CN109233563A - A kind of normal temperature quick-drying type water-based epoxy zinc-rich primer and its preparation process - Google Patents
A kind of normal temperature quick-drying type water-based epoxy zinc-rich primer and its preparation process Download PDFInfo
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- CN109233563A CN109233563A CN201810903088.6A CN201810903088A CN109233563A CN 109233563 A CN109233563 A CN 109233563A CN 201810903088 A CN201810903088 A CN 201810903088A CN 109233563 A CN109233563 A CN 109233563A
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- Prior art keywords
- normal temperature
- rich primer
- zinc
- based epoxy
- type water
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
- C09D5/106—Anti-corrosive paints containing metal dust containing Zn
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to a kind of normal temperature quick-drying type water-based epoxy zinc-rich primer and its preparation processes, using aqueous epoxy resins, aqueous epoxy curing agent as main base, match with zinc powder, filler, auxiliary agent, cosolvent, water etc., and the processes such as ground, dispersion are process.Water-based epoxy zinc-rich primer scene mixing of the invention will not generate dust, and environmental protection is harmless；Scene mixing is easy, it is only necessary to which simple agitation can be uniformly mixed；Safe and convenient to use, no pollution to the environment is harmless to construction personnel's health；It can be constructed by the way of airless spraying, compressed air spraying, roller coating, easy for construction, raising construction efficiency, paint film high mechanical strength, early stage wearability are good, adhesive force is strong, antiseptic property is excellent, it is applicable to the anti-corrosion and protection of the occasions such as ship, bridge steel structure, container, can also be used as shop primer use.
Description
[technical field]
It is especially a kind of for the water-thinned epoxy zinc-rich shop primer of container and its preparation the present invention relates to a kind of coating
Technique.
[background technique]
Traditional coating container is mostly solvent based coating, and common kind has epoxy, chlorinated rubber, acrylic acid, poly- ammonia
Ester etc., wherein containing a large amount of organic solvent, these solvents are harmful to construction personnel's health and pollute environment.Foreign countries were from 70 years
In generation, has just just carried out the environmentally friendly antiseptic and rustproof paint such as high solid, solvent-free, powder and water paint and has developed, wherein aqueous
For paint because cost is relatively low, construction safety is convenient, and film thickness is easy to control, and obtains more research.But because technical difficulty is larger, long-term is not
Obtain big progress.Since the mid-80, countries in the world legislations of environmental protection contains volatile organic solvent in coating (VOC)
The limitation of amount is increasingly strict, the upsurge for causing water-based anticorrosive paint to be studied.
Domestic and international existing aqueous heavy-d uty system priming paint has aqueous inorganic zinc-rich, water-based epoxy zinc-rich primer.Aqueous nothing
The antiseptic property of machine zinc rich primer is excellent, but harsher to ground processing, construction environment, the requirement of mating coating, such as ground
It is required that passing through blasting treatment or 2.5 grades of hand cleaning；Ambient humidity requires to be greater than 50%；Mating coating needs can be resistant to inorganic silicon
The strong basicity of hydrochlorate, it is desirable that have bottom closing paint in order to avoid there are a large amount of bubbles；Therefore certain use occasions limit its application.Such as
Container shop primer requires construction rhythm fast, and baking time is short, general only to be stacked within 90 seconds or so, existing water
Property epoxy zinc rich primer is unable to reach this requirement.
[summary of the invention]
It is an object of the invention in view of the above deficiencies, provide, a kind of antiseptic property is good, rate of drying is fast, surface initial stage is hard
Degree establishes fast water-based epoxy zinc-rich primer.
The technical solution of the present invention is as follows: a kind of water-based epoxy zinc-rich primer, including component A and B component,
Wherein component A includes:
Wherein B component includes:
65~75wt% of aqueous epoxy resins,
25~35wt% of softened water；
Component A and B component mass ratio are 100:28.
Preferably, the aqueous epoxy curing agent is that solid part changes for the fatty amine modification of 70~80wt% or polyamide
The aqueous epoxy curing agent of property.
Preferably, the zinc powder is the zinc powder that dry film content is 80wt%, wherein water-soluble substances content < 0.5wt%.
Preferably, the cosolvent can be one or more of propylene glycol monomethyl ether, butyl glycol ether, isopropanol
Mixture: its content is 8~15wt%.
Preferably, the anti-settling agent is one or more of fumed silica, cellaburate, modified urea solution
Mixture.
Preferably, the aqueous epoxy resins are the aqueous epoxy emulsions that solid part is 50-60wt%；
Preferably, the neutralizer is volatile organic amines.
Water-based epoxy zinc-rich primer scene mixing of the invention will not generate dust, and environmental protection is harmless；Scene mixing
It is easy, it is only necessary to which simple agitation can be uniformly mixed；It is safe and convenient to use, no pollution to the environment, to construction personnel's health
It is harmless；It can be constructed by the way of airless spraying, compressed air spraying, roller coating, easy for construction, raising construction effect
Rate；Air drying speed only needs that next process can be carried out within tens seconds fastly e.g. to stack, punching press etc., paint film mechanical strength
Height, early stage wearability are good, and adhesive force is strong, and antiseptic property is excellent, is applicable to the occasions such as ship, bridge steel structure, container
Anti-corrosion and protection can also be used as shop primer use.
[specific embodiment]
Technical solution of the present invention is further elaborated now in conjunction with embodiment, it is believed that be for a person skilled in the art
Clearly.
If table 1 is the embodiment of the present invention, wherein each component content is mass percentage, but the invention is not limited to
Following instance.
Table 1
In table 1, aqueous epoxy curing agent can equally replace with the fatty amine that other solid parts are 70~80wt% and change
The aqueous epoxy curing agent of property；Propylene glycol monomethyl ether can equally replace with acetone；The graceful epoxy emulsion 3961-1 of Hensel can be waited
Replace with to amount the water-base epoxy dispersion or aqueous epoxy emulsion that other solid parts are 50~55wt%.
Table 2 is listed in by primer performance prepared by above-mentioned formula.Comparative example is the quick-dry type waterborne zinc-rich of the prior art in table 2
Priming paint.
Table 2
Paint preparation technology are as follows:
Component A:
1. part cosolvent, curing agent, dispersing agent, the defoaming agent accurately measured is added in a reservoir, neutralizer, use is adjustable
Formula high speed disperser stirs 5-10 minutes, and revolving speed is 400-600 revs/min.
2. fumed silica, 5A molecular sieve, titanium dioxide are added while stirring, stir 10-15 minutes, revolving speed 600-
800 revs/min, the rear sand mill that carries out is sanded to 20 μm of fineness.
3. walking the slurry of completion in taking-up, zinc is continuously added under the high speed disperser stirring that revolving speed is 600-800 revs/min
Powder, adding and promoting revolving speed is 800-1200 revs/min, is dispersed to 40 μm of fineness or less.
4. remaining cosolvent, cellaburate, anti-flash rusting agent, thickener, promotor, stirring 15-30 minutes, revolving speed is added
It is 600-800 revs/min.
5. with 100 mesh copper mesh or nylon net filter.
6. being packed with big mouth plastic barrel or tinplate bucket, finished product is obtained.
B component:
1. the aqueous epoxy resins accurately measured, softened water are added in a reservoir, 5- is stirred with adjustable high-speed dispersing agent
10 minutes, revolving speed was 400-600 revs/min.
2. with 100 mesh nylon net filters.
3. being packed with big mouth plastic barrel, finished product is obtained.
A, B component are mixed according to mass ratio 100:28 proportion when use, can be constructed after mixing evenly.
Claims (8)
1. a kind of normal temperature quick-drying type water-based epoxy zinc-rich primer, which is characterized in that including component A and B component,
Wherein component A includes:
Wherein B component includes:
65~75wt% of aqueous epoxy resins,
25~35wt% of softened water；
Component A and B component mass ratio are 100:28.
2. a kind of normal temperature quick-drying type water-based epoxy zinc-rich primer as described in claim 1, which is characterized in that the water-base epoxy
Curing agent is the fatty amine modification or polyamide modified aqueous epoxy curing agent that solid part is 70~80wt%.
3. a kind of normal temperature quick-drying type water-based epoxy zinc-rich primer as described in claim 1, which is characterized in that the zinc powder is dry
Film content is the zinc powder of 80wt%, wherein water-soluble substances content < 0.5wt%.
4. a kind of normal temperature quick-drying type water-based epoxy zinc-rich primer as described in claim 1, which is characterized in that the cosolvent is
The mixture of one or more of propylene glycol monomethyl ether, butyl glycol ether, isopropanol: its content is 8~15wt%.
5. a kind of normal temperature quick-drying type water-based epoxy zinc-rich primer as described in claim 1, it is characterised in that: the anti-settling agent is
The mixture of one or more of fumed silica, cellaburate, modified urea solution.
6. a kind of normal temperature quick-drying type water-based epoxy zinc-rich primer as described in claim 1, it is characterised in that: the water-base epoxy
Resin is the aqueous epoxy emulsion that solid part is 50-60wt%；Its content is 65~75wt%.
7. a kind of normal temperature quick-drying type water-based epoxy zinc-rich primer as described in claim 1, it is characterised in that: the neutralizer is
Volatile organic amines.
8. a kind of preparation process of normal temperature quick-drying type water-based epoxy zinc-rich primer as described in claim 1, which is characterized in that including
Following steps:
Component A:
1. part cosolvent, curing agent, dispersing agent, the defoaming agent accurately measured is added in a reservoir, neutralizer, with adjustable height
Fast dispersion machine stirs 5-10 minutes, and revolving speed is 400-600 revs/min；
2. fumed silica, 5A molecular sieve, titanium dioxide are added while stirring, stir 10-15 minute, revolving speed be 600-800 turn/
Point, the rear sand mill that carries out is sanded to 20 μm of fineness；
3. walking the slurry of completion in taking-up, zinc powder is continuously added under the high speed disperser stirring that revolving speed is 600-800 revs/min,
Adding and promoting revolving speed is 800-1200 revs/min, is dispersed to 40 μm of fineness or less；
4. the remaining cosolvent of addition, cellaburate, anti-flash rusting agent, thickener, promotor stir 15-30 minutes, revolving speed is
600-800 revs/min；
5. with 100 mesh copper mesh or nylon net filter；
6. being packed with big mouth plastic barrel or tinplate bucket, finished product is obtained；
B component:
1. the aqueous epoxy resins accurately measured, softened water are added in a reservoir, with 5-10 points of adjustable high-speed dispersing agent stirring
Clock, revolving speed are 400-600 revs/min；
2. with 100 mesh nylon net filters；
3. being packed with big mouth plastic barrel, finished product is obtained；
A, B component are mixed according to mass ratio 100:28 proportion when use, can be constructed after mixing evenly.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810903088.6A CN109233563A (en) | 2018-08-09 | 2018-08-09 | A kind of normal temperature quick-drying type water-based epoxy zinc-rich primer and its preparation process |
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| CN201810903088.6A CN109233563A (en) | 2018-08-09 | 2018-08-09 | A kind of normal temperature quick-drying type water-based epoxy zinc-rich primer and its preparation process |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110540790A (en) * | 2019-09-09 | 2019-12-06 | 江苏德威涂料有限公司 | water-based epoxy anticorrosive primer for container |
| CN111171676A (en) * | 2020-01-21 | 2020-05-19 | 山东七维新材料有限公司 | Water-based metal paint applied to corrosion prevention of marine equipment and preparation method thereof |
| CN111909594A (en) * | 2020-08-11 | 2020-11-10 | 江苏万源新材料股份有限公司 | Molecular sieve coating aluminum foil with anticorrosion function and preparation process thereof |
| CN115368802A (en) * | 2021-05-20 | 2022-11-22 | 株式会社Kcc | Water-based heavy-duty coating composition |
| CN115746671A (en) * | 2022-11-01 | 2023-03-07 | 中远关西涂料（上海）有限公司 | Preparation method of waterborne epoxy zinc-rich shop primer |
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| CN101104771A (en) * | 2007-08-20 | 2008-01-16 | 维新环保涂料（深圳）有限公司 | Water-based epoxy zinc-rich primer |
| CN103409040A (en) * | 2013-08-14 | 2013-11-27 | 张家港保税区金企鹅贸易有限公司 | Waterborne epoxy zinc-rich primer |
| CN104774526A (en) * | 2015-01-22 | 2015-07-15 | 南京长江涂料有限公司 | Room temperature-curing two-component aqueous epoxy zinc-rich primer |
| CN107118664A (en) * | 2017-06-14 | 2017-09-01 | 无锡华东锌盾科技有限公司 | Bi-component aqueous epoxy zinc rich primer and preparation method thereof |
| CN108219623A (en) * | 2017-12-20 | 2018-06-29 | 江苏德威涂料有限公司 | A kind of water-based epoxy zinc-rich primer pre-processed for container and preparation method thereof |
-
2018
- 2018-08-09 CN CN201810903088.6A patent/CN109233563A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101104771A (en) * | 2007-08-20 | 2008-01-16 | 维新环保涂料（深圳）有限公司 | Water-based epoxy zinc-rich primer |
| CN103409040A (en) * | 2013-08-14 | 2013-11-27 | 张家港保税区金企鹅贸易有限公司 | Waterborne epoxy zinc-rich primer |
| CN104774526A (en) * | 2015-01-22 | 2015-07-15 | 南京长江涂料有限公司 | Room temperature-curing two-component aqueous epoxy zinc-rich primer |
| CN107118664A (en) * | 2017-06-14 | 2017-09-01 | 无锡华东锌盾科技有限公司 | Bi-component aqueous epoxy zinc rich primer and preparation method thereof |
| CN108219623A (en) * | 2017-12-20 | 2018-06-29 | 江苏德威涂料有限公司 | A kind of water-based epoxy zinc-rich primer pre-processed for container and preparation method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110540790A (en) * | 2019-09-09 | 2019-12-06 | 江苏德威涂料有限公司 | water-based epoxy anticorrosive primer for container |
| CN111171676A (en) * | 2020-01-21 | 2020-05-19 | 山东七维新材料有限公司 | Water-based metal paint applied to corrosion prevention of marine equipment and preparation method thereof |
| CN111909594A (en) * | 2020-08-11 | 2020-11-10 | 江苏万源新材料股份有限公司 | Molecular sieve coating aluminum foil with anticorrosion function and preparation process thereof |
| CN115368802A (en) * | 2021-05-20 | 2022-11-22 | 株式会社Kcc | Water-based heavy-duty coating composition |
| CN115368802B (en) * | 2021-05-20 | 2024-03-08 | 株式会社Kcc | Aqueous heavy duty coating composition |
| CN115746671A (en) * | 2022-11-01 | 2023-03-07 | 中远关西涂料（上海）有限公司 | Preparation method of waterborne epoxy zinc-rich shop primer |
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Application publication date: 20190118 |