CN105315781A - Quick-drying type water-based gold ink and preparation method thereof - Google Patents
Quick-drying type water-based gold ink and preparation method thereof Download PDFInfo
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Abstract
The invention relates to quick-drying type water-based gold ink and a preparation method thereof. The quick-drying type water-based gold ink is prepared from, by weight, 30-60% of pigment, 10-40% of connecting materials and 20-50% of a solvent. The connecting materials are one or the mixture of two or more of water-soluble modified cellulose ester, polyvinyl alcohol, acrylic copolymer and polyurethane. The quantitative solvent is placed in a stirring barrel, the quantitative pigment is added into the solvent with stirring, and a pigment solution is obtained after the pigment is completely dissolved; the quantitative connecting materials are added into the pigment solution with stirring, stirring is uniformly carried, and the evenly-scattered water-based gold ink is obtained. Compared with the prior art, the quick-drying type water-based gold ink is applicable to intaglio printing, and the problem that some intaglio printing devices in China cause the ink inverted adhesion due to the fact that an oven has the high temperature and no cooling device exits is solved.
Description
Technical field
The present invention relates to a kind of ink and preparation method thereof, especially relate to a kind of quick-dry type water-based gold ink and preparation method thereof.
Background technology
Along with ink technology is constantly to high-technicalization development, improving constantly of people's environmental consciousness, exploitation environment-friendlyink ink is the problem that must first consider of ink development from now on.
Developed country launches respectively policy, the application of restriction solvent borne ink in the field such as food and medical package.Prohibit the use the solvent type ink containing benzene in the U.S. and some European countries, the substitute is environmental type ink.Other developed countries, as Japanese, German, French etc., in plastic film printing, also more and more use water color ink, Britain has made laws and has prohibitted the use the film of solvent type ink printing packaging food.At present, Plastics in China base gravure ink, based on solvent type ink, accounts for more than 50% of gravure ink total amount.High volatile solvent contains aromatic hydrocarbon, not only poisonous but also inflammable, but due to gravure speed fast, the ink of high volatility must be used to meet print request, and this just makes the environmental issue of gravure particularly outstanding in all typographies.
Water color ink is the novel ink arisen at the historic moment under a kind of environment more and more paid close attention to low-carbon environment-friendly people, has the unrivaled safety and environmental protection feature of other ink.Water color ink, being called for short ink, take water as primary solvent, by aqueous high molecular compound as binder and the auxiliary agent such as pigment, tensio-active agent through designing, allocating, a kind of novel printing ink of attrition process.It is compared with traditional solvent-borne ink, and solvent used replaces tradition based on the solvent of benzene class with water; In resin, use water-base resin, can dissolve or stable dispersion in water.Water color ink is low glutinous due to it, the features such as green non-pollution, and current topmost application is packing and decorating printing, particularly to safety, environmental protection, the printed matter for packing that health requirements is high, as fields such as food product pack, tobacco and wine packaging, toy for children packagings.
The research and development of China's water color ink are started late, although water color ink has fairly obvious advantage, but most of water color ink of domestic production has the shortcomings such as rate of drying is slow, water resisting property is poor, glossiness is low, these shortcomings also inhibits its fast development and utilization.Because water color ink rate of drying is slow, need the oven temperature improving printing press to accelerate the rate of drying of ink, and partial domestic press oven does not have cooling system, can not make to be heated the temperature return of printable fabric to normal temperature, and the printable fabric of high temperature will cause the anti-sticky of ink thus cause printed matter to be scrapped after dancing roll.These shortcomings are main relevant with the auxiliary agent of ink to the performance of ink resin used.
Chinese patent CN103421386A discloses the special-purpose aqueous gold ink of a kind of cork paper, and its raw material by weight, comprises following component: aqueous color paste 60-65 part; Water soluble acrylic resin 10-16 part; Dispersion agent 10-15 part; Water 10-30 part; Auxiliary agent 0.5-1 part.By special recipe optimization treatment scheme, solve water-based gold ink meet water generation oxidizing reaction thus become aeruginous problem, the printing fastness of gained water-based gold ink also makes moderate progress, its printing effect can meet or exceed the effect of the solvent-borne type gold ink used at present, has very large actual application value.The binder selected in this patent is water soluble acrylic resin, its quick-drying poor-performing.
Summary of the invention
Object of the present invention be exactly in order to overcome above-mentioned prior art exist defect and provide a kind of safety and environmental protection, stable in properties quick-dry type water-based gold ink and preparation method thereof, quick-dry type water-based gold ink of the present invention is applicable to being applied to intaglio printing, solves the anti-sticky problem of ink that Some Domestic gravure printing apparatus causes because of oven temperature high shortage cooling apparatus.
Object of the present invention can be achieved through the following technical solutions:
A quick-dry type water-based gold ink, formulated according to weight percentage by following component:
Colorant 30 ~ 60%;
Binder 10 ~ 40%;
Solvent 20 ~ 50%.
As preferably, quick-dry type water-based gold ink is formulated according to weight percentage by following component:
Colorant 42 ~ 54%;
Binder 18 ~ 30%;
Solvent 28 ~ 40%.
Described colorant is selected from the mixture of a kind of water-based gold paste or multiple water-based gold paste.
Described binder is one or more the mixture in water-soluble modified cellulose ester, polyvinyl alcohol, acrylic copolymer or urethane.
As preferably, described binder is polyvinyl alcohol and acrylic copolymer weight ratio is the compound of 1:4 ~ 4:1.Wherein, polyvinyl alcohol is a kind of excellent water soluble resin, has good dispersion stabilization and film forming properties; Methyl methacrylate in acrylic copolymer or vinylbenzene are hard monomer is that ink film forming provides high rigidity, preferably drying property and water resisting property, and butyl acrylate is soft monomer is that ink film forming provides excellent flexibility and extensibility.
Described water-soluble modified cellulose ester is specially Vltra tears ester.
Described acrylic copolymer is acrylic acid-methacrylic acid methyl esters-butyl acrylate copolymer, acrylicstyrene-butyl acrylate copolymer.
Described solvent is the mixture of water and technical grade dehydrated alcohol or 95v/v% ethanol.
A preparation method for quick-dry type water-based gold ink, comprises the following steps:
(1) prepare burden: accurately take quantitative colorant, binder and solvent respectively according to the weight percent ranges of each component and be placed in different stainless steel casks, for subsequent use;
(2) disperse: quantitative solvent is placed in agitation vat, under the state stirred, quantitative colorant is added in solvent, until colorant dissolves completely, obtain colorant solution; Continue under the state stirred, quantitative binder to be added in above-mentioned colorant solution, stir and obtain finely dispersed water-based gold ink;
(3) namely potting package: accurately take quantitative water-based gold ink in ink barrel by packed weight, cover bung and seal, labelledly obtain the black finished product of water-based gold.
Compared with prior art, water-based in the present invention gold ink adopts water-based gold paste, steady quality and glossiness is high, environmental protection more compared with solvent-borne type gold paste; Binder is the filmogen of ink, improves heat resistance and the rate of drying of ink, and the water-based obtained gold ink is applicable to various dissimilar gravure printing machine; Solvent is the dispersion medium of colorant, has good dispersion stabilization for colorant, and water-based gold ink can steady in a long-termly be preserved.Quick-dry type water-based that the present invention obtains gold ink is not containing poisonous hazardous solvent, and printing effect is good, steady quality, can be applicable to safety, environmental protection, printed matter that health requirements is high, as food product pack, tobacco and wine packaging etc.Specifically, the present invention has the following advantages and beneficial effect:
(1) water-based gold ink of the present invention has excellent temperature tolerance and quick-drying, the acrylic copolymer of heatproof quick-dry type is added in binder, it introduces methyl methacrylate or vinylbenzene quick-dry type hard monomer, improve drying property and the heat resistance of resin, the ink obtained can adapt to domestic various types of gravure printing machine well, and the part intaglio printing press of solution lacks the anti-sticky problem of ink that cooling roller causes.
(2) water-based gold performance of ink of the present invention is stablized, and printing figure message is clear, color is full, strong adhesion, wear resisting property are excellent, and printing effect is good.
(3) the black production technique of water-based gold of the present invention is simple, and production cost is low, can be used for large-scale industrial production.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail.
Embodiment 1
Preparation method:
1.1 weigh batchings: take each raw material respectively in different stainless steel casks by above-mentioned formula, for subsequent use;
1.2 dispersions: the mixed solvent of 18kg dehydrated alcohol and water is placed in agitation vat, under whipped state, 13kg water-based gold paste is slowly joined in the mixed solvent of dehydrated alcohol and water, until gold paste dissolves completely, continue to stir, under the state stirred, the urethane of 9kg and acrylic copolymer binder are progressively added in above-mentioned water-based gold solution, dispersed with stirring is even, by filter screen filtration after completing;
Namely 1.3 potting packages: accurately take quantitative water-based gold ink in ink barrel by packed weight, cover bung and seal, labelledly obtain the black finished product of water-based gold.
The water-based gold ink more than obtained prints under 120m/min, oven temperature 100 DEG C of conditions, can rapid drying occur without anti-sticky phenomenon.
Embodiment 2
Preparation method:
2.1 weigh batchings: take each raw material respectively in different stainless steel casks by above-mentioned formula, for subsequent use;
2.2 dispersions: the mixed solvent of 9kg95% ethanol and water is placed in agitation vat, under whipped state, 21kg water-based gold paste is slowly joined in the mixed solvent of 95% ethanol and water, until gold paste dissolves completely, continue to stir, under the state stirred, the Hybrid connections material of the polyvinyl alcohol of 10kg and acrylic copolymer is progressively added in above-mentioned water-based gold solution, dispersed with stirring is even, by filter screen filtration after completing;
Namely 2.3 potting packages: accurately take quantitative water-based gold ink in ink barrel by packed weight, cover bung and seal, labelledly obtain the black finished product of water-based gold.
The water-based gold ink more than obtained prints under 120m/min, oven temperature 100 DEG C of conditions, can rapid drying occur without anti-sticky phenomenon.
Embodiment 3
Preparation method:
3.1 weigh batchings: take each raw material respectively in different stainless steel casks by above-mentioned formula, for subsequent use;
3.2 dispersions: the mixed solvent of 12kg dehydrated alcohol and water is placed in agitation vat, under whipped state, 16kg water-based gold paste is slowly joined in the mixed solvent of dehydrated alcohol and water, until gold paste dissolves completely, continue to stir, under the state stirred, the Hybrid connections material of the modified cellulose ester of 12kg and acrylic copolymer is progressively added in above-mentioned water-based gold solution, dispersed with stirring is even, by filter screen filtration after completing;
Namely 3.3 potting packages: accurately take quantitative water-based gold ink in ink barrel by packed weight, cover bung and seal, labelledly obtain the black finished product of water-based gold.
The water-based gold ink more than obtained prints under 120m/min, oven temperature 100 DEG C of conditions, can rapid drying occur without anti-sticky phenomenon.
Embodiment 4
A quick-dry type water-based gold ink, formulated according to weight percentage by following component:
A preparation method for quick-dry type water-based gold ink, comprises the following steps:
(1) prepare burden: accurately take quantitative colorant, binder and solvent respectively according to the weight percent ranges of each component and be placed in different stainless steel casks, for subsequent use;
(2) disperse: quantitative solvent is placed in agitation vat, under the state stirred, quantitative colorant is added in solvent, until colorant dissolves completely, obtain colorant solution; Continue under the state stirred, quantitative binder to be added in above-mentioned colorant solution, stir and obtain finely dispersed water-based gold ink;
(3) namely potting package: accurately take quantitative water-based gold ink in ink barrel by packed weight, cover bung and seal, labelledly obtain the black finished product of water-based gold.
The water-based gold ink more than obtained prints under 120m/min, oven temperature 100 DEG C of conditions, can rapid drying occur without anti-sticky phenomenon.
Embodiment 5
A quick-dry type water-based gold ink, formulated according to weight percentage by following component:
Water-based gold paste 60kg;
Binder (polyvinyl alcohol) 20kg;
Solvent (mixture of 95v/v% ethanol and water volume ratio 1:1) 20kg.
A preparation method for quick-dry type water-based gold ink, comprises the following steps:
(1) prepare burden: accurately take quantitative colorant, binder and solvent respectively according to the weight percent ranges of each component and be placed in different stainless steel casks, for subsequent use;
(2) disperse: quantitative solvent is placed in agitation vat, under the state stirred, quantitative colorant is added in solvent, until colorant dissolves completely, obtain colorant solution; Continue under the state stirred, quantitative binder to be added in above-mentioned colorant solution, stir and obtain finely dispersed water-based gold ink;
(3) namely potting package: accurately take quantitative water-based gold ink in ink barrel by packed weight, cover bung and seal, labelledly obtain the black finished product of water-based gold.
The water-based gold ink more than obtained prints under 120m/min, oven temperature 100 DEG C of conditions, can rapid drying occur without anti-sticky phenomenon.
Embodiment 6
A quick-dry type water-based gold ink, formulated according to weight percentage by following component:
Water-based gold paste 50kg;
Binder (acrylic acid-methacrylic acid methyl esters-butyl acrylate copolymer) 10kg;
Solvent (water mixture more composite than 1:1 with ethanol contend) 40kg.
A preparation method for quick-dry type water-based gold ink, comprises the following steps:
(1) prepare burden: accurately take quantitative colorant, binder and solvent respectively according to the weight percent ranges of each component and be placed in different stainless steel casks, for subsequent use;
(2) disperse: quantitative solvent is placed in agitation vat, under the state stirred, quantitative colorant is added in solvent, until colorant dissolves completely, obtain colorant solution; Continue under the state stirred, quantitative binder to be added in above-mentioned colorant solution, stir and obtain finely dispersed water-based gold ink;
(3) namely potting package: accurately take quantitative water-based gold ink in ink barrel by packed weight, cover bung and seal, labelledly obtain the black finished product of water-based gold.
The water-based gold ink more than obtained prints under 120m/min, oven temperature 100 DEG C of conditions, can rapid drying occur without anti-sticky phenomenon.
Embodiment 7
A quick-dry type water-based gold ink, formulated according to weight percentage by following component:
Water-based gold paste 30%;
Binder (urethane) 40%;
Solvent (dehydrated alcohol of technical grade and water 2:1 mixture) 30%.
A preparation method for quick-dry type water-based gold ink, comprises the following steps:
(1) prepare burden: accurately take quantitative colorant, binder and solvent respectively according to the weight percent ranges of each component and be placed in different stainless steel casks, for subsequent use;
(2) disperse: quantitative solvent is placed in agitation vat, under the state stirred, quantitative colorant is added in solvent, until colorant dissolves completely, obtain colorant solution; Continue under the state stirred, quantitative binder to be added in above-mentioned colorant solution, stir and obtain finely dispersed water-based gold ink;
(3) namely potting package: accurately take quantitative water-based gold ink in ink barrel by packed weight, cover bung and seal, labelledly obtain the black finished product of water-based gold.
The water-based gold ink more than obtained prints under 120m/min, oven temperature 100 DEG C of conditions, can rapid drying occur without anti-sticky phenomenon.
Embodiment 8
A quick-dry type water-based gold ink, formulated according to weight percentage by following component:
Water-based gold paste 42kg;
Binder (polyvinyl alcohol and acrylic copolymer weight ratio are the mixture of 1:4) 18kg;
Solvent (dehydrated alcohol of technical grade and the mixture of water 1:2 volume ratio) 40kg.
Wherein, acrylic copolymer is acrylic acid-methacrylic acid methyl esters-butyl acrylate copolymer.
A preparation method for quick-dry type water-based gold ink, comprises the following steps:
(1) prepare burden: accurately take quantitative colorant, binder and solvent respectively according to the weight percent ranges of each component and be placed in different stainless steel casks, for subsequent use;
(2) disperse: quantitative solvent is placed in agitation vat, under the state stirred, quantitative colorant is added in solvent, until colorant dissolves completely, obtain colorant solution; Continue under the state stirred, quantitative binder to be added in above-mentioned colorant solution, stir and obtain finely dispersed water-based gold ink;
(3) namely potting package: accurately take quantitative water-based gold ink in ink barrel by packed weight, cover bung and seal, labelledly obtain the black finished product of water-based gold.
The water-based gold ink more than obtained prints under 120m/min, oven temperature 100 DEG C of conditions, can rapid drying occur without anti-sticky phenomenon.
Embodiment 9
A quick-dry type water-based gold ink, formulated according to weight percentage by following component:
Water-based gold paste 54kg;
Binder (polyvinyl alcohol and acrylic copolymer weight ratio are the compound of 4:1) 18kg;
Solvent (dehydrated alcohol of technical grade and the mixture of water 5:1) 28kg.
Acrylic copolymer is acrylicstyrene-butyl acrylate copolymer.
A preparation method for quick-dry type water-based gold ink, comprises the following steps:
(1) prepare burden: accurately take quantitative colorant, binder and solvent respectively according to the weight percent ranges of each component and be placed in different stainless steel casks, for subsequent use;
(2) disperse: quantitative solvent is placed in agitation vat, under the state stirred, quantitative colorant is added in solvent, until colorant dissolves completely, obtain colorant solution; Continue under the state stirred, quantitative binder to be added in above-mentioned colorant solution, stir and obtain finely dispersed water-based gold ink;
(3) namely potting package: accurately take quantitative water-based gold ink in ink barrel by packed weight, cover bung and seal, labelledly obtain the black finished product of water-based gold.
The water-based gold ink more than obtained prints under 120m/min, oven temperature 100 DEG C of conditions, can rapid drying occur without anti-sticky phenomenon.
Embodiment 10
A quick-dry type water-based gold ink, formulated according to weight percentage by following component:
Water-based gold paste 40kg;
Binder (polyvinyl alcohol and acrylic copolymer weight ratio are the compound of 1:1) 30kg;
Solvent (dehydrated alcohol of technical grade and the mixture of water 1:5) 30kg.
Acrylic copolymer is acrylic acid-methacrylic acid methyl esters-butyl acrylate copolymer.
A preparation method for quick-dry type water-based gold ink, comprises the following steps:
(1) prepare burden: accurately take quantitative colorant, binder and solvent respectively according to the weight percent ranges of each component and be placed in different stainless steel casks, for subsequent use;
(2) disperse: quantitative solvent is placed in agitation vat, under the state stirred, quantitative colorant is added in solvent, until colorant dissolves completely, obtain colorant solution; Continue under the state stirred, quantitative binder to be added in above-mentioned colorant solution, stir and obtain finely dispersed water-based gold ink;
(3) namely potting package: accurately take quantitative water-based gold ink in ink barrel by packed weight, cover bung and seal, labelledly obtain the black finished product of water-based gold.
The water-based gold ink more than obtained prints under 120m/min, oven temperature 100 DEG C of conditions, can rapid drying occur without anti-sticky phenomenon.
Above-mentioned is can understand and use invention for ease of those skilled in the art to the description of embodiment.Person skilled in the art obviously easily can make various amendment to these embodiments, and General Principle described herein is applied in other embodiments and need not through performing creative labour.Therefore, the invention is not restricted to above-described embodiment, those skilled in the art, according to announcement of the present invention, do not depart from improvement that scope makes and amendment all should within protection scope of the present invention.
Claims (8)
1. a quick-dry type water-based gold ink, is characterized in that, formulated according to weight percentage by following component:
Colorant 30 ~ 60%;
Binder 10 ~ 40%;
Solvent 20 ~ 50%;
Described binder is one or more the mixture in water-soluble modified cellulose ester, polyvinyl alcohol, acrylic copolymer or urethane.
2. a kind of quick-dry type water-based gold ink according to claim 1, is characterized in that, described quick-dry type water-based gold ink is formulated according to weight percentage by following component:
Colorant 42 ~ 54%;
Binder 18 ~ 30%;
Solvent 28 ~ 40%;
Described binder is one or more the mixture in water-soluble modified cellulose ester, polyvinyl alcohol, acrylic copolymer or urethane.
3. a kind of quick-dry type water-based gold ink according to claim 1 and 2, it is characterized in that, described binder is polyvinyl alcohol and acrylic copolymer weight ratio is the compound of 1:4 ~ 4:1.
4. a kind of quick-dry type water-based gold ink according to claim 1 and 2, it is characterized in that, described water-soluble modified cellulose ester is Vltra tears ester.
5. a kind of quick-dry type water-based gold ink according to claim 1 and 2, it is characterized in that, described acrylic copolymer is acrylic acid-methacrylic acid methyl esters-butyl acrylate copolymer or acrylicstyrene-butyl acrylate copolymer.
6. a kind of quick-dry type water-based gold ink according to claim 1 and 2, it is characterized in that, colorant is selected from the mixture of a kind of water-based gold paste or multiple water-based gold paste.
7. a kind of quick-dry type water-based gold ink according to claim 1 and 2, it is characterized in that, described solvent is the mixture of water and technical grade dehydrated alcohol or 95v/v% ethanol.
8. a preparation method for quick-dry type water-based gold ink as claimed in claim 1 or 2, is characterized in that, comprise the following steps:
(1) prepare burden: accurately take quantitative colorant, binder and solvent respectively according to the weight percent ranges of each component and be placed in different stainless steel casks, for subsequent use;
(2) disperse: quantitative solvent is placed in agitation vat, under the state stirred, quantitative colorant is added in solvent, until colorant dissolves completely, obtain colorant solution; Continue under the state stirred, quantitative binder to be added in above-mentioned colorant solution, stir and obtain finely dispersed water-based gold ink;
(3) namely potting package: accurately take quantitative water-based gold ink in ink barrel by packed weight, cover bung and seal, labelledly obtain the black finished product of water-based gold.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510075329.9A CN105315781B (en) | 2015-02-12 | 2015-02-12 | Aqueous golden ink of a kind of quick-dry type and preparation method thereof |
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| CN201510075329.9A CN105315781B (en) | 2015-02-12 | 2015-02-12 | Aqueous golden ink of a kind of quick-dry type and preparation method thereof |
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| CN105315781B CN105315781B (en) | 2018-08-31 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106221370A (en) * | 2016-07-28 | 2016-12-14 | 上海杰易森股份有限公司 | A kind of fire resistant water-based ink and preparation method thereof |
| CN107903707A (en) * | 2017-11-27 | 2018-04-13 | 江苏顺泰包装印刷科技有限公司 | It is a kind of suitable for environment-friendly type aqueous ink of intaglio printing and preparation method thereof |
| WO2018120018A1 (en) * | 2016-12-30 | 2018-07-05 | 鹤山市怡信化工厂有限公司 | Thermally composite water-based ink coating for printing exterior/interior of pvc |
| CN111040520A (en) * | 2019-12-13 | 2020-04-21 | 成都新柯力化工科技有限公司 | Scratch-resistant pre-coating film with high adhesion effect for printed matters and preparation method thereof |
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| CN103666088A (en) * | 2013-12-06 | 2014-03-26 | 上海德粼水性油墨有限公司 | Special aqueous gold ink for tipping paper, preparation method and application thereof |
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| CN103666088A (en) * | 2013-12-06 | 2014-03-26 | 上海德粼水性油墨有限公司 | Special aqueous gold ink for tipping paper, preparation method and application thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106221370A (en) * | 2016-07-28 | 2016-12-14 | 上海杰易森股份有限公司 | A kind of fire resistant water-based ink and preparation method thereof |
| CN106221370B (en) * | 2016-07-28 | 2019-12-17 | 上海杰易森股份有限公司 | High-temperature-resistant water-based ink and preparation method thereof |
| WO2018120018A1 (en) * | 2016-12-30 | 2018-07-05 | 鹤山市怡信化工厂有限公司 | Thermally composite water-based ink coating for printing exterior/interior of pvc |
| CN107903707A (en) * | 2017-11-27 | 2018-04-13 | 江苏顺泰包装印刷科技有限公司 | It is a kind of suitable for environment-friendly type aqueous ink of intaglio printing and preparation method thereof |
| CN111040520A (en) * | 2019-12-13 | 2020-04-21 | 成都新柯力化工科技有限公司 | Scratch-resistant pre-coating film with high adhesion effect for printed matters and preparation method thereof |
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| CN105315781B (en) | 2018-08-31 |
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