CN106750569A - A kind of compound edible film of polysaccharide/tara gum and preparation method thereof - Google Patents
A kind of compound edible film of polysaccharide/tara gum and preparation method thereof Download PDFInfo
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- CN106750569A CN106750569A CN201611074268.5A CN201611074268A CN106750569A CN 106750569 A CN106750569 A CN 106750569A CN 201611074268 A CN201611074268 A CN 201611074268A CN 106750569 A CN106750569 A CN 106750569A
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- polysaccharide
- tara gum
- edible film
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L5/00—Compositions of polysaccharides or of their derivatives not provided for in groups C08L1/00 or C08L3/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2305/00—Characterised by the use of polysaccharides or of their derivatives not provided for in groups C08J2301/00 or C08J2303/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2405/00—Characterised by the use of polysaccharides or of their derivatives not provided for in groups C08J2401/00 or C08J2403/00
- C08J2405/08—Chitin; Chondroitin sulfate; Hyaluronic acid; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/14—Gas barrier composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Medicinal Preparation (AREA)
- General Preparation And Processing Of Foods (AREA)
- Jellies, Jams, And Syrups (AREA)
Abstract
The invention discloses a kind of compound edible film of polysaccharide/tara gum, it is made up of the following raw material of mass parts：20~40 parts of pulullan polysaccharide, 1~10 part of selenium polysaccharide, 1~5 part of shitosan, 100~200 parts of tara gum, 1~10 part of polyalcohols plasticizer；Described polyalcohols plasticizer be glycerine, sorbierite, polyethylene glycol one in or several compositions.The present invention compounds the blue polysaccharide in Shandong, selenium polysaccharide, shitosan, and use polyol plasticiser, obtained edible film close structure, block water it is high with oxygen resistance, mechanical strength is good, also the bacteriostasis property with spectrum and the health-care effect such as anti-metal poisoning, anti-oxidant, antiviral, antitumor, raising immunity of organisms.
Description
Technical field
The present invention relates to food technology field, and in particular to a kind of compound edible film of polysaccharide/tara gum and its preparation side
Method.
Background technology
Edible film be as a thin layer edible material of packaging for foodstuff, or between food component and food component formed
Thin film, according to the difference of material, usable film can be roughly divided into protein type, lard type, glycan and compound four
Class.Usable film typically has following feature：1st, with excellent barrier property, ridden with good resistance, fragrance protectiveness, blocked water
Property and oil resistance, the transmission of the matter that can completely cut off between food and environment and food product, improve food quality, extension shelf
Life-span；2nd, easily it is biodegradable, without any pollution；3rd, improve food machinery intensity to make it easier to processing and forge, prevent local flavor
Material volatilizees；3rd, can instant food carry out individual packaging；4th, can be used as nutrition fortifier, antioxidant, anti-microbial agents
Carrier.
With the further research of edible film, single group of edible film and the single edible film of performance of formation are using upper tool
Have certain limitation, the single edible film of performance can not meet the demand in market, can be used film performance lifting and
Research and development on multi-functional are increasingly taken seriously.
The content of the invention
It is an object of the present invention to be directed to prior art, there is provided a kind of compound edible film of polysaccharide/tara gum and its preparation
Method.
To achieve the above object, the present invention takes following technical scheme：A kind of compound edible film of polysaccharide/tara gum its by
The following raw material composition of mass parts：20~40 parts of pulullan polysaccharide, 1~10 part of selenium polysaccharide, 1~5 part of shitosan, tara gum 100~
200 parts, 1~10 part of polyalcohols plasticizer；Described polyalcohols plasticizer be glycerine, sorbierite, polyethylene glycol one in
Or several compositions.
Its preparation method is comprised the following steps：
(1) shitosan, selenium polysaccharide, shitosan are added to mass concentration dissolving has obtained polysaccharide solution in acid solution for 1%；
(2) by tara gum be made mass concentration I 1~5% solution, under the conditions of being placed in 80 DEG C stir 5 hours；
(3) tara gum solution is mixed with polysaccharide solution obtained in step (1), adds polyol plasticiser.Fully stirred under normal temperature
Mix uniform, ultrasonic de-bubbled；
(4) mixture taken obtained by step (3) is evenly laid out in dry mould, the forced air drying under the conditions of 45 DEG C, cooling
After take off film, by film storage in the drier that relative humidity is 53%, balance 72h under the conditions of 25 DEG C, obtain final product of the invention one
Plant the compound edible film of polysaccharide/tara gum.
Further, in described step (4), it is drier that saturation magnesium nitrate hexahydrate solution is used in drier.
In the present invention, polyalcohol is one or more of glycerine, sorbierite, polyethylene glycol, glycerine, sorbierite, poly- second two
Alcohol influences film hot property, materialization and the barrier property of tara gum, addition glycerine, sorbierite, one kind of polyethylene glycol or and several
The tensile strength that can increase film is planted, elongation is improved.
In the present invention, shitosan is natural polysaccharide macromolecule, is the product of the N- deacetylations of chitin.Dissolve in organic
Acid, with natural nontoxicity, biocompatibility and biological degradability, and has the bacteriostatic activity of wide spectrum.But shitosan does not have
The oxygen resistance that blocks water having.
In the present invention, gas barrier property, plasticity, the viscosity of pulullan polysaccharide are relatively strong, and gas permeability is low, oxygen, nitrogen, carbon dioxide
Can hardly pass through with the gas such as fragrance, reduce the nutritive loss of food in storage process, and with grease resistance, can prevent
Spread and because the smell that dispensing and Oxidation of Fat and Oils contained by additive cause goes bad with taste.
In the present invention, selenium polysaccharide is a kind of organic selenium compounds, and natural selenium polysaccharide can be from ganoderma lucidum, mushroom, spirulina, potato
Extracted in the plants such as leaf, garlic, black fungus.The bioactivity of selenium polysaccharide is high, is easy to absorption of human body and utilization, with preferably raw
Reason and pharmacological function, selenium polysaccharide participate in the synthesis of edible film, at the same selenium polysaccharide have good health care make to have anti-metal poisoning,
The functions such as anti-oxidant, antiviral, antitumor, raising immunity of organisms, are alternatively arranged as health care of food additive and use.
Wherein, in the present invention, pulullan polysaccharide, selenium polysaccharide, shitosan it is compound, make three kinds of polysaccharide in edible film application
On, performance complement, solving pulullan polysaccharide solution shitosan has bacteriostatic activity but without the oxygen resistance that blocks water, selenium polysaccharide solution
Certainly edible film unitary function problem, makes also to have outside the performances such as the barrier that there is use film of the invention common edible film to have
Preferable biocidal property and health-care effect.
The beneficial effects of the invention are as follows：Edible film close structure of the invention, block water, mechanical strength high with oxygen resistance
It is good, while also having bacteriostasis property and the anti-metal poisoning of spectrum, anti-oxidant, antiviral, antitumor, raising immunity of organisms etc.
Health-care effect.
Specific embodiment
With reference to specific embodiment, to further instruction of the present invention.
Embodiment 1
A kind of compound edible film of polysaccharide/tara gum is made up of the following raw material of mass parts：40 parts of pulullan polysaccharide, selenium polysaccharide
1 part, 5 parts of shitosan, 100 parts of tara gum, 10 parts of polyalcohols plasticizer；Wherein, polyalcohols plasticizer is glycerine, sorb
Alcohol, polyethylene glycol.
Its preparation method is comprised the following steps：
(1) shitosan, selenium polysaccharide, shitosan are added to mass concentration dissolving has obtained polysaccharide solution in acid solution for 1%；
(2) by tara gum be made mass concentration I 5% solution, under the conditions of being placed in 80 DEG C stir 5 hours；
(3) tara gum solution is mixed with polysaccharide solution obtained in step (1), adds polyol plasticiser.Fully stirred under normal temperature
Mix uniform, ultrasonic de-bubbled；
(4) mixture taken obtained by step (3) is evenly laid out in dry mould, and use saturation magnesium nitrate hexahydrate solution for
Drier, the forced air drying under the conditions of 45 DEG C, takes off film after cooling, by film storage in the drier that relative humidity is 53%,
72h is balanced under the conditions of 25 DEG C, a kind of compound edible film of polysaccharide/tara gum of the invention is obtained final product.
Embodiment 2
A kind of compound edible film of polysaccharide/tara gum is made up of the following raw material of mass parts：20 parts of pulullan polysaccharide, selenium polysaccharide
10 parts, 1 part of shitosan, 200 parts of tara gum, 1 part of polyalcohols plasticizer；Wherein, polyalcohols plasticizer is glycerine.
Its preparation method is comprised the following steps：
(1) shitosan, selenium polysaccharide, shitosan are added to mass concentration dissolving has obtained polysaccharide solution in acid solution for 1%；
(2) by tara gum be made mass concentration I 1% solution, under the conditions of being placed in 80 DEG C stir 5 hours；
(3) tara gum solution is mixed with polysaccharide solution obtained in step (1), adds polyol plasticiser.Fully stirred under normal temperature
Mix uniform, ultrasonic de-bubbled；
(4) mixture taken obtained by step (3) is evenly laid out in dry mould, and use saturation magnesium nitrate hexahydrate solution for
Drier, the forced air drying under the conditions of 45 DEG C, takes off film after cooling, by film storage in the drier that relative humidity is 53%,
72h is balanced under the conditions of 25 DEG C, a kind of compound edible film of polysaccharide/tara gum of the invention is obtained final product.
Embodiment 3
A kind of compound edible film of polysaccharide/tara gum is made up of the following raw material of mass parts：30 parts of pulullan polysaccharide, selenium polysaccharide
5 parts, 2 parts of shitosan, 150 parts of tara gum, 5 parts of polyalcohols plasticizer；Wherein, polyalcohols plasticizer is sorbierite.
Its preparation method is with embodiment 1.
Embodiment 3
A kind of compound edible film of polysaccharide/tara gum is made up of the following raw material of mass parts：25 parts of pulullan polysaccharide, selenium polysaccharide
10 parts, 5 parts of shitosan, 180 parts of tara gum, 10 parts of polyalcohols plasticizer；Wherein, polyalcohols plasticizer is polyethylene glycol.
Its preparation method is with embodiment 2.
Claims (3)
1. a kind of compound edible film of polysaccharide/tara gum, it is characterised in that it is made up of the following raw material of mass parts：Propiram is more
20~40 parts of sugar, 1~10 part of selenium polysaccharide, 1~5 part of shitosan, 100~200 parts of tara gum, 1~10 part of polyalcohols plasticizer；
Described polyalcohols plasticizer be glycerine, sorbierite, polyethylene glycol one in or several compositions.
2. a kind of preparation method of compound edible film of polysaccharide/tara gum according to claim 1, it is characterised in that bag
Include following steps：
(1) shitosan, selenium polysaccharide, shitosan are added to mass concentration dissolving has obtained polysaccharide solution in acid solution for 1%；
(2) by tara gum be made mass concentration I 1~5% solution, under the conditions of being placed in 80 DEG C stir 5 hours；
(3) tara gum solution is mixed with polysaccharide solution obtained in step (1), adds polyol plasticiser.Fully stirred under normal temperature
Mix uniform, ultrasonic de-bubbled；
(4) mixture taken obtained by step (3) is evenly laid out in dry mould, the forced air drying under the conditions of 45 DEG C, cooling
After take off film, by film storage in the drier that relative humidity is 53%, balance 72h under the conditions of 25 DEG C, obtain final product of the invention one
Plant the compound edible film of polysaccharide/tara gum.
3. the preparation method of a kind of compound edible film of polysaccharide/tara gum according to claim 2, it is characterised in that：Institute
In the step of stating (4), it is drier that saturation magnesium nitrate hexahydrate solution is used in drier.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611074268.5A CN106750569A (en) | 2016-11-29 | 2016-11-29 | A kind of compound edible film of polysaccharide/tara gum and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611074268.5A CN106750569A (en) | 2016-11-29 | 2016-11-29 | A kind of compound edible film of polysaccharide/tara gum and preparation method thereof |
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| Publication Number | Publication Date |
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| CN106750569A true CN106750569A (en) | 2017-05-31 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201611074268.5A Withdrawn CN106750569A (en) | 2016-11-29 | 2016-11-29 | A kind of compound edible film of polysaccharide/tara gum and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109942902A (en) * | 2019-02-18 | 2019-06-28 | 浦江县欧立生物技术有限公司 | A kind of purposes of plant extract rich in selenium composite membrane-forming regulator |
| CN113698676A (en) * | 2021-08-10 | 2021-11-26 | 苏州优跃腾信息科技有限公司 | Preparation method of environment-friendly food packaging material |
| WO2024046488A1 (en) * | 2022-08-31 | 2024-03-07 | 江苏大学 | Method for preparing antibacterial and freshness-retaining packaging material for fruits by using 3d printing technology |
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| CN104140568A (en) * | 2014-07-30 | 2014-11-12 | 江南大学 | Edible film with continuous antioxidant function and preparation method and application thereof |
| CN104861187A (en) * | 2015-06-15 | 2015-08-26 | 东北林业大学 | Preparation method of tara gum edible membrane with hydrophobic performance |
| CN104987545A (en) * | 2015-06-23 | 2015-10-21 | 中山火炬职业技术学院 | Pulullan and pectin edible film |
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-
2016
- 2016-11-29 CN CN201611074268.5A patent/CN106750569A/en not_active Withdrawn
Patent Citations (5)
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| CN104140568A (en) * | 2014-07-30 | 2014-11-12 | 江南大学 | Edible film with continuous antioxidant function and preparation method and application thereof |
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| CN104987545A (en) * | 2015-06-23 | 2015-10-21 | 中山火炬职业技术学院 | Pulullan and pectin edible film |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109942902A (en) * | 2019-02-18 | 2019-06-28 | 浦江县欧立生物技术有限公司 | A kind of purposes of plant extract rich in selenium composite membrane-forming regulator |
| CN113698676A (en) * | 2021-08-10 | 2021-11-26 | 苏州优跃腾信息科技有限公司 | Preparation method of environment-friendly food packaging material |
| WO2024046488A1 (en) * | 2022-08-31 | 2024-03-07 | 江苏大学 | Method for preparing antibacterial and freshness-retaining packaging material for fruits by using 3d printing technology |
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Application publication date: 20170531 |