CN104293127A - Special unsaturated polyester clear primer for musical instrument - Google Patents

Special unsaturated polyester clear primer for musical instrument Download PDF

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Publication number
CN104293127A
CN104293127A CN201410659969.XA CN201410659969A CN104293127A CN 104293127 A CN104293127 A CN 104293127A CN 201410659969 A CN201410659969 A CN 201410659969A CN 104293127 A CN104293127 A CN 104293127A
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CN
China
Prior art keywords
unsaturated polyester
musical instrument
clear primer
special
initiator
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410659969.XA
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Chinese (zh)
Inventor
李文艳
刘志刚
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHENGDU ZHANCHEN CHEMICAL Co Ltd
Qingdao Zhan Chen Novel Material Co Ltd
SHANGHAI ZHANCHEN PAINT Co Ltd
Beijing Zhanchen Chemical Co Ltd
Zhanchen Paint Group Co Ltd
Original Assignee
CHENGDU ZHANCHEN CHEMICAL Co Ltd
Qingdao Zhan Chen Novel Material Co Ltd
SHANGHAI ZHANCHEN PAINT Co Ltd
Beijing Zhanchen Chemical Co Ltd
Zhanchen Paint Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by CHENGDU ZHANCHEN CHEMICAL Co Ltd, Qingdao Zhan Chen Novel Material Co Ltd, SHANGHAI ZHANCHEN PAINT Co Ltd, Beijing Zhanchen Chemical Co Ltd, Zhanchen Paint Group Co Ltd filed Critical CHENGDU ZHANCHEN CHEMICAL Co Ltd
Priority to CN201410659969.XA priority Critical patent/CN104293127A/en
Publication of CN104293127A publication Critical patent/CN104293127A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/06Unsaturated polyesters having carbon-to-carbon unsaturation
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/20Diluents or solvents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention relates to a special unsaturated polyester clear primer for a musical instrument. The special unsaturated polyester clear primer is characterized by consisting of a main agent containing unsaturated polyester and alkyd resin, an initiator, an accelerant and a diluent, wherein the main agent comprises the following heavy components: a mixture of the alkyd resin, unsaturated polyester resin, n-butyl acetate and styrene, an antifoaming agent, a levelling agent, an anti-settling agent, a dispersing agent and a polymerization inhibitor; the accelerant is cobalt iso-octoate with 6 percent of EC-6 metal cobalt; the initiator is methyl ethyl ketone peroxide; the diluent consists of the following components: n-butyl acetate, styrene and methylbenzene. By adopting the technical scheme, the special unsaturated polyester clear primer for the musical instrument has the following benefits: the special unsaturated polyester clear primer is suitable for coating of bottom layers of various musical instruments, and is coated in a manual spraying or brushing manner; the special unsaturated polyester clear primer has the characteristics of high hardness, good fullness, strong adhesive force, low possibility of generation of bubbles and pinholes, low possibility of cracking, easiness in polishing, good performance of filling wooden eyes, excellent punching effects and the like; moreover, compared with a mode that polyurethane paint and unsaturated polyester paint are mixed according to a ratio for construction in the market at present, the special unsaturated polyester clear primer for the musical instrument has simpler construction performance and a better coating appearance effect.

Description

The clear priming paint of unsaturated polyester special on a kind of musical instrument
Technical field
The present invention relates to a kind of unsaturated polyester varnish, being specifically related to one, to be exclusively used in bottom on musical instrument clear-coated, can meet the clear priming paint of unsaturated polyester of present musical instrument (as guitar etc.).
Background technology
Now a lot of musical instruments factory is due to every pressure, adds the singularity of the ground of musical instrument, thinks disposable or just can reach advantages such as having high, the high fullness ratio of hardness, sticking power excellence, good, the easy polishing of transparency, easy punching after repeatedly application.But other category product of existing market can not meet above demand completely, unsaturated polyester varnish can partly meet above demand, but easily occurs painting into not timber hole, floats over wooden hole surface, easily collapses the situations such as the disadvantage on limit during punching.Urgently existing musical instrument unsaturated polyester varnish is improved, invent and a kind ofly can meet the clear priming paint of unsaturated polyester special on musical instrument, to overcome the problems referred to above.
Summary of the invention
The object of this invention is to provide the clear priming paint of a kind of special unsaturated polyester on musical instrument, to solve the problem in prior art existing for woodwork coating.The present invention designs the clear priming paint of unsaturated polyester special on a kind of musical instrument, it is characterized in that, be made up of the host containing unsaturated polyester and Synolac, initiator, promotor and thinner, host: thinner: initiator: the weight ratio of promotor is 100: 40: 0.8-2.5: 1-2.8;
Preferably, described host comprises the component of following weight percent:
Synolac 5.0% ~ 7.0%,
Unsaturated polyester resin 80.6% ~ 85.0%,
N-BUTYL ACETATE, cinnamic mixture 5.0% ~ 10.0%, (N-BUTYL ACETATE: vinylbenzene=1:1)
Defoamer 0.1% ~ 0.3%,
Flow agent 0.05% ~ 0.1%,
Anti-settling agent 0. 1% ~ 0. 5%,
Dispersion agent 0.5% ~ 1.0%,
Stopper 0.3% ~ 0.5%,
The per-cent sum of component is 100%;
It is the unsaturated polyester resin of JD3309 that described unsaturated polyester resin is preferably the Bugle occasion chemical industry trade mark; Or on market sell the unsaturated polyester resin bought.
It is the Synolac of JD16-70 that described Synolac is preferably the Shanghai rich minister chemical industry trade mark; Or on market sell the Synolac bought.
Described defoamer is preferably EFKA2720 broken bubble polymkeric substance and polysiloxane solution;
Described flow agent is preferably as the polyether-modified polydimethylsiloxane of BYK333;
Described dispersion agent is preferably as BYK110 wetting dispersing agent;
Anti-settling agent is the modified urea solution of BYK410;
Described stopper is quinol solution;
Described promotor is the cobalt iso-octoate of EC-6 metallic cobalt content 6%;
Described initiator is methylethyl ketone peroxide;
Described thinner is made up of the component of following weight percent:
Described thinner is made up of the component of following weight percent:
N-BUTYL ACETATE 15.0% ~ 25.0%,
Vinylbenzene 25.0% ~ 30.0%,
Toluene 50.0% ~ 55.0%,
The per-cent sum of component is 100%;
Preparation method of the present invention is as follows:
Each component of host is mixed, obtains host;
Each component of thinner is mixed, obtains thinner;
When constructing, host, thinner, initiator and promotor are proportionally mixed.
The present invention is in order to meet application demand on musical instrument, the main unsaturated polyester resin high rigidity utilized in formula, but the feature that snappiness is poor, and Synolac consistency is good, snappiness is good, fullness ratio good etc. feature, the performance characteristics of two kinds of different resins is made to combine and make a kind of coating, can effectively solve construction complicacy, the problem of high-flexibility, and product height fullness ratio, grinability is good, high rigidity, fillibility is good, enter wooden eye excellent effect, ready-made musical instrument has splendid punching performance, limit is not collapsed after punching, the feature such as do not ftracture, be suitable for very much the painting of the bottoms such as various musical instruments.
The beneficial effect that the present invention adopts above-mentioned technical solution to reach is: the bottom that product is applicable on various musical instrument is covered with paint, lacquer, colour wash, etc.Application mode adopts manual spray or brushing.Product has that hardness is high, fullness ratio good, strong adhesion, not easily produce the feature such as bubble and pin hole, polishing not easy to crack, easy, punching effect that graving piece eye is good, splendid, and compares polyurethane paint used and unsaturated polyester varnish in the market and mix mode that proportioning constructs and have more simple workability, and appearance of film effect.
Embodiment
The clear priming paint of unsaturated polyester special on musical instrument, is characterized in that, is made up of, host: thinner: initiator: promotor=100: 40: 0.8-2.5: 1-2.8 the host containing unsaturated polyester and Synolac, initiator, promotor and thinner;
Preferably, described host comprises the component of following weight percent:
Synolac 5.0% ~ 7.0%,
Unsaturated polyester resin 80.6% ~ 85.0%,
N-BUTYL ACETATE, cinnamic mixture 5.0% ~ 10.0%, (N-BUTYL ACETATE: vinylbenzene=1:1)
Defoamer 0.1% ~ 0.3%,
Flow agent 0.05% ~ 0.1%,
Anti-settling agent 0. 1% ~ 0. 5%,
Dispersion agent 0.5% ~ 1.0%,
Stopper 0.3% ~ 0.5%,
The per-cent sum of component is 100%;
It is the unsaturated polyester resin of JD3309 that described unsaturated polyester resin is preferably the Bugle occasion chemical industry trade mark; Or on market sell the unsaturated polyester resin bought.
It is the Synolac of JD16-70 that described Synolac is preferably the Shanghai rich minister chemical industry trade mark; Or on market sell the Synolac bought.
Described defoamer is preferably EFKA2720 broken bubble polymkeric substance and polysiloxane solution;
Described flow agent is preferably as the polyether-modified polydimethylsiloxane of BYK333;
Described dispersion agent is preferably as BYK110 wetting dispersing agent;
Anti-settling agent is the modified urea solution of BYK410;
Described stopper is quinol solution;
Described promotor is the cobalt iso-octoate of EC-6 metallic cobalt content 6%;
Described initiator is methylethyl ketone peroxide;
Described thinner is made up of the component of following weight percent:
N-BUTYL ACETATE 15.0% ~ 25.0%,
Vinylbenzene 25.0% ~ 30.0%,
Toluene 50.0% ~ 55.0%,
The per-cent sum of component is 100%;
Preparation method of the present invention is as follows:
Each component of host is mixed, obtains host;
Each component of thinner is mixed, obtains thinner;
When constructing, host, thinner, initiator and promotor are proportionally mixed.
Embodiment 1
The clear priming paint of unsaturated polyester special on musical instrument, comprises paint host, initiator, promotor, thinner.
Described host following (1 part weight 1 kilogram):
Synolac 7 parts, unsaturated polyester resin 81.3 parts, N-BUTYL ACETATE and styrene solution 10 parts, defoamer 0.2 part, flow agent 0.2 part, dispersion agent 0.3 part, anti-settling agent 0.7 part, stopper 0.3 part; Obtain double centner.
Described thinner composition proportioning is: N-BUTYL ACETATE 15 parts, vinylbenzene 35 parts, toluene 50 parts, obtain double centner.
Get promotor 1 kilogram (cobalt iso-octoate of EC-6 metallic cobalt content 6%), get initiator 0.8 kilogram (methylethyl ketone peroxide).
The method of preparation:
Each component of host is mixed, obtains host;
Each component of thinner is mixed, obtains thinner;
When constructing, host, thinner, initiator and promotor are proportionally mixed.
Construction proportioning:
Host: thinner: initiator: the weight ratio of promotor is 100:40:0.8:1.
Form of construction work: manual spray.
According to " LYT--1740-2008 woodenware unsaturated polyester varnish " standard, actual detection data are as follows:
1, former paint outward appearance thick liquid, mechanical impurity
2, main paint solids content 90%
3, surface drying time (25 DEG C) 30min
4, (25 DEG C) 10h is done solid work the time
5, paint film appearance is transparent in, smooth morbid state
6, sticking power (cross-hatching) 1 grade
7, gelation time 20min
8, limits of harmful substances (dissoluble lead, cadmium, chromium, mercury) does not detect
9, sag prevention (22 seconds/25 DEG C, 2# cup) 200um
10, pencil hardness (scratch) 2H
11, sticking power (drawing compartment apart from 2mm)≤1 grade
12, grinability (12h) is easily polished
14, the paint film transparency is good
Embodiment 2
The special undersaturated clear end on a kind of musical instrument, comprise paint host, initiator, promotor, thinner.Paint host component and weight proportion following (1 part of weight is 1 kilogram): Synolac 5 parts, unsaturated polyester resin 85 parts, N-BUTYL ACETATE and styrene solution 8.3 parts, defoamer 0.1 part, flow agent 0.1 part, dispersion agent 0.5 part, anti-settling agent 0.5 part, stopper 0.5 part, obtain double centner host.
Described initiator is the methylethyl ketone peroxide 2.5 kilograms of oxygen level 10%, promotor 2.8 kilograms (cobalt iso-octoate of EC-6 metallic cobalt content 6%)
Described thinner composition proportioning is (1 part of weight is 1 kilogram): N-BUTYL ACETATE 20.0 parts, vinylbenzene 30.0 parts, toluene 50.0 parts, obtain double centner.
Construction proportioning: host: thinner: initiator: the weight ratio of promotor is 100:40:2.5:2.8.Form of construction work: manual spray.
The other the same as in Example 1.
According to " LYT--1740-2008 woodenware unsaturated polyester varnish " standard, actual detection data are as follows:
1, former paint outward appearance thick liquid, mechanical impurity
2, main paint solids content 95%
3, surface drying time (25 DEG C) 32min
4, (25 DEG C) 11h is done solid work the time
5, paint film appearance is transparent in, smooth morbid state
6, sticking power (cross-hatching) 1 grade
7, gelation time 20min
8, limits of harmful substances (dissoluble lead, cadmium, chromium, mercury) does not detect
9, sag prevention (22 seconds/25 DEG C, 2# cup) 200um
10, pencil hardness (scratch) 2H
11, sticking power (drawing compartment apart from 2mm)≤1 grade
12, grinability (12h) is easily polished
14, the paint film transparency is good.

Claims (1)

1. the clear priming paint of unsaturated polyester special on a musical instrument, it is characterized in that, be made up of the host containing unsaturated polyester and Synolac, initiator, promotor and thinner, host: thinner: initiator: the weight ratio of promotor is 100: 40: 0.8-2.5: 1-2.8;
Described host comprises the component of following weight percent:
Synolac 5.0% ~ 7.0%,
Unsaturated polyester resin 80.6% ~ 85.0%,
N-BUTYL ACETATE and vinylbenzene press the mixture 5.0% ~ 10.0% of 1:1,
Defoamer 0.1% ~ 0.3%,
Flow agent 0.05% ~ 0.1%,
Anti-settling agent 0. 1% ~ 0. 5%,
Dispersion agent 0.5% ~ 1.0%,
Stopper 0.3% ~ 0.5%,
The per-cent sum of component is 100%;
Described thinner is made up of the component of following weight percent:
N-BUTYL ACETATE 15.0% ~ 25.0%,
Vinylbenzene 25.0% ~ 30.0%,
Toluene 50.0% ~ 55.0%,
The per-cent sum of component is 100%;
Described promotor is the cobalt iso-octoate of EC-6 metallic cobalt content 6%,
Described initiator is methylethyl ketone peroxide.
CN201410659969.XA 2014-11-19 2014-11-19 Special unsaturated polyester clear primer for musical instrument Pending CN104293127A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410659969.XA CN104293127A (en) 2014-11-19 2014-11-19 Special unsaturated polyester clear primer for musical instrument

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410659969.XA CN104293127A (en) 2014-11-19 2014-11-19 Special unsaturated polyester clear primer for musical instrument

Publications (1)

Publication Number Publication Date
CN104293127A true CN104293127A (en) 2015-01-21

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Family Applications (1)

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Country Status (1)

Country Link
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105111902A (en) * 2015-10-09 2015-12-02 广东顺德漆强化工科技有限公司 Wax-free piano varnish and preparation method
CN105219237A (en) * 2015-10-23 2016-01-06 青岛展辰新材料有限公司 The special unsaturated pair of curing polyester light black flour paint of a kind of musical instrument
CN111500168A (en) * 2020-05-18 2020-08-07 上海大宝化工制品有限公司 Paint for melamine laminated cabinet and coating method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101705048A (en) * 2009-11-02 2010-05-12 深圳市广田环保涂料有限公司 Highly transparent unsaturated polyester primer and preparation method as well as use method thereof
CN101760119A (en) * 2009-11-06 2010-06-30 黄宏亭 Anti-impact and anti-yellowing wood lacquer
CN103045054A (en) * 2012-12-12 2013-04-17 澳达树熊涂料(惠州)有限公司 High-hardness white unsaturated polyester priming paint and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101705048A (en) * 2009-11-02 2010-05-12 深圳市广田环保涂料有限公司 Highly transparent unsaturated polyester primer and preparation method as well as use method thereof
CN101760119A (en) * 2009-11-06 2010-06-30 黄宏亭 Anti-impact and anti-yellowing wood lacquer
CN103045054A (en) * 2012-12-12 2013-04-17 澳达树熊涂料(惠州)有限公司 High-hardness white unsaturated polyester priming paint and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105111902A (en) * 2015-10-09 2015-12-02 广东顺德漆强化工科技有限公司 Wax-free piano varnish and preparation method
CN105219237A (en) * 2015-10-23 2016-01-06 青岛展辰新材料有限公司 The special unsaturated pair of curing polyester light black flour paint of a kind of musical instrument
CN111500168A (en) * 2020-05-18 2020-08-07 上海大宝化工制品有限公司 Paint for melamine laminated cabinet and coating method thereof
CN111500168B (en) * 2020-05-18 2021-08-06 上海大宝化工制品有限公司 Paint for melamine laminated cabinet and coating method thereof

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Address after: 8555 No. 201707 Shanghai city Qingpu District Songze Avenue

Applicant after: Shanghai Zhanchen Paint Co., Ltd.

Applicant after: CHINA ZHANCHEN PAINTS GROUP LTD.

Applicant after: Beijing Zhan Chen novel material company limited

Applicant after: Qingdao Zhan Chen novel material company limited

Applicant after: Chengdu Zhan Chen coating company limited

Address before: 8555 No. 201707 Shanghai city Qingpu District Songze Avenue

Applicant before: Shanghai Zhanchen Paint Co., Ltd.

Applicant before: Zhanchen Coatings Group Co., Ltd.

Applicant before: Beijing Zhanchen Chemical Industry Co., Ltd.

Applicant before: Qingdao Zhan Chen novel material company limited

Applicant before: Chengdu Zhanchen Chemical Co., Ltd.

COR Change of bibliographic data
C10 Entry into substantive examination
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WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20150121

WD01 Invention patent application deemed withdrawn after publication