CN106752854A - A kind of antibacterial aqueous UV paints of novel corrosion resistant - Google Patents
A kind of antibacterial aqueous UV paints of novel corrosion resistant Download PDFInfo
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- CN106752854A CN106752854A CN201611011497.2A CN201611011497A CN106752854A CN 106752854 A CN106752854 A CN 106752854A CN 201611011497 A CN201611011497 A CN 201611011497A CN 106752854 A CN106752854 A CN 106752854A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
Antibacterial aqueous UV paints the invention provides a kind of novel corrosion resistant and preparation method thereof, the paint is made up of the raw material of following mass component：15 20 parts of 40 50 parts of aqueous UV polyurethane-acrylate emulsions, 10 20 parts of epoxide modified alcohol ester, 5 10 parts of multifunctional modification agent, 5 10 parts of aqueous wetting dispersing agent, 10 15 parts of auxiliary agent, 0.3 0.5 parts of amine neutralizer and deionized water.The invention provides a kind of environmental protection, painting effect is good, while with good antibacterial and except effect of formaldehyde, has the aqueous UV paints of good decay resistance concurrently.
Description
Technical field
A kind of aqueous UV the invention belongs to technical field of coatings, more particularly to corrosion resistant antibacterial is painted.
Background technology
Furniture panel contains in substantial amounts of Form aldehyde release air, and formaldehyde is a kind of carcinogen, to living in such environment
In the person bring the paint of serious injury, furniture industry long-term use to be mainly traditional solvent-borne coating, with paint
During the furniture spray paint made to these sheet materials, more have substantial amounts of formaldehyde and produce；And traditional solvent-borne colouring agent is by spray
Construction is applied, efficiency is low, high cost, pollution environment influence the health of workmen；Containing a large amount of in making solvent based coating raw material
The inflammable organic volatile solvent such as inflammable and explosive dangerous goods such as toluene, acetone, ethyl acetate curing agent, after solvent based coating film forming
Product do not have fireproof flame-retardant effect yet, meet spark and easily burn and cause fire hazard.
Aqueous UV paint is free of organic solvent, VOC free volatilization because of it, harm will not be brought to be subject to air and operator
People like, but the technology content of aqueous UV paints is higher, and production is difficult larger, and the effect that film coated surface is showed is slightly worse than
PU finish paint products；
Attention with people to good inhabitation atmosphere, in addition to environmental protection is beneficial to physically and mentally healthy requirement, while also right
The scribble effect of paint, antibiotic and sterilizing effect are required to more and more higher, especially to the family for having child, how to ensure to paint ring
There is good bactericidal property again while guaranteed cost, be urgent problem in aqueous UV paints.
CN 105694706A disclose aqueous UV paints of a kind of new formaldehyde-removing antibiotic and preparation method thereof, and the paint is by following
The raw material of mass component is constituted：30-60 parts of aqueous UV polyurethane-acrylate emulsions, it is aqueous wetting dispersing agent 5-10 parts, aqueous
Defoamer 0.3-0.5 parts, cosolvent 5-10 parts, water-soluble photoinitiator 1.5-2.5 parts, amine neutralizer 0.3-0.5 parts, deionized water
15-20 parts, water-based thickener 2-3 parts, nano silica fume 10-40 parts, chitosan 0.5-1 parts.The aqueous UV of formaldehyde-removing antibiotic
Although painting with good antibacterial and except effect of formaldehyde, its decay resistance is poor, easily changes colour stripping in long-term use process
Fall.
The content of the invention
In order to solve the above problems, the invention provides a kind of environmental protection, painting effect is good, with good antibacterial and
While except effect of formaldehyde, the aqueous UV paints of good decay resistance are had concurrently.The present invention is to be achieved through the following technical solutions
's：
In a first aspect, the invention provides a kind of aqueous UV paints of novel antibacterial, being made up of the raw material of following mass component：
40-50 parts of aqueous UV polyurethane-acrylate emulsions, epoxide modified alcohol ester 10-20 parts, multifunctional modification agent 5-10
Part, aqueous wetting dispersing agent 5-10 parts, auxiliary agent 10-15 parts, amine neutralizer 0.3-0.5 parts and deionized water 15-20 parts.
Wherein, the mass parts of aqueous UV polyurethane-acrylate emulsions can be 40 parts, 42 parts, 44 parts, 46 parts, 48 parts or 50
Part etc.；The mass parts of epoxide modified alcohol ester can be 10 parts, 12 parts, 14 parts, 16 parts, 18 parts or 20 parts etc.；Multifunctional modification agent
Mass parts can be 5 parts, 6 parts, 7 parts, 8 parts, 9 parts or 10 parts etc.；The mass parts of aqueous wetting dispersing agent can for 10 parts, 12 parts, 14
Part, 16 parts, 18 parts or 20 parts etc.；The mass parts of auxiliary agent can be 10 parts, 11 parts, 12 parts, 13 parts, 14 parts or 15 parts etc.；Amine is neutralized
The mass parts of agent can be 0.3 part, 0.4 part or 0.5 part etc.；15 parts, 16 parts, 17 parts, 18 parts, 19 parts of the mass parts of deionized water or
20 parts etc..
Used as currently preferred technical scheme, the antibacterial aqueous UV paints are made up of the raw material of following mass component：
45 parts of aqueous UV polyurethane-acrylate emulsions, 15 parts of epoxide modified alcohol ester, 6 parts of multifunctional modification agent, aqueous profit
15 parts of 8 parts of hygroscopic water powder, 13 parts of auxiliary agent, 0.4 part of amine neutralizer and deionized water.
In the present invention, with the best performance that antibacterial aqueous UV obtained in said ratio is painted.
Used as currently preferred technical scheme, the epoxide modified alcohol ester is prepared into by weight by following raw material
Arrive：
Bisphenol A epoxide resin 0.5-0.8 parts
Maleic anhydride 1-1.5 parts
Ethylene glycol 10-15 parts；
Wherein, the weight portion of bisphenol A epoxide resin can be 0.5 part, 0.6 part, 0.7 part or 0.8 part etc.；The weight of maleic anhydride
Amount part can be 1 part, 1.1 parts, 1.2 parts, 1.3 parts, 1.4 parts or 1.5 parts etc.；The weight portion of ethylene glycol can for 10 parts, 11 parts, 12
Part, 13 parts, 14 parts or 15 parts etc..
Preferably, the preparation method of the epoxide modified alcohol ester is：
Raw materials bisphenol A epoxy resin, maleic anhydride and ethylene glycol are added in reactor under protective atmosphere, 100
1~2h of reaction is carried out at~120 DEG C, hydrochloric acid 5~10 is then added dropwise and is dripped, continue to react that epoxide modified alcohol ester is obtained.
Used as currently preferred technical scheme, the multifunctional modification agent is by aqueous defoamer, ethene-vinyl acetate
The compound of ester copolymer, soap and silica composition, each Parts by Ingredients proportioning is wherein in compound：It is aqueous to disappear
Infusion 5-10 parts, ethylene-vinyl acetate copolymer 3-5 parts, soap 5-10 parts and silica 3-5 parts.
Wherein, the weight portion of aqueous defoamer can be 5 parts, 6 parts, 7 parts, 8 parts, 9 parts or 10 parts etc.；Ethene-vinyl acetate
The weight portion of ester copolymer can be 3 parts, 4 parts or 5 parts etc.；The weight portion of soap can for 5 parts, 6 parts, 7 parts, 8 parts, 9 parts or
10 parts etc.；The weight portion of silica can be 3 parts, 4 parts or 5 parts etc..
Preferably, aqueous defoamer is Foamex3062.
Used as currently preferred technical scheme, the aqueous UV polyurethane-acrylate emulsions are that U.S.'s cyanogen specialization work is produced
Product, solid content is 40%, and outward appearance emulsus transparency liquid, molecular weight has for 5500 dalton；There are adhesive force, the timber of brilliance
Wetability is good, low viscous feature, can before mechanical cycles coating decoration, photocuring emulsifiable, paint film flexibility it is good.
Preferably, the aqueous wetting dispersing agent is enlightening Dispers760w high；For water-based printing ink and coating system
Wetting dispersing agent, the aqueous solution containing pigment affinity groups polymer high and surface-active substance of 35% active quantities is transparent
To slight haze liquid；It is applicable for water prescription, can strongly reduces grinding viscosity；And with excellent tinting strength, tinting power.
Preferably, the aqueous amine neutralizer is the modest chemical MA-95 of Taiwan moral；It is special with low smell and low volatility
Point, effective regulation system pH value, and assign system good pH value stability；Have simultaneously it is good help pigment-dispersing, can promote
Enter gloss of film represent and covering power raising；And effectively improve paint liquid freeze-thaw stability and in-can preservation corrosion energy.
Second aspect, the invention provides the preparation method of above-mentioned antibacterial aqueous UV paints, comprises the following steps：
During the aqueous UV polyurethane-acrylate emulsions of formula ratio and aqueous wetting dispersing agent first added into container, then slowly
Epoxide modified alcohol ester, multifunctional modification agent, auxiliary agent and the amine neutralizer dilution of formula ratio is added to stir；In 120~150 DEG C
Under be ground and react to fineness and reach below 25um, obtain antibacterial aqueous UV paints.
The beneficial effects of the present invention are：
The invention provides a kind of aqueous UV paints of corrosion resistant antibacterial, pass through the epoxide modified alcohol ester and many work(for being added
Energy modifying agent acts synergistically with aqueous UV polyurethane-acrylate emulsions so that the aqueous UV paints of obtained antibacterial have
Good antibacterial and while except effect of formaldehyde, has the aqueous UV paints of good decay resistance concurrently.
Water paint of the present invention is applied on the E1 grades of surface of wood-based plate, formaldehyde clearance can reach 90~95%,
Antibacterial effect can reach more than 99.9%；Meanwhile, it is placed under acid or alkaline environment, also it is not corroded.
Specific embodiment
With reference to specific embodiment, the present invention is elaborated.
Embodiment 1
A kind of aqueous UV paints of novel antibacterial are present embodiments provided, is made up of the raw material of following mass component：
45 parts of aqueous UV polyurethane-acrylate emulsions, 15 parts of epoxide modified alcohol ester, 6 parts of multifunctional modification agent, aqueous profit
15 parts of 8 parts of hygroscopic water powder, 13 parts of auxiliary agent, 0.4 part of amine neutralizer and deionized water.
Wherein, the epoxide modified alcohol ester is prepared by weight by following raw material：
0.6 part of bisphenol A epoxide resin
1.3 parts of maleic anhydride
13 parts of ethylene glycol；
The multifunctional modification agent is by aqueous defoamer, ethylene-vinyl acetate copolymer, soap and titanium dioxide
The compound of silicon composition, each Parts by Ingredients proportioning is wherein in compound：6 parts of aqueous defoamer, ethylene-vinyl acetate are common
4 parts of 4 parts of polymers, 7 parts of soap and silica.
The preparation method of the antibacterial aqueous UV paint is：
During the aqueous UV polyurethane-acrylate emulsions of formula ratio and aqueous wetting dispersing agent first added into container, then slowly
Epoxide modified alcohol ester, multifunctional modification agent, auxiliary agent and the amine neutralizer dilution of formula ratio is added to stir；In 120~150 DEG C
Under be ground and react to fineness and reach below 25um, obtain antibacterial aqueous UV paints.
Water paint obtained in the present embodiment is applied on the E1 grades of surface of wood-based plate, formaldehyde clearance can reach 95%,
Antibacterial effect can reach more than 99.9%；Meanwhile, it is placed under acid or alkaline environment, also it is not corroded.
Embodiment 2：
A kind of aqueous UV paints of novel antibacterial are present embodiments provided, is made up of the raw material of following mass component：
40 parts of aqueous UV polyurethane-acrylate emulsions, 10 parts of epoxide modified alcohol ester, 5 parts of multifunctional modification agent, aqueous profit
15 parts of 5 parts of hygroscopic water powder, 10 parts of auxiliary agent, 0.3 part of amine neutralizer and deionized water.
Wherein, the epoxide modified alcohol ester is prepared by weight by following raw material：0.5 part of bisphenol A epoxide resin,
10 parts of 1 part of maleic anhydride and ethylene glycol；Its preparation method is in the same manner as in Example 1.
The multifunctional modification agent is by aqueous defoamer, ethylene-vinyl acetate copolymer, soap and titanium dioxide
The compound of silicon composition, each Parts by Ingredients proportioning is wherein in compound：5 parts of aqueous defoamer, ethylene-vinyl acetate are common
3 parts of 3 parts of polymers, 5 parts of soap and silica.
The preparation method of the antibacterial aqueous UV paints is identical with preparation method described in embodiment 1.
Water paint obtained in the present embodiment is applied on the E1 grades of surface of wood-based plate, formaldehyde clearance can reach 92%,
Antibacterial effect can reach more than 99.9%；Meanwhile, it is placed under acid or alkaline environment, also it is not corroded.
Embodiment 3：
A kind of aqueous UV paints of novel antibacterial are present embodiments provided, is made up of the raw material of following mass component：
50 parts of aqueous UV polyurethane-acrylate emulsions, 20 parts of epoxide modified alcohol ester, 10 parts of multifunctional modification agent, aqueous profit
20 parts of 10 parts of hygroscopic water powder, 15 parts of auxiliary agent, 0.5 part of amine neutralizer and deionized water.
Wherein, the epoxide modified alcohol ester is prepared by weight by following raw material：0.8 part of bisphenol A epoxide resin,
15 parts of 1.5 parts of maleic anhydride and ethylene glycol；Its preparation method is in the same manner as in Example 1.
The multifunctional modification agent is by aqueous defoamer, ethylene-vinyl acetate copolymer, soap and titanium dioxide
The compound of silicon composition, each Parts by Ingredients proportioning is wherein in compound：10 parts of aqueous defoamer, ethylene-vinyl acetate
5 parts of 5 parts of copolymer, 10 parts of soap and silica.
The preparation method of the antibacterial aqueous UV paints is identical with preparation method described in embodiment 1.
Water paint obtained in the present embodiment is applied on the E1 grades of surface of wood-based plate, formaldehyde clearance can reach 91%,
Antibacterial effect can reach more than 99.9%；Meanwhile, it is placed under acid or alkaline environment, also it is not corroded.
Comparative example 1：
This comparative example provides a kind of antibacterial aqueous UV paints, and the preparing raw material of the antibacterial aqueous UV paints is not except including ring
Outside the modified alcohol ester of oxygen, unclassified stores consumption is in the same manner as in Example 1 with preparation method.
Water paint obtained in this comparative example is applied on the E1 grades of surface of wood-based plate, formaldehyde clearance is 86%, antibacterial
Effect is 98%；It is placed under acid or alkaline environment, the phenomenon that is corroded occurs after 5~10 days.
Comparative example 2：
This comparative example provides a kind of antibacterial aqueous UV paints, and the preparing raw material of the antibacterial aqueous UV paints is more except not including
Outside functional modifier, unclassified stores consumption is in the same manner as in Example 1 with preparation method.
Water paint obtained in this comparative example is applied on the E1 grades of surface of wood-based plate, formaldehyde clearance is 87%, antibacterial
Effect is 95%；It is placed under acid or alkaline environment, the phenomenon that is corroded occurs after 5~10 days.
The result of integrated embodiment 1-3 and comparative example 1-2 can be seen that the invention provides a kind of corrosion resistant antibacterial
Aqueous UV paint, passes through the epoxide modified alcohol ester that is added and multifunctional modification agent occurs with aqueous UV polyurethane-acrylate emulsions
Synergy so that the aqueous UV of obtained antibacterial is painted while with good antibacterial and except effect of formaldehyde, is had concurrently good
The aqueous UV paints of decay resistance.
Water paint of the present invention is applied on the E1 grades of surface of wood-based plate, formaldehyde clearance can reach 90~95%,
Antibacterial effect can reach more than 99.9%；Meanwhile, it is placed under acid or alkaline environment, also it is not corroded.
Applicant states that the present invention illustrates detailed construction feature of the invention and treatment side by above-described embodiment
Method, but the invention is not limited in above-mentioned detailed construction feature and processing method, that is, do not mean that the present invention has to rely on
Stating detailed construction feature and processing method could implement.Person of ordinary skill in the field is it will be clearly understood that to of the invention
Any improvement, increase, the selection of concrete mode to the equivalence replacement and accessory of part selected by the present invention etc., fall
Within the scope of protection scope of the present invention and disclosure.
Claims (7)
1. a kind of antibacterial aqueous UV of novel corrosion resistant is painted, it is characterised in that the antibacterial aqueous UV paints, by following mass component
Raw material constitute：
40-50 parts of aqueous UV polyurethane-acrylate emulsions, epoxide modified alcohol ester 10-20 parts, 5-10 parts of multifunctional modification agent, water
5-10 parts, auxiliary agent 10-15 parts, amine neutralizer 0.3-0.5 parts and deionized water 15-20 parts of wetting dispersing agent of property.
2. antibacterial aqueous UV as claimed in claim 1 is painted, it is characterised in that the antibacterial aqueous UV paints, by following quality group
The raw material for dividing is constituted：
45 parts of aqueous UV polyurethane-acrylate emulsions, 15 parts of epoxide modified alcohol ester, 6 parts of multifunctional modification agent, aqueous wetting point
15 parts of 8 parts of powder, 13 parts of auxiliary agent, 0.4 part of amine neutralizer and deionized water.
3. antibacterial aqueous UV as claimed in claim 1 or 2 is painted, it is characterised in that the epoxide modified alcohol ester is by following raw material
Prepare by weight：
Bisphenol A epoxide resin 0.5-0.8 parts
Maleic anhydride 1-1.5 parts
Ethylene glycol 10-15 parts；
Preferably, the preparation method of the epoxide modified alcohol ester is：
Raw materials bisphenol A epoxy resin, maleic anhydride and ethylene glycol are added in reactor under protective atmosphere, 100~120
1~2h of reaction is carried out at DEG C, hydrochloric acid 5~10 is then added dropwise and is dripped, continue to react that epoxide modified alcohol ester is obtained.
4. the antibacterial aqueous UV as described in claim any one of 1-3 is painted, it is characterised in that the multifunctional modification agent is by water
Property defoamer, ethylene-vinyl acetate copolymer, soap and silica composition compound, it is each wherein in compound
Parts by Ingredients is matched：Aqueous defoamer 5-10 parts, ethylene-vinyl acetate copolymer 3-5 parts, soap 5-10 parts and
Silica 3-5 parts；
Preferably, aqueous defoamer is Foamex3062.5. the antibacterial aqueous UV as described in claim any one of 1-4 is painted, its
It is characterised by, the aqueous UV polyurethane-acrylate emulsions are U.S.'s cyanogen specialization chemical product, and solid content is 40%, outward appearance emulsus
Transparency liquid, molecular weight is 5500 dalton；
Preferably, the aqueous wetting dispersing agent is enlightening Dispers760w high.
5. the antibacterial aqueous UV as described in claim any one of 1-5 is painted, it is characterised in that the aqueous amine neutralizer is Taiwan
The modest chemical MA-95 of moral.
6. the aqueous UV paints of new formaldehyde-removing antibiotic as described in claim any one of 1-6, it is characterised in that the deionized water
To be obtained after pure water deionization.
7. the preparation method that the antibacterial aqueous UV as described in claim any one of 1-8 is painted, it is characterised in that comprise the following steps：
First by the aqueous UV polyurethane-acrylate emulsions of formula ratio and aqueous wetting dispersing agent addition container, it is slow added into
The dilution of the epoxide modified alcohol ester of formula ratio, multifunctional modification agent, auxiliary agent and amine neutralizer stirs；Enter at 120~150 DEG C
Row grinds and reacts to fineness and reaches below 25um, obtains antibacterial aqueous UV paints.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611011497.2A CN106752854A (en) | 2016-11-17 | 2016-11-17 | A kind of antibacterial aqueous UV paints of novel corrosion resistant |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611011497.2A CN106752854A (en) | 2016-11-17 | 2016-11-17 | A kind of antibacterial aqueous UV paints of novel corrosion resistant |
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| CN106752854A true CN106752854A (en) | 2017-05-31 |
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| CN201611011497.2A Pending CN106752854A (en) | 2016-11-17 | 2016-11-17 | A kind of antibacterial aqueous UV paints of novel corrosion resistant |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107793917A (en) * | 2017-10-27 | 2018-03-13 | 北京展辰新材料有限公司 | A kind of water-based UV varnish of Diamond Search and preparation method and application |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103409026A (en) * | 2013-08-29 | 2013-11-27 | 江苏博开达工业化住宅制造有限公司 | Environment-friendly waterborne fire retardant coating |
| CN103436104A (en) * | 2013-09-17 | 2013-12-11 | 成都优品涂料有限公司 | Water-based UV (ultraviolet) woodware adhesion colorant mother solution and preparation method thereof |
| CN105348624A (en) * | 2015-08-31 | 2016-02-24 | 无锡市嘉邦电力管道厂 | Thermoplastic anti-cracking low-smoke halogen-free and flame-retardant polyolefin cable jacket material and preparation method therefor |
| CN105694706A (en) * | 2016-04-22 | 2016-06-22 | 成都优品化工有限公司 | Novel formaldehyde removal anti-microbial water-based UV paint |
-
2016
- 2016-11-17 CN CN201611011497.2A patent/CN106752854A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103409026A (en) * | 2013-08-29 | 2013-11-27 | 江苏博开达工业化住宅制造有限公司 | Environment-friendly waterborne fire retardant coating |
| CN103436104A (en) * | 2013-09-17 | 2013-12-11 | 成都优品涂料有限公司 | Water-based UV (ultraviolet) woodware adhesion colorant mother solution and preparation method thereof |
| CN105348624A (en) * | 2015-08-31 | 2016-02-24 | 无锡市嘉邦电力管道厂 | Thermoplastic anti-cracking low-smoke halogen-free and flame-retardant polyolefin cable jacket material and preparation method therefor |
| CN105694706A (en) * | 2016-04-22 | 2016-06-22 | 成都优品化工有限公司 | Novel formaldehyde removal anti-microbial water-based UV paint |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107793917A (en) * | 2017-10-27 | 2018-03-13 | 北京展辰新材料有限公司 | A kind of water-based UV varnish of Diamond Search and preparation method and application |
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Application publication date: 20170531 |