CN106748150A - A kind of method of low value ocean fish fermenting and producing amino acid foliage fertilizer - Google Patents
A kind of method of low value ocean fish fermenting and producing amino acid foliage fertilizer Download PDFInfo
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- CN106748150A CN106748150A CN201611205814.4A CN201611205814A CN106748150A CN 106748150 A CN106748150 A CN 106748150A CN 201611205814 A CN201611205814 A CN 201611205814A CN 106748150 A CN106748150 A CN 106748150A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B1/00—Superphosphates, i.e. fertilisers produced by reacting rock or bone phosphates with sulfuric or phosphoric acid in such amounts and concentrations as to yield solid products directly
- C05B1/02—Superphosphates
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C11/00—Other nitrogenous fertilisers
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
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Abstract
The present invention relates to fertilizer preparing technical field.The invention discloses a kind of method of low value ocean fish fermenting and producing amino acid foliage fertilizer, it include slurrying, sterilize, peculiar smell of dispelling, enzyme preparation, enzymolysis, inactivation and compounding etc. processing step, wherein enzyme preparation is obtained using protease and the compound method of inorganic mineral carrier, with enzymolysis enzymolysis efficiency higher.Low value ocean fish complete decomposition, it is easy to the absorption and utilization of crop；Preparation method in the present invention, less generation discarded object, will not pollute to environment, and this preparation method efficiency is higher；The amino acid foliage fertilizer prepared using the method in the present invention has compatibility reasonable, the features such as nutriment is abundant, and because it has and the more preferable compatibility in blade face, the longer time can be stopped on vegetables blade face, nutriment is with more fully by Foliage Absorption in also enabling foliar fertilizer.
Description
Technical field
The present invention relates to fertilizer preparing technical field, more particularly, to a kind of low value ocean fish fermenting and producing amino acid foliage fertilizer
Method.
Background technology
Liquid protein fertilizer is a kind of Crop fertilizer made of discarded animal/vegetable protein.Generally contain in liquid protein fertilizer
There are a large amount of biology peptides, the content of amino acid is particularly enriched, and containing various macroelements, trace element, vitamin etc., it is this
Fertilizer by means of the synergy with other active ingredients, can improve disease-resistant, the resistance of plant, can improve the product of crop
Matter, promotes plant growth, is a kind of new, environment-friendly type animal/vegetable protein fertilizer.Amino acid foliage fertilizer be liquid protein fertilizer in
A kind of main fertilizer.
China is an ocean big country, and fishing for for marine fishery processes quite flourishing, during marine fishery is processed
Often there are a large amount of low value ocean fish products because head is too small or condition is defective, these low value ocean fish products are generally regarded as giving up
Gurry and abandon, a large amount of low value ocean fish products often cause serious problem of environmental pollution after abandoning, while also result in huge
The big wasting of resources,
Therefore, it is a kind of to solve the problems, such as pollution and waste that low value ocean fish product is caused, China crop instantly can be solved again
Fertilizer present situation in short supply, using the teaching of the invention it is possible to provide the technique of a large amount of fertilizer of fine quality becomes have abnormal wide prospect.
Chinese patent notification number CN1260183C, on June 21 2006 day for announcing, discloses a kind of Fish protein biology peptide fertilizer
The preparation method of material, it is characterized in that first the leftover bits and pieces of fresh fish, fresh fish skin or fresh fish bone is crushed, with acid for adjusting pH to 1~6.5,
Add degraded trypsase or pepsin is degraded, then filter, in 0~40 DEG C of concentration, sterilizing.The fish egg of the invention
White biology peptide fertilizer contains biological peptide, and the content of amino acid is particularly enriched, and contains various macroelements, trace element, dimension
Raw element etc., this fertilizer by means of the synergy with other active ingredients, can improve disease-resistant, the resistance of plant, can change
The quality of kind crop, promotes plant growth, is a kind of new, environment-friendly type animal protein fertilizer.But this kind of method prepares albumen
There is inefficiency in fertilizer, obtained liquid protein fertilizer compatibility is unreasonable, lacks the defects such as the essential elements of some plant growths.
The content of the invention
To solve the above problems, the invention provides a kind of amino acid foliage fertilizer protein, content of peptides for preparing
Height, rationally, preparation process is simple is efficient, less generation pollutant for nutritious, compatibility, and it is additional fully to improve low value ocean fish
The method for preparing amino acid foliage fertilizer of value.
To realize above mentioned problem, the technical solution adopted by the present invention is as follows：
A kind of method of low value ocean fish fermenting and producing amino acid foliage fertilizer, comprises the following steps：
a）Slurrying：The water of 1~5 times of its weight is shredded and added after low value ocean fish is decaptitated, and slurrying afterwards is obtained low value ocean fish
Slurry；
b）Sterilizing：It is passed through chlorination in being starched to low value ocean fish to process, while stirring at low speed；
c）Dispel peculiar smell：By the low value ocean fish slurry after sterilization treatment, heated 50~80 minutes at 70~90 DEG C, low speed is stirred during heating
Mix, moisture is filtered off afterwards and obtains low value ocean fish dry, cleaned low value ocean fish dry 5~8 times with water, it is then low in addition
The water of 1~5 times of value ocean fish dry matter weight, is obtained low value ocean fish treatment slurry；
d）Enzyme preparation：By protease, carrier and water according to 1~2：2~3：3~5 weight ratio mixing, in 40~70 DEG C of temperature
Under degree, stirred 10~20 minutes with the rotating speed of 30~45rpm, then stirred 30~50 minutes with the rotating speed of 5~10rpm, then filtered
Except liquid, enzyme preparation is obtained；
e）Enzymolysis：By low value ocean fish treatment slurry with enzyme preparation according to 1：0.8~1.6 weight ratio mixing, and at 50~65 DEG C
Stirred 10~20 minutes with 30~40rpm speed, then stirred 12~16 hours with 4~8rpm speed, be then peeled off enzyme preparation,
Enzymolysis liquid is obtained；
f）Inactivation：To adding potassium carbonate to make the pH value of enzymolysis liquid be 7.5~8.5 in enzymolysis liquid, stir 5~10 minutes, be obtained low
Value ocean fish enzymolysis liquid；
g）Compounding：Low value ocean fish enzymolysis liquid, nutritional agents, wetting agent are pressed 100：5~8：6~12 weight is than well mixed, system
Obtain amino acid foliage fertilizer.
Low value ocean fish is often originated more complicated, and the time of storage also has larger difference, wherein being no lack of content of microorganisms
It is exceeded or even situations such as occur corrupt, it is therefore desirable to endanger small method for disinfection to obtaining using chlorine is this kind of efficiently, after treatment
Low value ocean fish carry out sterilization treatment, can produce hydrochloric acid and hypochlorous acid after chlorine and water reaction, hypochlorous acid primarily serves sterilization and goes out
The effect of bacterium, and hydrochloric acid can then reduce the pH value of raw material slurry, the pH value for starching raw material is in acid to highly acid state, this pH
Scope is conducive to the hydrolysis of protein, can greatly speed up the speed of subsequent protein enzymolysis；After sterilization treatment, the low value of acquisition
Ocean fish is long due to resting period before, it is understood that there may be peculiar smell, while also because being processed by chlorination, a small amount of chlorine of residual
Gas also brings along peculiar smell, needs to remove peculiar smell before further processing, the mode that eliminates the unusual smell of heating, i.e., simple and effective, energy
Enough remove most peculiar smell, but when eliminating the unusual smell herein due to may in right amount be added water with the presence of chlorine residue, when eliminating the unusual smell or
Person notes the measures such as the ventilation of operating environment, prevents chlorine residue from endangering operator's health；In the present invention enzyme preparation by will have work
The protease of property is supported on the composite inorganic carrier with multi-pore channel structure, can so increase the reaction surface of enzyme digestion reaction
Product, while substantial amounts of production cost also can be saved so in production beneficial to the recycling of enzyme preparation after enzyme digestion reaction,
Also can improve production efficiency；Enzyme digestion reaction, according to the suitable pH value of different choice of protease species for being used and corresponding
Reaction temperature, then it is aided with low rate mixing, low value ocean fish is fully contacted with protease, composition is equal after also ensureing enzyme preparation energy
Even distribution, will not settle and reunite；May there is part in the low value ocean fish enzymolysis liquid that enzyme preparation is obtained after separating
The enzyme preparation and protease not separate, in order to prevent these protease in storing process from now on to the quality of protein fertilizer
Impact, or to crop generation harmful effect in application, the inactivation to protease becomes indispensable；Due to by
Nutriment in liquid protein fertilizer obtained in low value ocean fish is main based on amino acid etc., therefore in order to make up wherein potassium, phosphorus
The shortage of element includes proper ratio, it is necessary to carry out compounding nutritional agents to obtained low value ocean fish enzymolysis liquid again in nutritional agents
The element favourable to crop production such as phosphorus potassium, simultaneously because amino acid foliage fertilizer is applied to the blade face of vegetables, and vegetables blade face
The reason for because of structure or secretion, is presented hydrophobicity, to ensure that what foliar fertilizer was capable of the longer time rests on vegetables blade face, therefore
Needing to add some has the wetting agent of surface-active to improve the compatibility of foliar fertilizer and blade face, simultaneously because obtained blade face
Composition is relatively complicated in fertilizer, micromolecule polypeptide and the thorough amino for decomposing that the protein of promising enzymolysis, decomposition are obtained
Acid, it is therefore desirable to which being prepared for different components has targetedly wetting agent.
Preferably, protease is papain or bromelain.
Preferably, in step b, the consumption of chlorine is 100~160mg/L in low value ocean fish slurry during sterilization treatment.
Preferably, in step b and step c, the speed of stirring at low speed is 4~8rpm.
Preferably, in step c, after low value ocean fish treatment slurry is obtained, the pH value of low value ocean fish treatment slurry is adjusted to 5.5
~6.5.
Preferably, in step g, nutritional agents presses 1 by potassium chloride, calcium superphosphate and ammonium dihydrogen phosphate：2.5~3.5：0.5
~1 weight ratio is mixed.
Preferably, in step g, wetting agent presses 2 by sodium alginate, Sucrose Fatty Acid Ester, polyglycerol ester and lecithin：1~2：2~
3：4~6 weight ratio is mixed.
Preferably, the carrier in step d is obtained by following steps：
1）Vermiculite is crushed to 400~500 mesh, is calcined 1~2 hour at 500~550 DEG C afterwards, chlorination is added to after cooling
In sodium solution, soak 4~6 hours；
2）Crushed crude pearlite is broken to 20~40 mesh, 0.5~1 hour is then calcined at 400~500 DEG C, then 1000~
Calcined 1~40 second at 1400 DEG C, 300~400 DEG C are cooled to afterwards, taking-up is added in sodium chloride solution, is soaked 2~3 hours；
3）The product mixing that step 1 and step 2 are obtained, ultrasonically treated 20~60 minutes, filters and uses sodium chloride solution afterwards
Rinse 2~5 times, composite inorganic mineral are obtained after drying；
4）Composite inorganic mineral are crushed to 40~100 mesh carrier is obtained.
Vermiculite is a kind of layer silicate mineral, and its interlayer ion is mainly magnesium ion, calcium ion, sodium ion and potassium ion
Deng, with hydratability higher, more intermediary water usually containing, intermediary water loses after the heating, can be formed wider
Interlayer structure, simultaneously because vermiculite layers amount of charge is larger, with ion-exchange performance higher, because this 2 reasons, leech
Protease needed for can be good at absorption enzymolysis after Shi Jing treatment.Vermiculite is first passed through the calcining of low temperature in this, at it not
On the premise of losing water absorbing properties, increase its interlamellar spacing, its interlayer is possessed the space of enough carrier protein molecule enzymes；Sodium chloride
Solution immersion can make the big ion of divalence between vermiculite layers be exchanged for sodium ion, after vermiculite interlayer ion is exchanged into sodium ion
Protease is adsorbed thereon, and will not be protease inactivation.Perlite is similar with vermiculite, but it is heated
What is expanded afterwards is better, can so be formed with vermiculite and coordinated, and a large amount of vermiculites with smaller layers spacing have more with a small amount of
The pearl petrofacies collaboration of big interlamellar spacing, makes the better good of load protease, it is also possible to increase the rate of recovery of protease.
Preferably, sodium chloride solution is sodium-chloride water solution that concentration expressed in percentage by weight is 20~40%.
Therefore, the invention has the advantages that：
（1）Low value ocean fish complete decomposition, it is easy to the absorption and utilization of crop；
（2）Preparation method in the present invention, less generation discarded object, will not be polluted to environment, and this preparation method is imitated
Rate is higher；
（3）The amino acid foliage fertilizer prepared using the method in the present invention has compatibility rationally, and nutriment fully waits special
Point, and due to its have with the more preferable compatibility in blade face, longer time can be stopped on vegetables blade face, also cause blade face
Nutriment can be with more fully by Foliage Absorption in fertilizer.
Specific embodiment
Technical scheme is further described with reference to specific embodiment.
Obviously, described embodiment is only a part of embodiment of the invention, rather than whole embodiments.Based on this
Embodiment in invention, all other reality that those of ordinary skill in the art are obtained under the premise of creative work is not made
Example is applied, the scope of protection of the invention is belonged to.
Embodiment 1
A kind of method of low value ocean fish fermenting and producing amino acid foliage fertilizer, comprises the following steps：
a）Slurrying：The water of 1 times of its weight is shredded and added after low value ocean fish is decaptitated, and slurrying afterwards is obtained low value ocean fish slurry；
b）Sterilizing：It is passed through chlorination in being starched to low value ocean fish to process, while with 4rpm speed stirring at low speed；It is low during sterilization treatment
The consumption of chlorine is 100mg/L in value ocean fish slurry；
c）Dispel peculiar smell：Heat 50 minutes, the low value ocean fish slurry after sterilization treatment with 4rpm speed low speed during heating at 70 DEG C
Stirring, filters off moisture and obtains low value ocean fish dry afterwards, is cleaned low value ocean fish dry 5 times with water, then low in addition
The water of 1 times of value ocean fish dry matter weight, is obtained low value ocean fish treatment slurry；After low value ocean fish treatment slurry is obtained, at low value ocean fish
The pH value for managing slurry is adjusted to 5.5；
d）Enzyme preparation：By papain, carrier and water according to 1：2：3 weight ratio mixing, at a temperature of 40 DEG C, with
The rotating speed of 30rpm is stirred 10 minutes, then is stirred 30 minutes with the rotating speed of 5rpm, then filters liquid, obtains enzyme preparation；
e）Enzymolysis：By low value ocean fish treatment slurry with enzyme preparation according to 1：0.8 weight is than mixing and fast with 30rpm at 50 DEG C
Rate is stirred 10 minutes, is then stirred 12 hours with 4rpm speed, is then peeled off enzyme preparation, and enzymolysis liquid is obtained；
f）Inactivation：To adding potassium carbonate to make the pH value of enzymolysis liquid be 7.5 in enzymolysis liquid, stir 5 minutes, low value ocean fish enzymolysis is obtained
Liquid；
g）Compounding：Low value ocean fish enzymolysis liquid, nutritional agents, wetting agent are pressed 100：5：6 weight is obtained amino acid than well mixed
Foliar fertilizer；Nutritional agents presses 1 by potassium chloride, calcium superphosphate and ammonium dihydrogen phosphate：2.5：0.5 weight ratio is mixed, wetting agent
2 are pressed by sodium alginate, Sucrose Fatty Acid Ester, polyglycerol ester and lecithin：1：2：4 weight ratio is mixed；
Wherein, the carrier in step d is obtained by following steps：
1）Vermiculite is crushed to 400 mesh, is calcined 1 hour at 500 DEG C afterwards, it is 20% that concentration expressed in percentage by weight is added to after cooling
Sodium chloride solution in, soak 4 hours；
2）Crushed crude pearlite is broken to 20 mesh, then calcining 0.5 hour at 400 DEG C, then calcining 1 second at 1000 DEG C, afterwards
300 DEG C are cooled to, taking-up is added in the sodium chloride solution that concentration expressed in percentage by weight is 20%, soaked 2 hours；
3）The product mixing that step 1 and step 2 are obtained, ultrasonically treated 20 minutes, filters and is with concentration expressed in percentage by weight afterwards
20% sodium chloride solution is rinsed 2 times, and composite inorganic mineral are obtained after drying；
4）Composite inorganic mineral are crushed to 40 mesh carrier is obtained.
Embodiment 2
A kind of method of low value ocean fish fermenting and producing amino acid foliage fertilizer, comprises the following steps：
a）Slurrying：The water of 2 times of its weight is shredded and added after low value ocean fish is decaptitated, and slurrying afterwards is obtained low value ocean fish slurry；
b）Sterilizing：It is passed through chlorination in being starched to low value ocean fish to process, while with 5rpm speed stirring at low speed；It is low during sterilization treatment
The consumption of chlorine is 120mg/L in value ocean fish slurry；
c）Dispel peculiar smell：Heat 60 minutes, the low value ocean fish slurry after sterilization treatment with 5rpm speed low speed during heating at 5 DEG C
Stirring, filters off moisture and obtains low value ocean fish dry afterwards, is cleaned low value ocean fish dry 6 times with water, then low in addition
The water of 2 times of value ocean fish dry matter weight, is obtained low value ocean fish treatment slurry；After low value ocean fish treatment slurry is obtained, at low value ocean fish
The pH value for managing slurry is adjusted to 6；
d）Enzyme preparation：By papain, carrier and water according to 1.5：2.5：4 weight ratio mixing, at a temperature of 50 DEG C,
Stirred 15 minutes with the rotating speed of 35rpm, then stirred 35 minutes with the rotating speed of 7rpm, then filter liquid, obtain enzyme preparation；
e）Enzymolysis：By low value ocean fish treatment slurry with enzyme preparation according to 1：1.2 weight is than mixing and fast with 35rpm at 55 DEG C
Rate is stirred 15 minutes, is then stirred 14 hours with 6rpm speed, is then peeled off enzyme preparation, and enzymolysis liquid is obtained；
f）Inactivation：To adding potassium carbonate to make the pH value of enzymolysis liquid be 8 in enzymolysis liquid, stir 7 minutes, low value ocean fish enzymolysis is obtained
Liquid；
g）Compounding：Low value ocean fish enzymolysis liquid, nutritional agents, wetting agent are pressed 100：6：8 weight is obtained amino acid than well mixed
Foliar fertilizer；Nutritional agents presses 1 by potassium chloride, calcium superphosphate and ammonium dihydrogen phosphate：3：0.7 weight ratio is mixed, wetting agent by
Sodium alginate, Sucrose Fatty Acid Ester, polyglycerol ester and lecithin press 2：1.5：2.5：5 weight ratio is mixed；
Wherein, the carrier in step d is obtained by following steps：
1）Vermiculite is crushed to 450 mesh, is calcined 1.5 hours at 520 DEG C afterwards, concentration expressed in percentage by weight is added to after cooling is
In 25% sodium chloride solution, soak 5 hours；
2）Crushed crude pearlite is broken to 25 mesh, then calcining 0.6 hour at 430 DEG C, then calcining 15 seconds at 1150 DEG C, afterwards
330 DEG C are cooled to, taking-up is added in the sodium chloride solution that concentration expressed in percentage by weight is 25%, soaked 2.5 hours；
3）The product mixing that step 1 and step 2 are obtained, ultrasonically treated 30 minutes, filters and is with concentration expressed in percentage by weight afterwards
25% sodium chloride solution is rinsed 2~5 times, and composite inorganic mineral are obtained after drying；
4）Composite inorganic mineral are crushed to 60 mesh carrier is obtained.
Embodiment 3
A kind of method of low value ocean fish fermenting and producing amino acid foliage fertilizer, comprises the following steps：
a）Slurrying：The water of 4 times of its weight is shredded and added after low value ocean fish is decaptitated, and slurrying afterwards is obtained low value ocean fish slurry；
b）Sterilizing：It is passed through chlorination in being starched to low value ocean fish to process, while with 6rpm speed stirring at low speed；It is low during sterilization treatment
The consumption of chlorine is 140mg/L in value ocean fish slurry；
c）Dispel peculiar smell：Heat 70 minutes, the low value ocean fish slurry after sterilization treatment with 6rpm speed low speed during heating at 85 DEG C
Stirring, filters off moisture and obtains low value ocean fish dry afterwards, is cleaned low value ocean fish dry 7 times with water, then low in addition
The water of 4 times of value ocean fish dry matter weight, is obtained low value ocean fish treatment slurry；After low value ocean fish treatment slurry is obtained, at low value ocean fish
The pH value for managing slurry is adjusted to 6；
d）Enzyme preparation：By bromelain, carrier and water according to 1.5：2.5：4 weight ratio mixing, at a temperature of 60 DEG C,
Stirred 17 minutes with the rotating speed of 40rpm, then stirred 45 minutes with the rotating speed of 8rpm, then filter liquid, obtain enzyme preparation；
e）Enzymolysis：By low value ocean fish treatment slurry with enzyme preparation according to 1：1.4 weight is than mixing and fast with 35rpm at 60 DEG C
Rate is stirred 15 minutes, is then stirred 14 hours with 6rpm speed, is then peeled off enzyme preparation, and enzymolysis liquid is obtained；
f）Inactivation：To adding potassium carbonate to make the pH value of enzymolysis liquid be 8 in enzymolysis liquid, stir 8 minutes, low value ocean fish enzymolysis is obtained
Liquid；
g）Compounding：Low value ocean fish enzymolysis liquid, nutritional agents, wetting agent are pressed 100：7：10 weight is obtained amino than well mixed
Sour foliar fertilizer；Nutritional agents presses 1 by potassium chloride, calcium superphosphate and ammonium dihydrogen phosphate：3：0.8 weight ratio is mixed, wetting agent
2 are pressed by sodium alginate, Sucrose Fatty Acid Ester, polyglycerol ester and lecithin：1.5：2.5：5 weight ratio is mixed；
Wherein, the carrier in step d is obtained by following steps：
1）Vermiculite is crushed to 450 mesh, is calcined 1.5 hours at 540 DEG C afterwards, concentration expressed in percentage by weight is added to after cooling is
In 35% sodium chloride solution, soak 5 hours；
2）Crushed crude pearlite is broken to 35 mesh, then calcining 0.8 hour at 470 DEG C, then calcining 30 seconds at 1300 DEG C, afterwards
370 DEG C are cooled to, taking-up is added in the sodium chloride solution that concentration expressed in percentage by weight is 35%, soaked 2.5 hours；
3）The product mixing that step 1 and step 2 are obtained, ultrasonically treated 40 minutes, filters and is with concentration expressed in percentage by weight afterwards
35% sodium chloride solution is rinsed 4 times, and composite inorganic mineral are obtained after drying；
4）Composite inorganic mineral are crushed to 80 mesh carrier is obtained.
Embodiment 4
A kind of method of low value ocean fish fermenting and producing amino acid foliage fertilizer, comprises the following steps：
a）Slurrying：The water of 5 times of its weight is shredded and added after low value ocean fish is decaptitated, and slurrying afterwards is obtained low value ocean fish slurry；
b）Sterilizing：It is passed through chlorination in being starched to low value ocean fish to process, while with 8rpm speed stirring at low speed；It is low during sterilization treatment
The consumption of chlorine is 160mg/L in value ocean fish slurry；
c）Dispel peculiar smell：Heat 80 minutes, the low value ocean fish slurry after sterilization treatment with 8rpm speed low speed during heating at 90 DEG C
Stirring, filters off moisture and obtains low value ocean fish dry afterwards, is cleaned low value ocean fish dry 8 times with water, then low in addition
The water of 5 times of value ocean fish dry matter weight, is obtained low value ocean fish treatment slurry；After low value ocean fish treatment slurry is obtained, at low value ocean fish
The pH value for managing slurry is adjusted to 6.5；
d）Enzyme preparation：By bromelain, carrier and water according to 2：3：5 weight ratio mixing, at a temperature of 70 DEG C, with
The rotating speed of 45rpm is stirred 20 minutes, then is stirred 50 minutes with the rotating speed of 10rpm, then filters liquid, obtains enzyme preparation；
e）Enzymolysis：By low value ocean fish treatment slurry with enzyme preparation according to 1：1.6 weight is than mixing and fast with 40rpm at 65 DEG C
Rate is stirred 20 minutes, is then stirred 16 hours with 8rpm speed, is then peeled off enzyme preparation, and enzymolysis liquid is obtained；
f）Inactivation：To adding potassium carbonate to make the pH value of enzymolysis liquid be 8.5 in enzymolysis liquid, stir 10 minutes, low value ocean fish enzyme is obtained
Solution liquid；
g）Compounding：Low value ocean fish enzymolysis liquid, nutritional agents, wetting agent are pressed 100：8：12 weight is obtained amino than well mixed
Sour foliar fertilizer；Nutritional agents presses 1 by potassium chloride, calcium superphosphate and ammonium dihydrogen phosphate：3.5：1 weight ratio is mixed, wetting agent
2 are pressed by sodium alginate, Sucrose Fatty Acid Ester, polyglycerol ester and lecithin：2：3：6 weight ratio is mixed；
Wherein, the carrier in step d is obtained by following steps：
1）Vermiculite is crushed to 500 mesh, is calcined 2 hours at 550 DEG C afterwards, it is 40% that concentration expressed in percentage by weight is added to after cooling
Sodium chloride solution in, soak 6 hours；
2）Crushed crude pearlite is broken to 40 mesh, is then calcined at 500 DEG C 1 hour, then calcined 40 seconds at 1400 DEG C, Zhi Houleng
But to 400 DEG C, taking-up is added in the sodium chloride solution that concentration expressed in percentage by weight is 40%, is soaked 3 hours；
3）The product mixing that step 1 and step 2 are obtained, ultrasonically treated 60 minutes, filters and is with concentration expressed in percentage by weight afterwards
40% sodium chloride solution is rinsed 5 times, and composite inorganic mineral are obtained after drying；
4）Composite inorganic mineral are crushed to 100 mesh carrier is obtained.
It should be appreciated that to those skilled in the art, can according to the above description be improved or be become
Change, and all these modifications and variations should all belong to the protection domain of appended claims of the present invention.
Claims (9)
1. a kind of method of low value ocean fish fermenting and producing amino acid foliage fertilizer, it is characterised in that comprise the following steps：
a）Slurrying：The water of 1~5 times of its weight is shredded and added after low value ocean fish is decaptitated, and slurrying afterwards is obtained low value ocean fish
Slurry；
b）Sterilizing：It is passed through chlorination in being starched to low value ocean fish to process, while stirring at low speed；
c）Dispel peculiar smell：By the low value ocean fish slurry after sterilization treatment, heated 50~80 minutes at 70~90 DEG C, low speed is stirred during heating
Mix, moisture is filtered off afterwards and obtains low value ocean fish dry, cleaned low value ocean fish dry 5~8 times with water, it is then low in addition
The water of 1~5 times of value ocean fish dry matter weight, is obtained low value ocean fish treatment slurry；
d）Enzyme preparation：By protease, carrier and water according to 1~2：2~3：3~5 weight ratio mixing, in 40~70 DEG C of temperature
Under degree, stirred 10~20 minutes with the rotating speed of 30~45rpm, then stirred 30~50 minutes with the rotating speed of 5~10rpm, then filtered
Except liquid, enzyme preparation is obtained；
e）Enzymolysis：By low value ocean fish treatment slurry with enzyme preparation according to 1：0.8~1.6 weight ratio mixing, and at 50~65 DEG C
Stirred 10~20 minutes with 30~40rpm speed, then stirred 12~16 hours with 4~8rpm speed, be then peeled off enzyme preparation,
Enzymolysis liquid is obtained；
f）Inactivation：To adding potassium carbonate to make the pH value of enzymolysis liquid be 7.5~8.5 in enzymolysis liquid, stir 5~10 minutes, be obtained low
Value ocean fish enzymolysis liquid；
g）Compounding：Low value ocean fish enzymolysis liquid, nutritional agents, wetting agent are pressed 100：5~8：6~12 weight is than well mixed, system
Obtain amino acid foliage fertilizer.
2. the method for a kind of low value ocean fish fermenting and producing amino acid foliage fertilizer according to claim 1, it is characterised in that：Institute
The protease stated is papain or bromelain.
3. the method for a kind of low value ocean fish fermenting and producing amino acid foliage fertilizer according to claim 1, it is characterised in that：Institute
State in step b, the consumption of chlorine is 100~160mg/L in low value ocean fish slurry during sterilization treatment.
4. the method for a kind of low value ocean fish fermenting and producing amino acid foliage fertilizer according to claim 1, it is characterised in that：Institute
State in step b and step c, the speed of stirring at low speed is 4~8rpm.
5. the method for a kind of low value ocean fish fermenting and producing amino acid foliage fertilizer according to claim 1, it is characterised in that：Institute
State in step c, after low value ocean fish treatment slurry is obtained, the pH value of low value ocean fish treatment slurry is adjusted to 5.5~6.5.
6. the method for a kind of low value ocean fish fermenting and producing amino acid foliage fertilizer according to claim 1, it is characterised in that：Institute
State in step g, nutritional agents presses 1 by potassium chloride, calcium superphosphate and ammonium dihydrogen phosphate：2.5~3.5：0.5~1 weight is than mixing
Form.
7. the method for a kind of low value ocean fish fermenting and producing amino acid foliage fertilizer according to claim 1, it is characterised in that：Institute
State in step g, wetting agent presses 2 by sodium alginate, Sucrose Fatty Acid Ester, polyglycerol ester and lecithin：1~2：2~3：4~6 weight ratio
Mix.
8. a kind of method of low value ocean fish fermenting and producing amino acid foliage fertilizer according to claim 1, it is characterised in that institute
The carrier stated in step d is obtained by following steps：
1）Vermiculite is crushed to 400~500 mesh, is calcined 1~2 hour at 500~550 DEG C afterwards, chlorination is added to after cooling
In sodium solution, soak 4~6 hours；
2）Crushed crude pearlite is broken to 20~40 mesh, 0.5~1 hour is then calcined at 400~500 DEG C, then 1000~
Calcined 1~40 second at 1400 DEG C, 300~400 DEG C are cooled to afterwards, taking-up is added in sodium chloride solution, is soaked 2~3 hours；
3）The product mixing that step 1 and step 2 are obtained, ultrasonically treated 20~60 minutes, filters and uses sodium chloride solution afterwards
Rinse 2~5 times, composite inorganic mineral are obtained after drying；
4）Composite inorganic mineral are crushed to 40~100 mesh carrier is obtained.
9. the method for a kind of low value ocean fish fermenting and producing amino acid foliage fertilizer according to claim 8, it is characterised in that：Institute
The sodium chloride solution stated is sodium-chloride water solution that concentration expressed in percentage by weight is 20~40%.
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108083909A (en) * | 2017-12-25 | 2018-05-29 | 中国科学院化学研究所 | A kind of functional plants organic nutrient solution for cultivating and preparation method thereof |
| CN109180378A (en) * | 2018-09-15 | 2019-01-11 | 湖南泰谷生态工程有限公司 | A method of Amino acid liquid fertilizer is prepared using dead fish shrimp |
| CN112500224A (en) * | 2020-12-05 | 2021-03-16 | 安丘市天赐生物肥料有限公司 | Method for preparing water-soluble fertilizer by using fish protein hydrolysate |
| CN112661557A (en) * | 2019-10-14 | 2021-04-16 | 付颖翱 | Plant foliar fertilizer and preparation method and application thereof |
| CN114085101A (en) * | 2021-12-09 | 2022-02-25 | 山东省神农生态科技股份有限公司 | Production method of fish protein fertilizer and fish protein fertilizer prepared by same |
| CN115477554A (en) * | 2022-10-09 | 2022-12-16 | 广东博沃特生物技术有限公司 | Selenium-enriched foliar fertilizer and preparation method and application thereof |
| CN115812070A (en) * | 2021-06-30 | 2023-03-17 | 华川郡 | Preparation method of fermentation liquor of oncorhynchus masou |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101088970A (en) * | 2006-12-27 | 2007-12-19 | 浙江大学 | Process of extracting amino acid for farm use with low value fish |
| CN104557339A (en) * | 2015-02-03 | 2015-04-29 | 舟山源丰海洋生物科技有限公司 | Preparation method of soluble fish protein ammonia acid fertilizer |
| CN104892037A (en) * | 2015-06-10 | 2015-09-09 | 荣成鸿德海洋生物科技有限公司 | Method for producing water-soluble fish protein organic fertilizer from fish |
| CN105152690A (en) * | 2015-08-07 | 2015-12-16 | 浙江海洋学院 | Method for preparing protein fertilizer from fish solubles |
-
2016
- 2016-12-23 CN CN201611205814.4A patent/CN106748150A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101088970A (en) * | 2006-12-27 | 2007-12-19 | 浙江大学 | Process of extracting amino acid for farm use with low value fish |
| CN104557339A (en) * | 2015-02-03 | 2015-04-29 | 舟山源丰海洋生物科技有限公司 | Preparation method of soluble fish protein ammonia acid fertilizer |
| CN104892037A (en) * | 2015-06-10 | 2015-09-09 | 荣成鸿德海洋生物科技有限公司 | Method for producing water-soluble fish protein organic fertilizer from fish |
| CN105152690A (en) * | 2015-08-07 | 2015-12-16 | 浙江海洋学院 | Method for preparing protein fertilizer from fish solubles |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108083909A (en) * | 2017-12-25 | 2018-05-29 | 中国科学院化学研究所 | A kind of functional plants organic nutrient solution for cultivating and preparation method thereof |
| CN109180378A (en) * | 2018-09-15 | 2019-01-11 | 湖南泰谷生态工程有限公司 | A method of Amino acid liquid fertilizer is prepared using dead fish shrimp |
| CN112661557A (en) * | 2019-10-14 | 2021-04-16 | 付颖翱 | Plant foliar fertilizer and preparation method and application thereof |
| CN112500224A (en) * | 2020-12-05 | 2021-03-16 | 安丘市天赐生物肥料有限公司 | Method for preparing water-soluble fertilizer by using fish protein hydrolysate |
| CN115812070A (en) * | 2021-06-30 | 2023-03-17 | 华川郡 | Preparation method of fermentation liquor of oncorhynchus masou |
| CN114085101A (en) * | 2021-12-09 | 2022-02-25 | 山东省神农生态科技股份有限公司 | Production method of fish protein fertilizer and fish protein fertilizer prepared by same |
| CN115477554A (en) * | 2022-10-09 | 2022-12-16 | 广东博沃特生物技术有限公司 | Selenium-enriched foliar fertilizer and preparation method and application thereof |
| CN116553975A (en) * | 2023-07-07 | 2023-08-08 | 山东嘉禾海洋生物科技有限公司 | Fish protein fermentation liquor and application |
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