CN106590147A - Modified ink containing zirconium 2-ethylhexanoate assistant and preparation technology thereof - Google Patents
Modified ink containing zirconium 2-ethylhexanoate assistant and preparation technology thereof Download PDFInfo
- Publication number
- CN106590147A CN106590147A CN201611111917.4A CN201611111917A CN106590147A CN 106590147 A CN106590147 A CN 106590147A CN 201611111917 A CN201611111917 A CN 201611111917A CN 106590147 A CN106590147 A CN 106590147A
- Authority
- CN
- China
- Prior art keywords
- hexanoic acid
- ethyl hexanoic
- ink
- acid zirconium
- auxiliary agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/06—Printing inks based on fatty oils
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/103—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses modified ink containing a zirconium 2-ethylhexanoate assistant and a preparation technology thereof. In preparation of plant oil-based ink, through use of the zirconium 2-ethylhexanoate assistant, oxidization of unsaturated oil in a plant oil solvent is promoted and the unsaturated oil is transformed from a liquid into solids so that oil film formation and drying are accelerated. The modified ink has a fast drying rate and a good application prospect.
Description
Technical field
The present invention relates to a kind of ink, more particularly to a kind of ink of addition 2 ethyl hexanoic acid zirconium and preparation method thereof, category
In ink manufacture field.
Background technology
Ink is that one kind is equably mixed by pigment, link stuff and auxiliary agent etc. and Jing repeat-rollings form a kind of viscosity glue
Fluid.Conventionally manufactured ink is the raw material using industrial Petropols as ink, and this not only consumes substantial amounts of organic solvent, and
Also pollute the environment, the carcinogenic components for containing can also endanger user's health.
Make solvent with vegetable oil, not only resource that is environmentally friendly but also can use regeneration replaces non-renewable oil molten to the ink of preparation
Agent, the ink made using pure plant oil, resin and gel, printing color is bright-coloured, gloss is high, wear-resisting strong, printing turns
Shifting property more preferably, and it is more excellent for manufacture paper products degradability, with more preferable deinking, but plant oil base contain it is a large amount of not
Saturated fatty acid, slow drying speed.
The present invention can promote to plant by plant oil-based ink preparation process, adding 2 ethyl hexanoic acid zirconium drying aids
Consaturated oil in thing oil solvent is aoxidized, and from liquid solid-state is become, and by small molecule macromolecular is become, so as to accelerate grease
Xeroma, the plant oil-based ink rate of drying of preparation is fast, with preferable application prospect.
The content of the invention
The present invention provides a kind of modified ink of addition 2 ethyl hexanoic acid zirconium auxiliary agent, and the ink includes following components：
Vegetable fat 20-40%
Monoethanolamine 10-20%
Newtrex phenol-formaldehyde resin modified 10-15%
Water soluble acrylic resin 10-15%
Water soluble acrylic acid mill base 10-20%
Soybean lecithin wetting agent 1-2%
Organic silicon defoamer 1-2%
2 ethyl hexanoic acid zirconium 1-2%
Water surplus.
The preparation method of the ink of said components content comprises the steps：
(1) a container is taken, by a certain proportion of vegetable fat, monoethanolamine, organic silicon defoamer and soybean lecithin wetting agent and suitable
Amount water adds together mixing, and is heated to uniform temperature；
(2) keep under steady temperature, mixed solution is mixed with agitator, be uniformly dispersed；
(3) after disperseing, a certain amount of water soluble acrylic resin, newtrex phenol-formaldehyde resin modified and aqueous acrylamide are sequentially added
Sour mill base；
(4) mixed solution system is mixed under certain rotating speed, be uniformly dispersed；
(5) a certain amount of 2 ethyl hexanoic acid zirconium and organic silicon defoamer are subsequently adding；
(6) finally filtrate is collected with filter filtration, you can obtain a kind of modified ink of addition 2 ethyl hexanoic acid zirconium auxiliary agent.
Preferentially, step (2) in, heating-up temperature be 50-60 DEG C.
Preferentially, step (2) in, agitator presses the rotating speed of 500-600 r/min, dispersed 3-4 hours.
Preferentially, step (4) in, agitator presses the rotating speed of 600-700r/min, dispersed 3-5 hours.
The present invention has following advantages and characteristic：
(1) rate of drying is fast；
(2) flow process is simple, easy to operate, easy to use；
(3) drying aids usage amount is few, low cost.
Specific embodiment
Embodiment one：
A heatable stirring container is taken, the organosilicon of the soybean grease of 20% ratio, the monoethanolamine of 10% ratio, 1% ratio is disappeared
The water of infusion, the soybean lecithin wetting agent of 1% ratio and 16% ratio adds together mixing, and is heated to 50 DEG C, keeps this temperature
Under degree, by mixed solution in the speed conditions by 500 r/min, dispersed 4 hours, after being uniformly dispersed, 15% is sequentially added
Water soluble acrylic resin, 15% newtrex phenol-formaldehyde resin modified, the water soluble acrylic acid mill base of 20% ratio, then will mixing
Solution disperses 5 hours under the conditions of rotating speed is 600 r/min, after dispersion terminates, is eventually adding the 2 ethyl hexanoic acid zirconium of 1% ratio
With the organic silicon defoamer of 1% ratio, finally filtered with filter, collect filtrate, you can obtain a kind of addition 2 ethyl hexanoic acid zirconium
The modified ink of auxiliary agent.
Embodiment two：
Take a heatable stirring container, by the soybean grease of 30% ratio, the monoethanolamine of 20% ratio, 0.5% ratio organosilicon
The water of defoamer, the soybean lecithin wetting agent of 2% ratio and 10.5% ratio is mixed addition mixing, and is heated to 55 DEG C,
At a temperature of keeping this, by mixed solution by 550 r/min speed conditions, dispersed 3.5 hours, after being uniformly dispersed, then
Sequentially add 10% water soluble acrylic resin, 15% newtrex phenol-formaldehyde resin modified, the water soluble acrylic acid color of 10% ratio
Slurry, then mixed solution is disperseed 4 hours under the conditions of rotating speed is 650r/min, after dispersion terminates, it is eventually adding 1.5% ratio
The organic silicon defoamer of 2 ethyl hexanoic acid zirconium and 0.5% ratio, is finally filtered with filter, collects filtrate, you can obtain a kind of adding
Plus the modified ink of 2 ethyl hexanoic acid zirconium auxiliary agent.
Embodiment three：
Take a heatable stirring container, by the soybean grease of 40% ratio, the monoethanolamine of 15% ratio, 0.5% ratio organosilicon
The water of defoamer, the soybean lecithin wetting agent of 1% ratio and 16% ratio adds together mixing, and is heated to 60 DEG C, keeps this
At a temperature of, by mixed solution in the speed conditions by 600 r/min, dispersed 3 hours, after being uniformly dispersed, sequentially add
10% water soluble acrylic resin, 10% newtrex phenol-formaldehyde resin modified, the water soluble acrylic acid mill base of 15% ratio, then will
Mixed solution disperses 3 hours under the conditions of rotating speed is 700r/min, after dispersion terminates, is eventually adding the 2- ethyl hexyls of 2% ratio
Sour zirconium and the organic silicon defoamer of 0.5%, are finally filtered with filter, collect filtrate, you can obtain a kind of addition 2- ethyl hexyls
The modified ink of sour zirconium auxiliary agent.
Claims (5)
1. a kind of modified ink of addition 2 ethyl hexanoic acid zirconium auxiliary agent, it is characterised in that the ink component is：Vegetable fat：
20-40%, monoethanolamine：10-20%, newtrex phenol-formaldehyde resin modified：10-15%, water soluble acrylic resin：10-15%, it is aqueous
Acrylic acid mill base：10-20%, soybean lecithin wetting agent：1-2%, organic silicon defoamer：1-2%, 2 ethyl hexanoic acid zirconium：1-2%,
Water：Surplus.
2. it is according to claim 1 it is a kind of addition 2 ethyl hexanoic acid zirconium auxiliary agent modified ink, it is characterised in that the oil
The preparation method of ink comprises the steps：
(1) a container is taken, by a certain proportion of vegetable fat, monoethanolamine, organic silicon defoamer and soybean lecithin wetting agent and suitable
Amount water adds together mixing, and is heated to uniform temperature；
(2) keep under steady temperature, mixed solution is mixed with agitator, be uniformly dispersed；
(3) after disperseing, a certain amount of water soluble acrylic resin, newtrex phenol-formaldehyde resin modified and aqueous acrylamide are sequentially added
Sour mill base；
(4) mixed solution system is mixed under certain rotating speed, be uniformly dispersed；
(5) a certain amount of 2 ethyl hexanoic acid zirconium and organic silicon defoamer are subsequently adding；
(6) finally filtrate is collected with filter filtration, you can obtain a kind of modified ink of addition 2 ethyl hexanoic acid zirconium auxiliary agent.
3. it is according to claim 2 it is a kind of addition 2 ethyl hexanoic acid zirconium auxiliary agent modified ink, it is characterised in that in step
It is rapid (2) in, heating-up temperature is 50-60 DEG C.
4. it is according to claim 2 it is a kind of addition 2 ethyl hexanoic acid zirconium auxiliary agent modified ink, it is characterised in that in step
It is rapid (2) in, agitator presses the rotating speed of 500-600 r/min, dispersed 3-4 hours.
5. it is according to claim 2 it is a kind of addition 2 ethyl hexanoic acid zirconium auxiliary agent modified ink, it is characterised in that in step
It is rapid (4) in, agitator presses the rotating speed of 600-700r/min, dispersed 3-5 hours.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611111917.4A CN106590147A (en) | 2016-12-06 | 2016-12-06 | Modified ink containing zirconium 2-ethylhexanoate assistant and preparation technology thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611111917.4A CN106590147A (en) | 2016-12-06 | 2016-12-06 | Modified ink containing zirconium 2-ethylhexanoate assistant and preparation technology thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106590147A true CN106590147A (en) | 2017-04-26 |
Family
ID=58596137
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611111917.4A Pending CN106590147A (en) | 2016-12-06 | 2016-12-06 | Modified ink containing zirconium 2-ethylhexanoate assistant and preparation technology thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106590147A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109337439A (en) * | 2018-11-13 | 2019-02-15 | 中山市富日印刷材料有限公司 | A kind of environment-friendly type high chroma art ink and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101250350A (en) * | 2008-03-26 | 2008-08-27 | 中国印钞造币总公司 | Soybean oil based protruding printing ink |
| CN102585591A (en) * | 2012-03-12 | 2012-07-18 | 洋紫荆油墨（河北）有限公司 | Method for making blue offset printing ink |
| CN105017858A (en) * | 2015-07-31 | 2015-11-04 | 李可 | Polymerized-rosin-modified-phenolic-resin-added ink and preparation method thereof |
| CN105062210A (en) * | 2015-08-09 | 2015-11-18 | 吴房文 | Preparation method of printing ink by adding colophony modified phenolic resin |
-
2016
- 2016-12-06 CN CN201611111917.4A patent/CN106590147A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101250350A (en) * | 2008-03-26 | 2008-08-27 | 中国印钞造币总公司 | Soybean oil based protruding printing ink |
| CN102585591A (en) * | 2012-03-12 | 2012-07-18 | 洋紫荆油墨（河北）有限公司 | Method for making blue offset printing ink |
| CN105017858A (en) * | 2015-07-31 | 2015-11-04 | 李可 | Polymerized-rosin-modified-phenolic-resin-added ink and preparation method thereof |
| CN105062210A (en) * | 2015-08-09 | 2015-11-18 | 吴房文 | Preparation method of printing ink by adding colophony modified phenolic resin |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109337439A (en) * | 2018-11-13 | 2019-02-15 | 中山市富日印刷材料有限公司 | A kind of environment-friendly type high chroma art ink and preparation method thereof |
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Application publication date: 20170426 |