CN106784026A - A kind of solar cell wiring board and preparation method thereof - Google Patents

A kind of solar cell wiring board and preparation method thereof Download PDF

Info

Publication number
CN106784026A
CN106784026A CN201611146604.2A CN201611146604A CN106784026A CN 106784026 A CN106784026 A CN 106784026A CN 201611146604 A CN201611146604 A CN 201611146604A CN 106784026 A CN106784026 A CN 106784026A
Authority
CN
China
Prior art keywords
copper foil
solar cell
wiring board
cell wiring
circuit
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611146604.2A
Other languages
Chinese (zh)
Inventor
闫勇
高小君
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou City-State Dali Material Technology Co Ltd
Original Assignee
Suzhou City-State Dali Material Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou City-State Dali Material Technology Co Ltd filed Critical Suzhou City-State Dali Material Technology Co Ltd
Priority to CN201611146604.2A priority Critical patent/CN106784026A/en
Publication of CN106784026A publication Critical patent/CN106784026A/en
Priority to PCT/CN2017/109777 priority patent/WO2018107922A1/en
Priority to JP2018600028U priority patent/JP3224280U/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02Details
    • H01L31/02016Circuit arrangements of general character for the devices
    • H01L31/02019Circuit arrangements of general character for the devices for devices characterised by at least one potential jump barrier or surface barrier
    • H01L31/02021Circuit arrangements of general character for the devices for devices characterised by at least one potential jump barrier or surface barrier for solar cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
    • H01L21/48Manufacture or treatment of parts, e.g. containers, prior to assembly of the devices, using processes not provided for in a single one of the subgroups H01L21/06 - H01L21/326
    • H01L21/4814Conductive parts
    • H01L21/4846Leads on or in insulating or insulated substrates, e.g. metallisation
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L24/00Arrangements for connecting or disconnecting semiconductor or solid-state bodies; Methods or apparatus related thereto
    • H01L24/80Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected
    • H01L24/83Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected using a layer connector
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/80Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected
    • H01L2224/83Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected using a layer connector
    • H01L2224/838Bonding techniques
    • H01L2224/83801Soldering or alloying
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

Abstract

The invention discloses a kind of solar cell wiring board and preparation method thereof, including:Solar battery sheet and resin base material, are coated with adhesive layer on resin base material, Copper Foil is compounded with adhesive layer, and etching forms circuit on Copper Foil, and the surface of circuit is coated with anti-oxidation coating;Circuit is engaged with solar battery sheet by low temperature scolding tin.The solar cell wiring board is prepared simply, and has preferable inoxidizability and solderability in the presence of a harsh environment.

Description

A kind of solar cell wiring board and preparation method thereof
Technical field
The present invention relates to technical field of solar batteries, more particularly to a kind of solar cell wiring board and its preparation side Method.
Background technology
Solar energy is a kind of clean and environment-friendly energy of new renewable sustainable use, and development and utilization solar energy turns into The important content of the strategy of sustainable development is formulated in countries in the world, and is also preferably research contents using solar energy, improves the sun The generating efficiency of energy is also important research topic.
The content of the invention
It is an object of the invention to propose a kind of solar cell wiring board and preparation method thereof, have in the presence of a harsh environment Preferable inoxidizability and solderability.
It is that, up to this purpose, the present invention uses following technical scheme:
A kind of solar cell wiring board, including:Solar battery sheet and resin base material, are coated with the resin base material Adhesive layer, is compounded with Copper Foil on the adhesive layer, etching forms circuit on the Copper Foil, and the surface of the circuit is coated with anti- Oxide coating;The circuit is engaged with the solar battery sheet by low temperature scolding tin.
Wherein, Zn content is 0.5~25mg/m in the anti-oxidation coating2, nickel content be 0.5~10mg/m2, chromium content It is 0.5~8mg/m2
Wherein, the adhesive layer includes the component of following weight portion:20~100 parts of resin;1~5 part of curing agent;Auxiliary agent 0.1~0.5 part;0.1~0.5 part of filler;5~10 parts of solvent;The thickness of the adhesive layer is 8~20 μm.
Wherein, the resin is the mixing of one or more in polyurethane, epoxy resin, acrylic resin.
Wherein, the resin base material be PEN (PEN), polyethylene terephthalate (PET), The mixing of one or more in polyimides (PI);The thickness of the resin base material is 45~125um.
Wherein, the thickness of the Copper Foil is 10~45um.
The Copper Foil carried out microetch treatment before etching forms the circuit.
A kind of preparation method of above-mentioned solar cell wiring board, comprises the following steps:
Step A:Adhesive is prepared, even spread adhesive forms after adhesive layer composite copper foil and ripe on the resin base material Change forms flexible copper-clad plate;
Step B:Smooth surface (S faces) to the Copper Foil in the step A carries out microetch treatment, is prevented with the Copper Foil for removing Copper Foil Sheath, exposes Copper Foil basic unit;
Step C:Copper Foil after being processed through the step B is etched to form circuit, is cleaned and is dried;
Step D:Anti-oxidation coating is electroplated on circuit in the step C;
Step E:Circuit after being processed through the step D is engaged with solar battery sheet by low temperature scolding tin.
Wherein, the Copper Foil in the step B etches 30s~60s in concentration is sulfuric acid-hydrogen peroxide micro etching solution.
Wherein, the Copper Foil in the step C is through the dry film post-exposure of fitting, development, in the chlorination that concentration is 200~300g/L It is etched in iron etching solution, etch process parameters are:Temperature is 40~60 DEG C, and pressure is 1.5~3kg/cm2, etching period It is 2~4min.
Beneficial effects of the present invention are:The present invention proposes a kind of solar cell wiring board and preparation method thereof, prepares letter It is single, and there is preferable inoxidizability and solderability in the presence of a harsh environment.
Brief description of the drawings
Fig. 1 is the structural representation that a kind of solar cell wiring board that the present invention is provided connects solar battery sheet;
Fig. 2 a are a kind of structural representations of solar cell wiring board that the present invention is provided;
Fig. 2 b are the A-A sectional views in Fig. 2 a;
Fig. 2 c are a kind of solar cell wiring board in Fig. 2 a structural representations before the etch;
Fig. 2 d are a kind of structural representation of solar cell wiring board in Fig. 2 c after microetch;
Fig. 2 e are a kind of structural representation of solar cell wiring board in Fig. 2 d after dry film of fitting;
Fig. 2 f are a kind of structural representation of solar cell wiring board in Fig. 2 e after circuit is etched;
Fig. 2 g are a kind of structural representation of solar cell wiring board in Fig. 2 f after dry film is peeled off;
Fig. 2 h are a kind of structure of solar cell wiring board in Fig. 2 g after Copper Foil plates anti-oxidation coating
Schematic diagram.
In figure:1- solar cell wiring boards;2- resin base materials;3- circuits;41- Copper Foils basic unit;42- Copper Foil overcoats; 4- Copper Foils;5- dry films;6- adhesive layers;The anti-oxidation coating of 7-;8- solar battery sheets.
Specific embodiment
Further illustrate technical scheme below in conjunction with the accompanying drawings and by specific embodiment.
As shown in Figure 1, Figure 2 shown in a and Fig. 2 b, a kind of solar cell wiring board 1 proposed by the present invention, including:Solar-electricity Pond piece 8 and resin base material 2, are coated with adhesive layer 6 on resin base material 2, Copper Foil 4 is compounded with adhesive layer 6, are lost on Copper Foil 4 Form circuit 3 quarter, the surface of circuit 3 is coated with anti-oxidation coating 7;Circuit 3 is engaged with solar battery sheet 8 by low temperature scolding tin. The solar cell wiring board 1 has preferable inoxidizability and solderability in the presence of a harsh environment.
Embodiment
In the present embodiment, resin base material 2 is polyethylene terephthalate (PET), in thickness gathering to benzene for 50um The adhesive that 8um is coated with naphthalate (PET) forms adhesive layer 6, then 20um Copper Foils are combined on adhesive layer 6 4, form flexible copper-clad plate through curing.As shown in Figure 2 c.Wherein, Copper Foil 4 includes Copper Foil basic unit 41 and for preventing Copper Foil basic unit The Copper Foil overcoat 42 of 41 oxidations, wherein, in Copper Foil overcoat 42:Zn content is 33.68mg/m2, nickel content be 11.79mg/ m2, chromium content 7.2mg/m2.The thickness of flexible copper-clad plate is 78um, TD=340mm, MD=340mm.
It is 4 samples of 170mm*170mm by the cutting of above-mentioned flexible copper-clad plate, these samples is labeled as:Sample 1, sample Product 2, sample 3 and sample 4.By sample 1,3 three samples of sample 2 and sample etched in sulfuric acid-hydrogen peroxide micro etching solution 30s~ Taken out after 60s, cleaned up with clear water, the Copper Foil overcoat 42 of Copper Foil 4 is etched away, expose Copper Foil basic unit 41, such as schemed Shown in 2d.It is whether complete to judge its Copper Foil overcoat 42 with EDS testers determination sample 1, sample 2 and the constituent content of sample 3 Etch away entirely.
To be again exposed after above-mentioned 4 samples laminating 40um dry films 5, developed, then be 2KG/cm in temperature 50 C pressure2 Taken out after etching 3min during concentration is 250mol/L iron chloride etching solutions down, to etch circuit 3, clean dry with clear water Only, 4 170mm*170mm samples are obtained.Wherein, the structure of sample 1, sample 2 and sample 3 is as shown in Figure 2 e.
By above-mentioned 4 samples carry out peel off the operation of dry film 5, wherein, sample 4 etch and peel off dry film 5 during, its Constituent content loss in Copper Foil overcoat 42, is reduced to:Zn content 26.35mg/m2, nickel content 10.41mg/m2, chromium content 5.01mg/m2.Above-mentioned sample 1 by etching process, sample 2 and sample 3 are electroplated by anti-oxidation treatment trough, is formed Anti-oxidation coating 7, makes in anti-oxidation coating 7 each element amount respectively in following scope:Zinc-plated amount 0mg/m2, 0.5mg/m2~ 10mg/m2, 10mg/m2~20mg/m2;Nickel plating amount 0mg/m2, 0.5mg/m2~5mg/m2, 5mg/m2~10mg/m2;Tin Free Steel 0mg/m2, 0.5mg/m2~3mg/m2, 3mg/m2~5mg/m2.By the constituent content of the anti-oxidation coating 7 of EDS measurements determinations. Structure of sample 1, sample 2 and sample 3 is as shown in Fig. 2 f to Fig. 2 h during this.
Above-mentioned 4 samples and raw sample are cut to the size of 5cm*5cm, are 42%, bi content by being coated with Theil indices 57%, silver 1% low temperature tin cream at 160 DEG C~180 DEG C heating and melting, 4 samples of visual observations can solderability.Again will be upper Stating 4 samples and raw sample carries out 85 DEG C, the aging 24h tests of 85%RH, estimates oxygen-proof property and scolding tin adherence.
Above-mentioned raw sample and sample 1 to the testing result of the solderability, oxygen-proof property and scolding tin adherence of sample 4 see below Table:
Project Anti-oxidation coating constituent content (mg/m2) Solderability Oxygen-proof property Scolding tin adherence
Sample 1 Zn=0, Ni=0, Cr=0 It is excellent Difference It is excellent
Sample 2 Zn=8.12, Ni=4.76, Cr=2.96 It is excellent Well It is excellent
Sample 3 Zn=18.56, Ni=9.29, Cr=4.19 Well Well Well
Sample 4 Zn=26.35, Ni=10.41, Cr=5.01 Difference It is excellent Difference
Raw sample Zn=33.68, Ni=11.79, Cr=7.2 Difference It is excellent Difference
From the above, it is seen that a kind of solar cell wiring board proposed by the present invention, prepares simply, and in severe ring There is preferable inoxidizability and solderability under border.In addition, the FPC passes through scolding tin by solar battery sheet 8 and circuit 3 engagements, can both improve heat sinking function, internal resistance reduced, also with fine oxygen-proof property and processability.
Know-why of the invention is described above in association with specific embodiment.These descriptions are intended merely to explain of the invention Principle, and can not by any way be construed to limiting the scope of the invention.Based on explanation herein, the technology of this area Personnel associate other specific embodiments of the invention by would not require any inventive effort, these modes fall within Within protection scope of the present invention.

Claims (10)

1. a kind of solar cell wiring board, it is characterised in that including:Solar battery sheet (8) and resin base material (2), it is described Adhesive layer (6) is coated with resin base material (2), Copper Foil (4) is compounded with the adhesive layer (6), lost on the Copper Foil (4) Form circuit (3) quarter, the surface of the circuit (3) is coated with anti-oxidation coating (7);The circuit (3) and the solar cell Piece (8) is engaged by low temperature scolding tin.
2. a kind of solar cell wiring board according to claim 1, it is characterised in that in the anti-oxidation coating (7) Zn content is 0.5~25mg/m2, nickel content be 0.5~10mg/m2, chromium content be 0.5~8mg/m2
3. a kind of solar cell wiring board according to claim 1, it is characterised in that the adhesive layer (6) includes The component of following weight portion:20~100 parts of resin;1~5 part of curing agent;0.1~0.5 part of auxiliary agent;0.1~0.5 part of filler;It is molten 5~10 parts of agent;The thickness of the adhesive layer (6) is 8~20 μm.
4. a kind of solar cell wiring board according to claim 3, it is characterised in that the resin is polyurethane, ring The mixing of one or more in oxygen tree fat, acrylic resin.
5. a kind of solar cell wiring board according to claim 1, it is characterised in that the resin base material (2) is poly- In (ethylene naphthalate) (PEN), polyethylene terephthalate (PET), polyimides (PI) one or more Mixing;The thickness of the resin base material (2) is 45~125um.
6. a kind of solar cell wiring board according to claim 1, it is characterised in that the thickness of the Copper Foil (4) is 10~45um.
7. a kind of solar cell wiring board according to claim 1 and 2, it is characterised in that the Copper Foil (4) is in etching Microetch treatment is carried out before forming the circuit (3).
8. a kind of preparation method of solar cell wiring board of claim 1 is used for, it is characterised in that comprised the following steps:
Step A:Adhesive is prepared, even spread adhesive forms adhesive layer (6) composite copper foil afterwards on resin base material (2) (4) and curing form flexible copper-clad plate;
Step B:Top surface to the Copper Foil (4) in the step A carries out microetch treatment, is protected with the Copper Foil for removing Copper Foil (4) Layer (42), exposes Copper Foil basic unit (41);
Step C:Copper Foil (4) after being processed through the step B is etched to mold to form circuit (3), is cleaned and is dried;
Step D:Anti-oxidation coating (7) is electroplated on circuit (3) in the step C;
Step E:Circuit (3) after being processed through the step D is engaged with solar battery sheet (8) by low temperature scolding tin.
9. a kind of preparation method of solar cell wiring board according to claim 8, it is characterised in that the step B In Copper Foil (4) 30s~60s is etched in sulfuric acid-hydrogen peroxide micro etching solution.
10. a kind of preparation method of solar cell wiring board according to claim 8, it is characterised in that the step C In Copper Foil (4) through fit dry film (5) post-exposure, development, lost in the iron chloride etching solution that concentration is 200~300g/L Carve, etch process parameters are:Temperature is 40~60 DEG C, and pressure is 1.5~3kg/cm2, etching period is 2~4min.
CN201611146604.2A 2016-12-13 2016-12-13 A kind of solar cell wiring board and preparation method thereof Pending CN106784026A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CN201611146604.2A CN106784026A (en) 2016-12-13 2016-12-13 A kind of solar cell wiring board and preparation method thereof
PCT/CN2017/109777 WO2018107922A1 (en) 2016-12-13 2017-11-07 Solar cell circuit board and preparation method therefor, and solar cell
JP2018600028U JP3224280U (en) 2016-12-13 2017-11-07 Solar cell substrate and solar cell

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611146604.2A CN106784026A (en) 2016-12-13 2016-12-13 A kind of solar cell wiring board and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106784026A true CN106784026A (en) 2017-05-31

Family

ID=58880684

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611146604.2A Pending CN106784026A (en) 2016-12-13 2016-12-13 A kind of solar cell wiring board and preparation method thereof

Country Status (3)

Country Link
JP (1) JP3224280U (en)
CN (1) CN106784026A (en)
WO (1) WO2018107922A1 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107325489A (en) * 2017-08-14 2017-11-07 通威太阳能(安徽)有限公司 A kind of anticorrosion epoxy novolac glue and its application in battery dies etching technique
WO2018107922A1 (en) * 2016-12-13 2018-06-21 苏州城邦达力材料科技有限公司 Solar cell circuit board and preparation method therefor, and solar cell
WO2018107924A1 (en) * 2016-12-13 2018-06-21 苏州城邦达力材料科技有限公司 Flexible circuit board and preparation method, and solar photovoltaic assembly

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101374388A (en) * 2008-03-28 2009-02-25 苏陟 Method for preparing fine line flexible circuit board with high peeling strength
CN201479455U (en) * 2009-04-16 2010-05-19 惠州国展电子有限公司 Metal base flexible circuit copper-clad plate and metal base flexible circuit board
CN102265711A (en) * 2008-12-26 2011-11-30 吉坤日矿日石金属株式会社 Rolled copper foil or electrolytic copper foil for electronic circuit, and method for forming electronic circuit using the rolled copper foil or electrolytic copper foil
CN105350046A (en) * 2015-10-23 2016-02-24 衢州顺络电路板有限公司 Circuit board for replacing golden metal strips and manufacturing method of circuit board

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN204348742U (en) * 2015-01-05 2015-05-20 苏州中来光伏新材股份有限公司 Without main grid high efficiency back contact solar cell and assembly thereof
CN106604538A (en) * 2016-12-13 2017-04-26 苏州城邦达力材料科技有限公司 Flexible circuit board and preparing method thereof
CN106784026A (en) * 2016-12-13 2017-05-31 苏州城邦达力材料科技有限公司 A kind of solar cell wiring board and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101374388A (en) * 2008-03-28 2009-02-25 苏陟 Method for preparing fine line flexible circuit board with high peeling strength
CN102265711A (en) * 2008-12-26 2011-11-30 吉坤日矿日石金属株式会社 Rolled copper foil or electrolytic copper foil for electronic circuit, and method for forming electronic circuit using the rolled copper foil or electrolytic copper foil
CN201479455U (en) * 2009-04-16 2010-05-19 惠州国展电子有限公司 Metal base flexible circuit copper-clad plate and metal base flexible circuit board
CN105350046A (en) * 2015-10-23 2016-02-24 衢州顺络电路板有限公司 Circuit board for replacing golden metal strips and manufacturing method of circuit board

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018107922A1 (en) * 2016-12-13 2018-06-21 苏州城邦达力材料科技有限公司 Solar cell circuit board and preparation method therefor, and solar cell
WO2018107924A1 (en) * 2016-12-13 2018-06-21 苏州城邦达力材料科技有限公司 Flexible circuit board and preparation method, and solar photovoltaic assembly
CN107325489A (en) * 2017-08-14 2017-11-07 通威太阳能(安徽)有限公司 A kind of anticorrosion epoxy novolac glue and its application in battery dies etching technique
CN107325489B (en) * 2017-08-14 2019-07-16 通威太阳能(安徽)有限公司 A kind of anticorrosion epoxy-phenol glue and its application in battery dies etching technique

Also Published As

Publication number Publication date
WO2018107922A1 (en) 2018-06-21
JP3224280U (en) 2019-12-12

Similar Documents

Publication Publication Date Title
CN106604538A (en) Flexible circuit board and preparing method thereof
CN106784026A (en) A kind of solar cell wiring board and preparation method thereof
US9882078B2 (en) Integrated back-sheet assembly for photovoltaic module
KR100389468B1 (en) Resin-coated composite foil, production and use thereof
CN1179611C (en) Composite foil of aluminium and copper
CN106232350B (en) With the metal foil and printed circuit board (PCB) for peeling off resin bed
CN202310279U (en) Graphical printed board at bottom of dual-step ladder groove
CN104752234B (en) A kind of Microvia preparation method of flexible encapsulating substrate
TWI492675B (en) Peelable copper foil-clad substrate, and method for manufacturing circuit board
CN102555333B (en) Composite metallic material, its manufacture method and printed wiring board
TW201247046A (en) Method of manufacturing multi-layer printed wiring board and multi-layer printed wiring board obtained by the manufacturing method
CN105007687A (en) Copper foil with carrier, printed wiring board, laminated body, electronic machine and method for manufacturing printed wiring board
CN106341944B (en) A kind of rigid-flex combined board and preparation method thereof for protecting internal layer pad
CN105746004B (en) Cambial support substrate, multilayer laminate, the manufacturing method of multilayer printed circuit board and the multilayer printed circuit board of circuit is had with the cambial support substrate of circuit, two sides
WO2012105481A1 (en) Resin-coated metal plate
CN104582297A (en) Printed circuit selective electroplating addition and preparation technology
CN106164327B (en) Surface treatment copper foil and its manufacture method, use in printed circuit board copper-clad laminated board and printed circuit board (PCB)
JP6104260B2 (en) Metal foil with carrier
CN110834442A (en) TPX release film
CN108221477B (en) Glue-blocking release paper for flexible circuit board pressing and preparation method thereof
CN110191597A (en) A kind of manufacture craft of multilayer circuit board
JP2015010273A5 (en) Copper foil with carrier and method for producing the same, method for producing copper-clad laminate and method for producing printed wiring board
CN203974166U (en) High heat-resisting separable copper foil structure
CN102963064B (en) Metamaterial and preparation method thereof
CN207120536U (en) A kind of aluminum-based copper-clad plate

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20170531