CN108504225A - Insulating moulding coating - Google Patents

Insulating moulding coating Download PDF

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Publication number
CN108504225A
CN108504225A CN201810251673.2A CN201810251673A CN108504225A CN 108504225 A CN108504225 A CN 108504225A CN 201810251673 A CN201810251673 A CN 201810251673A CN 108504225 A CN108504225 A CN 108504225A
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Prior art keywords
microsphere
insulating moulding
added
moulding coating
hollow silica
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CN201810251673.2A
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Chinese (zh)
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张健
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Shenzhen Lingdu Intelligent Control Technology Co Ltd
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Shenzhen Lingdu Intelligent Control Technology Co Ltd
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Priority to CN201810251673.2A priority Critical patent/CN108504225A/en
Publication of CN108504225A publication Critical patent/CN108504225A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04Homopolymers or copolymers of monomers containing silicon
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • C09D7/62Additives non-macromolecular inorganic modified by treatment with other compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of insulating moulding coatings, by water 20%, appropriate dispersant, wetting agent and antifoaming agent are uniformly dispersed under the stirring of 3000r/min rotating speeds, add infrared ceramic powder 6%, titanium dioxide 12%, talcum powder 6% and dicalcium powder 11%, it stirs evenly, appropriate coalescents are added to stir evenly, mixing speed is reduced to 300r/min, titania modified hollow silica microsphere 15% is added, silicone acrylic emulsion 30%, appropriate thickener stirring, pH is adjusted to 9.0 or so with pH adjusting agent, it is good to obtain heat-proof quality, and there is good weatherability and acid resistance, quick solidifying, the good insulating moulding coating of application property.

Description

Insulating moulding coating
Technical field
The present invention relates to technical field of coatings more particularly to a kind of insulating moulding coatings.
Background technology
With the rapid development of China's building trade and becoming increasingly conspicuous for energy crisis, the energy-saving of building is got over Send out important.The building energy consumption in China accounts for about the 27% of national energy aggregate consumption, occupies first of all kinds of energy consumptions in the whole nation.Heating and air-conditioning Energy consumption account for building total energy consumption 55%, but also with annual 1 percentage point of speed increase.Because a little, research and development is built Building insulating moulding coating has great economic benefit, environmental benefit and social benefit.It is used with heat insulating function in external wall The original decoration of coating, protection and the functions such as mould proof not only may be implemented in coating, but also it is heat-insulated so that coating is had the function of, guarantor It holds that indoor temperature is constant, increases the temperature difference of indoor and outdoor, reduce warm energy consumption in summer, reduce heat cost in winter.Currently, heat-insulated Material is just experiencing from the heat-insulated transformation to based on heat-insulating of industry, this be also heat-barrier material from now on the main direction of development it One.Insulating moulding coating mainly uses glass microballoon or ceramic microsphere currently on the market, has the disadvantage that:Poor insulation property, storage Deposit stability difference etc..
Invention content
The main purpose of the present invention is to provide a kind of insulating moulding coatings, improve the heat-proof quality of coating, and with good Weatherability and acid resistance, quick solidifying, application property is good.
To achieve the above object, the present invention provides a kind of insulating moulding coating, and the insulating moulding coating presses mass percentage, master Including:Titania modified hollow silica microsphere 10%-18%,
Silicone acrylic emulsion 25%-35%,
Titanium dioxide 10%-16%,
Infrared ceramic powder 2%-10%,
Talcum powder 2%-10%,
Dicalcium powder 5%-15%,
Water 10%-30%,
And suitable dispersant, wetting agent, coalescents, antifoaming agent, pH adjusting agent and thickener.
Optionally, the titania modified hollow silica microsphere prepares hollow silica microsphere first, so Titanium dioxide is added to hollow silica microsphere afterwards to be modified.
Optionally, the polystyrene of hollow silica microsphere synthesizing spherical first, then in polystyrene microsphere Surface coated silica, after drying is polystyrene moulding to inside, and outside is wrapped in the complex microsphere of silica, most Afterwards by the polystyrene microsphere inside the removal of the method for calcining, hollow silicon dioxide microsphere is obtained.
Optionally, the hollow silica microsphere is gathered using deionized water as synthetic polystyrene microballoon reaction medium Vinylpyrrolidone is added deionized water, polyvinylpyrrolidone is then added in a kettle as dispersant and activator, After being sufficiently stirred, be slowly added dropwise polystyrene monomers and ultrasonic disperse 10min, it is to be mixed uniformly after, slowly by ammonium persulfate Solution is added in reaction kettle, and polystyrene microsphere is obtained by the reaction.
Optionally, polystyrene microsphere is made lotion and fully shaken up, taken by the polystyrene microsphere for selecting the 100nm It is appropriate to be added in reaction medium absolute ethyl alcohol, and surfactant gamma-aminopropyl-triethoxy-silane (KH550) is added, it utilizes KH550 can form hydrophilic radical on the surface of polystyrene microsphere, to promote the silica that reaction generates on its surface Forming core accumulates, and mixed liquor is sufficiently stirred so that polyethylene microballoon is evenly dispersed, and template surface is activated, and then adds Enter the pH value that suitable ammonium hydroxide adjusts reaction environment, increases temperature later, and keep temperature constant, silicic acid tetrem is added dropwise Ester, reaction persistently carry out 3h, obtain silicon dioxide-poly phenylethylene micro ball complex microsphere lotion, are distinguished using pure water and ethyl alcohol Washing for several times, is put into the dry 6h of 35 DEG C of drying box, silicon dioxide-poly phenylethylene micro ball complex microsphere powder is obtained, most afterwards through height Temperature calcining obtains hollow silica microsphere powder.
Optionally, described that hollow silica microsphere addition titanium dioxide is modified, by hollow silica microsphere It is made into the slurries that mass fraction is 10% with deionized water;Slurries pH is adjusted 3.0 or so, surfactant sodium dodecyl base benzene Sodium sulfonate and slurries, which are added together in reaction kettle, keeps the temperature 70 DEG C;It is mixed with the rotating speed of 300r/min;0.5mol/ is slowly added dropwise The titania solution of L adjusts the pH value of whole system with 10% NaOH solution, it is made to maintain 3.0 or so always, until Titania solution all drips off;It is constant to control pH, continues insulated and stirred and is aged 30min;Modified microballon is filtered, and is done It is dry;It places it in 800 DEG C to calcine 1 hour, obtains titania modified hollow silica microsphere.
Optionally, the titania modified hollow silica microsphere mass percentage is 15%.
Optionally, the silicone acrylic emulsion mass percentage is 30%.
Optionally, the titanium dioxide mass percentage is 12%, and the infrared ceramic powder mass percentage is 6%.
Optionally, the talcum powder uses 800 mesh, mass percentage 6%.
A kind of insulating moulding coating provided by the invention, using titania modified hollow silica microsphere silicone acrylic emulsion, Titanium dioxide, infrared ceramic powder, talcum powder, dicalcium powder and water, are reacted in proportion, and it is good to obtain heat-proof quality, and with good Good weatherability and acid resistance, quick solidifying, the good insulating moulding coating of application property.
Specific implementation mode
For the present invention is better described, it is easy to understand technical scheme of the present invention, of the invention is typical but non-limiting Embodiment is as follows:
Raw material preparation:
Titania modified hollow silica microsphere:
Hollow silica microsphere:
The polystyrene of synthesizing spherical first, then in Surfaces of Polystyrene Microparticles coated silica, arriving after drying Inside is polystyrene moulding, and outside is wrapped in the complex microsphere of silica, inside the method removal of calcining Polystyrene microsphere obtains hollow silicon dioxide microsphere.
Using deionized water as synthetic polystyrene microballoon reaction medium, polyvinylpyrrolidone is as dispersant and activation Agent is added deionized water, polyvinylpyrrolidone is then added in a kettle, and after being sufficiently stirred, polystyrene is slowly added dropwise Monomer and ultrasonic disperse 10min, it is to be mixed uniformly after, slowly ammonium persulfate solution is added in reaction kettle, is obtained by the reaction Polystyrene microsphere.
It is 100nm polystyrene microspheres as the template for preparing hollow microsphere, reaction temperature, tetraethyl orthosilicate to select grain size Additive amount, the pH value of reaction environment can have an impact experimental result, and experiment shows reaction temperature at 45-51 DEG C, silicic acid Tetra-ethyl ester volume fraction 4%-6%ml, microsphere surface morphology is the best when pH is 10, and uniform particle sizes are big through the visible grain sizes of TEM Small is 150nm, shell thickness 25nm, internal diameter 100nm, and thermal conductivity is 0.0347W/ (mk), and specific surface area is 190.834m2/g.Silica aerogel powder prepared by the normal temperature and pressure seasoning method of selection is through measuring thermal conductivity 0.0215W/ (mk), specific surface area 480.079m2/g。
It is described that hollow silica microsphere addition titanium dioxide is modified, by hollow silica microsphere and deionization Water is made into the slurries that mass fraction is 10%;Slurries pH is adjusted 3.0 or so, surfactant sodium dodecyl base benzene sulfonic acid sodium salt with Slurries, which are added together in reaction kettle, keeps the temperature 70 DEG C;It is mixed with the rotating speed of 300r/min;The dioxy of 0.5mol/L is slowly added dropwise Change titanium solution, adjusts the pH value of whole system with 10% NaOH solution, so that it is maintained 3.0 or so always, until titanium dioxide Titanium solution all drips off;It is constant to control pH, continues insulated and stirred and is aged 30min;Modified microballon is filtered, and dry;By its It is placed in 800 DEG C to calcine 1 hour, obtains titania modified hollow silica microsphere.Characterization obtains, and thermal coefficient is 0.2663W/ (mK), sun luminous reflectance are 0.8514, and the reflectivity than ordinary white pigment 0.7 is high.
Silicone acrylic emulsion:Nantong life reaches chemical industry.
Titanium dioxide:100nm, rutile-type, Aladdin reagent.
Infrared ceramic powder:Tianjin silicate research institute.
Talcum powder:800 mesh, Aladdin reagent.
Dicalcium powder:Jiangxi Guang Yuan chemical industry.
Dispersant:P-19, section's Ninghua work.
Wetting agent:346, German BYK auxiliary agents.
Coalescents:505, Nantong life reaches chemical industry.
Antifoaming agent:034, German BYK auxiliary agents.
PH adjusting agent:NaOH solution.
Thickener:GM-808, Dongguan City are total to bright industry.
Embodiment 1:
By water 20%, appropriate dispersant, wetting agent and antifoaming agent are uniformly dispersed under the stirring of 3000r/min rotating speeds, then add Enter infrared ceramic powder 6%, titanium dioxide 12%, talcum powder 6% and dicalcium powder 11%, stir evenly, adds appropriate coalescents It stirs evenly, mixing speed is reduced to 300r/min, and titania modified hollow silica microsphere 10%, silicone acrylic emulsion is added 35%, pH is adjusted to 9.0 or so to get to insulating moulding coating by the stirring of appropriate thickener with pH adjusting agent.
Embodiment 2:
By water 18%, appropriate dispersant, wetting agent and antifoaming agent are uniformly dispersed under the stirring of 3000r/min rotating speeds, then add Enter infrared ceramic powder 6%, titanium dioxide 12%, talcum powder 6% and dicalcium powder 11%, stir evenly, adds appropriate coalescents It stirs evenly, mixing speed is reduced to 300r/min, and titania modified hollow silica microsphere 12%, silicone acrylic emulsion is added 35%, pH is adjusted to 9.0 or so to get to insulating moulding coating by the stirring of appropriate thickener with pH adjusting agent.
Embodiment 3:
By water 15%, appropriate dispersant, wetting agent and antifoaming agent are uniformly dispersed under the stirring of 3000r/min rotating speeds, then add Enter infrared ceramic powder 6%, titanium dioxide 12%, talcum powder 6% and dicalcium powder 11%, stir evenly, adds appropriate coalescents It stirs evenly, mixing speed is reduced to 300r/min, and titania modified hollow silica microsphere 15%, silicone acrylic emulsion is added 35%, pH is adjusted to 9.0 or so to get to insulating moulding coating by the stirring of appropriate thickener with pH adjusting agent.
Embodiment 4:
By water 12%, appropriate dispersant, wetting agent and antifoaming agent are uniformly dispersed under the stirring of 3000r/min rotating speeds, then add Enter infrared ceramic powder 6%, titanium dioxide 12%, talcum powder 6% and dicalcium powder 11%, stir evenly, adds appropriate coalescents It stirs evenly, mixing speed is reduced to 300r/min, and titania modified hollow silica microsphere 18%, silicone acrylic emulsion is added 35%, pH is adjusted to 9.0 or so to get to insulating moulding coating by the stirring of appropriate thickener with pH adjusting agent.
Embodiment 5:
By water 25%, appropriate dispersant, wetting agent and antifoaming agent are uniformly dispersed under the stirring of 3000r/min rotating speeds, then add Enter infrared ceramic powder 6%, titanium dioxide 12%, talcum powder 6% and dicalcium powder 11%, stir evenly, adds appropriate coalescents It stirs evenly, mixing speed is reduced to 300r/min, and titania modified hollow silica microsphere 15%, silicone acrylic emulsion is added 25%, pH is adjusted to 9.0 or so to get to insulating moulding coating by the stirring of appropriate thickener with pH adjusting agent.
Embodiment 6:
By water 22%, appropriate dispersant, wetting agent and antifoaming agent are uniformly dispersed under the stirring of 3000r/min rotating speeds, then add Enter infrared ceramic powder 6%, titanium dioxide 12%, talcum powder 6% and dicalcium powder 11%, stir evenly, adds appropriate coalescents It stirs evenly, mixing speed is reduced to 300r/min, and titania modified hollow silica microsphere 15%, silicone acrylic emulsion is added 28%, pH is adjusted to 9.0 or so to get to insulating moulding coating by the stirring of appropriate thickener with pH adjusting agent.
Embodiment 7:
By water 20%, appropriate dispersant, wetting agent and antifoaming agent are uniformly dispersed under the stirring of 3000r/min rotating speeds, then add Enter infrared ceramic powder 6%, titanium dioxide 12%, talcum powder 6% and dicalcium powder 11%, stir evenly, adds appropriate coalescents It stirs evenly, mixing speed is reduced to 300r/min, and titania modified hollow silica microsphere 15%, silicone acrylic emulsion is added 30%, pH is adjusted to 9.0 or so to get to insulating moulding coating by the stirring of appropriate thickener with pH adjusting agent.
Embodiment 8:
By water 18%, appropriate dispersant, wetting agent and antifoaming agent are uniformly dispersed under the stirring of 3000r/min rotating speeds, then add Enter infrared ceramic powder 6%, titanium dioxide 12%, talcum powder 6% and dicalcium powder 11%, stir evenly, adds appropriate coalescents It stirs evenly, mixing speed is reduced to 300r/min, and titania modified hollow silica microsphere 15%, silicone acrylic emulsion is added 32%, pH is adjusted to 9.0 or so to get to insulating moulding coating by the stirring of appropriate thickener with pH adjusting agent.
For substantially matching for infrared ceramic powder, rutile type titanium white, talcum powder and this kind of functional color stuffing of dicalcium powder Than as above optimizing each substance proportioning, details are not described herein by Orthogonal Experiment and Design again.
By above example, insulating moulding coating of the present invention is preferred, is made of following mass percent material:By water 20%, appropriate dispersant, wetting agent and antifoaming agent are uniformly dispersed under the stirring of 3000r/min rotating speeds, add infrared ceramic powder 6%, titanium dioxide 12%, talcum powder 6% and dicalcium powder 11% stir evenly, add appropriate coalescents and stir evenly, and stir Speed is reduced to 300r/min, and titania modified hollow silica microsphere 15% is added, and silicone acrylic emulsion 30% is appropriate to thicken Agent is stirred, and pH is adjusted to 9.0 or so to get to insulating moulding coating with pH adjusting agent.Characterization obtains, the insulating moulding coating sun light reflection Than being 0.5152, thermal coefficient is 0.2209W/ (mK), and hemispherical emissivity 0.91, the heat-insulated temperature difference is 14.1 DEG C, Suo Youcan Count the regulation that is up to state standards.
Although the embodiments of the present invention have been disclosed as above, but its is not only in the description and the implementation listed With it can be fully applied to various fields suitable for the present invention, for those skilled in the art, can be easily Realize other modification, therefore without departing from the general concept defined in the claims and the equivalent scope, the present invention is simultaneously unlimited In specific details and embodiment shown and described herein.

Claims (10)

1. a kind of insulating moulding coating, which is characterized in that the insulating moulding coating presses mass percentage, includes mainly:Titanium dioxide Modified hollow silica microsphere 10%-18%,
Silicone acrylic emulsion 25%-35%,
Titanium dioxide 10%-16%,
Infrared ceramic powder 2%-10%,
Talcum powder 2%-10%,
Dicalcium powder 5%-15%,
Water 10%-30%,
And suitable dispersant, wetting agent, coalescents, antifoaming agent, pH adjusting agent and thickener.
2. insulating moulding coating as described in claim 1, which is characterized in that the titania modified hollow silica microsphere Hollow silica microsphere is prepared first, and titanium dioxide then, which is added, to hollow silica microsphere is modified.
3. insulating moulding coating as claimed in claim 2, which is characterized in that hollow silica microsphere synthesizing spherical first Polystyrene, then arriving internal after Surfaces of Polystyrene Microparticles coated silica, drying is polystyrene moulding, external It is wrapped in the complex microsphere of silica, finally by the polystyrene microsphere inside the method removal of calcining, is obtained hollow Silicon dioxide microsphere.
4. insulating moulding coating as claimed in claim 3, which is characterized in that the hollow silica microsphere using deionized water as Synthetic polystyrene microballoon reaction medium, polyvinylpyrrolidone as dispersant and activator, be added in a kettle go from Sub- water, is then added polyvinylpyrrolidone, after being sufficiently stirred, polystyrene monomers and ultrasonic disperse 10min is slowly added dropwise, waits for After stirring evenly, slowly ammonium persulfate solution is added in reaction kettle, polystyrene microsphere is obtained by the reaction.
5. insulating moulding coating as claimed in claim 4, which is characterized in that the polystyrene microsphere for selecting the 100nm, by polyphenyl Ethylene microballoon is made lotion and fully shakes up, and takes in appropriate addition reaction medium absolute ethyl alcohol, and surfactant γ-ammonia third is added Ethyl triethoxy silicane alkane (KH550) can form hydrophilic radical, to promote using KH550 on the surface of polystyrene microsphere The silica generated is reacted in its surface forming core accumulation, and mixed liquor is sufficiently stirred so that polyethylene microballoon is evenly dispersed, and Template surface is activated, the pH value that suitable ammonium hydroxide adjusts reaction environment is then added, increases temperature later, and keeps temperature It spends constant, is added dropwise tetraethyl orthosilicate, reaction persistently carries out 3h, obtains silicon dioxide-poly phenylethylene micro ball complex microsphere Lotion is washed for several times respectively using pure water and ethyl alcohol, is put into the dry 6h of 35 DEG C of drying box, and it is micro- to obtain silicon dioxide-poly styrene Ball complex microsphere powder most obtains hollow silica microsphere powder through high-temperature calcination afterwards.
6. insulating moulding coating as claimed in claim 2, which is characterized in that described that titanium dioxide is added to hollow silica microsphere It is modified, hollow silica microsphere and deionized water is made into the slurries that mass fraction is 10%;Slurries pH is adjusted 3.0 Left and right is together added surfactant sodium dodecyl base benzene sulfonic acid sodium salt and slurries in reaction kettle and keeps the temperature 70 DEG C;With 300r/min's Rotating speed is mixed;The titania solution of 0.5mol/L is slowly added dropwise, the pH of whole system is adjusted with 10% NaOH solution Value, makes it maintain 3.0 or so always, until titania solution all drips off;It is constant to control pH, continues insulated and stirred ageing 30min;Modified microballon is filtered, and dry;It places it in 800 DEG C to calcine 1 hour, obtain titania modified hollow Silicon dioxide microsphere.
7. insulating moulding coating as described in claim 1, which is characterized in that the titania modified hollow silica microsphere Mass percentage is 15%.
8. insulating moulding coating as described in claim 1, which is characterized in that the silicone acrylic emulsion mass percentage is 30%.
9. insulating moulding coating as described in claim 1, which is characterized in that the titanium dioxide mass percentage is 12%, described Infrared ceramic powder mass percentage is 6%.
10. insulating moulding coating as described in claim 1, which is characterized in that the talcum powder uses 800 mesh, mass percentage It is 6%.
CN201810251673.2A 2018-03-26 2018-03-26 Insulating moulding coating Withdrawn CN108504225A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110157282A (en) * 2019-06-11 2019-08-23 天津隆烨科技发展有限公司 A kind of high-performance heat-insulating anti-corrosive coating
CN110357686A (en) * 2019-07-29 2019-10-22 石家庄富铭生物有机肥有限公司 A kind of process equipment of biological organic fertilizer
CN112552760A (en) * 2020-12-15 2021-03-26 李桂丽 Composite nano waterproof heat-insulating coating for buildings and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110157282A (en) * 2019-06-11 2019-08-23 天津隆烨科技发展有限公司 A kind of high-performance heat-insulating anti-corrosive coating
CN110357686A (en) * 2019-07-29 2019-10-22 石家庄富铭生物有机肥有限公司 A kind of process equipment of biological organic fertilizer
CN112552760A (en) * 2020-12-15 2021-03-26 李桂丽 Composite nano waterproof heat-insulating coating for buildings and preparation method thereof
CN112552760B (en) * 2020-12-15 2022-05-17 艾斯贝科环保科技(北京)有限公司 Composite nano waterproof heat-insulating coating for buildings and preparation method thereof

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