CN106726766A - A kind of mascara and preparation method thereof - Google Patents

A kind of mascara and preparation method thereof Download PDF

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Publication number
CN106726766A
CN106726766A CN201611214075.5A CN201611214075A CN106726766A CN 106726766 A CN106726766 A CN 106726766A CN 201611214075 A CN201611214075 A CN 201611214075A CN 106726766 A CN106726766 A CN 106726766A
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parts
weight
mascara
deionized water
peg
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CN106726766B (en
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晏金
陈国祥
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Hangzhou Sincere Cosmetics Co Ltd
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Hangzhou Sincere Cosmetics Co Ltd
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/4973Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom
    • A61K8/498Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom having 6-membered rings or their condensed derivatives, e.g. coumarin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
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    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
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    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25Silicon; Compounds thereof
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    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
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    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/31Hydrocarbons
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    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
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    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
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    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • A61K8/345Alcohols containing more than one hydroxy group
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
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    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36Carboxylic acids; Salts or anhydrides thereof
    • A61K8/361Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • A61K8/731Cellulose; Quaternized cellulose derivatives
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
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    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • A61K8/732Starch; Amylose; Amylopectin; Derivatives thereof
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    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
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    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8129Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers or esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers, e.g. polyvinylmethylether
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
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    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8147Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
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    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86Polyethers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
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    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/927Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of insects, e.g. shellac
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments
    • A61Q1/10Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara

Abstract

The present invention discloses a kind of mascara and preparation method thereof, wherein, a kind of mascara includes 35 43 parts of deionized water;2 3.5 parts of polyvinylpyrrolidone;2.5 4 parts of polyvinyl alcohol;25 parts of butanediol;0.1 0.5 parts of hydroxyethyl cellulose;6 10 parts of ethanol;CI77499 is 58 parts;1 3.5 parts of dextrin isostearate;46 parts of babassu vegetable wax;4.5 6 parts of beeswax;1 3.5 parts of stearic acid;13 parts of surfactant;0.2 1.5 parts of 40 stearates of PEG;3.5 6.5 parts of cyclomethicone;8 11 parts of film forming agent;35 parts of silica;Film forming agent is styrene, acrylic acid(Ester)The mixture that analog copolymer sodium, deionized water, dehydroactic acid sodium are formed, styrene, acrylic acid(Ester)Analog copolymer sodium, deionized water, the ratio of weight and number of dehydroactic acid sodium are 1:3‑5:1:2‑3.

Description

A kind of mascara and preparation method thereof
Technical field
The present invention relates to cosmetic technical field, more specifically, it relates to a kind of mascara and preparation method thereof.
Background technology
Mascara product species is various in the market, has dense type, fine elongated, volume to stick up type, plentiful volume and stick up type, dense fibre Elongated etc., gets consumer reception very much.Wherein, the mascara of dense type has significant makeup effect due to it, deep by vast The women's that likes to be beautiful likes.However, after user's makeup, once perspiring or being drenched with rain, then mascara can be caused to melt, finally There is the phenomenon of profit adornment.Therefore, there is dense effect after a kind of makeup and the mascara of waterproof has certain commercial value.
The content of the invention
In view of the shortcomings of the prior art, the purpose of the present invention one is to provide a kind of mascara, which solves eyelashes Cream easily moistens the problem of adornment, has the advantages that dense makeup effect and is difficult to moisten adornment.
To achieve the above object one, the invention provides following technical scheme:
A kind of mascara, including following parts by weight component:
Deionized water 35-43 parts;
Polyvinylpyrrolidone 2-3.5 parts;
Polyvinyl alcohol 2.5-4 parts;
Butanediol 2-5 parts;
Hydroxyethyl cellulose 0.1-0.5 parts;
Ethanol 6-10 parts;
CI77499 is 5-8 parts;
1-3.5 parts of dextrin isostearate;
4-6 parts of babassu vegetable wax;
Beeswax 4.5-6 parts;
Stearic acid 1-3.5 parts;
Surfactant 1-3 parts;
0.2-1.5 parts of PEG-40 stearates;
Cyclomethicone 3.5-6.5 parts;
Film forming agent 8-11 parts;
Silica 3-5 parts;
The mixture that the film forming agent is styrene, acrylic acid (ester) analog copolymer sodium, deionized water, dehydroactic acid sodium are formed, The styrene, acrylic acid (ester) analog copolymer sodium, deionized water, the ratio of weight and number of dehydroactic acid sodium are 1: 3-5: 1: 2-3.
Using above-mentioned technical proposal, butanediol, ethanol, with excellent dissolution, promote each group to divide it as solvent Between mixing so that each component reaches dispersed effect;And both also have sterilized, volatile and fast drying work With, after mascara is through makeup, can rapid draing, reduce undried mascara and adhered on eye part skin during blink May.CI77499 is a kind of black iron oxide, has the advantages that fine and smooth, color and luster is good, uniform particle sizes, increases makeup effect, is scribbled Eyelashes in the application after mascara make eyes more added with god.
Polyvinyl alcohol is a kind of thickener, and ductility can be increased under dampness, so that the mascara in the application After use, can eyelashes be reached with preferable dense effect.Hydroxyethyl cellulose is a kind of non-ionic water soluble polymer Compound, in deionized water is substantially dissolved in, and easily forms relatively stable network-like structure, promote itself and other components it Between connection, reach stabilization, thickening, control viscosity effect.Dextrin isostearate has preferable emulsification, reduces water The phenomenon that oil is separate occurs, and promotes have preferably dispersion and stability between component.Cyclomethicone has pole Solute effect high, cooperates with ethanol, butanediol, increases volatilization effect, promotes mascara rapid solidification, meanwhile, also have There is lubrication, and PEG-40 stearates, silica coordinate, and can adjust the viscosity in liquid phase, reach salubrious not glutinous greasy effect. Found, polyvinyl alcohol, hydroxyethyl cellulose, dextrin isostearate, cyclomethicone, silica through research (experiment one) Complex role, helps to adhere to CI77499 and eyelashes, makes the application to be formed with preferable makeup effect, and reaching makes Eyelashes become denser purpose.
Polyvinylpyrrolidone has stabilization, the effect of waterproof, and can form bonding to component around.Beeswax and cohune Palmitic acid vegetable wax is excellent soft effect, makes the eyelashes after smearing more submissive, is difficult to be mutually bonded in one, meanwhile, both With lipophile, the viscosity of the system with oily matter can be increased.Styrene, acrylic acid (ester) analog copolymer in film forming agent The ratio of weight and number that sodium, deionized water, dehydroactic acid sodium are formed is 1: 3-5: 1: 2-3, and the film forming agent formed by the proportioning is had There is excellent film-formation result, CI77499 can be firmly adhered to eyelashes surface.Found, polyethylene pyrrole through research (experiment two) Pyrrolidone, beeswax, babassu vegetable wax, film forming agent mutual cooperation effect, reach preferable waterproof effect, make the eyelash in the application After hair cream is through makeup, the phenomenon of profit adornment is less prone to.
More preferably:Component including following parts by weight:
Deionized water 37-41 parts;
Polyvinylpyrrolidone 2.3-3.2 parts;
Polyvinyl alcohol 2.8-3.7 parts;
Butanediol 2.5-4.5 parts;
Hydroxyethyl cellulose 0.2-0.45 parts;
Ethanol 7-9 parts;
CI77499 is 5.5-7 parts;
1.5-3 parts of dextrin isostearate;
4.5-5.5 parts of babassu vegetable wax;
Beeswax 4.7-5.8 parts;
Stearic acid 1.2-3.3 parts;
Surfactant 1.3-2.5 parts;
0.5-1.3 parts of PEG-40 stearates;
Cyclomethicone 3.8-6 parts;
Film forming agent 8.5-10 parts;
Silica 3.3-4.5 parts;
The mixture that the film forming agent is styrene, acrylic acid (ester) analog copolymer sodium, deionized water, dehydroactic acid sodium are formed, The styrene, acrylic acid (ester) analog copolymer sodium, deionized water, the ratio of weight and number of dehydroactic acid sodium are 1: 3-5: 1: 2-3.
It has been investigated that, using the component in the range of the parts by weight, it is more conducive to make the eyelashes in the application to be formed Cream has increases the dense sense of eyelashes, and lifts the waterproof action of mascara.
More preferably:The surfactant includes stearine, PEG-100 stearates, the glycerine The ratio of stearate and PEG-100 stearates is 2-4: 1.
After stearine, PEG-100 stearates cooperate, with excellent lubricant effect, promote mascara In each component uniformly mix, and it has preferable emulsification, is mutually compounded between, is lived so as to reach preferable surface Property effect, found through research (experiment one), surfactant and polyvinyl alcohol, hydroxyethyl cellulose, dextrin isostearate, ring Dimethyl silicone polymer, silica complex role, so that mascara has more preferable dense effect.
More preferably:Also include preservative, the parts by weight of the preservative are 0.1-1.5 parts, the preservative Including Bis(hydroxymethyl)imidazolidinyl urea, iodine propilolic alcohol butyl mephenesin Carbamate, methyl hydroxybenzoate, propane diols, double (methylols) Imidazolidinyl urea, iodine propilolic alcohol butyl mephenesin Carbamate, methyl hydroxybenzoate, the ratio of weight and number of propane diols are 1: 1-2: 1-2: 2-3.5.
Using above-mentioned technical proposal, by Bis(hydroxymethyl)imidazolidinyl urea, iodine propilolic alcohol butyl mephenesin Carbamate, oxybenzene first Ester, the ratio of weight and number of propane diols are 1: 1-2: 1-2: the 2-3.5 preservative for being formed, and it has more preferable antibacterial, anti-corrosion, protection Effect, and viscosity is controlled, make the preservative to be formed be difficult to make skin damage.
The purpose of the present invention two is to provide a kind of preparation method of mascara.
To achieve the above object two, the invention provides following technical scheme:
A kind of preparation method of mascara, comprises the following steps:
S1, the deionized water of corresponding parts by weight, polyvinylpyrrolidone, polyvinyl alcohol, butanediol, hydroxyethyl cellulose are filled Divide mixing, be heated to 80-85 DEG C, form water phase;
S2, by the dextrin isostearate of corresponding parts by weight, babassu vegetable wax, beeswax, stearic acid, PEG-40 stearic acid Ester, cyclomethicone, surfactant, are heated to 80-85 DEG C, form oil phase;
S3, the CI77499 of corresponding parts by weight is well mixed with the oil phase obtained in step S2, is incubated to 80-85 DEG C, is formed Black oil phase;
S4, the black oil obtained in step S3 is added in the water phase obtained in step S1, and homogeneous forms water oil mixture;
S5, the water oil mixture deaeration that will be obtained in step S4 is cooled to 38-43 DEG C, forms cooling water oil mixture;
S6, in the cooling water oil mixture that will be obtained in the film forming agent of corresponding parts by weight, silica addition step S5, mixing is equal It is even, finished product is obtained, detection, discharging is filling.
Using above-mentioned technical proposal, black oil phase is slowly inserted in water phase, both temperature are in 80-85 DEG C of scope It is interior, being mutually mixed between two-phase is helped lend some impetus to, make to be less prone to the phenomenon of caking in the water oil mixture to be formed, and reduce The generation of precipitation.When temperature is down in the range of 38-43 DEG C, film forming agent is added, reduce the damage to film forming agent, and promote whole Being sufficiently mixed between each component in individual system, makes mascara have the dense effect of dispersed and makeup.
Stearine, PEG-100 stearates are Ester, within the temperature range of 80-85 DEG C, are more easy to and paste The oil phase things such as smart isostearate, babassu vegetable wax, beeswax, stearic acid, PEG-40 stearates, cyclomethicone Matter is mutually mixed, and the oil phase to be formed is had preferably uniform, stabilization effect.
More preferably:The preservative of corresponding parts by weight is added in the step S6, is well mixed.
Using above-mentioned technical proposal, preservative is added within the temperature range of 38-43 DEG C, reduces the loss to preservative, And make the mascara in the application that there is good sterilization and antiseptic effect, and extend the effective life of mascara.
In sum, the invention has the advantages that:
1st, the mixture that stearine, PEG-100 stearates are formed, different with polyvinyl alcohol, hydroxyethyl cellulose, dextrin Stearate, cyclomethicone, silica complex role, help to adhere to C177499 and eyelashes, make this to be formed Shen Please with preferable makeup effect, the purpose for making eyelashes become denser is reached;
2nd, polyvinylpyrrolidone, beeswax, babassu vegetable wax, film forming agent mutual cooperation effect, reach preferable waterproof effect, After making the mascara in the application through makeup, the phenomenon of profit adornment is less prone to.
Specific embodiment
With reference to embodiment, the present invention will be described in detail.
Embodiment 1:A kind of mascara, is made by the steps acquisition:
S1, the deionized water of corresponding parts by weight, polyvinylpyrrolidone, polyvinyl alcohol, butanediol, hydroxyethyl cellulose are filled Divide mixing, be heated to 80-85 DEG C, form water phase;
S2, by the dextrin isostearate of corresponding parts by weight, babassu vegetable wax, beeswax, stearic acid, PEG-40 stearic acid Ester, cyclomethicone, surfactant, are heated to 80-85 DEG C, form oil phase, wherein, the surfactant is glycerine Stearate, PEG-100 stearates, both parts by weight ratio are 2: 1;
S3, the CI77499 of corresponding parts by weight is well mixed with the oil phase obtained in step S2, is incubated to 80-85 DEG C, is formed Black oil phase;
S4, the black oil obtained in step S3 is added in the water phase obtained in step S1, and homogeneous forms water oil mixture;
S5, the water oil mixture deaeration that will be obtained in step S4 is cooled to 38-43 DEG C, forms cooling water oil mixture;
S6, by the styrene of corresponding parts by weight, acrylic acid (ester) analog copolymer sodium, deionized water, the weight of dehydroactic acid sodium During portion rate is 1: 3: 1: 2 film forming agents for being formed, and silica adds the cooling water oil mixture obtained in step S5, mixing is equal It is even, finished product is obtained, detection, discharging is filling.
Each component and its corresponding parts by weight are as shown in table 1 in embodiment 1.
Embodiment 2:A kind of mascara, the difference with embodiment 1 is to add preventing for corresponding parts by weight in step s 6 Rotten agent, is well mixed, and the preservative includes Bis(hydroxymethyl)imidazolidinyl urea, the iodine propilolic alcohol that ratio of weight and number is 1: 1: 1: 2 Butyl mephenesin Carbamate, methyl hydroxybenzoate, propane diols.
Embodiment 3:A kind of mascara, the difference with embodiment 2 is that each component and its parts by weight are as shown in table 1, its In, in film forming agent, styrene, acrylic acid (ester) analog copolymer sodium, deionized water, the ratio of weight and number of dehydroactic acid sodium are 1: 4: 1∶2.5;In surfactant, stearine, the parts by weight ratio of PEG-100 stearates are 3: 1;It is double in preservative (methylol) imidazolidinyl urea, iodine propilolic alcohol butyl mephenesin Carbamate, methyl hydroxybenzoate, the parts by weight ratio of propane diols are 1: 1.5: 1.5∶2.5。
Embodiment 4:A kind of mascara, the difference with embodiment 2 is that each component and its parts by weight are as shown in table 1, respectively Component and its parts by weight as shown in table 1, wherein, in film forming agent, styrene, acrylic acid (ester) analog copolymer sodium, deionized water, The ratio of weight and number of dehydroactic acid sodium is 1: 5: 1: 3;In surfactant, stearine, the weight of PEG-100 stearates Amount number ratio is 4: 1;Bis(hydroxymethyl)imidazolidinyl urea, iodine propilolic alcohol butyl mephenesin Carbamate, methyl hydroxybenzoate, third in preservative The parts by weight ratio of glycol is 1: 2: 1.5: 2.5.
Embodiment 5:A kind of mascara, the difference with embodiment 2 is that each component and its parts by weight are as shown in table 1, respectively Component and its parts by weight as shown in table 1, wherein, in film forming agent, styrene, acrylic acid (ester) analog copolymer sodium, deionized water, The ratio of weight and number of dehydroactic acid sodium is 1: 3.5: 1: 2.5;In surfactant, stearine, PEG-100 stearates Parts by weight ratio be 2.5: 1;Bis(hydroxymethyl)imidazolidinyl urea, iodine propilolic alcohol butyl mephenesin Carbamate, oxybenzene in preservative Methyl esters, the parts by weight ratio of propane diols are 1: 2: 2: 3.5.
Embodiment 6:A kind of mascara, the difference with embodiment 2 is that each component and its parts by weight are as shown in table 1, respectively Component and its parts by weight as shown in table 1, wherein, in film forming agent, styrene, acrylic acid (ester) analog copolymer sodium, deionized water, The ratio of weight and number of dehydroactic acid sodium is 1: 4.5: 1: 3;In surfactant, stearine, PEG-100 stearates Parts by weight ratio is 3.5: 1;Bis(hydroxymethyl)imidazolidinyl urea, iodine propilolic alcohol butyl mephenesin Carbamate, oxybenzene first in preservative Ester, the parts by weight ratio of propane diols are 1: 2: 2: 3.
Each component and its parts by weight in the embodiment 1-6 of table 1
Wherein, polyvinylpyrrolidone, preservative are good rich purchased from hundred;Polyvinyl alcohol is newly schemed purchased from Guangdong;Butanediol is purchased from Upper Taiwan Strait Exchange Association is auspicious;Hydroxyethyl cellulose, film forming agent are purchased from Shanghai Ke Naiou;Ethanol is special purchased from peace;C177499, babassu vegetable wax, Beeswax is purchased from the Xiang chief of a tribe;Dextrin isostearate is purchased from Ke Sifa;Stearic acid is purchased from Shanghai brocade harmony;Stearine, PEG-100 Stearate, PEG-40 stearates are purchased from Shanghai higher-dimension;Cyclomethicone is stepped on purchased from Shanghai side;Silica is purchased from Shanghai The connection iron of fine quality.
Comparative example 1-7:A kind of mascara, compared with Example 3, each component and its corresponding parts by weight are as shown in table 2.
Each component and its parts by weight in the comparative example 1-7 of table 2
Comparative example 8:A kind of mascara, component and its corresponding parts by weight are same as Example 3, but as follows Prepare:
S1, the deionized water of corresponding parts by weight, polyvinylpyrrolidone, polyvinyl alcohol, butanediol, hydroxyethyl cellulose are filled Divide mixing, be heated to 70-79 DEG C, form water phase;
S2, by the dextrin isostearate of corresponding parts by weight, babassu vegetable wax, beeswax, stearic acid, PEG-40 stearic acid Ester, cyclomethicone, surfactant, are heated to 70-79 DEG C, form oil phase, wherein, the surfactant is glycerine Stearate, PEG-100 stearates, both parts by weight ratio are 2: 1;
S3, the CI77499 of corresponding parts by weight is well mixed with the oil phase obtained in step S2, is incubated to 70-79 DEG C, is formed Black oil phase;
S4, the black oil obtained in step S3 is added in the water phase obtained in step S1, and homogeneous forms water oil mixture;
S5, the water oil mixture deaeration that will be obtained in step S4 is cooled to 30-37 DEG C, forms cooling water oil mixture;
S6, by the styrene of corresponding parts by weight, acrylic acid (ester) analog copolymer sodium, deionized water, the weight of dehydroactic acid sodium During portion rate is 1: 3: 1: 2 film forming agents for being formed, and silica adds the cooling water oil mixture obtained in step S5, mixing is equal It is even, finished product is obtained, detection, discharging is filling.
Comparative example 9-13:A kind of mascara, compared with Example 3, each component and its corresponding parts by weight such as institute of table 3 Show.
Each component and its parts by weight in the comparative example 9-13 of table 3
Test makeup experiment
Test specimen:Using the mascara obtained in embodiment 1,3,5 as test specimen 1-3, obtained using in comparative example 1-8 Mascara as control sample 1-8.
Test method:Selection eyelash length is similar, eyelashes negligible amounts, the areal, age is 18-25 one full year of life Women white collar subject 1100, be divided into 11 groups, respectively numbering 1-11.Wherein, 1-3 groups subject uses examination respectively Sample 1-3 is tested, 4-11 groups subject then uses control sample 1-8 respectively.When using, using the lash curler of same type by phase The equivalent sample answered is applied on eyelashes, and every group of the makeup effect and use feeling of subject are recorded after 1min.And observation is implemented The usable time limit of the mascara obtained in example 1,3,5.
Result of the test:In first group of subject, after 99% subject thinks to smear test specimen 1, test specimen 1 is uniformly applied Eyelashes surface is put on, eyelashes is substantially become dense, and it is not viscous glutinous between eyelashes, expression in the eyes is become have god;By long-term use, try Testing after sample 1 is opened 3 months to be continuing with;
In second group of subject, after 100% subject thinks to smear test specimen 2, the uniform application of test specimen 2 is in eyelashes table Face, eyelashes substantially become dense, natural, and the degree of crook of eyelashes is unaffected, and not viscous glutinous between eyelashes, expression in the eyes is become god Adopt radiating power and vitality;By long-term use, the shelf-life of test specimen 2 was up to 6 months;
In 3rd group of subject, after 100% subject thinks to smear test specimen 3, the uniform application of test specimen 3 is in eyelashes table Face, eyelashes substantially become dense, and not viscous glutinous between eyelashes, expression in the eyes is become have god;By long-term use, the guarantor of test specimen 3 The matter phase was up to 6 months;
In 4th group of subject, after 95% subject thinks to smear control sample 1, eyelashes are unchanged dense, and the eyelashes on eyelashes Cream is not smeared uniformly;
In 5th group of subject, after 88% subject thinks to smear control sample 2, eyelashes are unchanged dense, and the eyelashes on eyelashes Cream is not smeared uniformly;
In 6th group of subject, after 81% subject thinks to smear control sample 3, eyelashes are unchanged dense, and the eyelashes on eyelashes Cream is not smeared uniformly;
In 7th group of subject, after 73% subject thinks to smear control sample 4, eyelashes are unchanged dense, and the eyelashes on eyelashes Cream is not smeared uniformly;
In 8th group of subject, after 55% subject thinks to smear control sample 5, eyelashes are unchanged dense, and the eyelashes on eyelashes Cream does not smear the phenomenon for uniformly forming fly pin;
In 9th group of subject, after 60% subject thinks to smear control sample 6, eyelashes are not than smearing during control sample 6 somewhat It is thicker, but mascara does not smear the phenomenon for uniformly forming fly pin;
In tenth group of subject, after 75% subject thinks to smear control sample 7, eyelashes slightly show during control sample 7 than not smeared It is dense, but mascara application is not uniform enough, forms the phenomenon of fly pin;
In 11st group of subject, after 85% subject thinks to smear control sample 8, eyelashes are not than smearing during control sample 8 slightly It is aobvious dense, but mascara application is not uniform enough, forms more serious fly pin phenomenon;
In sum, the surfactant that stearine, PEG-100 stearates are formed, it is fine with polyvinyl alcohol, ethoxy Dimension element, dextrin isostearate, cyclomethicone, silica complex role, help to adhere to CI77499 and eyelashes, Make the application to be formed with preferable makeup effect, eyelashes is become denser.And mascara preparation process also can Dense degree to eyelashes after its makeup effect and makeup is impacted.
Test two waterproof tests
Test specimen:Using the mascara obtained in embodiment 2,4,6,7 as test specimen 1-4, using in comparative example 9-13 The mascara of acquisition is used as control sample 1-5.
Test method:Normal body temperature is divided into 9 groups in 37 DEG C of subject 900 in percent test one, numbers respectively 1-9.Wherein, 1-4 groups subject uses test specimen 1-4,5-9 groups subject then to use control sample 1-5 respectively respectively. When using, corresponding equivalent sample is applied on eyelashes using the lash curler of same type, after fully drying, using temperature After being rinsed 10 times for the water of 37 DEG C (similar to body temperature), waterproof effect 1 is recorded;Again through the motion using same intensity After 30min, waterproof effect 2 is recorded.
Result of the test:The waterproof effect of subject's 1-9 groups is as shown in table 4.As shown in Table 4, polyvinylpyrrolidone, honeybee Wax, babassu vegetable wax, by styrene, acrylic acid (ester) analog copolymer sodium, deionized water, dehydroactic acid sodium parts by weight Than being 1: 4: 1: the 2.5 film forming agent mutual cooperation effects for being formed, preferable anti-warm water, anti-sweat effect are reached, be less prone to profit The phenomenon of adornment.
The waterproof effect of the subject's 1-9 groups of table 4
The above is only the preferred embodiment of the present invention, and protection scope of the present invention is not limited merely to above-mentioned implementation Example, all technical schemes belonged under thinking of the present invention belong to protection scope of the present invention.It should be pointed out that for the art Those of ordinary skill for, some improvements and modifications without departing from the principles of the present invention, these improvements and modifications Should be regarded as protection scope of the present invention.

Claims (6)

1. a kind of mascara, it is characterised in that the component including following parts by weight:
Deionized water 35-43 parts;
Polyvinylpyrrolidone 2-3.5 parts;
Polyvinyl alcohol 2.5-4 parts;
Butanediol 2-5 parts;
Hydroxyethyl cellulose 0.1-0.5 parts;
Ethanol 6-10 parts;
CI77499 is 5-8 parts;
1-3.5 parts of dextrin isostearate;
4-6 parts of babassu vegetable wax;
Beeswax 4.5-6 parts;
Stearic acid 1-3.5 parts;
Surfactant 1-3 parts;
0.2-1.5 parts of PEG-40 stearates;
Cyclomethicone 3.5-6.5 parts;
Film forming agent 8-11 parts;
Silica 3-5 parts;
The film forming agent is styrene, acrylic acid(Ester)The mixture that analog copolymer sodium, deionized water, dehydroactic acid sodium are formed, The styrene, acrylic acid(Ester)Analog copolymer sodium, deionized water, the ratio of weight and number of dehydroactic acid sodium are 1:3-5:1:2-3.
2. mascara according to claim 1, it is characterised in that the component including following parts by weight:
Deionized water 37-41 parts;
Polyvinylpyrrolidone 2.3-3.2 parts;
Polyvinyl alcohol 2.8-3.7 parts;
Butanediol 2.5-4.5 parts;
Hydroxyethyl cellulose 0.2-0.45 parts;
Ethanol 7-9 parts;
CI77499 is 5.5-7 parts;
1.5-3 parts of dextrin isostearate;
4.5-5.5 parts of babassu vegetable wax;
Beeswax 4.7-5.8 parts;
Stearic acid 1.2-3.3 parts;
Surfactant 1.3-2.5 parts;
0.5-1.3 parts of PEG-40 stearates;
Cyclomethicone 3.8-6 parts;
Film forming agent 8.5-10 parts;
Silica 3.3-4.5 parts;
The film forming agent is styrene, acrylic acid(Ester)The mixture that analog copolymer sodium, deionized water, dehydroactic acid sodium are formed, The styrene, acrylic acid(Ester)Analog copolymer sodium, deionized water, the ratio of weight and number of dehydroactic acid sodium are 1:3-5:1:2-3.
3. mascara according to claim 1, it is characterised in that the surfactant include stearine, The ratio of PEG-100 stearates, the stearine and PEG-100 stearates is 2-4:1.
4. mascara according to claim 1, it is characterised in that also including preservative, the parts by weight of the preservative It it is 0.1-1.5 parts, the preservative includes double(Methylol)Imidazolidinyl urea, iodine propilolic alcohol butyl mephenesin Carbamate, methyl hydroxybenzoate, Propane diols, it is described double(Methylol)Imidazolidinyl urea, iodine propilolic alcohol butyl mephenesin Carbamate, methyl hydroxybenzoate, the weight portion of propane diols Number is than being 1:1-2:1-2:2-3.5.
5. a kind of a kind of preparation method of mascara as claimed in claim 1, it is characterised in that comprise the following steps:
S1, the deionized water of corresponding parts by weight, polyvinylpyrrolidone, polyvinyl alcohol, butanediol, hydroxyethyl cellulose are filled Divide mixing, be heated to 80-85 DEG C, form water phase;
S2, by the dextrin isostearate of corresponding parts by weight, babassu vegetable wax, beeswax, stearic acid, PEG-40 stearic acid Ester, cyclomethicone, surfactant, are heated to 80-85 DEG C, form oil phase;
S3, the CI77499 of corresponding parts by weight is well mixed with the oil phase obtained in step S2, is incubated to 80-85 DEG C, is formed Black oil phase;
S4, the black oil obtained in step S3 is added in the water phase obtained in step S1, and homogeneous forms water oil mixture;
S5, the water oil mixture deaeration that will be obtained in step S4 is cooled to 38-43 DEG C, forms cooling water oil mixture;
S6, in the cooling water oil mixture that will be obtained in the film forming agent of corresponding parts by weight, silica addition step S5, mixing is equal It is even, finished product is obtained, detection, discharging is filling.
6. the preparation method of a kind of mascara according to claim 5, it is characterised in that added in the step S6 corresponding The preservative of parts by weight, is well mixed.
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108096121A (en) * 2018-02-08 2018-06-01 王志群 A kind of anti-infection mascara and preparation method thereof
CN108309844A (en) * 2018-02-08 2018-07-24 王志群 A kind of mascara and preparation method of quick-hardening
CN110433088A (en) * 2019-08-24 2019-11-12 江西联锴新材料有限公司 A kind of alcohol packet oil mascara and preparation method thereof
CN111480926A (en) * 2019-01-29 2020-08-04 鞍山欣晟美容品有限公司 A adsorption structure and makeup ornaments for making up ornaments
CN113332185A (en) * 2021-07-06 2021-09-03 韩佛化妆品(湖州)有限公司 Mascara and preparation method thereof

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CN102274134A (en) * 2010-06-12 2011-12-14 浙江美雪化妆品有限公司 Eyelash mascara and preparation method thereof
CN103251525A (en) * 2013-05-10 2013-08-21 上海创馨化妆品有限公司 Grafting liquid for making up eyelashes and using method thereof
US20140286887A1 (en) * 2013-03-22 2014-09-25 L'oreal Stable, long wearing cosmetic compositions comprising film forming polymers and a microcrystalline wax

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Publication number Priority date Publication date Assignee Title
CN102274134A (en) * 2010-06-12 2011-12-14 浙江美雪化妆品有限公司 Eyelash mascara and preparation method thereof
US20140286887A1 (en) * 2013-03-22 2014-09-25 L'oreal Stable, long wearing cosmetic compositions comprising film forming polymers and a microcrystalline wax
CN103251525A (en) * 2013-05-10 2013-08-21 上海创馨化妆品有限公司 Grafting liquid for making up eyelashes and using method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108096121A (en) * 2018-02-08 2018-06-01 王志群 A kind of anti-infection mascara and preparation method thereof
CN108309844A (en) * 2018-02-08 2018-07-24 王志群 A kind of mascara and preparation method of quick-hardening
CN111480926A (en) * 2019-01-29 2020-08-04 鞍山欣晟美容品有限公司 A adsorption structure and makeup ornaments for making up ornaments
CN110433088A (en) * 2019-08-24 2019-11-12 江西联锴新材料有限公司 A kind of alcohol packet oil mascara and preparation method thereof
CN110433088B (en) * 2019-08-24 2023-10-27 江西联锴新材料有限公司 Oil-in-alcohol mascara and preparation method thereof
CN113332185A (en) * 2021-07-06 2021-09-03 韩佛化妆品(湖州)有限公司 Mascara and preparation method thereof

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