CN106768515B - Differential type pressure cell and its method of production based on double hamburger structures - Google Patents

Differential type pressure cell and its method of production based on double hamburger structures Download PDF

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Publication number
CN106768515B
CN106768515B CN201710032959.7A CN201710032959A CN106768515B CN 106768515 B CN106768515 B CN 106768515B CN 201710032959 A CN201710032959 A CN 201710032959A CN 106768515 B CN106768515 B CN 106768515B
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phase content
electrode
film
encapsulating film
window
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CN106768515A (en
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王璐珩
王斐
朱红求
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Central South University
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Central South University
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01LMEASURING FORCE, STRESS, TORQUE, WORK, MECHANICAL POWER, MECHANICAL EFFICIENCY, OR FLUID PRESSURE
    • G01L1/00Measuring force or stress, in general
    • G01L1/18Measuring force or stress, in general using properties of piezo-resistive materials, i.e. materials of which the ohmic resistance varies according to changes in magnitude or direction of force applied to the material
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01LMEASURING FORCE, STRESS, TORQUE, WORK, MECHANICAL POWER, MECHANICAL EFFICIENCY, OR FLUID PRESSURE
    • G01L19/00Details of, or accessories for, apparatus for measuring steady or quasi-steady pressure of a fluent medium insofar as such details or accessories are not special to particular types of pressure gauges
    • G01L19/04Means for compensating for effects of changes of temperature, i.e. other than electric compensation
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01LMEASURING FORCE, STRESS, TORQUE, WORK, MECHANICAL POWER, MECHANICAL EFFICIENCY, OR FLUID PRESSURE
    • G01L9/00Measuring steady of quasi-steady pressure of fluid or fluent solid material by electric or magnetic pressure-sensitive elements; Transmitting or indicating the displacement of mechanical pressure-sensitive elements, used to measure the steady or quasi-steady pressure of a fluid or fluent solid material, by electric or magnetic means
    • G01L9/02Measuring steady of quasi-steady pressure of fluid or fluent solid material by electric or magnetic pressure-sensitive elements; Transmitting or indicating the displacement of mechanical pressure-sensitive elements, used to measure the steady or quasi-steady pressure of a fluid or fluent solid material, by electric or magnetic means by making use of variations in ohmic resistance, e.g. of potentiometers, electric circuits therefor, e.g. bridges, amplifiers or signal conditioning

Abstract

The present invention relates to a kind of differential type pressure cell and its method of production based on double hamburger structures, belongs to field of sensing technologies.Differential type pressure cell based on double hamburger structures includes the highly conductor phase content list hamburger structure sheaf being made of window encapsulating film, highly conductor phase content pressure-sensitive film, hot-setting adhesive and small electrode encapsulating film and low conductive phase content list hamburger structure sheaf for being made of large electrode encapsulating film, low conductive phase content pressure-sensitive film, hot-setting adhesive and window encapsulating film.The adverse effect that temperature exports pressure cell can be reduced using highly conductor phase content list hamburger structure sheaf and low conductive phase content list hamburger structure sheaf as the adjacent bridge arm of electric bridge.Using method development proposed by the present invention the differential type pressure cell based on double hamburger structures number of electrodes than traditional based on the few of single hamburger structure, be conducive to simplify component structure, in order to be mounted on small space, it is suitable for the fields such as the narrow interlayer pressure measurement of military and civil equipment or the realization of robot finger tip tactile.

Description

Differential type pressure cell and its method of production based on double hamburger structures
Technical field
The invention belongs to field of sensing technologies, are related specifically to narrow interlayer pressure measurement.
Background technique
Not only there is piezoresistive characteristic by the conductive polymer composite that conductive nano powder and macromolecule matrix are constituted, and And there is workability and good flexibility.Therefore, more and more scientific research institutions are all developing based on this composite material Flexible pressure-sensitive element to realize the pressure measurement of modern national defense and industrial circle, such as: the narrow interlayer pressure of large scale equipment is surveyed Amount and the development of artificial electron's skin etc..Since the resistance of this composite material has temperature dependency, caused by temperature meeting Pressure cell output shift.So how to reduce the influence that temperature exports pressure cell is the current critical issue in the field. The resistance of the pressure-sensitive subelement of highly conductor phase content and the pressure-sensitive subelement of low conductive phase content with pressure trend mutually instead It varies with temperature that trend is identical, therefore can be used based on the differential bridge of both pressure-sensitive subelements and reduce as caused by temperature Pressure cell output shift.Since traditional pressure-sensitive subelement all uses single hamburger structure, increase the quantity meeting of pressure-sensitive subelement Cause sensing probe increasingly complex.For example, four electrodes are then needed according to half-bridge differential form, than traditional single hamburger structure Number of electrodes increases one times.But the narrow space of sensor can be installed in many engineer applications, therefore, need to simplify pressure The structure of quick subelement, can be installed in the structure of narrow space to complete measurement task.
Summary of the invention
The purpose of the present invention is the shortcomings to overcome prior art, propose a kind of differential type based on double hamburger structures Pressure cell and its method of production.The differential type pressure cell based on double hamburger structures includes the highly conductor phase content list Chinese Fort structure sheaf and low conductive phase content list hamburger structure sheaf, highly conductor phase content list hamburger structure sheaf are led by window encapsulating film, height Electric phase content pressure-sensitive film, hot-setting adhesive and small electrode encapsulating film are constituted, and low conductive phase content list hamburger structure sheaf is encapsulated by large electrode Film, low conductive phase content pressure-sensitive film, hot-setting adhesive and window encapsulating film are constituted.
The method of production of the flexible piezoresistance sensor based on built-in electrode the following steps are included:
In the electrode and its lead conduct that the side of first insulation film is a length of 3.36 centimetres laminating, width is 5.12 centimetres Large electrode encapsulating film;In the electrode that the side of second insulation film is a length of 0.38 centimetre laminating, width is 0.59 centimetre and its draw Line is as small electrode encapsulating film;In the electrode that the side of third insulation film is a length of 3.36 centimetres laminating, width is 5.12 centimetres And its lead, and in the window that the side of the third not laminating electrode of insulation film opens a length of 0.38 centimetre, width is 0.59 centimetre, It is exposed by window in the side of not laminating electrode to make the laminating electrode on third insulation film, and ensures the window Axle center is overlapped with the laminating electrode axle center on third insulation film, and then completes the preparation of window encapsulating film;By small electrode Encapsulating film is placed in spare on rotating platform, and ensures that the laminating side for having electrode is upward;
Carbon black, room temperature vulcanized silicone rubber and n-hexane that average grain diameter is 30 nanometers are mixed by 1: 8: 100 volume ratio, Disperse carbon black in the mixed solution being made of room temperature vulcanized silicone rubber and n-hexane using mechanical stirring and sonic oscillation, to After n-hexane volatilization, the carbon black filled silicon rubber composite material of highly conductor phase content is formed;The carbon black of highly conductor phase content is filled out Silicon rubber composite material is filled to instill on the electrode for the small electrode encapsulating film being fixed on rotating platform;Highly conductor phase content Carbon black filled silicon rubber composite material spin coating ensures the carbon black filled silicon rubber composite wood of highly conductor phase content at required thickness Material is completely covered on the electrode of small electrode encapsulating film;Carbon black filled silicon rubber composite material to highly conductor phase content vulcanizes After molding, the carbon black filled silicon rubber composite material of the highly conductor phase content except the electrode of small electrode encapsulating film is removed, it is remaining The electrode for being covered on small electrode encapsulating film on the carbon black filled silicon rubber composite material of highly conductor phase content led as height The highly conductor phase content pressure-sensitive film of electric phase content list hamburger structure sheaf;Highly conductor phase content pressure-sensitive film on small electrode encapsulating film Hot-setting adhesive is applied on the insulation film of surrounding, window encapsulating film is covered on highly conductor phase content pressure-sensitive film and hot-setting adhesive, and Ensure the window of window encapsulating film with highly conductor phase content pressure-sensitive film face and the laminating electrode on window encapsulating film is not covering The part that the side of composite electrode is exposed by window is completely attached to highly conductor phase content pressure-sensitive film, utilizes flexible material hot pressing Sealing machine carries out packaging by hot pressing to window encapsulating film, highly conductor phase content pressure-sensitive film, hot-setting adhesive and small electrode encapsulating film, and then complete At the highly conductor phase content list Chinese being made of window encapsulating film, highly conductor phase content pressure-sensitive film, hot-setting adhesive and small electrode encapsulating film The preparation of fort structure sheaf;
The fixation of highly conductor phase content list hamburger structure sheaf is spare on the rotating platform, and make laminating on window encapsulating film Electrode side it is upward;Carbon black, room temperature vulcanized silicone rubber and n-hexane that average grain diameter is 30 nanometers are pressed to 1: 16: 180 body Product makes carbon black in the mixed solution being made of room temperature vulcanized silicone rubber and n-hexane than mixing using mechanical stirring and sonic oscillation Middle dispersion forms the carbon black filled silicon rubber composite material of low conductive phase content after n-hexane volatilization;By low conductive phase content Carbon black filled silicon rubber composite material instill the rotating platform for being fixed with highly conductor phase content list hamburger structure sheaf it On, the carbon black filled silicon rubber composite material spin coating of low conductive phase content at required thickness, and ensure low conductive phase content Carbon black filled silicon rubber composite material be completely covered on the window encapsulating film of highly conductor phase content list hamburger structure sheaf electrode it On;After the carbon black filled silicon rubber composite material sulfidization molding of low conductive phase content, except the electrode for removing window encapsulating film Part, the carbon black filled silicon rubber composite material of the low conductive phase content on the remaining electrode for being covered on window encapsulating film Low conductive phase content pressure-sensitive film as low conductive phase content list hamburger structure sheaf;Window around low conductive phase content pressure-sensitive film Apply hot-setting adhesive on the insulation film of mouthful encapsulating film, by large electrode encapsulating film be covered on low conductive phase content pressure-sensitive film and hot-setting adhesive it On, and ensure electrode and low conductive phase content pressure-sensitive film face and the full contact of large electrode encapsulating film, utilize flexible material heat Press seal is installed to highly conductor phase content list hamburger structure sheaf, low conductive phase content pressure-sensitive film and hot-setting adhesive and large electrode encapsulating film Packaging by hot pressing is carried out, is made of with completion large electrode encapsulating film, low conductive phase content pressure-sensitive film, hot-setting adhesive and window encapsulating film The preparation of low conductive phase content list hamburger structure sheaf, and then complete to be contained by highly conductor phase content list hamburger structure sheaf and low conductive phase Measure the preparation for the differential type pressure cell based on double hamburger structures that single hamburger structure sheaf is constituted.
The features of the present invention and effect:
Utilize the differential type pressure cell based on double hamburger structures of method preparation of the invention comprising highly conductor phase The volume ratio of the carbon black and room temperature vulcanized silicone rubber of content pressure-sensitive film and low conductive phase content pressure-sensitive film be by many experiments and Analysis obtains, it can be ensured that the resistance of highly conductor phase content pressure-sensitive film and low conductive phase content pressure-sensitive film with pressure variation tendency On the contrary and variation with temperature is identical, therefore can make the adjacent bridge arm of an electric bridge and then reduce temperature drift and increase sensitivity.It is high Conductive phase content list hamburger structure sheaf and low conductive phase content list hamburger structure sheaf shared window encapsulating film, with traditional based on list The differential type pressure cell of hamburger structure is compared, and is saved an electrode, is more advantageous to and simplifies component structure, and then be applied to more Add narrow space, is realized especially suitable for the narrow interlayer pressure measurement of large-scale military and civil equipment or robot finger tip tactile Equal fields.
Detailed description of the invention
Fig. 1 (A) is the laminating top view for having electrode side of large electrode encapsulating film.
Fig. 1 (B) is the sectional view of large electrode encapsulating film.
Fig. 2 (A) is the laminating top view for having electrode side of small electrode encapsulating film.
Fig. 2 (B) is the sectional view of small electrode encapsulating film.
Fig. 3 (A) is the laminating top view for having electrode side of window encapsulating film.
Fig. 3 (B) is the sectional view of window encapsulating film.
Fig. 3 (C) is the top view for being provided with window side of window encapsulating film.
Fig. 4 is the sectional view of highly conductor phase content list hamburger structure sheaf.
Fig. 5 is the sectional view of the differential type pressure cell based on double hamburger structures.
In Fig. 1-Fig. 5, a represents the insulating film (that is: first insulating film) of large electrode encapsulating film;B represents laminating in big electricity Electrode on the insulating film of pole encapsulating film;C represents the laminating lead on the insulating film of large electrode encapsulating film;D represents small electrode The insulating film (that is: second insulating film) of encapsulating film;E represents the laminating electrode on the insulating film of small electrode encapsulating film;F is represented The laminating lead on the insulating film of small electrode encapsulating film;G represents the insulating film (that is: third insulating film) of window encapsulating film;h Represent the laminating electrode on the insulating film of window encapsulating film;I represents the laminating lead on the insulating film of window encapsulating film;j1 Represent the window that the side of not laminating electrode is opened on the insulating film in window encapsulating film;J2 represents laminating on window encapsulating film The part that is exposed in the side of not laminating electrode by window of electrode;K represents highly conductor phase content pressure-sensitive film;1 represents position Hot-setting adhesive between small electrode encapsulating film and window encapsulating film;M represents low conductive phase content pressure-sensitive film;N, which is represented, is located at window Hot-setting adhesive between encapsulating film and large electrode encapsulating film.
Specific embodiment
Illustrate the development side of the differential type pressure cell proposed by the present invention based on double hamburger structures with reference to embodiments Method:
In the electrode b and its lead c that the side of first insulation film a is a length of 3.36 centimetres laminating, width is 5.12 centimetres As large electrode encapsulating film;In the electrode e that the side of second insulation film d is a length of 0.38 centimetre laminating, width is 0.59 centimetre And its lead f is as small electrode encapsulating film;The side of third insulation film g is a length of 3.36 centimetres laminating, width is 5.12 lis The electrode h and its lead i of rice, and a length of 0.38 centimetre, width 0.59 are opened in the side of the third not laminating electrode of insulation film g Centimetre window j1, keep the laminating electrode h on third insulation film g naked by window j1 in the side of not laminating electrode Dew, and ensure that the axle center window j1 is overlapped with the laminating axle center electrode h on third insulation film g, and then complete window The preparation of mouth encapsulating film;Small electrode encapsulating film is placed in spare on rotating platform, and ensures that the laminating side for having electrode is upward;
Carbon black, room temperature vulcanized silicone rubber and n-hexane that average grain diameter is 30 nanometers are mixed by 1: 8: 100 volume ratio, Disperse carbon black in the mixed solution being made of room temperature vulcanized silicone rubber and n-hexane using mechanical stirring and sonic oscillation, to After n-hexane volatilization, the carbon black filled silicon rubber composite material of highly conductor phase content is formed;The carbon black of highly conductor phase content is filled out Silicon rubber composite material is filled to instill on the electrode e for the small electrode encapsulating film being fixed on rotating platform;Highly conductor phase content Carbon black filled silicon rubber composite material spin coating at required thickness, and ensure that the carbon black filled silicon rubber of highly conductor phase content is compound Material is completely covered on the electrode e of small electrode encapsulating film;Carbon black filled silicon rubber composite material to highly conductor phase content After sulfidization molding, the carbon black filled silicon rubber composite material of the highly conductor phase content except the electrode of small electrode encapsulating film is removed, The carbon black filled silicon rubber composite material conduct of highly conductor phase content on the remaining electrode for being covered on small electrode encapsulating film The highly conductor phase content pressure-sensitive film k of highly conductor phase content list hamburger structure sheaf;Highly conductor phase content on small electrode encapsulating film Hot-setting adhesive 1 is applied on insulation film around pressure-sensitive film k, and window encapsulating film is covered on highly conductor phase content pressure-sensitive film k and thermosetting On glue 1, and ensure the window j1 and highly conductor phase content pressure-sensitive film k face and laminating in window encapsulating film of window encapsulating film On electrode connect completely in the part j2 and highly conductor phase content pressure-sensitive film k that the side of not laminating electrode is exposed by window Touching encapsulates window encapsulating film, highly conductor phase content pressure-sensitive film k, hot-setting adhesive 1 and small electrode using flexible material packaging by hot pressing machine Film carries out packaging by hot pressing, and then completes by window encapsulating film, highly conductor phase content pressure-sensitive film, hot-setting adhesive and small electrode encapsulating film structure At highly conductor phase content list hamburger structure sheaf preparation;
The fixation of highly conductor phase content list hamburger structure sheaf is spare on the rotating platform, and make laminating on window encapsulating film The side electrode h it is upward;Carbon black, room temperature vulcanized silicone rubber and n-hexane that average grain diameter is 30 nanometers are pressed to 1: 16: 180 body Product makes carbon black in the mixed solution being made of room temperature vulcanized silicone rubber and n-hexane than mixing using mechanical stirring and sonic oscillation Middle dispersion forms the carbon black filled silicon rubber composite material of low conductive phase content after n-hexane volatilization;By low conductive phase content Carbon black filled silicon rubber composite material instill the rotating platform for being fixed with highly conductor phase content list hamburger structure sheaf it On, the carbon black filled silicon rubber composite material spin coating of low conductive phase content at required thickness, and ensure low conductive phase content Carbon black filled silicon rubber composite material be completely covered on the window encapsulating film of highly conductor phase content list hamburger structure sheaf electrode h it On;After the carbon black filled silicon rubber composite material sulfidization molding of low conductive phase content, except the electrode h for removing window encapsulating film Part, the carbon black filled silicon rubber composite wood of the low conductive phase content on the remaining electrode h for being covered on window encapsulating film Expect the low conductive phase content pressure-sensitive film m as low conductive phase content list hamburger structure sheaf;Around low conductive phase content pressure-sensitive film m Window encapsulating film insulation film on apply hot-setting adhesive n, large electrode encapsulating film is covered on low conductive phase content pressure-sensitive film m and heat On solid glue n, and ensure large electrode encapsulating film electrode b and low conductive phase content pressure-sensitive film m face and full contact, utilization it is soft Property material packaging by hot pressing machine to highly conductor phase content list hamburger structure sheaf, low conductive phase content pressure-sensitive film m and hot-setting adhesive n and big Electrode package film carries out packaging by hot pressing, to complete by large electrode encapsulating film, low conductive phase content pressure-sensitive film m, hot-setting adhesive n and window The preparation for low conductive phase content list hamburger structure sheaf that encapsulating film is constituted, and then complete by highly conductor phase content list hamburger structure sheaf The preparation of the differential type pressure cell based on double hamburger structures constituted with low conductive phase content list hamburger structure sheaf.
Embodiment
In the copper electrode and its copper that the side of first Kapton is a length of 3.36 centimetres laminating, width is 5.12 centimetres Lead is as large electrode encapsulating film;The side of second Kapton is a length of 0.38 centimetre laminating, width is 0.59 centimetre Copper electrode and its copper lead as small electrode encapsulating film;In laminating a length of 3.36 lis of the side of third Kapton Rice, the copper electrode h and its copper lead that width is 5.12 centimetres, and opened in the side of the third not laminating copper electrode of Kapton A length of 0.38 centimetre, the window j 1 that width is 0.59 centimetre are covering the laminating copper electrode on third Kapton not The side for closing copper electrode is exposed by window, and ensures the window axle center with laminating on third Kapton Copper electrode axle center is overlapped, and then completes the preparation of window encapsulating film;Small electrode encapsulating film is placed in spare on rotating platform and true It is upward to protect the laminating side for having electrode;
Carbon black, room temperature vulcanized silicone rubber and n-hexane that average grain diameter is 30 nanometers are mixed by 1: 8: 100 volume ratio, Disperse carbon black in the mixed solution being made of room temperature vulcanized silicone rubber and n-hexane using mechanical stirring and sonic oscillation, to After n-hexane volatilization, the carbon black filled silicon rubber composite material of highly conductor phase content is formed;The carbon black of highly conductor phase content is filled out Silicon rubber composite material is filled to instill on the electrode for the small electrode encapsulating film being fixed on rotating platform;Highly conductor phase content Carbon black filled silicon rubber composite material spin coating ensures the carbon black filled silicon of highly conductor phase content at the thin slice with a thickness of 80 microns Rubber composite material is completely covered on the electrode of small electrode encapsulating film;Carbon black filled silicon rubber to highly conductor phase content is multiple After condensation material sulfidization molding, the carbon black filled silicon rubber for removing the highly conductor phase content except the electrode of small electrode encapsulating film is compound Material, the carbon black filled silicon rubber composite material of the highly conductor phase content on the remaining electrode for being covered on small electrode encapsulating film Highly conductor phase content pressure-sensitive film as highly conductor phase content list hamburger structure sheaf;Highly conductor phase on small electrode encapsulating film contains Hot-setting adhesive is applied on Kapton around amount pressure-sensitive film, window encapsulating film is covered on highly conductor phase content pressure-sensitive film and heat On solid glue, and ensure the window and highly conductor phase content pressure-sensitive film k face and laminating on window encapsulating film of window encapsulating film The part that is exposed in the side of not laminating electrode by window of electrode and highly conductor phase content pressure-sensitive film completely attach to, utilize Flexible material packaging by hot pressing machine carries out heat to window encapsulating film, highly conductor phase content pressure-sensitive film, hot-setting adhesive and small electrode encapsulating film Press seal dress, and then complete to be led by the height that window encapsulating film, highly conductor phase content pressure-sensitive film, hot-setting adhesive and small electrode encapsulating film are constituted The preparation of electric phase content list hamburger structure sheaf;
The fixation of highly conductor phase content list hamburger structure sheaf is spare on the rotating platform, and make laminating on window encapsulating film Electrode side it is upward;Carbon black, room temperature vulcanized silicone rubber and n-hexane that average grain diameter is 30 nanometers are pressed to 1: 16: 180 body Product makes carbon black in the mixed solution being made of room temperature vulcanized silicone rubber and n-hexane than mixing using mechanical stirring and sonic oscillation Middle dispersion forms the carbon black filled silicon rubber composite material of low conductive phase content after n-hexane volatilization;By low conductive phase content Carbon black filled silicon rubber composite material instill the rotating platform for being fixed with highly conductor phase content list hamburger structure sheaf it On, the carbon black filled silicon rubber composite material spin coating of low conductive phase content at the thin slice with a thickness of 80 microns, and ensure low lead The carbon black filled silicon rubber composite material of electric phase content is completely covered on the window encapsulation of highly conductor phase content list hamburger structure sheaf On the electrode of film;After the carbon black filled silicon rubber composite material sulfidization molding of low conductive phase content, window encapsulating film is removed Electrode except part, the carbon black filled silicon rubber of the low conductive phase content on the remaining electrode for being covered on window encapsulating film Low conductive phase content pressure-sensitive film of the glue composite material as low conductive phase content list hamburger structure sheaf;It is pressure-sensitive in low conductive phase content Hot-setting adhesive is applied on the Kapton of window encapsulating film around film, large electrode encapsulating film is covered on low conductive phase content pressure On quick film and hot-setting adhesive, and ensure electrode and low conductive phase content pressure-sensitive film face and the full contact of large electrode encapsulating film, Using flexible material packaging by hot pressing machine to highly conductor phase content list hamburger structure sheaf, low conductive phase content pressure-sensitive film and hot-setting adhesive Packaging by hot pressing is carried out with large electrode encapsulating film, to complete by large electrode encapsulating film, low conductive phase content pressure-sensitive film, hot-setting adhesive and window The preparation for low conductive phase content list hamburger structure sheaf that mouth encapsulating film is constituted, and then complete by highly conductor phase content list hamburger structure The preparation for the differential type pressure cell based on double hamburger structures that layer and low conductive phase content list hamburger structure sheaf are constituted.

Claims (1)

1. a kind of method of production of the differential type pressure cell based on double hamburger structures, which is characterized in that this method includes following Step:
In the electrode and its lead that the side of first insulation film is a length of 3.36 centimetres laminating, width is 5.12 centimetres as big electricity Pole encapsulating film;Make in the electrode and its lead that the side of second insulation film is a length of 0.38 centimetre laminating, width is 0.59 centimetre For small electrode encapsulating film;In the electrode that the side of third insulation film is a length of 3.36 centimetres laminating, width is 5.12 centimetres and its Lead, and in the window that the side of the third not laminating electrode of insulation film opens a length of 0.38 centimetre, width is 0.59 centimetre, make to cover The electrode closed on third insulation film is exposed by window in the side of not laminating electrode, and ensures the window axle center It is overlapped with the laminating electrode axle center on third insulation film, and then completes the preparation of window encapsulating film;Small electrode is encapsulated Film is placed in spare on rotating platform, and ensures that the laminating side for having electrode is upward;
Carbon black, room temperature vulcanized silicone rubber and n-hexane that average grain diameter is 30 nanometers are mixed by 1: 8: 100 volume ratio, utilized Mechanical stirring and sonic oscillation disperse carbon black in the mixed solution being made of room temperature vulcanized silicone rubber and n-hexane, to just oneself After alkane volatilization, the carbon black filled silicon rubber composite material of highly conductor phase content is formed;By the carbon black filled silicon of highly conductor phase content Rubber composite material instills on the electrode for the small electrode encapsulating film being fixed on rotating platform;The carbon black of highly conductor phase content Filled silicon rubber composite material spin coating ensures that the carbon black filled silicon rubber composite material of highly conductor phase content is complete at required thickness All standing is on the electrode of small electrode encapsulating film;Carbon black filled silicon rubber composite material sulfidization molding to highly conductor phase content Afterwards, the carbon black filled silicon rubber composite material of the highly conductor phase content except the electrode of small electrode encapsulating film is removed, it is remaining to cover The carbon black filled silicon rubber composite material of the highly conductor phase content on the electrode of small electrode encapsulating film is covered as highly conductor phase The highly conductor phase content pressure-sensitive film of content list hamburger structure sheaf;Around the highly conductor phase content pressure-sensitive film on small electrode encapsulating film Insulation film on apply hot-setting adhesive, window encapsulating film is covered on highly conductor phase content pressure-sensitive film and hot-setting adhesive, and is ensured The window and highly conductor phase content pressure-sensitive film face and the laminating electrode on window encapsulating film of window encapsulating film are in not laminating electricity The part that the side of pole is exposed by window is completely attached to highly conductor phase content pressure-sensitive film, utilizes flexible material packaging by hot pressing Machine to window encapsulating film, highly conductor phase content pressure-sensitive film, hot-setting adhesive and small electrode encapsulating film carry out packaging by hot pressing, and then complete by Highly conductor phase content list hamburger knot that window encapsulating film, highly conductor phase content pressure-sensitive film, hot-setting adhesive and small electrode encapsulating film are constituted The preparation of structure layer;
The fixation of highly conductor phase content list hamburger structure sheaf is spare on the rotating platform, and make the laminating electricity on window encapsulating film Pole side is upward;Carbon black, room temperature vulcanized silicone rubber and n-hexane that average grain diameter is 30 nanometers are pressed to 1: 16: 180 volume ratio Mixing divides carbon black in the mixed solution being made of room temperature vulcanized silicone rubber and n-hexane using mechanical stirring and sonic oscillation It dissipates, after n-hexane volatilization, forms the carbon black filled silicon rubber composite material of low conductive phase content;By the charcoal of low conductive phase content Black filled silicon rubber composite material instillation is described to be fixed on the rotating platform of highly conductor phase content list hamburger structure sheaf, The carbon black filled silicon rubber composite material spin coating of low conductive phase content ensures that the carbon black of low conductive phase content is filled out at required thickness It fills on the electrode for the window encapsulating film that silicon rubber composite material is completely covered on highly conductor phase content list hamburger structure sheaf;To low After the carbon black filled silicon rubber composite material sulfidization molding of conductive phase content, the part except the electrode of window encapsulating film is removed, The carbon black filled silicon rubber composite material of low conductive phase content on the remaining electrode for being covered on window encapsulating film is as low The low conductive phase content pressure-sensitive film of conductive phase content list hamburger structure sheaf;Window encapsulation around low conductive phase content pressure-sensitive film Hot-setting adhesive is applied on the insulation film of film, large electrode encapsulating film is covered on low conductive phase content pressure-sensitive film and hot-setting adhesive, and Electrode and low conductive phase content pressure-sensitive film face and the full contact for ensuring large electrode encapsulating film, utilize flexible material packaging by hot pressing Machine carries out hot pressing to highly conductor phase content list hamburger structure sheaf, low conductive phase content pressure-sensitive film, hot-setting adhesive and large electrode encapsulating film Encapsulation, to complete the low conductive phase being made of large electrode encapsulating film, low conductive phase content pressure-sensitive film, hot-setting adhesive and window encapsulating film The preparation of content list hamburger structure sheaf, and then complete by highly conductor phase content list hamburger structure sheaf and low conductive phase content list hamburger The preparation for the differential type pressure cell based on double hamburger structures that structure sheaf is constituted.
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