CN106752245A - A kind of lintel renovation is filled up with atomized ash and preparation method thereof - Google Patents
A kind of lintel renovation is filled up with atomized ash and preparation method thereof Download PDFInfo
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- CN106752245A CN106752245A CN201611216218.6A CN201611216218A CN106752245A CN 106752245 A CN106752245 A CN 106752245A CN 201611216218 A CN201611216218 A CN 201611216218A CN 106752245 A CN106752245 A CN 106752245A
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- parts
- ash
- rice hull
- filled
- lintel
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/34—Filling pastes
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Filled up with atomized ash and preparation method thereof the invention discloses a kind of renovation of lintel, be prepared from the following raw materials in parts by weight：50 60 parts of unsaturated polyester resin, 58 parts of medical stone powder, 12 15 parts of magnesia, 13 parts of manganese solid impurity particle, 36 parts of modified nano montmorillonite powder, modified 37 parts of rice hull ash, 15 25 parts of dibutyl phthalate, 13 parts of cobalt iso-octoate, 20 25 parts of polymethyl methacrylate, 13 parts of pineapple flaxen fiber, 12 parts of dimethylaniline, 35 parts of epoxidized soybean oil.Lintel renovation of the invention is filled up and uses atomized ash, and with excellent weatherability and waterproof, seepage control performance, impact strength is good, fire prevention, anti-biological bite and corrosion, environmental protection.
Description
Technical field
Filled up with atomized ash and its preparation side the present invention relates to lintel reconditioning technology field, more particularly to a kind of renovation of lintel
Method.
Background technology
Lintel, is exactly the crossbeam on main entrance top doorframe top, and typically all big and heavy wood just, can install mark on lintel
Knowledge, font etc., often expose to the sun and rain due to lintel outside, and the time one is grown, it may appear that discoloration, the phenomenon damaged.Have at present
It is directly to replace, causes a large amount of wastes, and high cost；Have plenty of to lintel by being reused after renovation.Lintel is renovated
During need to be filled up by end of door plate, need to use atomized ash when filling up.
Atomized ash is commonly called as putty, is to develop new pointing material a kind of faster, energy also known as unsaturated polyester resin putty
Body surface is perfectly adhered to, and is not cracked in drying process.The shortcoming of existing atomized ash is：Become in the morning and evening temperature difference
Easily it is cracked under the larger environment of change, or even is come off, adhesive force is low, and weatherability is poor.
The content of the invention
The purpose of the present invention is to overcome the deficiencies in the prior art, there is provided a kind of lintel renovation is filled up and uses atomized ash, fillibility
Good with anti-contracility, painting scrapes that film forming defensive position sense is fine and smooth, smooth densification, with excellent weatherability and waterproof, seepage control performance, can be through
Do not made a variation by the long-time test of the subzero 30 DEG C of severe cold of north of china in winter and 40 DEG C of cold and hot weathers of high temperature of southern summer, still with very
Good adhesive force is big, and impact strength is good, fire prevention, anti-biological bite and corrosion, environmental protection.
To achieve these goals, the present invention is adopted the following technical scheme that：
A kind of lintel renovation is filled up and uses atomized ash, is made from the following raw materials in parts by weight：Unsaturated polyester resin 50-60
Part, medical stone powder 5-8 part, magnesia 12-15 parts, 1-3 parts of manganese solid impurity particle, 3-6 parts of modified nano montmorillonite powder, be modified rice hull ash
3-7 parts, dibutyl phthalate 15-25 parts, cobalt iso-octoate 1-3 parts, polymethyl methacrylate 20-25 parts, pineapple fibre fibre
1-3 parts, dimethylaniline 1-2 parts, epoxidized soybean oil 3-5 parts of dimension.
Described modified nano montmorillonite powder is montmorillonite powder and N-METHYLFORMAMIDE in mass ratio 1:5 in stirring at 75 DEG C
Mixing 5 hours, is separated by filtration and is vacuum dried 5 hours after 60 DEG C, finally grinds to form nano particle, obtains final product modified nano montmorillonite
Powder.
Described modified rice hull ash is prepared by following methods：First with 10% hydrogen peroxide dipping rice hull ash 1 hour after, spend from
Sub- water washing to neutrality, drying is subsequently adding nano-sized carbon, 1% polyisobutene, 1% lemon equivalent to rice hull ash weight 2%
After lemon acid tributyl, 1% crosslinking agent TAC, 2% ferrocene, 3500 revs/min of stirrings 30 minutes, dries pulverizing into powder, i.e.,
Must be modified rice hull ash.
Described lintel renovation is filled up with the preparation method of atomized ash, is comprised the following steps：
(1) by medical stone powder, magnesia, manganese solid impurity particle, dibutyl phthalate, cobalt iso-octoate, poly- epoxidized soybean oil
Dispensing is weighed by proportioning, is sequentially placed into mixer, through being sufficiently stirred for, add pulverizer to be crushed to less than 120 after being well mixed
Mesh, obtains mixture A；
(2) by modified nano montmorillonite powder, modified rice hull ash, methyl methacrylate, pineapple flaxen fiber, dimethylaniline
Dispensing is weighed by proportioning, is sequentially placed into mixer, through being sufficiently stirred for, be ground 10 minutes after being well mixed, obtain mixture
B；
(3) unsaturated polyester resin is put into by proportional quantity it is fully dispersed on high speed dispersor, under 800r/min rotating speeds
Mixture thing A and mixture B is sequentially added, resulting material is stirred, and grind to form uniform lotion, you can.
Compared with the prior art, beneficial effects of the present invention are as follows：
Lintel renovation of the invention is filled up and uses atomized ash, and fillibility and anti-contracility are good, and film forming defensive position sense exquisiteness, light are scraped in painting
Slip close, with excellent weatherability and waterproof, seepage control performance, be amenable to the subzero 30 DEG C of severe cold of north of china in winter and southern summer 40
The long-time test of DEG C cold and hot weather of high temperature does not make a variation, still big with very good adhesive force, and impact strength is good, prevents
Fiery, anti-biological bite and corrosion, environmental protection.By adding modified nano montmorillonite powder and modified rice hull ash, original can be effectively improved
Sub grey weatherability, water resistance and product tack, while making product that there are excellent fire prevention, anti-biological bite and corrosion；Addition manganese
Slag, manganese slag is a kind of industrial residue of cellular structures, and it is high temperature furnace during manganeisen and manganese alloy smelting
Slag is formed through water quenching cooling, with the architectural feature similar to glass bead：Light weight, porous, nature of glass shell, and containing a large amount of
Closed pore structures, absorbability is strong, stable chemical nature, wear-resisting, heat-resisting, can for atomized ash provide excellent surface property, increase-volume,
Thickening and raising adhesive force, because it has larger pore volume, can make film shorten drying time, can also reduce unsaturation
The consumption of resin, reduces cost makes film coated surface gloss, increases the wearability and mar-resistance of film, easily applies and scrape, dry, removing
Smelly, and water resistance is good, permeability is good, and has good impact strength and tensile force, it is possible to increase atomized ash is deposited
The storage life-span.
Specific embodiment
The present invention is further illustrated with reference to embodiments, but the present invention is not limited only to these embodiments, not
On the premise of departing from present inventive concept, any improvement made is within the scope of the present invention.
Embodiment 1：
A kind of lintel renovation is filled up and uses atomized ash, is made from the following raw materials in parts by weight：50 parts of unsaturated polyester resin, wheat
8 parts of meal stone flour, 12 parts of magnesia, 1 part of manganese solid impurity particle, 3 parts of modified nano montmorillonite powder, modified 3 parts of rice hull ash, phthalic acid
15 parts of dibutyl ester, 1 part of cobalt iso-octoate, 20 parts of polymethyl methacrylate, 1 part of pineapple flaxen fiber, 1 part of dimethylaniline, epoxy
3 parts of soybean oil.
Described modified nano montmorillonite powder is montmorillonite powder and N-METHYLFORMAMIDE in mass ratio 1:5 in stirring at 75 DEG C
Mixing 5 hours, is separated by filtration and is vacuum dried 5 hours after 60 DEG C, finally grinds to form nano particle, obtains final product modified nano montmorillonite
Powder.
Described modified rice hull ash is prepared by following methods：First with 10% hydrogen peroxide dipping rice hull ash 1 hour after, spend from
Sub- water washing to neutrality, drying is subsequently adding nano-sized carbon, 1% polyisobutene, 1% lemon equivalent to rice hull ash weight 2%
After lemon acid tributyl, 1% crosslinking agent TAC, 2% ferrocene, 3500 revs/min of stirrings 30 minutes, dries pulverizing into powder, i.e.,
Must be modified rice hull ash.
Described lintel renovation is filled up with the preparation method of atomized ash, is comprised the following steps：
(1) by medical stone powder, magnesia, manganese solid impurity particle, dibutyl phthalate, cobalt iso-octoate, poly- epoxidized soybean oil
Dispensing is weighed by proportioning, is sequentially placed into mixer, through being sufficiently stirred for, add pulverizer to be crushed to less than 120 after being well mixed
Mesh, obtains mixture A；
(2) by modified nano montmorillonite powder, modified rice hull ash, methyl methacrylate, pineapple flaxen fiber, dimethylaniline
Dispensing is weighed by proportioning, is sequentially placed into mixer, through being sufficiently stirred for, be ground 10 minutes after being well mixed, obtain mixture
B；
(3) unsaturated polyester resin is put into by proportional quantity it is fully dispersed on high speed dispersor, under 800r/min rotating speeds
Mixture thing A and mixture B is sequentially added, resulting material is stirred, and grind to form uniform lotion, you can.
Embodiment 2：
A kind of lintel renovation is filled up and uses atomized ash, is made from the following raw materials in parts by weight：55 parts of unsaturated polyester resin, wheat
6 parts of meal stone flour, 13 parts of magnesia, 2 parts of manganese solid impurity particle, 5 parts of modified nano montmorillonite powder, modified 5 parts of rice hull ash, phthalic acid
120 parts of dibutyl ester, 2 parts of cobalt iso-octoate, 22 parts of polymethyl methacrylate, 2 parts of pineapple flaxen fiber, 2 parts of dimethylaniline, epoxy
4 parts of soybean oil.
Described modified nano montmorillonite powder is montmorillonite powder and N-METHYLFORMAMIDE in mass ratio 1:5 in stirring at 75 DEG C
Mixing 5 hours, is separated by filtration and is vacuum dried 5 hours after 60 DEG C, finally grinds to form nano particle, obtains final product modified nano montmorillonite
Powder.
Described modified rice hull ash is prepared by following methods：First with 10% hydrogen peroxide dipping rice hull ash 1 hour after, spend from
Sub- water washing to neutrality, drying is subsequently adding nano-sized carbon, 1% polyisobutene, 1% lemon equivalent to rice hull ash weight 2%
After lemon acid tributyl, 1% crosslinking agent TAC, 2% ferrocene, 3500 revs/min of stirrings 30 minutes, dries pulverizing into powder, i.e.,
Must be modified rice hull ash.
Described lintel renovation is filled up with the preparation method of atomized ash, is comprised the following steps：
(1) by medical stone powder, magnesia, manganese solid impurity particle, dibutyl phthalate, cobalt iso-octoate, poly- epoxidized soybean oil
Dispensing is weighed by proportioning, is sequentially placed into mixer, through being sufficiently stirred for, add pulverizer to be crushed to less than 120 after being well mixed
Mesh, obtains mixture A；
(2) by modified nano montmorillonite powder, modified rice hull ash, methyl methacrylate, pineapple flaxen fiber, dimethylaniline
Dispensing is weighed by proportioning, is sequentially placed into mixer, through being sufficiently stirred for, be ground 10 minutes after being well mixed, obtain mixture
B；
(3) unsaturated polyester resin is put into by proportional quantity it is fully dispersed on high speed dispersor, under 800r/min rotating speeds
Mixture thing A and mixture B is sequentially added, resulting material is stirred, and grind to form uniform lotion, you can.
Embodiment 3：
A kind of lintel renovation is filled up and uses atomized ash, is made from the following raw materials in parts by weight：60 parts of unsaturated polyester resin, wheat
5 parts of meal stone flour, 15 parts of magnesia, 3 parts of manganese solid impurity particle, 6 parts of modified nano montmorillonite powder, modified 7 parts of rice hull ash, phthalic acid
25 parts of dibutyl ester, 3 parts of cobalt iso-octoate, 25 parts of polymethyl methacrylate, 3 parts of pineapple flaxen fiber, 2 parts of dimethylaniline, epoxy
5 parts of soybean oil.
Described modified nano montmorillonite powder is montmorillonite powder and N-METHYLFORMAMIDE in mass ratio 1:5 in stirring at 75 DEG C
Mixing 5 hours, is separated by filtration and is vacuum dried 5 hours after 60 DEG C, finally grinds to form nano particle, obtains final product modified nano montmorillonite
Powder.
Described modified rice hull ash is prepared by following methods：First with 10% hydrogen peroxide dipping rice hull ash 1 hour after, spend from
Sub- water washing to neutrality, drying is subsequently adding nano-sized carbon, 1% polyisobutene, 1% lemon equivalent to rice hull ash weight 2%
After lemon acid tributyl, 1% crosslinking agent TAC, 2% ferrocene, 3500 revs/min of stirrings 30 minutes, dries pulverizing into powder, i.e.,
Must be modified rice hull ash.
Described lintel renovation is filled up with the preparation method of atomized ash, is comprised the following steps：
(1) by medical stone powder, magnesia, manganese solid impurity particle, dibutyl phthalate, cobalt iso-octoate, poly- epoxidized soybean oil
Dispensing is weighed by proportioning, is sequentially placed into mixer, through being sufficiently stirred for, add pulverizer to be crushed to less than 120 after being well mixed
Mesh, obtains mixture A；
(2) by modified nano montmorillonite powder, modified rice hull ash, methyl methacrylate, pineapple flaxen fiber, dimethylaniline
Dispensing is weighed by proportioning, is sequentially placed into mixer, through being sufficiently stirred for, be ground 10 minutes after being well mixed, obtain mixture
B；
(3) unsaturated polyester resin is put into by proportional quantity it is fully dispersed on high speed dispersor, under 800r/min rotating speeds
Mixture thing A and mixture B is sequentially added, resulting material is stirred, and grind to form uniform lotion, you can.
Claims (4)
1. a kind of lintel renovation is filled up and uses atomized ash, it is characterised in that：It is made from the following raw materials in parts by weight：Unsaturated polyester (UP) tree
Fat 70-90 parts, medical stone powder 5-8 parts, magnesia 12-15 parts, 1-3 parts of manganese solid impurity particle, 3-6 parts of modified nano montmorillonite powder, change
3-7 parts of rice hull ash of property, dibutyl phthalate 15-25 parts, cobalt iso-octoate 1-3 parts, polymethyl methacrylate 20-25 parts,
1-3 parts, dimethylaniline 1-2 parts, epoxidized soybean oil 3-5 parts of pineapple flaxen fiber.
2. lintel renovation according to claim 1 is filled up and uses atomized ash, it is characterised in that：Described modified nano montmorillonite
Powder is montmorillonite powder and N-METHYLFORMAMIDE in mass ratio 1:5 in mixing 5 hours is stirred at 75 DEG C, be separated by filtration true after 60 DEG C
Sky is dried 5 hours, finally grinds to form nano particle, obtains final product modified nano montmorillonite powder.
3. lintel renovation according to claim 1 is filled up and uses atomized ash, it is characterised in that：Described modified rice hull ash by with
It is prepared by lower section method：First with 10% hydrogen peroxide dipping rice hull ash 1 hour after, be washed with deionized to neutrality, drying is subsequently adding
Nano-sized carbon, 1% polyisobutene, 1% ATBC, 1% crosslinking agent TAC equivalent to rice hull ash weight 2%,
2% ferrocene, after 3500 revs/min are stirred 30 minutes, dries pulverizing obtains final product modified rice hull ash into powder.
4. lintel renovation according to claim 1 is filled up with the preparation method of atomized ash, it is characterised in that：Including following step
Suddenly：
(1) by medical stone powder, magnesia, manganese solid impurity particle, dibutyl phthalate, cobalt iso-octoate, poly- epoxidized soybean oil by matching somebody with somebody
Than weighing dispensing, it is sequentially placed into mixer, through being sufficiently stirred for, adds pulverizer to be crushed to less than 120 mesh after being well mixed, obtains
Mixture A；
(2) by modified nano montmorillonite powder, modified rice hull ash, methyl methacrylate, pineapple flaxen fiber, dimethylaniline by matching somebody with somebody
Than weighing dispensing, it is sequentially placed into mixer, through being sufficiently stirred for, is ground 10 minutes after being well mixed, obtains mixture B；
(3) unsaturated polyester resin is put into by proportional quantity it is fully dispersed on high speed dispersor, under 800r/min rotating speeds successively
Mixture thing A and mixture B is added, resulting material is stirred, and grind to form uniform lotion, you can.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611216218.6A CN106752245A (en) | 2016-12-26 | 2016-12-26 | A kind of lintel renovation is filled up with atomized ash and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611216218.6A CN106752245A (en) | 2016-12-26 | 2016-12-26 | A kind of lintel renovation is filled up with atomized ash and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN106752245A true CN106752245A (en) | 2017-05-31 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611216218.6A Pending CN106752245A (en) | 2016-12-26 | 2016-12-26 | A kind of lintel renovation is filled up with atomized ash and preparation method thereof |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101570655A (en) * | 2009-05-26 | 2009-11-04 | 广东三和化工科技有限公司 | Environment-friendly aqueous putty |
| CN103171232A (en) * | 2013-03-21 | 2013-06-26 | 芜湖众力部件有限公司 | Method for compositing leather on surface of bonder used by car door interior parts and containing modified diatomite |
| CN105315750A (en) * | 2014-07-07 | 2016-02-10 | 侯霞 | Environmentally friendly putty |
-
2016
- 2016-12-26 CN CN201611216218.6A patent/CN106752245A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101570655A (en) * | 2009-05-26 | 2009-11-04 | 广东三和化工科技有限公司 | Environment-friendly aqueous putty |
| CN103171232A (en) * | 2013-03-21 | 2013-06-26 | 芜湖众力部件有限公司 | Method for compositing leather on surface of bonder used by car door interior parts and containing modified diatomite |
| CN105315750A (en) * | 2014-07-07 | 2016-02-10 | 侯霞 | Environmentally friendly putty |
Non-Patent Citations (3)
| Title |
|---|
| 宁平等: "《大宗工业固废环境风险评价》", 31 July 2014, 冶金工业出版社 * |
| 欧育湘: "《阻燃塑料手册》", 31 January 2008, 国防工业出版社 * |
| 粮食大辞典编辑委员会: "《粮食大辞典》", 31 December 2009, 中国物资出版社 * |
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Application publication date: 20170531 |