CN106758511B - A kind of preparation method of heat preservation wallpaper and obtained heat preservation wallpaper - Google Patents
A kind of preparation method of heat preservation wallpaper and obtained heat preservation wallpaper Download PDFInfo
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- CN106758511B CN106758511B CN201611236977.9A CN201611236977A CN106758511B CN 106758511 B CN106758511 B CN 106758511B CN 201611236977 A CN201611236977 A CN 201611236977A CN 106758511 B CN106758511 B CN 106758511B
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/40—Coatings with pigments characterised by the pigments siliceous, e.g. clays
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/64—Inorganic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/82—Paper comprising more than one coating superposed
- D21H19/822—Paper comprising more than one coating superposed two superposed coatings, both being pigmented
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/84—Paper comprising more than one coating on both sides of the substrate
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/34—Ignifugeants
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
- D21H27/20—Flexible structures being applied by the user, e.g. wallpaper
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/002—Coverings or linings, e.g. for walls or ceilings made of webs, e.g. of fabrics, or wallpaper, used as coverings or linings
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paper (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to a kind of preparation methods of heat preservation wallpaper, and described method includes following steps：(1) hollow glass bead of titanium dioxide in-stiu coating is prepared；(2) heat-insulating slurry of the hollow glass bead comprising step (1) titanium dioxide in-stiu coating is prepared；(3) heat-insulating slurry is coated on wallpaper matrix, baking and curing obtains heat preservation wallpaper.The present invention coats hollow glass bead using titanium dioxide, especially in-stiu coating, it carries out cooperateing with use with fumed silica, obtain a kind of fire-retardant high-efficiency insulated heat-insulated wallpaper paste material, this heat-insulated wallpaper paste material is applied in pure paper wallpaper, obtains the heat-insulated wallpaper of fire-retardant heat insulation by solidification.
Description
Technical field
The invention belongs to Material Field more particularly to a kind of functional wallpapers, and in particular to a kind of heat preservation wallpaper.
Background technique
Building energy consumption in the entire energy consumption of the mankind proportion generally in 30-40%, heat preserving and insulating material and product
It is to influence one important influence factor of building energy conservation.The development of building thermal insulation material is with application increasingly by countries in the world
Most attention.After the 1970s, production and the application under construction of external most attention thermal insulation material are made every effort to significantly
The consumption of the energy is reduced, to reduce environmental pollution and greenhouse effects.The development of Chinese thermal insulation material is relatively slow, but China
Effort in more than 30 years is passed through in thermal insulation material industry, especially passes through nearly 20 years high speed developments, many products from scratch, from list
One arrives diversification, and quality from low to high, has formed expanded perlite, mineral wool, mineral wool, foamed plastics, refractory fibre, silicic acid
The complete industry of variety protection based on calcium insulating product etc..
The heat-insulating heat-preserving material of Chinese architecture also relatively falls behind at present, and the energy loss of Chinese house house is substantially
Wall accounts for about 50%；Roofing accounts for about 10%；Door and window accounts for about 25%；Basement and ground account for about 15%.Chinese architecture will be 2020
Year realizes fractional energy savings 60%, need to carry out modernization overlay to building thermal insulation material, the market of wall heat insulation material will significantly increase
Add.
Wallpaper is as a kind of widely used indoor wall ornament materials, with its color abundant, pattern abundant, height
The decorative effect of your elegance is increasingly liked by masses.Certainly present wallpaper has been different from the wallpaper before the more than ten years, is
A kind of environmentally protective high-tech product, in addition to being used to decorate, in response to the call of national energy conservation and emission reduction, heat preservation, fire prevention
Etc. performances be also indispensable, but the thermal and insulating performance of wallpaper is also in relatively low level at present, and fire line
It can be bad.The present invention precisely in order to improve wallpaper insulation and flame retardant property, using it is homemade it is fire-retardant it is high-efficiency insulated every
Hot wall paper paste material prepares heat-insulated wallpaper, to achieve the effect that high-efficiency insulated heat-insulated.
Summary of the invention
In view of the deficiencies of the prior art, one of the objects of the present invention is to provide a kind of preparation method of heat preservation wallpaper, institutes
The method of stating includes the following steps：
(1) hollow glass bead of titanium dioxide in-stiu coating is prepared；
(2) heat-insulating slurry of the hollow glass bead comprising step (1) titanium dioxide in-stiu coating is prepared；
(3) heat-insulating slurry is coated on wallpaper matrix, baking and curing obtains heat preservation wallpaper.
The present invention coats hollow glass bead using titanium dioxide, carries out cooperateing with use with fumed silica,
A kind of fire-retardant high-efficiency insulated heat-insulated wallpaper paste material is obtained, this heat-insulated wallpaper paste material is applied in pure paper wallpaper, is passed through
It crosses following process and obtains the heat-insulated wallpaper of fire-retardant heat insulation.
Preferably, the hollow glass bead of the titanium dioxide in-stiu coating is prepared via a method which to obtain：
Titanous salt is dispersed in deionized water, dispersion liquid to be obtained after stirring and dissolving with even phase precipitating reagent, addition glass is empty
Then heart microballon reacts the in-situ deposition in mixed liquor water heating kettle, carrying out titanium dioxide；End of reaction, natural cooling, solid-liquid
Separation, solid is the hollow glass bead of titanium dioxide in-stiu coating.
Preferably, the titanous salt includes titanous inorganic matter, preferably includes titanous alkoxide, tri-chlorination titanous, titanium sesquisulfate
In any a kind or at least two kinds of of combination.
Titanous refers to titanium ion existing for trivalent form or titanium atom.Titanous alkoxide refers to the titanium ion and alcohol root of trivalent
Compound compound, such as Asia-Pacific ethylate (Ti2 (C2H5OH) 3)；Titanium trichloride refers to TiCl3；Titanium sesquisulfate refers to Ti2 (SO4) 3.
Preferably, the even phase precipitating reagent includes urea and/or polyvinylpyrrolidone.
Preferably, the molar ratio of the titanous salt and even phase precipitating reagent additive amount is 1:4~10, such as 1:5,1:6,1:
7,1:8,1:9 etc..
Preferably, in the dispersion liquid, the concentration of titanous salt is 0.1~1mol/L, such as 0.2mol/L, 0.3mol/L,
0.4mol/L, 0.5mol/L, 0.6mol/L, 0.7mol/L, 0.8mol/L, 0.9mol/L etc..
Preferably, the in-situ deposition reaction of the titanium dioxide carries out under agitation, and preferably 10~500rpm's stirs
It mixes and is carried out under speed；Such as mixing speed be 12rpm, 18rpm, 25rpm, 35pm, 60rpm, 90rpm, 120rpm, 150rpm,
190rpm, 220rpm, 280rpm, 320rpm, 360rpm, 380rpm, 420rpm, 480rpm etc..
Preferably, the reaction temperature of the in-situ deposition reaction of the titanium dioxide is 120~200 DEG C, the reaction time 12
~48h.
Preferably, the hollow glass bead partial size D50 is 2~50 μm, such as 3 μm, 6 μm, 9 μm, 13 μm, 16 μm, 19 μ
M, 23 μm, 26 μm, 29 μm, 33 μm, 36 μm, 39 μm, 43 μm, 46 μm, 49 μm etc., real density in 0.3~0.6g/cm3, such as
0.4g/cm3,0.5g/cm3 etc..
Preferably, the hollow glass bead and the mass ratio of deionized water are 1:5~50, such as 1:6,1:8,1:11,
1:14,1:17,1:21,1:24,1:27,1:31,1:34,1:37,1:41,1:44,1:47 etc..
Preferably, the heat-insulating slurry includes following component in parts by weight：
Resin 50~100
Thermal insulating filling 10~50
Fire-retardant filler 5~40
Auxiliary agent 3~20
Diluent 0~30.
Preferably, the resin includes PVC paste resin.
Preferably, the thermal insulating filling includes the hollow glass bead of titanium dioxide in-stiu coating.
Preferably, the thermal insulating filling further includes aerosil.
Preferably, the fire-retardant filler includes nano-aluminum hydroxide, nano-sized magnesium hydroxide, magnalium hydrotalcite, laminar silicic acid
Aluminium, stratiform montmorillonite, any a kind or at least two kinds of of combination of ammonium polyphosphate, zinc borate, antimony oxide and molybdenum compound.
Preferably, the auxiliary agent includes any a kind or at least two kinds of of combination of plasticizer, stabilizer and catalyst.
Preferably, the method carry out after the step (3) heat preservation wallpaper that step (4) are obtained in step (3) far from every
Hot slurry coated side side coats waterproof coating.
Preferably, the method carries out the heat-insulated of the heat preservation wallpaper that step (5) are obtained in step (3) after the step (3)
Slurry coats side and continues application to printed face.
The second object of the present invention is to providing the heat preservation wallpaper that preparation method described in a kind of first purpose is prepared.
Compared with prior art, the present invention has the advantages that：
The present invention coats hollow glass bead using titanium dioxide, especially in-stiu coating, with gas phase titanium dioxide
Silicon carries out collaboration use, obtains a kind of fire-retardant high-efficiency insulated heat-insulated wallpaper paste material, this heat-insulated wallpaper paste material is coated with
Onto pure paper wallpaper, the heat-insulated wallpaper of fire-retardant heat insulation is obtained by solidification.
Specific embodiment
Of the invention for ease of understanding, it is as follows that the present invention enumerates embodiment.Those skilled in the art are it will be clearly understood that the implementation
Example is only to aid in the understanding present invention, should not be regarded as a specific limitation of the invention.
Heat preservation wallpaper described in embodiment 1 is prepared via a method which：
(1) hollow glass bead of titanium dioxide in-stiu coating is prepared；
15.4kg titanium trichloride, 24kg urea are added in 700kg deionized water, after stirring and dissolving, add 14kg glass
Then glass cenosphere is transferred in 1000L water heating kettle, at 120 DEG C, under 10rpm, and hydro-thermal 12h；It is completed wait react, it is natural
It is cooling, it is separated by solid-liquid separation using centrifuge, the paste product obtained after washing, is that the glass of titanium dioxide in-stiu coating is empty
Heart microballon, Seal and preservation；
(2) heat-insulating slurry is prepared；
By 100.0kg polyvinyl chloride resin (Pevikon PE712), the hollow glass bead of 30.0kg titanium dioxide in-stiu coating
(step (1) preparation), 10.0kg magnalium hydrotalcite, 5.0kg aerosil premix 10min, are transferred in three-roller and grind
Then 3.0kg epoxidized soybean oil, 2.0kg K-Zn stabilizer, 1.5kg AC foaming agent, 75kg DOP (adjacent benzene two is added in Bao Tong
Formic acid dioctyl ester), 10kg diluent (water), first 300r/min stirs 15min, and then 1000r/min stirs 15min, obtain every
Hot wall paper paste material；
(3) heat-insulating slurry of step (2) is coated on wallpaper matrix, baking and curing obtains heat preservation wallpaper.
Embodiment 2
The heat preservation wallpaper is prepared via a method which：
(1) hollow glass bead of titanium dioxide in-stiu coating is prepared；
400g titanium sesquisulfate, 600g urea, 100gPVP are added in 800g deionized water, after stirring and dissolving, add 60g
Then hollow glass micropearl is transferred in 1000mL water heating kettle, at 160 DEG C, under 200r/min, hydro-thermal is for 24 hours；To fully reacting, certainly
It is so cooling, it is separated by solid-liquid separation using centrifuge, the paste product obtained after washing, is the glass of titanium dioxide in-stiu coating
Cenosphere, Seal and preservation；
(2) heat-insulating slurry is prepared；
By 50.0kg polyvinyl chloride resin (Pevikon PE712), 50.0kg polyvinyl chloride resin (Pevikon PE709), 20.0kg
Hollow glass bead (step (1) preparation), the 15.0kg antimony trioxide, 1.0kg silica airsetting of titanium dioxide in-stiu coating
Glue premixes 10min, is then transferred in three-roller and grinds thin logical, 1.0kg Ba-Zn stabilizer, 1.5kg AC foaming is then added
Agent, 3.0kg epoxidized soybean oil, 65.0kg DOP, first 300r/min stir 30min, and then 1000r/min stirs 30min, obtains
Heat-insulated wallpaper paste material；
(3) heat-insulating slurry of step (2) is coated on wallpaper matrix, baking and curing obtains heat preservation wallpaper.
Embodiment 3
The heat preservation wallpaper is prepared via a method which：
(1) hollow glass bead of titanium dioxide in-stiu coating is prepared；
307g titanium sesquisulfate, 480g urea are added in 800g deionized water, after stirring and dissolving, add 160g hollow glass
Then microballon is transferred in 1000mL water heating kettle, at 200 DEG C, under 200r/min, and hydro-thermal 48h.To fully reacting, natural cooling, benefit
It is separated by solid-liquid separation with centrifuge, the paste product obtained after washing, is the hollow glass bead of titanium dioxide in-stiu coating,
Seal and preservation；
(2) heat-insulating slurry is prepared；
By 100.0kg polyvinyl chloride resin (Pevikon PE702), the hollow glass bead of 50.0kg titanium dioxide in-stiu coating
(step (1) preparation), 15.0kg antimony trioxide, 2.0kg aerosil premix 10min, are then transferred in three-roller and grind
Wear down is logical, and 3.0kg Ba-Zn stabilizer, 1.5kg AC foaming agent, 75.0kg DOP, first 300r/min stirring is then added
15min, then 1000r/min stirs 15min, obtains heat-insulated wallpaper paste material；
(3) heat-insulating slurry of step (2) is coated on wallpaper matrix, baking and curing obtains heat preservation wallpaper.
Comparative example
Select the wallpaper matrix of heat preservation wallpaper as a comparison case.
Performance test：
Using the thermal coefficient of GB/T13475-2008 Heat-box method measurement heat preservation wallpaper：
| Example | Thermal coefficient (w/m2k) |
| Embodiment 1 | 0.035 |
| Embodiment 2 | 0.033 |
| Embodiment 3 | 0.032 |
| Comparative example | 0.200 |
The Applicant declares that the present invention is explained by the above embodiments detailed process equipment and process flow of the invention,
But the present invention is not limited to the above detailed process equipment and process flow, that is, it is above-mentioned detailed not mean that the present invention must rely on
Process equipment and process flow could be implemented.It should be clear to those skilled in the art, any improvement in the present invention,
Addition, selection of concrete mode of equivalence replacement and auxiliary element to each raw material of product of the present invention etc., all fall within of the invention
Within protection scope and the open scope.
Claims (7)
1. a kind of preparation method of heat preservation wallpaper, which is characterized in that described method includes following steps：
(1) hollow glass bead of titanium dioxide in-stiu coating is prepared；
(2) heat-insulating slurry of the hollow glass bead comprising step (1) titanium dioxide in-stiu coating is prepared；
(3) heat-insulating slurry is coated on wallpaper matrix, baking and curing obtains heat preservation wallpaper；
The hollow glass bead of the titanium dioxide in-stiu coating is prepared via a method which to obtain：
Titanous salt is dispersed in deionized water, dispersion liquid to be obtained after stirring and dissolving with even phase precipitating reagent, addition glass hollow is micro-
Then pearl in mixed liquor water heating kettle, will carry out the in-situ deposition reaction of titanium dioxide, instead under the mixing speed of 10~500rpm
Answering temperature is 120~200 DEG C, and the reaction time is 12~48h；End of reaction, natural cooling are separated by solid-liquid separation, and solid is dioxy
Change the hollow glass bead of titanium in-stiu coating；
The titanous salt includes titanous inorganic matter；The even phase precipitating reagent includes urea and/or polyvinylpyrrolidone；
The molar ratio of the titanous salt and even phase precipitating reagent additive amount is 1:4~10；
In the dispersion liquid, the concentration of titanous salt is 0.1~1mol/L；
The hollow glass bead partial size D50 is 2~50 μm, and real density is in 0.3~0.6g/cm3；
The hollow glass bead and the mass ratio of deionized water are 1:5~50；
Step (2) described heat-insulating slurry includes following component in parts by weight：
Resin 50~100
Thermal insulating filling 10~50
Fire-retardant filler 5~40
Auxiliary agent 3~20
Diluent 0~30；
The thermal insulating filling includes the hollow glass bead and aerosil of titanium dioxide in-stiu coating.
2. preparation method as described in claim 1, which is characterized in that the titanous salt include titanous alkoxide, tri-chlorination titanous,
Any a kind or at least two kinds of of combination in titanium sesquisulfate.
3. preparation method as described in claim 1, which is characterized in that the resin includes PVC paste resin.
4. preparation method as described in claim 1, which is characterized in that the fire-retardant filler includes nano-aluminum hydroxide, nanometer
Magnesium hydroxide, magnalium hydrotalcite, layer aluminium silicate, stratiform montmorillonite, ammonium polyphosphate, zinc borate, antimony oxide and molybdenum compound
Any a kind or at least two kinds of of combination.
5. preparation method as described in claim 1, which is characterized in that the auxiliary agent includes plasticizer, stabilizer and catalyst
Any a kind or at least two kinds of of combination.
6. preparation method as described in claim 1, which is characterized in that the method carries out step (4) after step (3) and exists
The heat preservation wallpaper that step (3) obtains coats waterproof coating far from heat-insulating slurry coated side side.
7. preparation method as described in claim 1, which is characterized in that the method carries out step (5) after step (3) and exists
Continue application to printed face in the heat-insulating slurry coating side for the heat preservation wallpaper that step (3) obtains.
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| CN201611236977.9A CN106758511B (en) | 2016-12-28 | 2016-12-28 | A kind of preparation method of heat preservation wallpaper and obtained heat preservation wallpaper |
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| CN101857267B (en) * | 2010-06-13 | 2012-11-28 | 上海海洋大学 | Preparation method of titanium dioxide nano material with core-shell structure |
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