CN106746865A - The concrete and its construction method of a kind of sulfate resistance physical erosion - Google Patents

The concrete and its construction method of a kind of sulfate resistance physical erosion Download PDF

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Publication number
CN106746865A
CN106746865A CN201611160007.5A CN201611160007A CN106746865A CN 106746865 A CN106746865 A CN 106746865A CN 201611160007 A CN201611160007 A CN 201611160007A CN 106746865 A CN106746865 A CN 106746865A
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CN
China
Prior art keywords
concrete
acrylic acid
sulfate resistance
physical erosion
resistance physical
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611160007.5A
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Chinese (zh)
Inventor
殷雨时
范颖芳
王万德
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dalian Maritime University
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Dalian Maritime University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dalian Maritime University filed Critical Dalian Maritime University
Priority to CN201611160007.5A priority Critical patent/CN106746865A/en
Publication of CN106746865A publication Critical patent/CN106746865A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039Premixtures of ingredients
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24Macromolecular compounds
    • C04B24/26Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B24/2641Polyacrylates; Polymethacrylates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/60Agents for protection against chemical, physical or biological attack
    • C04B2103/61Corrosion inhibitors
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/2038Resistance against physical degradation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

A kind of concrete of sulfate resistance physical erosion, the concrete of sulfate resistance physical erosion is that the concrete that acrylic acid polymer is constituted is added in the concrete allocated by the strength grade of concrete of engine request, acrylic acid polymer is the product that acrylic acid crosslinked resin reconciles with water, glycerine and triethanolamine, and the mass percent of the acrylic acid polymer of addition is 1%~3% of cement quality in the concrete allocated by the strength grade of concrete of engine request.Construction method is the concrete layer for irrigating sulfate resistance physical erosion in baseline upper and lower surface 30cm with ground surface as baseline, and the concrete of the strength grade of concrete allotment of engine request is pressed in the perfusion of other positions.Beneficial effect is:Raw material is easy to buying and cost is relatively low, concrete matched and than simple, and construction method simplicity, sulfate resistance physical erosion ability is strong.

Description

The concrete and its construction method of a kind of sulfate resistance physical erosion
Technical field
The invention belongs to technical field of buildings, more particularly to concrete construction process, more particularly to sulfate resistance physics is invaded The concrete and its construction technique of erosion.
Background technology
Concrete can receive sulfate thing in collapsible loess region, coastal cities, the ground mountain area rich in sulfate ion Reason corrodes.To prevent and reducing destruction of the sulfate physical erosion to concrete, the method for prior art is allotment sulfate resistance The concrete of physical erosion, the concrete of the sulfate resistance physical erosion of prior art typically has two kinds, and one is in concrete Addition flyash, silicon ash etc., two is to improve strength grade of concrete.The deficiencies in the prior art are:The tools such as addition flyash, silicon ash There is air-free concrete hole, but this closely knit often strengthen capillarity so that concrete physical erosion aggravates;Carry High concrete strength grade can increase cost, be unsuitable for mass concrete engineering.
The content of the invention
The invention aims to overcome the shortcomings of existing sulfate resistance physical erosion concrete, there is provided a kind of new mixes Solidifying soil and its construction technology, improve the ability of Concrete Resist Reinforcing Sulfate Corrosion, and low cost.
The technical scheme is that:A kind of concrete of sulfate resistance physical erosion, including by the coagulation of engine request The concrete of native strength grade allotment, it is characterised in that:The concrete of the sulfate resistance physical erosion is by engineering described It is required that strength grade of concrete allotment concrete in add acrylic acid polymer composition concrete, the polypropylene of addition Acid polymer is the product that acrylic acid crosslinked resin reconciles with water, glycerine and triethanolamine, the polyacrylic acid polymerization of addition The mass percent of thing is 1%~3% of cement quality in the concrete allocated by the strength grade of concrete of engine request.
A kind of concrete of sulfate resistance physical erosion of the present invention, it is characterised in that:The acrylic acid polymer The proportion of composing of middle acrylic acid crosslinked resin, water, glycerine and triethanolamine is:Contain acrylic acid in per 100g acrylic acid polymers Crosslinked resin 6g, water 90g, glycerine 2g and triethanolamine 2g.
A kind of compound method of the acrylic acid polymer of the concrete of sulfate resistance physical erosion of the present invention, it is special Levy and be:The compound method of the acrylic acid polymer 100g is as follows:
1. 2g glycerine is poured into 6g acrylic acid crosslinked resins, moistens acrylic acid crosslinked resin,
2. water 90g is added, is stirred, placed 2~3 hours, acrylic acid crosslinked resin is fully expanded,
3. 2g triethanolamines, regulation pH value to 6~7, acrylic acid polymer is added to prepare and complete.
The construction method of the concrete of sulfate resistance physical erosion of the present invention, including by the strong concrete of engine request The perfusion of the concrete of degree grade allotment and the filling concrete of sulfate resistance physical erosion, it is characterised in that:The sulfuric-resisting The filling concrete of salt physical erosion be the ground design elevation with construction ground as baseline, irrigate base respectively in baseline upper and lower surface The concrete layer of the sulfate resistance physical erosion above the concrete layer and baseline of the sulfate resistance physical erosion below line, it is described The concrete layer of the sulfate resistance physical erosion above the concrete layer and baseline of the sulfate resistance physical erosion below baseline Thickness is not less than 30cm, by the concrete layer sulfur resistive respectively below baseline that the strength grade of concrete of engine request is allocated Above the concrete layer of the sulfate resistance physical erosion below the concrete layer of hydrochlorate physical erosion and above line.
Principle of the invention is that there is acrylic acid polymer (PAA-VLMW) suppression physics salt knot is produced in concrete Brilliant effect, using this effect of acrylic acid polymer (PAA-VLMW), is added into by the strong concrete of engine request In the concrete of degree grade allotment, the destruction of sulfate physical erosion can be prevented and reduced;It is certain in ground surface in construction (solution-air/gas-soil) irrigates the concrete of sulfate resistance physical erosion in region, improves the most heavy interface of sulfate physical erosion The resisting erosion of sulfate ability in region, so as to strengthen the strength and stiffness of whole engineering structural system.
The beneficial effects of the invention are as follows:Raw material is easy to buying and cost is relatively low, concrete matched and than simple, and construction method is simple Just, sulfate resistance physical erosion ability is strong.
Brief description of the drawings
Fig. 1 is the concrete construction structural representation of sulfate resistance physical erosion
In Fig. 1,1 is the concrete layer allocated by the strength grade of concrete of engine request, and 2 is ground design elevation, and 3 are The concrete layer of the sulfate resistance physical erosion below baseline, 4 is the concrete layer of the sulfate resistance physical erosion above baseline.
Specific embodiment
The present invention will be further described with reference to the accompanying drawings and examples.
Concrete includes the concrete and sulfate resistance physical erosion that the strength grade of concrete for press engine request is allocated Concrete, the concrete of sulfate resistance physical erosion is added in the concrete allocated by the strength grade of concrete of engine request The concrete of addition polymerization acrylate copolymer composition, the acrylic acid polymer of addition be acrylic acid crosslinked resin with water, glycerine and The product that triethanolamine reconciles, the mass percent of the acrylic acid polymer of addition is by the strong concrete of engine request The 1%~3% of cement quality in the concrete of degree grade allotment.Acrylic acid crosslinked resin, water, glycerine in acrylic acid polymer Proportion of composing with triethanolamine is:The 6g of crosslinked resin containing acrylic acid, water 90g, glycerine 2g in per 100g acrylic acid polymers With triethanolamine 2g.
The compound method of 100g acrylic acid polymers is as follows:
1. 2g glycerine is poured into 6g acrylic acid crosslinked resins, moistens acrylic acid crosslinked resin,
2. water 90g is added, is stirred, placed 2~3 hours, acrylic acid crosslinked resin is fully expanded,
3. 2g triethanolamines, regulation pH value to 6~7, acrylic acid polymer is added to prepare and complete.
Construction technique includes pressing perfusion and the sulfuric-resisting of the concrete of the strength grade of concrete allotment of engine request The filling concrete of salt physical erosion, the filling concrete of sulfate resistance physical erosion is with the ground design elevation 2 of construction ground It is baseline, on concrete layer 3 and baseline that the upper and lower two parts of baseline irrigate the sulfate resistance physical erosion below baseline respectively The concrete layer 4 of the sulfate resistance physical erosion in face, on the concrete layer 3 and baseline of the sulfate resistance physical erosion below baseline The thickness of the concrete layer 4 of the sulfate resistance physical erosion in face is 30cm, is allocated by the strength grade of concrete of engine request The sulfate resistance physical erosion respectively below baseline of concrete layer 1 concrete layer 3 below and baseline above sulfuric-resisting Above the concrete layer 4 of salt physical erosion.Specific construction is:First pressed with lower portion perfusion apart from ground design elevation 30cm The concrete of the strength grade of concrete allotment of engine request, then presses the strength grade of concrete allotment of engine request at this The concrete layer of sulfate resistance physical erosion is irrigated above concrete to ground surface above 30cm, then it is anti-in ground surface above 30cm Continue to irrigate concrete that the strength grade of concrete for press engine request allocates above the concrete of sulfate physical erosion to work The height of range request.
When filling concrete engineering is smaller, the filling concrete of sulfate resistance physical erosion can be all used.

Claims (4)

1. a kind of concrete of sulfate resistance physical erosion, including the coagulation allocated by the strength grade of concrete of engine request Soil, it is characterised in that:The concrete of the sulfate resistance physical erosion is in the strength grade of concrete by engine request The concrete of acrylic acid polymer composition is added in the concrete of allotment, the acrylic acid polymer of addition is acrylic acid crosslinking The product that resin reconciles with water, glycerine and triethanolamine, the mass percent of the acrylic acid polymer of addition is by work The 1%~3% of cement quality in the concrete of the strength grade of concrete allotment of range request.
2. as claimed in claim 1 a kind of concrete of sulfate resistance physical erosion, it is characterised in that:The polyacrylic acid polymerization The proportion of composing of acrylic acid crosslinked resin, water, glycerine and triethanolamine is in thing:Contain propylene in per 100g acrylic acid polymers Sour crosslinked resin 6g, water 90g, glycerine 2g and triethanolamine 2g.
3. a kind of compound method of the acrylic acid polymer of the concrete of sulfate resistance physical erosion described in claim 2, its It is characterised by:The compound method of the acrylic acid polymer 100g is as follows:
1. 2g glycerine is poured into 6g acrylic acid crosslinked resins, moistens acrylic acid crosslinked resin,
2. water 90g is added, is stirred, placed 2~3 hours, acrylic acid crosslinked resin is fully expanded, 3. add the ethanol of 2g tri- Amine, regulation pH value to 6~7, acrylic acid polymer is prepared and completed.
4. the construction method of the concrete of sulfate resistance physical erosion described in claim 1, including by the concrete of engine request The perfusion of the concrete of strength grade allotment and the filling concrete of sulfate resistance physical erosion, it is characterised in that:The sulfur resistive The filling concrete of hydrochlorate physical erosion be the ground design elevation (2) with construction ground as baseline, baseline upper and lower surface difference The coagulation of the sulfate resistance physical erosion above the concrete layer (3) and baseline of the sulfate resistance physical erosion below perfusion baseline Soil layer (4), the sulfate resistance physics above the concrete layer (3) and baseline of the sulfate resistance physical erosion below the baseline is invaded The thickness of the concrete layer (4) of erosion is not less than 30cm, by the concrete layer (1) that the strength grade of concrete of engine request is allocated Respectively the concrete layer (3) of the sulfate resistance physical erosion below baseline below with line above sulfate resistance physical erosion Above concrete layer (4).
CN201611160007.5A 2016-12-15 2016-12-15 The concrete and its construction method of a kind of sulfate resistance physical erosion Pending CN106746865A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111423172A (en) * 2020-05-14 2020-07-17 辽宁省交通高等专科学校 Sulfate physical erosion resistant concrete and construction method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU606932A1 (en) * 1975-11-20 1978-05-15 Украинское Научно-Производственное Проектно-Технологическое И Конструкторское Объединение "Укрниистромпроект" Симферопольский Филиал Method of protecting concrete in aggressive medium from corrosion
CN101070705A (en) * 2007-03-13 2007-11-14 中南大学 Concrete structure member of resisting salt-erosion broken and construction method
CN102765915A (en) * 2012-07-30 2012-11-07 水利部交通运输部国家能源局南京水利科学研究院 Resin emulsion mortar resistant to seepage, cracking and sulfate corrosion
CN104150837A (en) * 2014-08-04 2014-11-19 河北建设勘察研究院有限公司 Formula of anti-corrosion concrete used for filling pile and preparation method of anti-corrosion concrete

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU606932A1 (en) * 1975-11-20 1978-05-15 Украинское Научно-Производственное Проектно-Технологическое И Конструкторское Объединение "Укрниистромпроект" Симферопольский Филиал Method of protecting concrete in aggressive medium from corrosion
CN101070705A (en) * 2007-03-13 2007-11-14 中南大学 Concrete structure member of resisting salt-erosion broken and construction method
CN102765915A (en) * 2012-07-30 2012-11-07 水利部交通运输部国家能源局南京水利科学研究院 Resin emulsion mortar resistant to seepage, cracking and sulfate corrosion
CN104150837A (en) * 2014-08-04 2014-11-19 河北建设勘察研究院有限公司 Formula of anti-corrosion concrete used for filling pile and preparation method of anti-corrosion concrete

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* Cited by examiner, † Cited by third party
Title
李继业: "《混凝土外加剂速查手册》", 30 June 2016, 中国建筑工业出版 *
王宝民,潘宝峰: "《道路建筑材料》", 31 August 2010, 中国建材工业出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111423172A (en) * 2020-05-14 2020-07-17 辽宁省交通高等专科学校 Sulfate physical erosion resistant concrete and construction method thereof

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