
-在24小时内至少约0至约500g/m2，包括在24小时内约50至约1000g/m2或在24小时内约100至约500g/m2的水蒸汽渗透率。湿气透过率可根据ASTM标准E 96-00“材料的水蒸气透过的标准测试方法（Standard Test Methods for Water Vapor Transmission ofMaterials）”进行测试。
尽管已经描述了目前被认为是本发明的优选实施例的内容，但是本领域技术人员将认识到，在不脱离本发明的精神的情况下，可以对其进行改变和修改，包括落入本发明的真实范围内的所有这样的改变和修改。
Claims (11)
1.一种制品，其包含聚氨酯组合物和纤维阵列，其中所述纤维阵列嵌入所述聚氨酯组合物中，使得所述纤维的一部分延伸超出所述成型制品的内表面和所述成型制品的外表面。
2.根据权利要求1所述的制品，其在24小时或更长时间内具有约100g/m2的水蒸气输送。
3.根据权利要求1所述的制品，其中所述聚氨酯组合物由聚氨酯分散体形成。
4.根据权利要求1所述的制品，其中所述制品是成型的。
5.一种用于制备制品的方法，其包含：
（a）提供具有制品接触表面的基底，其中所述制品接触表面包括表面活性剂或润湿剂；
（b）将内部纤维阵列施用到所述制品接触表面；
（c）将聚氨酯分散体施用到所述纤维阵列；
（d）将外部纤维阵列施用到所述分散体；
（e）干燥所述制品；
（f）从所述基底移出所述制品。
6.根据权利要求5所述的方法，其中所述基底是模具。
7.根据权利要求5所述的方法，其还包括在施用所述外部纤维阵列之前施用多于一个的附加的聚氨酯分散体层。
8.根据权利要求7所述的方法，其还包括在添加一个或多个附加的聚氨酯分散体层之前施用一个或多个附加的纤维阵列。
9.根据权利要求5所述的方法，其中所述聚氨酯分散体包含聚氨酯脲。
10.根据权利要求5所述的方法，其中所述内部纤维阵列和所述外部纤维阵列嵌入聚氨酯分散体层中并且部分地延伸超出所述制品的内表面和外表面。
11.根据权利要求5所述的方法，其中所述制品选自由服装、袖套、绷带和手套组成的群组。
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201462010832P | 2014-06-11 | 2014-06-11 | |
| US62/010832 | 2014-06-11 | ||
| US201562103449P | 2015-01-14 | 2015-01-14 | |
| US62/103449 | 2015-01-14 | ||
| PCT/US2015/035106 WO2015191712A1 (en) | 2014-06-11 | 2015-06-10 | Aqueous polyurethaneurea compositions including dispersions and films |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106795693A true CN106795693A (zh) | 2017-05-31 |
Family
ID=54834243
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201580030966.2A Pending CN106795693A (zh) | 2014-06-11 | 2015-06-10 | 包括水性聚氨酯组合物的分散体和膜 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20170136715A1 (zh) |
| EP (1) | EP3155165A4 (zh) |
| JP (1) | JP2017519075A (zh) |
| KR (1) | KR20170016850A (zh) |
| CN (1) | CN106795693A (zh) |
| BR (1) | BR112016028640A2 (zh) |
| TW (1) | TW201612374A (zh) |
| WO (1) | WO2015191712A1 (zh) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20180305842A1 (en) * | 2015-06-30 | 2018-10-25 | Invista North America S.A R.L. | Polyurethane fiber including copolymer polyol |
| JP6677540B2 (ja) * | 2016-03-15 | 2020-04-08 | セーレン株式会社 | 車両用複合表皮材 |
| US20190011221A1 (en) * | 2017-07-04 | 2019-01-10 | Grant T. Harris | Systems And Related Methods For Concealing A Self-Defense Device |
| CN111101386A (zh) * | 2019-12-31 | 2020-05-05 | 合肥科天水性科技有限责任公司 | 一种干法透气透湿生物基服装革及其制备方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101155847A (zh) * | 2005-02-11 | 2008-04-02 | 因维斯塔技术有限公司 | 无溶剂聚氨酯水分散体及其成形制品 |
| US20080292788A1 (en) * | 2004-11-05 | 2008-11-27 | Tamicare Ltd. | Methods to Produce Stretchable Products |
| CN102015281A (zh) * | 2007-05-08 | 2011-04-13 | 因维斯塔技术有限公司 | 具有热激活的聚氨酯脲组合物的层压织物构造 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3098755A (en) * | 1959-06-29 | 1963-07-23 | Int Latex Corp | Coated rubber articles and method of producing same |
| US5126182A (en) * | 1989-10-17 | 1992-06-30 | Malden Mills Industries, Inc. | Drapable, water vapor permeable, wind and water resistant composite fabric and method of manufacturing same |
| US5403884A (en) * | 1993-01-13 | 1995-04-04 | National Starch And Chemical Investment Holding Corporation | Process for flocking EDPM substrates |
| US20010008672A1 (en) * | 1996-03-20 | 2001-07-19 | Jean Norvell | Flocked articles |
| US6924000B2 (en) * | 2002-03-07 | 2005-08-02 | Lord Corporation | Environmentally preferred high solids, low viscosity flock adhesives |
| US7897236B2 (en) * | 2002-06-10 | 2011-03-01 | Playtex Products, Inc. | Electrostatic flocking and articles made therefrom |
| US7410682B2 (en) * | 2002-07-03 | 2008-08-12 | High Voltage Graphics, Inc. | Flocked stretchable design or transfer |
| US8709573B2 (en) * | 2003-12-19 | 2014-04-29 | Ansell Healthcare Products Llc | Polymer bonded fibrous coating on dipped rubber articles skin contacting external surface |
| US20060183849A1 (en) * | 2005-02-11 | 2006-08-17 | Invista North America S.A R.L. | Solvent free aqueous polyurethane dispersions and adhesive films therefrom for stretch fabrics |
| US20060183850A1 (en) * | 2005-02-11 | 2006-08-17 | Invista North America S.A.R.L. | Solvent free aqueous polyurethane dispersions and shaped articles therefrom |
| WO2007035809A2 (en) * | 2005-09-20 | 2007-03-29 | High Voltage Graphics, Inc. | Flocked elastomeric articles |
| NZ571295A (en) * | 2006-02-17 | 2011-10-28 | William Rodgers | Article manufactured by rotational moulding and having a fibrous layer at least partially embedded in a thermoplastics material |
| US8969221B2 (en) * | 2007-03-19 | 2015-03-03 | Honeywell International Inc | Inhibition of water penetration into ballistic materials |
| TW201007634A (en) * | 2008-08-06 | 2010-02-16 | Univ Nat Taiwan | Fire-fighting detection system and its weighting-value correction method |
| MY161156A (en) * | 2010-11-18 | 2017-04-14 | Lubrizol Advanced Mat Inc | Polymer for surgeons gloves |
| US9926654B2 (en) * | 2012-09-05 | 2018-03-27 | Gpcp Ip Holdings Llc | Nonwoven fabrics comprised of individualized bast fibers |
| AU2016287768B2 (en) * | 2015-07-02 | 2020-08-27 | Ansell Limited | Thermally conductive glove |
-
2015
- 2015-06-10 KR KR1020167034394A patent/KR20170016850A/ko unknown
- 2015-06-10 BR BR112016028640A patent/BR112016028640A2/pt not_active Application Discontinuation
- 2015-06-10 CN CN201580030966.2A patent/CN106795693A/zh active Pending
- 2015-06-10 WO PCT/US2015/035106 patent/WO2015191712A1/en active Application Filing
- 2015-06-10 EP EP15806818.9A patent/EP3155165A4/en not_active Withdrawn
- 2015-06-10 US US15/315,394 patent/US20170136715A1/en not_active Abandoned
- 2015-06-10 JP JP2016572639A patent/JP2017519075A/ja active Pending
- 2015-06-11 TW TW104118946A patent/TW201612374A/zh unknown
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080292788A1 (en) * | 2004-11-05 | 2008-11-27 | Tamicare Ltd. | Methods to Produce Stretchable Products |
| CN101155847A (zh) * | 2005-02-11 | 2008-04-02 | 因维斯塔技术有限公司 | 无溶剂聚氨酯水分散体及其成形制品 |
| CN102015281A (zh) * | 2007-05-08 | 2011-04-13 | 因维斯塔技术有限公司 | 具有热激活的聚氨酯脲组合物的层压织物构造 |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20170016850A (ko) | 2017-02-14 |
| US20170136715A1 (en) | 2017-05-18 |
| EP3155165A4 (en) | 2018-01-10 |
| EP3155165A1 (en) | 2017-04-19 |
| TW201612374A (en) | 2016-04-01 |
| WO2015191712A1 (en) | 2015-12-17 |
| JP2017519075A (ja) | 2017-07-13 |
| BR112016028640A2 (pt) | 2018-05-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP6291011B2 (ja) | 水性ポリウレタン尿素組成物含有分散体およびフィルム | |
| US11473237B2 (en) | Garment incorporating aqueous polyurethane dispersions having altered stress profile | |
| CN101969801B (zh) | 具有改变的应力分布的衣服 | |
| CN101155847B (zh) | 无溶剂聚氨酯水分散体及其成形制品 | |
| KR20100017682A (ko) | 열 활성화 폴리우레탄우레아 조성물을 갖는 적층 직물 구조체 | |
| JP5391278B2 (ja) | 分散液およびフィルムを包含する水性ポリウレタン尿素組成物 | |
| KR101578233B1 (ko) | 가소제를 포함하는 열-활성화 필름의 결합 | |
| US11692304B2 (en) | Garment incorporating waterproof or water resilient aqueous polyurethane dispersions and/or having altered stress profile | |
| CN106795693A (zh) | 包括水性聚氨酯组合物的分散体和膜 | |
| CN109790273A (zh) | 水性聚氨酯分散体、预聚物、以及由其制成的成型制品 | |
| BR122016024838B1 (pt) | Article, methods for making the article, clothing and clothing piece |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170531 |