CN101760090A - Alcohol acid and polyurethane resin modified nitrocellulose matt varnish - Google Patents
Alcohol acid and polyurethane resin modified nitrocellulose matt varnish Download PDFInfo
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- CN101760090A CN101760090A CN200810207682A CN200810207682A CN101760090A CN 101760090 A CN101760090 A CN 101760090A CN 200810207682 A CN200810207682 A CN 200810207682A CN 200810207682 A CN200810207682 A CN 200810207682A CN 101760090 A CN101760090 A CN 101760090A
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- varnish
- polyurethane resin
- alcohol acid
- resin modified
- modified nitrocellulose
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Abstract
The invention provides an alcohol acid and polyurethane resin modified nitrocellulose matt varnish, containing the following components in parts by weight: 100 parts of nitrocellulose varnishes, 95-105 parts of alcoholic acid varnishes, 40-50 parts of curing agents and 80-90 parts of diluents. The alcohol acid and polyurethane resin-modified nitrocellulose matt varnish has the characteristics of rapid drying, good decorating effect, easy construction, excellent mechanical property, high film hardness and favorable chemical resistance.
Description
Technical field
The present invention relates to a kind of clear finish, be specifically related to a kind of nitro clear finish that is coated with the alcohol acid and polyurethane modification that is contained in the woodenware surface.
Background technology
Now the pyroxylin(e)finish of selling on the market all is that to adopt Synolac or acrylic resin be raw material, adds the product that properties-correcting agent forms with the snappiness of improving it and sticking power.It has fast drying, good decorating effect, easy working advantage.Component as now general pyroxylin(e)finish is: paint host: thinner=1: 0.6-1.2, its paint host mainly is made of following component: contain soluble cotton 25-30%, dioctyl phthalate (DOP) 3-6%, Synolac 20-25%, methyl iso-butyl ketone (MIBK) 5-10%, butylacetate 10-15%, toluene 5-10%, dimethylbenzene 5-10%, isopropylcarbinol 7-15%, ethylene glycol monobutyl ether 2-5%, thinner mainly is made of following component: isopropylcarbinol 10-15%, methyl iso-butyl ketone (MIBK) 10-15%, butylacetate 20-30%, dimethylbenzene 30-45%, ethylene glycol monobutyl ether 4-10%, but because its membrane formation mechanism is physical dryness fully, so hardness of paint film is low, bad mechanical strength, not anti-solvent, heat-resisting, drawbacks such as resistance to acids and bases difference.
Summary of the invention
The purpose of this invention is to provide a kind of alcohol acid and polyurethane resin modified nitrocellulose matt varnish, to overcome the bad mechanical strength that has pyroxylin(e)finish now and exist, the technological deficiency of chemicals-resistant difference.
Alcohol acid and polyurethane resin modified nitrocellulose matt varnish of the present invention is made up of zapon varnish, alkyd varnish, solidifying agent and thinner, and the parts by weight proportioning is:
Zapon varnish: alkyd varnish: solidifying agent: thinner=100: 95～105: 40-50: 80-90;
Preferably:
Zapon varnish: alkyd varnish: solidifying agent: thinner=100: 100: 40-50: 80-90;
Described zapon varnish comprises following components in weight percentage:
/ 4th seconds nitro-cotton 70%-80%
Flatting silica 0.3%-1%
Defoamer 0.3%-0.4%
Flow agent 0.2%-0.3%
Anti-settling agent 0.2-0.4%
The mixture 15%-25% of butylacetate, methyl iso-butyl ketone (MIBK) and butanone
Described alkyd varnish comprises following components in weight percentage:
Synolac 70%-85%
Flatting silica 0.3%-1%
Defoamer 0.3%-0.4%
Flow agent 0.2%-0.3%
Anti-settling agent 0.2-0.4%
The mixture 10%-28% of butylacetate, methyl iso-butyl ketone (MIBK) and butanone
Flatting silica is a silicon dioxide powder, and can adopt the Grace company trade mark is the product of MSK C7;
Defoamer is the broken bubble of a BYK066 siloxane solution, and can adopt the Bi Ke company trade mark is the product of BYK066;
Flow agent is a polyester modification polydimethylsiloxane solution, and can adopt the Bi Ke company trade mark is the product of BYK310;
Anti-settling agent is a polyamide wax, and can adopt the modest company of the moral trade mark is 229 product;
Described solidifying agent comprises following components in weight percentage:
Tolylene diisocyanate (TDI) tripolymer 30.0%-35%
Hexamethylene diisocyanate (HDI) tripolymer 30.0%-35%
Butylacetate 32.0%-36%
Described thinner composition proportioning is:
Butylacetate 45.0%～60.0%
1-Methoxy-2-propyl acetate 10.0%～15.0%
Dimethylbenzene 25.0%～40.0%
The preparation method of alcohol acid and polyurethane resin modified nitrocellulose matt varnish of the present invention, physical mixed method for routine, being about to various materials proportionally mixes, preparation earlier becomes zapon varnish, alkyd varnish, solidifying agent and thinner, then with its mixing, obtain product, can adopt conventional method to carry out coating decoration.
Alcohol acid and polyurethane resin modified nitrocellulose matt varnish of the present invention has fast drying, good decorating effect, easily construction, mechanical property excellence, hardness of paint film height and the good characteristics of chemicals-resistant.
Embodiment
Embodiment 1
Prescription: (weight)
Zapon varnish, alkyd varnish, solidifying agent, thinner.
Zapon varnish component and weight proportion are as follows:
Soluble cotton 75%, butylacetate 10%, methyl iso-butyl ketone (MIBK) 9%, butanone 5%, flatting silica 0.3%, defoamer 0.3%, flow agent 0.2%, anti-settling agent 0.2%.
Described alkyd varnish component and weight proportion are as follows: Synolac 75%, butylacetate 10%, methyl iso-butyl ketone (MIBK) 9%, butanone 5%, flatting silica 0.3%, defoamer 0.3%, flow agent 0.2%, anti-settling agent 0.2%.
Described curing agent component and weight proportion are as follows: tolylene diisocyanate (TDI) tripolymer 32%, hexamethylene diisocyanate (HDI) tripolymer 32.0%, N-BUTYL ACETATE 36.0%.
Described thinner composition proportioning is: N-BUTYL ACETATE 50.0%, 1-Methoxy-2-propyl acetate 15.0%, dimethylbenzene 35.0%.
Construction proportioning: zapon varnish: alkyd varnish: solidifying agent: thinner=100: 100: 40: 80.Form of construction work: hand spray or electrostatic spraying.
Detect according to HG/T 2592-94 " zapon varnish " and GB 18581-2001 " limits of harmful substances in the indoor decorating material solvent type woodwork coating ", the actual detected data are as follows:
1, stirs evenly no lump of back in the condition in container parameter
2, application property applies accessible
3, surface drying time≤10min
4, do solid work time≤50min
5, package stability is (50 ℃/7d) no abnormal
6, appearance of film is normal
7, gloss (60 ° of angles) 70%
8, pencil hardness (scratch) 2H
9, sticking power (draw compartment apart from 2mm)≤1 grade
10, water tolerance (24h) is no abnormal
11, alkali resistance (50g/LNaHCO
3, 2h) no abnormal
12, alcohol resistance (70% ethanol, 1h) no abnormal
13, anti-vinegar contaminative (1h) is no abnormal
14, anti-tea contaminative (1h) is no abnormal
15, volatile organic compounds (VOC) 620g/L
16, benzene does not detect in the coating
17, toluene and dimethylbenzene summation 20% in the coating
18, tolylene diisocyanate monomer (TDI) 0.05% in the coating
Embodiment 2
Described curing agent component and weight proportion are as follows: a kind of polyurethane-modified nitro matte varnish of tolylene diisocyanate (TDI) trimerization comprises zapon varnish, alkyd varnish, solidifying agent, thinner.Described zapon varnish component and weight proportion are as follows: soluble cotton 80%, butylacetate 8%, methyl iso-butyl ketone (MIBK) 6%, butanone 5%, flatting silica 0.3%, defoamer 0.3%, flow agent 0.2%, anti-settling agent 0.2%.
Described alkyd varnish component and weight proportion are as follows: Synolac 79%, butylacetate 6%, methyl iso-butyl ketone (MIBK) 8%, butanone 6%, flatting silica 0.3%, defoamer 0.3%, flow agent 0.2%, anti-settling agent 0.2%.
Described curing agent component and weight proportion are as follows: tolylene diisocyanate (TDI) tripolymer 30.0%, hexamethylene diisocyanate (HDI) tripolymer 32.0%, N-BUTYL ACETATE 38.0%.
Described thinner composition proportioning is: N-BUTYL ACETATE 55.0%,, 1-Methoxy-2-propyl acetate 15.0%, dimethylbenzene 30.0%.
Construction proportioning: zapon varnish: alkyd varnish: solidifying agent: thinner=100: 100: 50: 90.Form of construction work: hand spray or electrostatic spraying.
Detect according to HG/T 2592-94 " zapon varnish " and GB 18581-2001 " limits of harmful substances in the indoor decorating material solvent type woodwork coating ", the actual detected data are as follows:
1, stirs evenly no lump of back in the condition in container parameter
2, application property applies accessible
3, surface drying time≤10min
4, do solid work time≤50min
5, package stability is (50 ℃/7d) no abnormal
6, appearance of film is normal
7, gloss (60 ° of angles) 70%
8, pencil hardness (scratch) 2H
9, sticking power (draw compartment apart from 2mm)≤1 grade
10, water tolerance (24h) is no abnormal
11, alkali resistance (50g/LNaHCO
3, 2h) no abnormal
12, alcohol resistance (70% ethanol, 1h) no abnormal
13, anti-vinegar contaminative (1h) is no abnormal
14, anti-tea contaminative (1h) is no abnormal
15, volatile organic compounds (VOC) 520g/L
16, benzene does not detect in the coating
17, toluene and dimethylbenzene summation 24% in the coating
18, tolylene diisocyanate monomer (TDI) 0.05% in the coating
Claims (7)
1. alcohol acid and polyurethane resin modified nitrocellulose matt varnish is characterized in that, the parts by weight proportioning is: zapon varnish: alkyd varnish: solidifying agent: thinner=100: 95～105: 40-50: 80-90.
2. alcohol acid and polyurethane resin modified nitrocellulose matt varnish according to claim 1 is characterized in that, the parts by weight proportioning is: zapon varnish: alkyd varnish: solidifying agent: thinner=100: 100: 40-50: 80-90.
3. alcohol acid and polyurethane resin modified nitrocellulose matt varnish according to claim 1 is characterized in that, described zapon varnish comprises following components in weight percentage:
/ 4th seconds nitro-cotton 70%-80%
Flatting silica 0.3%-1%
Defoamer 0.3%-0.4%
Flow agent 0.2%-0.3%
Anti-settling agent 0.2-0.4%
The mixture 15%-25% of butylacetate, methyl iso-butyl ketone (MIBK) and butanone
Described alkyd varnish comprises following components in weight percentage:
Synolac 70%-85%
Flatting silica 0.3%-1%
Defoamer 0.3%-0.4%
Flow agent 0.2%-0.3%
Anti-settling agent 0.2-0.4%
The mixture 10%-28% of butylacetate, methyl iso-butyl ketone (MIBK) and butanone;
Described solidifying agent comprises following components in weight percentage:
Tolylene diisocyanate (TDI) tripolymer 30.0%-35%
Hexamethylene diisocyanate (HDI) tripolymer 30.0%-35%
Butylacetate 32.0%-36%
Described thinner composition proportioning is:
Butylacetate 45.0%～60.0%
1-Methoxy-2-propyl acetate 10.0%～15.0%
Dimethylbenzene 25.0%～40.0%.
4. alcohol acid and polyurethane resin modified nitrocellulose matt varnish according to claim 3 is characterized in that, flatting silica is a silicon dioxide powder.
5. alcohol acid and polyurethane resin modified nitrocellulose matt varnish according to claim 3 is characterized in that, defoamer is broken bubble siloxane solution.
6. alcohol acid and polyurethane resin modified nitrocellulose matt varnish according to claim 3 is characterized in that, flow agent is a polyester modification polydimethylsiloxane solution.
7. alcohol acid and polyurethane resin modified nitrocellulose matt varnish according to claim 3 is characterized in that, anti-settling agent is a polyamide wax.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008102076828A CN101760090B (en) | 2008-12-24 | 2008-12-24 | Alcohol acid and polyurethane resin modified nitrocellulose matt varnish |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008102076828A CN101760090B (en) | 2008-12-24 | 2008-12-24 | Alcohol acid and polyurethane resin modified nitrocellulose matt varnish |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101760090A true CN101760090A (en) | 2010-06-30 |
| CN101760090B CN101760090B (en) | 2012-02-01 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2008102076828A Active CN101760090B (en) | 2008-12-24 | 2008-12-24 | Alcohol acid and polyurethane resin modified nitrocellulose matt varnish |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102533094A (en) * | 2011-12-20 | 2012-07-04 | 东莞大宝化工制品有限公司 | Transparent polyurethane primer for coating with three-dimensional effect of production line and preparation method thereof |
| CN102634275A (en) * | 2012-04-18 | 2012-08-15 | 广东三和化工科技有限公司 | Sterilization and aldehyde-removal nanometer polyurethane paint |
| CN102863889A (en) * | 2012-09-28 | 2013-01-09 | 中华制漆（深圳）有限公司 | Double-component polyurethane white high-gloss woodware paint, and preparation method and application thereof |
| CN103031051A (en) * | 2012-12-27 | 2013-04-10 | 合众（佛山）化工有限公司 | Preparation method of scratch-resistant bicomponent polyurethane carpentry matt varnish |
| CN103483925A (en) * | 2012-06-12 | 2014-01-01 | 上海富臣化工有限公司 | Wood pulp cotton nitro varnish |
| CN103666115A (en) * | 2013-12-06 | 2014-03-26 | 上海德粼水性油墨有限公司 | Photochromic printing ink applicable to intaglio printing |
| CN103740249A (en) * | 2013-11-28 | 2014-04-23 | 苏州长风航空电子有限公司 | Paint liquid and spraying method by using same |
| CN103834286A (en) * | 2012-11-23 | 2014-06-04 | 展辰涂料集团股份有限公司 | Polyurethane elastic crack paint |
| CN103923504A (en) * | 2013-01-14 | 2014-07-16 | 严易舒 | Conductive agent for double-component polyurethane paint and PU diluent |
| CN104130697A (en) * | 2014-07-30 | 2014-11-05 | 广东花王涂料有限公司 | Vertical-face spraying PU matte clean finishing paint with good instant leveling property |
| CN106634542A (en) * | 2016-11-15 | 2017-05-10 | 惠州市长润发涂料有限公司 | Open clear finish paint suitable for shallow wood grain PU odor removal |
| CN112442316A (en) * | 2019-08-27 | 2021-03-05 | 立邦涂料（中国）有限公司 | Transparent solvent type low-construction VOC (volatile organic compound) polyurethane composition for woodware surface and preparation method thereof |
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2008
- 2008-12-24 CN CN2008102076828A patent/CN101760090B/en active Active
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102533094A (en) * | 2011-12-20 | 2012-07-04 | 东莞大宝化工制品有限公司 | Transparent polyurethane primer for coating with three-dimensional effect of production line and preparation method thereof |
| CN102533094B (en) * | 2011-12-20 | 2013-09-04 | 东莞大宝化工制品有限公司 | Transparent polyurethane primer for coating with three-dimensional effect of production line and preparation method thereof |
| CN102634275A (en) * | 2012-04-18 | 2012-08-15 | 广东三和化工科技有限公司 | Sterilization and aldehyde-removal nanometer polyurethane paint |
| CN103483925A (en) * | 2012-06-12 | 2014-01-01 | 上海富臣化工有限公司 | Wood pulp cotton nitro varnish |
| CN102863889A (en) * | 2012-09-28 | 2013-01-09 | 中华制漆（深圳）有限公司 | Double-component polyurethane white high-gloss woodware paint, and preparation method and application thereof |
| CN102863889B (en) * | 2012-09-28 | 2015-03-25 | 中华制漆（深圳）有限公司 | Double-component polyurethane white high-gloss woodware paint, and preparation method and application thereof |
| CN103834286A (en) * | 2012-11-23 | 2014-06-04 | 展辰涂料集团股份有限公司 | Polyurethane elastic crack paint |
| CN103834286B (en) * | 2012-11-23 | 2016-12-07 | 展辰新材料集团股份有限公司 | A kind of elastic polyurethane crackle coating |
| CN103031051A (en) * | 2012-12-27 | 2013-04-10 | 合众（佛山）化工有限公司 | Preparation method of scratch-resistant bicomponent polyurethane carpentry matt varnish |
| CN103923504A (en) * | 2013-01-14 | 2014-07-16 | 严易舒 | Conductive agent for double-component polyurethane paint and PU diluent |
| CN103740249A (en) * | 2013-11-28 | 2014-04-23 | 苏州长风航空电子有限公司 | Paint liquid and spraying method by using same |
| CN103666115A (en) * | 2013-12-06 | 2014-03-26 | 上海德粼水性油墨有限公司 | Photochromic printing ink applicable to intaglio printing |
| CN103666115B (en) * | 2013-12-06 | 2015-08-19 | 上海德粼水性油墨有限公司 | A kind of photochromic ink being applicable to intaglio printing |
| CN104130697A (en) * | 2014-07-30 | 2014-11-05 | 广东花王涂料有限公司 | Vertical-face spraying PU matte clean finishing paint with good instant leveling property |
| CN106634542A (en) * | 2016-11-15 | 2017-05-10 | 惠州市长润发涂料有限公司 | Open clear finish paint suitable for shallow wood grain PU odor removal |
| CN112442316A (en) * | 2019-08-27 | 2021-03-05 | 立邦涂料（中国）有限公司 | Transparent solvent type low-construction VOC (volatile organic compound) polyurethane composition for woodware surface and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN101760090B (en) | 2012-02-01 |
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Owner name: QINGDAO VISION CHEMICAL CO., LTD. Free format text: FORMER OWNER: SHANGHAI FUCHEN CHEMICAL CO. LTD. Effective date: 20130427 Free format text: FORMER OWNER: ZHANCHEN COATINGS GROUP CO., LTD. BEIJING ZHANCHEN CHEMICAL INDUSTRY CO., LTD. Effective date: 20130427 |
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Effective date of registration: 20130427 Address after: 266706, Shandong province Qingdao Pingdu and the Street Office Fu Fu Avenue 1 Patentee after: Qingdao Fuchen Chemical Co., Ltd. Address before: 201700 Shanghai City Industrial Park, No. 8555 Qingpu Songze Avenue Patentee before: Shanghai Fuchen Chemical Co., Ltd. Patentee before: Zhanchen Coatings Group Co., Ltd. Patentee before: Beijing Zhanchen Chemical Industry Co., Ltd. |
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Address after: 266706, Shandong province Qingdao Pingdu and the Street Office Fu Fu Avenue 1 Patentee after: Qingdao Zhan Chen novel material company limited Address before: 266706, Shandong province Qingdao Pingdu and the Street Office Fu Fu Avenue 1 Patentee before: Qingdao Fuchen Chemical Co., Ltd. |