CN106752311A - A kind of ink composite for adding 2 ethyl hexanoic acid bismuth - Google Patents
A kind of ink composite for adding 2 ethyl hexanoic acid bismuth Download PDFInfo
- Publication number
- CN106752311A CN106752311A CN201611111848.7A CN201611111848A CN106752311A CN 106752311 A CN106752311 A CN 106752311A CN 201611111848 A CN201611111848 A CN 201611111848A CN 106752311 A CN106752311 A CN 106752311A
- Authority
- CN
- China
- Prior art keywords
- ink
- hexanoic acid
- ethyl hexanoic
- acid bismuth
- ink composite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/06—Printing inks based on fatty oils
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/103—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The present invention discloses a kind of ink composite for adding 2 ethyl hexanoic acid bismuth and preparation method thereof.This ink is to make ink prepared by solvent with vegetable oil, and adds 2 thylhexoic acid bismuth drying aids, promotes the consaturated oil in vegetable oil solvent to aoxidize, accelerate grease xeroma, overcome the slow-footed shortcoming of ink setting, its preparation flow is simple, easy to use；Drying aids usage amount is few, low cost.
Description
Technical field
The present invention relates to a kind of ink, more particularly to a kind of ink composite for adding 2 ethyl hexanoic acid bismuth and its preparation side
Method, belongs to ink manufacture field.
Background technology
As continuing to develop for press, ink application are also increasingly extensive, yield constantly increases,《Chinese ink industry is produced
Pin demand is looked forward to the prospect with investment forecasting analysis report》Statistics, national ink gross annual output amount amounts to 58.99 ten thousand tons, accounts for the whole world
14%, occupy the second in the world more than Germany, Japan first.Ink is that one kind is equably mixed simultaneously by pigment, link stuff and auxiliary agent etc.
A kind of sticky colloidal fluid is formed through repeat-rolling.Conventionally manufactured ink is the raw material using industrial Petropols as ink, this
Substantial amounts of organic solvent is not only consumed, but also is polluted the environment, the carcinogenic components for containing can also endanger user's health.
Because the security requirement that the environmental consciousness enhancing of people and people print to packaging for foodstuff is improved, developed country is
Policy is launched respectively, limitation solvent borne ink facilitates aromatic hydrocarbon in ink composition in the application in the field such as food and medical package
Toxic volatile organic principle ratio reduction, ink industry has occurred in that the oil from traditional solvent-borne ink to such as aqueous flexible plate
Ink, Soybean Oil Ink, the trend of environment-friendly ink transfer as UV ink.The exploitation of environment-friendly ink and production capacity have become
One of key factor that ink manufacturers future wins victory.
Make solvent with vegetable oil, the ink of preparation is not only environmentally friendly but also can use the resource of regeneration to replace non-renewable oil molten
Agent, the ink made using pure plant oil, resin and gel, printing color is bright-coloured, gloss is high, wear-resisting strong, printing turns
Shifting property more preferably, and it is more excellent for manufacture paper products degradability, with more preferable deinking, but plant oil base contain it is a large amount of not
Saturated fatty acid, slow drying speed.
In order to overcome the dry slow-footed shortcoming of vegetable oil backbone, the present invention is by ink-making process, adding 2- second
Base caproic acid bismuth drying aids, can promote the consaturated oil in vegetable oil solvent to aoxidize, and become solid-state from liquid, by small point
Son becomes macromolecular, so as to accelerate grease xeroma, the ink setting speed of preparation is fast, with preferable application prospect.
The content of the invention
The present invention provides a kind of ink composite for adding 2 ethyl hexanoic acid bismuth, and the ink includes following components：
Vegetable fat 20-40%
Monoethanolamine 10-20%
Newtrex phenol-formaldehyde resin modified 10-15%
Water soluble acrylic resin 10-15%
Water soluble acrylic acid mill base 10-20%
Soybean lecithin wetting agent 1-2%
Organic silicon defoamer 1-2%
2 ethyl hexanoic acid bismuth 1-2%
Water surplus.
The preparation method of the ink of said components content comprises the following steps：
(1) a container is taken, by a certain proportion of vegetable fat, monoethanolamine, organic silicon defoamer and soybean lecithin wetting agent and suitable
Amount water adds mixing together, and is heated to uniform temperature；
(2) keep under steady temperature, mixed solution is mixed with agitator, be uniformly dispersed；
(3) after disperseing, a certain amount of water soluble acrylic resin, newtrex phenol-formaldehyde resin modified and aqueous acrylamide are sequentially added
Sour mill base；
(4) mixed solution system is mixed under certain rotating speed, be uniformly dispersed；
(5) a certain amount of 2 ethyl hexanoic acid bismuth and organic silicon defoamer are subsequently adding；
(6) finally filtered with filter, collect filtrate, you can obtain a kind of quick-drying ink.
Preferentially, step (1) in, vegetable fat is soybean grease.
Preferentially, step (2) in, heating-up temperature be 50-60 DEG C.
Preferentially, step (2) in, agitator presses the rotating speed of 500-600 r/min, dispersed 3-4 hours.
Preferentially, step (4) in, agitator presses the rotating speed of 600-700r/min, dispersed 3-5 hours.
The present invention has following advantages and characteristic：
(1) rate of drying is fast；
(2) flow is simple, easy to operate, easy to use；
(3) drying aids usage amount is few, low cost.
Specific embodiment
Embodiment one：
A heatable stirring container is taken, the organosilicon of the soybean grease of 20% ratio, the monoethanolamine of 10% ratio, 1% ratio is disappeared
The water of infusion, the soybean lecithin wetting agent of 1% ratio and 16% ratio adds mixing together, and is heated to 50 DEG C, keeps this temperature
Under degree, by mixed solution in the speed conditions by 500 r/min, dispersed 4 hours, after being uniformly dispersed, 15% is sequentially added
Water soluble acrylic resin, 15% newtrex phenol-formaldehyde resin modified, the water soluble acrylic acid mill base of 20% ratio, then will mixing
Solution disperses 5 hours under the conditions of rotating speed is 600 r/min, after dispersion terminates, is eventually adding the 2 ethyl hexanoic acid bismuth of 1% ratio
With the organic silicon defoamer of 1% ratio, finally filtered with filter, collect filtrate, you can obtain a kind of quick-drying ink.
Embodiment two：
Take a heatable stirring container, by the soybean grease of 30% ratio, the monoethanolamine of 20% ratio, 0.5% ratio organosilicon
The water of defoamer, the soybean lecithin wetting agent of 2% ratio and 10.5% ratio is mixed addition mixing, and is heated to 55 DEG C,
At a temperature of keeping this, by mixed solution in the speed conditions by 550 r/min, dispersed 3.5 hours, after being uniformly dispersed, then
Sequentially add 10% water soluble acrylic resin, 15% newtrex phenol-formaldehyde resin modified, the water soluble acrylic acid color of 10% ratio
Slurry, then mixed solution is disperseed 4 hours under the conditions of rotating speed is 650r/min, after dispersion terminates, it is eventually adding 1.5% ratio
The organic silicon defoamer of 2 ethyl hexanoic acid bismuth and 0.5% ratio, is finally filtered with filter, collects filtrate, you can obtain a kind of quick-drying
Property ink.
Embodiment three：
Take a heatable stirring container, by the soybean grease of 40% ratio, the monoethanolamine of 15% ratio, 0.5% ratio organosilicon
The water of defoamer, the soybean lecithin wetting agent of 1% ratio and 16% ratio adds mixing together, and is heated to 60 DEG C, keeps this
At a temperature of, by mixed solution in the speed conditions by 600 r/min, dispersed 3 hours, after being uniformly dispersed, sequentially add
10% water soluble acrylic resin, 10% newtrex phenol-formaldehyde resin modified, the water soluble acrylic acid mill base of 15% ratio, then will
Mixed solution disperses 3 hours under the conditions of rotating speed is 700r/min, after dispersion terminates, is eventually adding the 2 ethyl hexanoic acid of 2% ratio
Bismuth and the organic silicon defoamer of 0.5%, are finally filtered with filter, collect filtrate, you can obtain a kind of quick-drying ink.
Claims (6)
1. a kind of ink composite for adding 2 ethyl hexanoic acid bismuth, it is characterised in that the ink composition components are：Vegetable oil
Fat：20-40%, monoethanolamine：10-20%, newtrex phenol-formaldehyde resin modified：10-15%, water soluble acrylic resin：10-15%,
Water soluble acrylic acid mill base：10-20%, soybean lecithin wetting agent：1-2%, organic silicon defoamer：1-2%, 2 ethyl hexanoic acid bismuth：1-
2%, water：Surplus.
2. it is according to claim 1 it is a kind of add 2 ethyl hexanoic acid bismuth ink composite, it is characterised in that the ink
Preparation method comprise the following steps：
(1) a container is taken, by a certain proportion of vegetable fat, monoethanolamine, organic silicon defoamer and soybean lecithin wetting agent and suitable
Amount water adds mixing together, and is heated to uniform temperature；
(2) keep under steady temperature, mixed solution is mixed with agitator, be uniformly dispersed；
(3) after disperseing, a certain amount of water soluble acrylic resin, newtrex phenol-formaldehyde resin modified and aqueous acrylamide are sequentially added
Sour mill base；
(4) mixed solution system is mixed under certain rotating speed, be uniformly dispersed；
(5) a certain amount of 2 ethyl hexanoic acid bismuth and organic silicon defoamer are subsequently adding；
(6) finally filtered with filter, collect filtrate, you can obtain a kind of quick-drying ink.
3. it is according to claim 2 it is a kind of add 2 ethyl hexanoic acid bismuth ink composite, it is characterised in that in step
(1) in, vegetable fat is soybean grease.
4. it is according to claim 2 it is a kind of add 2 ethyl hexanoic acid bismuth ink composite, it is characterised in that in step
(2) in, heating-up temperature is 50-60 DEG C.
5. it is according to claim 2 it is a kind of add 2 ethyl hexanoic acid bismuth ink composite, it is characterised in that in step
(2) in, agitator presses the rotating speed of 500-600 r/min, dispersed 3-4 hours.
6. it is according to claim 2 it is a kind of add 2 ethyl hexanoic acid bismuth ink composite, it is characterised in that in step
(4) in, agitator presses the rotating speed of 600-700r/min, dispersed 3-5 hours.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611111848.7A CN106752311A (en) | 2016-12-06 | 2016-12-06 | A kind of ink composite for adding 2 ethyl hexanoic acid bismuth |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611111848.7A CN106752311A (en) | 2016-12-06 | 2016-12-06 | A kind of ink composite for adding 2 ethyl hexanoic acid bismuth |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106752311A true CN106752311A (en) | 2017-05-31 |
Family
ID=58874509
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611111848.7A Pending CN106752311A (en) | 2016-12-06 | 2016-12-06 | A kind of ink composite for adding 2 ethyl hexanoic acid bismuth |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106752311A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102585591A (en) * | 2012-03-12 | 2012-07-18 | 洋紫荆油墨（河北）有限公司 | Method for making blue offset printing ink |
| CN105062210A (en) * | 2015-08-09 | 2015-11-18 | 吴房文 | Preparation method of printing ink by adding colophony modified phenolic resin |
-
2016
- 2016-12-06 CN CN201611111848.7A patent/CN106752311A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102585591A (en) * | 2012-03-12 | 2012-07-18 | 洋紫荆油墨（河北）有限公司 | Method for making blue offset printing ink |
| CN105062210A (en) * | 2015-08-09 | 2015-11-18 | 吴房文 | Preparation method of printing ink by adding colophony modified phenolic resin |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
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| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170531 |
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| WD01 | Invention patent application deemed withdrawn after publication |