CN104610853A - Unsaturated polyester varnish primer with high fullness and high pore access property - Google Patents
Unsaturated polyester varnish primer with high fullness and high pore access property Download PDFInfo
- Publication number
- CN104610853A CN104610853A CN201310540148.XA CN201310540148A CN104610853A CN 104610853 A CN104610853 A CN 104610853A CN 201310540148 A CN201310540148 A CN 201310540148A CN 104610853 A CN104610853 A CN 104610853A
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- China
- Prior art keywords
- unsaturated polyester
- permeability
- agent
- priming paint
- high fullness
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
Abstract
The invention provides an unsaturated polyester varnish primer with high fullness and high pore access property. The unsaturated polyester varnish primer is composed of a main agent containing unsaturated polyester and alkyd resins, an initiator, a promoter and a diluent; the main agent comprises 4.0-5.0wt% of alkyd resin, 60.0-65.0wt% of unsaturated polyester resin, 5.0-10.0wt% of a butyl acetate and styrene mixture, 0.1-0.3wt% of an antifoaming agent, 0.05-0.1wt% of a leveling agent, 0.1-0.5wt% of an anti-settling agent, 0.5-1.0wt% of a dispersant and 0.3-0.5wt% of a polymerization inhibitor. The unsaturated polyester varnish primer is suitable for finishing the base layer of various types of furniture, has the characteristics of high hardness, high fullness, strong adhesion, uneasily generation of bubbles or pin holes, uneasily cracking, easy polishing and good wood pore filling property; and the construction performance of the varnish primer provided by the invention is simpler than present polyurethane paint and unsaturated polyester paint mixing construction modes, and the film appearance effect is good.
Description
Technical field
The present invention relates to a kind of unsaturated polyester varnish, be specifically related to a kind of clear-coated for furniture bottom, the clear priming paint of unsaturated polyester of the dark wooden eyes such as the disposable filling Cortex Fraxini mandshuricae plate of energy.
Background technology
Now a lot of Furniture Factory is due to the pressure of cost, adds the singularity of ground, just can reach after thinking disposable application there is high, the high fullness ratio of hardness, the advantage such as sticking power is excellent, transparency is good, easy polishing.But other category product of existing market can not meet above demand completely, unsaturated polyester varnish can partly meet above demand, but easily occurs painting into not timber hole, floats over the situations such as the disadvantage of wooden hole surface.
Summary of the invention
The object of this invention is to provide a kind of high fullness ratio, height enters the clear priming paint of permeability unsaturated polyester, to solve the problem in prior art existing for woodwork coating.
Described high fullness ratio, height enter the clear priming paint of permeability unsaturated polyester, it is characterized in that, are made up of the host containing unsaturated polyester and Synolac, initiator, promotor and thinner, and weight proportion during construction is:
Host: thinner: initiator: promotor=100: 40: 0.8-2.5: 1-2.8.
Preferably, described host comprises the component of following weight percent:
Synolac 4.0% ~ 5.0%
Unsaturated polyester resin 60.0% ~ 65.0%
N-BUTYL ACETATE, cinnamic mixture 5.0% ~ 10.0%
Defoamer 0.1% ~ 0.3%
Flow agent 0.05% ~ 0.1%
Anti-settling agent 0. 1% ~ 0. 5%
Dispersion agent 0.5% ~ 1.0%
Stopper 0.3% ~ 0.5%
The per-cent sum of component is 100%.
It is the unsaturated polyester resin of JD3309 that described unsaturated polyester resin is preferably the Shanghai rich minister chemical industry trade mark;
It is the Synolac of JD16-70 that described Synolac is preferably the Shanghai rich minister chemical industry trade mark;
Described defoamer is preferably the peaceful BYK141 of section broken bubble polymkeric substance and polysiloxane solution;
Described flow agent is polyether-modified polydimethylsiloxane;
Described dispersion agent is the copolymer solution containing acidic-group;
Anti-settling agent is modified urea solution;
Described stopper is the quinol solution of weight 10 concentration %;
Described promotor is the cobalt iso-octoate of Shanghai long weathering EC-6 metallic cobalt content 6%;
Described initiator is the methylethyl ketone peroxide of weight 10 concentration %;
Described thinner is made up of the component of following weight percent:
N-BUTYL ACETATE 15.0% ~ 20.0%
Vinylbenzene 25.0% ~ 30.0
Toluene 50.0% ~ 55.0%
The per-cent sum of component is 100%.
Preparation method of the present invention is as follows:
Each component of host is mixed, obtains host;
Each component of thinner is mixed, obtains thinner;
When constructing, host, thinner, initiator and promotor are proportionally mixed.
The present invention is in order to reduce furniture painting cost, the main unsaturated polyester resin high rigidity utilized in formula, but the feature that snappiness is poor, and Synolac consistency is good, snappiness is good, fullness ratio good etc. feature, the performance characteristics of two kinds of different resins is made to combine and make a kind of coating, effectively can solve construction complicacy, problem that cost is high, and product height fullness ratio, grinability is good, high rigidity, fillibility is good, enters wooden eye excellent, is suitable for very much the painting of the bottoms such as various furniture and showcase.
The beneficial effect that the present invention adopts above-mentioned technical solution to reach is:
The bottom that product of the present invention is applicable to various furniture is covered with paint, lacquer, colour wash, etc.Application mode adopts manual spray.Product has that hardness is high, fullness ratio good, strong adhesion, not easily produce the features such as bubble and pin hole, polishing not easy to crack, easy, graving piece eye are good, and compares polyurethane paint used and unsaturated polyester varnish in the market and mix mode that proportioning constructs and have more simple workability, and appearance of film effect.
Embodiment
In embodiment, if no special instructions, component is weight ratio.
Defoamer is the peaceful BYK141 of section broken bubble polymkeric substance and polysiloxane solution;
Flow agent is the Bi Ke company trade mark is the polyether-modified polydimethylsiloxane of BYK333;
Described dispersion agent is the Bi Ke company trade mark is BYK110 wetting dispersing agent, and chemistry is called the copolymer solution containing acidic-group;
The modified urea solution of anti-settling agent to be company of the Bi Ke company trade mark be BYK410;
Described stopper is the quinol solution of 10% concentration;
Described promotor is the cobalt iso-octoate of Shanghai long weathering EC-6 metallic cobalt content 6%;
Described initiator is the methylethyl ketone peroxide of 10% concentration;
Embodiment 1
High fullness ratio, height enter the clear priming paint of unsaturated polyester of permeability, comprise paint host, initiator, promotor, thinner.
Paint host component and weight proportion as follows:
Synolac 5%, unsaturated polyester resin 60%, N-BUTYL ACETATE 5%, vinylbenzene 5%, defoamer 0.3%, flow agent 0.3%, dispersion agent 0.3%, anti-settling agent 0.1%, stopper 0.5%;
Described thinner composition proportioning is: N-BUTYL ACETATE 15.0%, vinylbenzene 25.0%, toluene 50.0%.
The method of preparation:
Each component of host is mixed, obtains host;
Each component of thinner is mixed, obtains thinner;
When constructing, host, thinner, initiator and promotor are proportionally mixed.
Construction proportioning:
Host: thinner: initiator: promotor=100:40:0.8-2.5:1-2.8.
Form of construction work: manual spray.
According to " LYT--1740-2008 woodenware unsaturated polyester varnish " standard, actual detection data are as follows:
1, former paint outward appearance thick liquid, mechanical impurity
2, main paint solids content 90%
3, surface drying time (25 DEG C) 30min
4, (25 DEG C) 10h is done solid work the time
5, paint film appearance is transparent in, smooth morbid state
6, sticking power (cross-hatching) 1 grade
7, gelation time 20min
8, limits of harmful substances (dissoluble lead, cadmium, chromium, mercury) does not detect
9, sag prevention (22 seconds/25 DEG C, 2# cup) 200um
10, pencil hardness (scratch) 2H
11, sticking power (drawing compartment apart from 2mm)≤1 grade
12, grinability (12h) is easily polished
14, the paint film transparency is good
Embodiment 2
The clear end in unsaturated high fullness ratio height graving piece hole, comprise paint host, initiator, promotor, thinner.Paint host component and weight proportion as follows: Synolac 5%, unsaturated polyester resin 65%, N-BUTYL ACETATE 5%, vinylbenzene 25%, defoamer 0.3%, flow agent 0.3%, dispersion agent 0.3%, anti-settling agent 0.1%, stopper 0.2%.Described initiator is the methylethyl ketone peroxide of oxygen level 10%.Described thinner composition proportioning is: N-BUTYL ACETATE 20.0%, vinylbenzene 20.0%, toluene 60.0%, construction proportioning: host: thinner: initiator: promotor=100:40:0.8-2.5:2.8.Form of construction work: manual spray.
The other the same as in Example 1.
According to " LYT--1740-2008 woodenware unsaturated polyester varnish " standard, actual detection data are as follows:
1, former paint outward appearance thick liquid, mechanical impurity
2, main paint solids content 95%
3, surface drying time (25 DEG C) 32min
4, (25 DEG C) 11h is done solid work the time
5, paint film appearance is transparent in, smooth morbid state
6, sticking power (cross-hatching) 1 grade
7, gelation time 20min
8, limits of harmful substances (dissoluble lead, cadmium, chromium, mercury) does not detect
9, sag prevention (22 seconds/25 DEG C, 2# cup) 200um
10, pencil hardness (scratch) 2H
11, sticking power (drawing compartment apart from 2mm)≤1 grade
12, grinability (12h) is easily polished
14, the paint film transparency is good.
Claims (6)
1. high fullness ratio, height enter the clear priming paint of permeability unsaturated polyester, it is characterized in that, be made up of the host containing unsaturated polyester and Synolac, initiator, promotor and thinner, weight proportion during construction is: host: thinner: initiator: promotor=100: 40: 0.8-2.5: 1-2.8.
2. high fullness ratio according to claim 1, height enter the clear priming paint of permeability unsaturated polyester, and it is characterized in that, described host comprises the component of following weight percent:
Synolac 4.0% ~ 5.0%
Unsaturated polyester resin 60.0% ~ 65.0%
N-BUTYL ACETATE, cinnamic mixture 5.0% ~ 10.0%
Defoamer 0.1% ~ 0.3%
Flow agent 0.05% ~ 0.1%
Anti-settling agent 0. 1% ~ 0. 5%
Dispersion agent 0.5% ~ 1.0%
Stopper 0.3% ~ 0.5%
The per-cent sum of component is 100%.
3. high fullness ratio according to claim 2, height enter the clear priming paint of permeability unsaturated polyester, it is characterized in that, described defoamer is broken bubble polymkeric substance and polysiloxane solution;
Described flow agent is polyether-modified polydimethylsiloxane;
The copolymer solution for containing acidic-group of described dispersion agent;
Described anti-settling agent is modified urea solution;
Described stopper is the quinol solution of weight concentration 10%.
4. high fullness ratio according to claim 1, height enter the clear priming paint of permeability unsaturated polyester, and it is characterized in that, described thinner is made up of the component of following weight percent:
N-BUTYL ACETATE 15.0% ~ 20.0%
Vinylbenzene 25.0% ~ 30.0
Toluene 50.0% ~ 55.0%
The per-cent sum of component is 100%.
5. high fullness ratio according to claim 1, height enter the clear priming paint of permeability unsaturated polyester, it is characterized in that, described promotor is the cobalt iso-octoate of EC-6 metallic cobalt content 6%.
6. high fullness ratio according to claim 1, height enter the clear priming paint of permeability unsaturated polyester, it is characterized in that, described initiator is the methylethyl ketone peroxide of weight concentration 10%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310540148.XA CN104610853A (en) | 2013-11-05 | 2013-11-05 | Unsaturated polyester varnish primer with high fullness and high pore access property |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310540148.XA CN104610853A (en) | 2013-11-05 | 2013-11-05 | Unsaturated polyester varnish primer with high fullness and high pore access property |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104610853A true CN104610853A (en) | 2015-05-13 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310540148.XA Pending CN104610853A (en) | 2013-11-05 | 2013-11-05 | Unsaturated polyester varnish primer with high fullness and high pore access property |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104610853A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105219237A (en) * | 2015-10-23 | 2016-01-06 | 青岛展辰新材料有限公司 | The special unsaturated pair of curing polyester light black flour paint of a kind of musical instrument |
| CN105925152A (en) * | 2016-05-09 | 2016-09-07 | 江苏凯特尔新型复合饰材有限公司 | Production process of metal printing plate roll coated with nano ceramic paint in advance |
| CN106280930A (en) * | 2015-06-11 | 2017-01-04 | 上海福岛化工科技发展有限公司 | Water alcohol acid aerosol finish paint and preparation method thereof |
| CN106752778A (en) * | 2016-12-01 | 2017-05-31 | 展辰新材料集团股份有限公司 | A kind of unsaturated polyester (UP) based white primer |
| CN111073436A (en) * | 2019-12-20 | 2020-04-28 | 珠海展辰新材料股份有限公司 | Unsaturated polyester varnish |
| CN111534203A (en) * | 2020-05-18 | 2020-08-14 | 上海大宝化工制品有限公司 | Unsaturated polyester high-filling white primer for melamine laminated cabinet and preparation method thereof |
Citations (4)
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| CN101705048A (en) * | 2009-11-02 | 2010-05-12 | 深圳市广田环保涂料有限公司 | Highly transparent unsaturated polyester primer and preparation method as well as use method thereof |
| CN101760119A (en) * | 2009-11-06 | 2010-06-30 | 黄宏亭 | Anti-impact and anti-yellowing wood lacquer |
| CN102719181A (en) * | 2012-05-11 | 2012-10-10 | 北京展辰化工有限公司 | Priming paint with absorption resistance, preparation method and application |
| CN103045054A (en) * | 2012-12-12 | 2013-04-17 | 澳达树熊涂料(惠州)有限公司 | High-hardness white unsaturated polyester priming paint and preparation method thereof |
-
2013
- 2013-11-05 CN CN201310540148.XA patent/CN104610853A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101705048A (en) * | 2009-11-02 | 2010-05-12 | 深圳市广田环保涂料有限公司 | Highly transparent unsaturated polyester primer and preparation method as well as use method thereof |
| CN101760119A (en) * | 2009-11-06 | 2010-06-30 | 黄宏亭 | Anti-impact and anti-yellowing wood lacquer |
| CN102719181A (en) * | 2012-05-11 | 2012-10-10 | 北京展辰化工有限公司 | Priming paint with absorption resistance, preparation method and application |
| CN103045054A (en) * | 2012-12-12 | 2013-04-17 | 澳达树熊涂料(惠州)有限公司 | High-hardness white unsaturated polyester priming paint and preparation method thereof |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106280930A (en) * | 2015-06-11 | 2017-01-04 | 上海福岛化工科技发展有限公司 | Water alcohol acid aerosol finish paint and preparation method thereof |
| CN105219237A (en) * | 2015-10-23 | 2016-01-06 | 青岛展辰新材料有限公司 | The special unsaturated pair of curing polyester light black flour paint of a kind of musical instrument |
| CN105925152A (en) * | 2016-05-09 | 2016-09-07 | 江苏凯特尔新型复合饰材有限公司 | Production process of metal printing plate roll coated with nano ceramic paint in advance |
| CN106752778A (en) * | 2016-12-01 | 2017-05-31 | 展辰新材料集团股份有限公司 | A kind of unsaturated polyester (UP) based white primer |
| CN111073436A (en) * | 2019-12-20 | 2020-04-28 | 珠海展辰新材料股份有限公司 | Unsaturated polyester varnish |
| CN111534203A (en) * | 2020-05-18 | 2020-08-14 | 上海大宝化工制品有限公司 | Unsaturated polyester high-filling white primer for melamine laminated cabinet and preparation method thereof |
| CN111534203B (en) * | 2020-05-18 | 2021-08-06 | 上海大宝化工制品有限公司 | Unsaturated polyester high-filling white primer for melamine laminated cabinet and preparation method thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C53 | Correction of patent of invention or patent application | ||
| CB02 | Change of applicant information |
Address after: 8555 No. 201707 Shanghai city Qingpu District Songze Avenue Applicant after: Shanghai Zhanchen Paint Co., Ltd. Applicant after: Zhanchen Coatings Group Co., Ltd. Applicant after: Beijing Zhanchen Chemical Industry Co., Ltd. Applicant after: Qingdao Zhan Chen novel material company limited Applicant after: Chengdu Zhanchen Chemical Co., Ltd. Address before: 8555 No. 201707 Shanghai city Qingpu District Songze Avenue Applicant before: Shanghai Fuchen Chemical Co., Ltd. Applicant before: Zhanchen Coatings Group Co., Ltd. Applicant before: Beijing Zhanchen Chemical Industry Co., Ltd. Applicant before: Qingdao Fuchen Chemical Co., Ltd. Applicant before: Chengdu Zhanchen Chemical Co., Ltd. |
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| COR | Change of bibliographic data |
Free format text: CORRECT: APPLICANT; FROM: SHANGHAI FUCHEN CHEMICAL CO. LTD. TO: SHANGHAI ZHANCHEN PAINT CO., LTD. Free format text: CORRECT: APPLICANT; FROM: ZHANCHEN COATINGS GROUP CO., LTD. BEIJING ZHANCHEN CHEMICAL INDUSTRY CO., LTD. QINGDAO VISION CHEMICAL CO., LTD. CHENGDU ZHANCHEN CHEMICAL CO., LTD. TO: ZHANCHEN COATINGS GROUP CO., LTD. BEIJING ZHANCHEN CHEMICAL INDUSTRY CO., LTD. QINGDAO ZHANCHEN NEW MATERIAL CO., LTD. CHENGDU ZHANCHEN CHEMICAL CO., LTD. |
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| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information |
Address after: 8555 No. 201707 Shanghai city Qingpu District Songze Avenue Applicant after: Shanghai Zhanchen Paint Co., Ltd. Applicant after: CHINA ZHANCHEN PAINTS GROUP LTD. Applicant after: Beijing Zhan Chen novel material company limited Applicant after: Qingdao Zhan Chen novel material company limited Applicant after: Chengdu Zhan Chen coating company limited Address before: 8555 No. 201707 Shanghai city Qingpu District Songze Avenue Applicant before: Shanghai Zhanchen Paint Co., Ltd. Applicant before: Zhanchen Coatings Group Co., Ltd. Applicant before: Beijing Zhanchen Chemical Industry Co., Ltd. Applicant before: Qingdao Zhan Chen novel material company limited Applicant before: Chengdu Zhanchen Chemical Co., Ltd. |
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| COR | Change of bibliographic data | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20150513 |
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| WD01 | Invention patent application deemed withdrawn after publication |