CN106719710A - A kind of bactericidal composition containing fluorine thiazole pyrrole ethyl ketone - Google Patents
A kind of bactericidal composition containing fluorine thiazole pyrrole ethyl ketone Download PDFInfo
- Publication number
- CN106719710A CN106719710A CN201710051892.1A CN201710051892A CN106719710A CN 106719710 A CN106719710 A CN 106719710A CN 201710051892 A CN201710051892 A CN 201710051892A CN 106719710 A CN106719710 A CN 106719710A
- Authority
- CN
- China
- Prior art keywords
- ethyl ketone
- fluorine thiazole
- thiazole pyrrole
- copper
- pyrrole ethyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/04—Sulfonic acids; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of bactericidal composition containing fluorine thiazole pyrrole ethyl ketone, comprising effective constituents A and active ingredient B and conventional auxiliary component, effective constituents A is selected from fluorine thiazole pyrrole ethyl ketone, and active ingredient B is selected from the one kind in Thiodiazole-copper, nonylphenolsulfonate copper, the gloomy copper of thiophene, and the weight ratio of effective constituents A and B is 1:1~1:60, effective constituents A and B gross weight percentage composition in the composition are 2%~80%.Bactericidal composition of the present invention has significant synergistic function to the multiple diseases of the growth that harms the crops, Pesticide use amount is reduced simultaneously, residual quantity of the agricultural chemicals on crops is reduced, the pollution to environment is alleviated, delay the drug-fast generation of pathogen, increased the Pesticide use life-span.
Description
Technical field
The present invention relates to pesticide sterilizing composite and its application field, the preventing and treating of disease on crops is applied to.
Background technology
Fluorine thiazole pyrrole ethyl ketone (Oxathiapiprolin)：Reached by the suppression to oxidation steroid binding proteins (OSBP)
Bactericidal effect.
The gloomy copper of Thiodiazole-copper, nonylphenolsulfonate copper, thiophene：This three kinds of compounds belong to organic copper class, by with pathogen surface of cell membrane
Cation is swapped, and causes the protein coagulating on germ cell membrane；The copper ion for penetrating into pathogenic cell simultaneously, causes enzyme
Activity is reduced and even inactivated, so that the pathogen dysfunction, final exhaustion is dead.
Fluorine thiazole pyrrole ethyl ketone and the gloomy copper of Thiodiazole-copper, nonylphenolsulfonate copper, thiophene are known compounds, single in agriculturally disease control skill
Art is disclosed.
Agricultural chemicals it is independent continuous for a long time using easily producing resistance risk and the consumption to increase risk, and then increase cost and
Carrying capacity of environment, and pass through agriculture chemical compounding and filter out the composition with notable synergistic function, Pesticide use can not only be reduced
Amount, reduction use cost, reduction resistance risk, moreover it is possible to reduce potential environmental risk.
Factual survey research in, it has been found that by fluorine thiazole pyrrole ethyl ketone respectively with Thiodiazole-copper, nonylphenolsulfonate copper, the gloomy copper of thiophene in
One kind compounded, have obviously preventive and therapeutic effect to corps diseases, according to long-term tracking test, the built agent
Type, is difficult to produce resistance in actual application.And in use, consumption is very low, the negative effect to environment
Very little.
The content of the invention
The present invention is intended to provide a kind of bactericidal composition containing fluorine thiazole pyrrole ethyl ketone, the bactericidal composition has significant
Synergistic function, can be used for the preventing and treating of disease on crops.
Technical scheme：To achieve the above object, the present invention provides a kind of sterilization containing fluorine thiazole pyrrole ethyl ketone
Composition, by effective constituents A and B binary combinations, the part by weight of A and B is 1:1~60, effective constituents A is selected from fluorine thiazole pyrrole second
Ketone, active ingredient B is selected from the one kind in Thiodiazole-copper, nonylphenolsulfonate copper, the gloomy copper of thiophene；Effective constituents A and B gross weight hundred in the composition
Content is divided to be 2%~80%.
In bactericidal composition of the present invention, in addition to active ingredient, also including solvent, cosolvent, emulsifying agent, dispersant, wetting
Agent, thickener, antifreezing agent, cyst material, pH adjusting agent, defoamer, disintegrant, stabilizer, bleeding agent, diffusant, preservative,
Allow to use in the agricultural chemicals such as adhesive, synergist, poisoning palliative, binding agent, electrostatic agent, density adjuster and filler and can be with
The auxiliary element of receiving, is all to commonly use in pesticidal preparations or allow the composition for using, and is not particularly limited, specific composition and consumption
Determined by testing according to recipe requirements.
Solvent can be solvent naphtha S-200, trimethylbenzene, durene, methyl naphthalene, methyl oleate, fatty acid methyl ester, Song Ji
One or more in oil, soybean oil, biodiesel, sec-Butyl Acetate, dimethyl carbonate, diesel oil, white oil, machine oil etc..
Emulsifying agent can be calcium dodecyl benzene sulfonate, AEO, triphenoethyl benzene phenol polyoxypropylene gather
Oxygen ethylene block polymer, dibenzyl xenyl APEO, phenethyl phenol polyethenoxy ether, castor oil polyoxyethylene ether,
Phenethyl phenol formaldehyde resin APEO, phenethyl phenol polyoxyethylene polyoxypropylene ether, alkylaryl polyoxypropylene polyoxy
Vinethene, phenethyl phenol formaldehyde resin APEO, Sorbitan fatty acid ester, sorbitan fatty acid ester polyoxy second
In alkene ether, natural fatty alcohol and ethylene oxide adduct, aliphatic acid and ethylene oxide condensate, polyoxyethylene fatty acid ester etc.
One or more.
Wetting agent can be sodium butylnaphthalenesulfonate, lauryl sodium sulfate, aliphatic alcohol polyethenoxy (6-7) ether, sulfonation amber
One or more in amber dioctyl phthalate sodium salt, Morwet EFW, alkylnaphthalene sulfonate etc..
Disintegrant can be compound sodium nitrophenolate, sodium acid carbonate, magnesium chloride, aluminium chloride, sodium chloride, urea, ammonium sulfate, bentonite
One or more in.
Dispersant can be polycarboxylate, the formaldehyde condensation products of methyl naphthalene sulfonic acid sodium, sodium lignin sulfonate, lignin sulfonic acid
Calcium, sodium lignin sulfonate, naphthalene sulfonic acid condensate sodium salt, alkylnaphthalene to methoxyl group fatty acyl anilinesulfonic acid, desugar and classification
One or more in sulfonic acid condensation polymer sodium salt, APES formaldehyde condensation product sulfuric acid etc..
Thickener can be one or more in xanthans, aluminium-magnesium silicate, bentonite, white carbon etc..
During pH adjusting agent can be ammonium hydroxide, potassium hydroxide, NaOH, hydrochloric acid, acetic acid, citric acid, phosphoric acid etc.
One or more.
Stabilizer can be dibutyl phthalate, hexamethylene diisocyanate, epoxidized soybean oil, epoxy chloropropionate
One or more in alkane, butylated hydroxy anisole, dibutyl hydroxy toluene, propylgallate, tert-butylhydroquinone etc..
Defoamer can be one or more in silicone compound, methyl alcohol, silicone oil, azone etc..
Antifreezing agent can be one or more in glycerine, ethylene glycol, propane diols, sorbierite, polyethylene glycol etc..
Carrier can be kaolin, diatomite, bentonite, white carbon, precipitated calcium carbonate, attapulgite, clay, talcum
One or more in powder, quartz sand, starch, APG, urea, potassium chloride, ammonium chloride etc..
Sustained release agent can be one or two in polyvinyl alcohol, Arabic gum.
Binding agent can be one or two in polyethylene glycol, industrial gelatine.
Bactericidal composition of the present invention can be prepared into suitable agricultural production the various application forms for using, relatively good agent
Type has microcapsule suspending agent, suspending agent, water dispersible granules, wettable powder.
The production technology of the various application forms of described bactericidal composition belongs to existing known technology, will not be repeated here.
Compared with prior art, the advantage of the invention is that：
1st, composition has significant synergistic function, is used alone than single dose and significantly improved to disease on crops
Harmful prevention effect, and expand fungicidal spectrum.
2nd, composition reduces single usage amount, reduces use cost, alleviates the pollution to environment.
3rd, two kinds of active ingredient mechanisms of action that composition contains are different, and action site increases, and has delayed pathogen
Drug-fast generation, increased the service life of agricultural chemicals.
Specific embodiment
Essence for a better understanding of the present invention, is described further with reference to embodiment to present disclosure,
But limitation of the present invention can not be considered as, it is as described below to be only used for explaining the present invention, for without departing from spirit of the invention and principle
Modification, replacement or the improvement made, belong to the scope of protection of present invention.
Embodiment one：21% fluorine thiazole pyrrole ethyl ketone Thiodiazole-copper water dispersible granules
Following material is weight percentage：Fluorine thiazole pyrrole ethyl ketone (effective constituents A) 1%, Thiodiazole-copper (active ingredient B)
20%th, lauryl sodium sulfate (disintegrant) 5%, lignosulfonates (dispersant) 2%, polycarboxylate (dispersant) 4%, shallow lake
Paste mixing essence (adhesive) 2%, magnesium chloride (stabilizer) 2%, urea (adhesive) 3%, potassium sorbate (preservative) 2%, swelling
Native (filler) complements to 100%.Above-mentioned material is weighed in proportion, is well mixed into blender, then through ultra micro air-flow powder
Broken machine is crushed, and through mediating, is subsequently adding in fluidized-bed granulation dryer and is granulated, dry, sieve, i.e., prepared 21% fluorine thiazole
Pyrrole ethyl ketone Thiodiazole-copper water dispersible granules.
The embodiment is used to prevent and treat tomato late blight, and sick early period of origination carries out first time dispenser, applied for the second time after 10d
Medicine, respectively at 10d, 20 days investigation prevention tomato late blight results after second dispenser：21% fluorine thiazole pyrrole ethyl ketone Thiodiazole-copper
Water dispersible granules consumption 100g a.i./ha preventive effects 93.41%, 94.06%, 10% fluorine thiazole pyrrole ethyl ketone dispersibles oil-suspending agent
Consumption 30g a.i./ha preventive effects 81.07%, 76.28%, 20% Thiodiazole-copper suspending agent consumption 500g a.i./ha preventive effects
76.37%th, 71.55%.It can be seen that, 21% fluorine thiazole pyrrole ethyl ketone Thiodiazole-copper water dispersible granules lifting using effect, the lasting period is long,
Preventive effect to tomato late blight is used alone significantly better than each single dose, meanwhile, do not find that the present invention is combined in process of the test
Thing produces harmful effect to tomato.
Embodiment two：21% fluorine thiazole pyrrole ethyl ketone nonylphenolsulfonate copper suspending agent
Following material is weight percentage：Fluorine thiazole pyrrole ethyl ketone (effective constituents A) 1%, nonylphenolsulfonate copper (active ingredient B)
20%th, methyl naphthalene sulfonate formaldehyde condensate (wetting agent) 2%, polycarboxylate (dispersant) 5%, glycerine (antifreezing agent) 4%,
Xanthans (thickener) 1%, sorb sodium alkoxide (preservative) 0.2%, C10-20 saturated fat acid compounds (defoamer)
0.2%th, triethanolamine (pH adjusting agent) 0.2%, vegetable oil (synergist) 2%, deionized water supplies 100%.Will be above-mentioned effective
Composition, wetting agent, dispersant, antifreezing agent, thickener, preservative, defoamer, pH adjusting agent, synergist and deionized water are through height
It is sanded in speed shearing dispersion, sand mill, high dispersive, the suspension system of stabilization formed in water-medium, you can be obtained 21%
Fluorine thiazole pyrrole ethyl ketone nonylphenolsulfonate copper suspending agent.
The embodiment is used to prevent and treat cucumber downy mildew, and sick early period of origination carries out first time dispenser, applied for the second time after 10d
Medicine, respectively at 10d, 20 days investigation prevention tomato late blight results after second dispenser：21% fluorine thiazole pyrrole ethyl ketone nonylphenolsulfonate copper
Suspending agent consumption 100g a.i./ha preventive effects 92.54%, 93.40%, 10% fluorine thiazole pyrrole ethyl ketone dispersibles oil-suspending agent consumption
30g a.i./ha preventive effects 83.14%, 77.82%, 20% nonylphenolsulfonate copper microemulsion consumption 600g a.i./ha preventive effects 78.27%,
73.91%.It can be seen that, 21% fluorine thiazole pyrrole ethyl ketone nonylphenolsulfonate copper suspending agent lifting using effect, the lasting period is long, to tomato late blight
Preventive effect significantly better than each single dose be used alone, meanwhile, do not found in process of the test the present composition to tomato produce
Harmful effect.
Embodiment three：The 11% fluorine thiazole pyrrole gloomy copper of ethyl ketone thiophene dispersibles oil-suspending agent
Following material is weight percentage：The fluorine thiazole pyrrole gloomy copper (active ingredient B) of ethyl ketone (effective constituents A) 1%, thiophene
20%th, trimethylbenzene (solvent) 20%, methylated vegetable oil (solvent) 10%, polycarboxylate (dispersant) 2%, phenethyl phenol polyoxy
Ethene ether phosphate (emulsifying agent) 5%, thiophene ketone (bleeding agent) 2%, soybean oil (filler) complement to 100%.By it is above-mentioned effectively into
Divide after being dissolved with stirring solvent, add emulsifying agent, dispersant, emulsifying agent, bleeding agent, filler, be thoroughly mixed uniformly, i.e.,
The 11% fluorine thiazole pyrrole gloomy copper of ethyl ketone thiophene can be obtained and dispersibles oil-suspending agent.
The embodiment is used to prevent and treat target, and sick early period of origination carries out first time dispenser, is carried out after 10d second
Dispenser, respectively at 10d, 20 days investigation prevention tomato late blight results after second dispenser：21% fluorine thiazole pyrrole ethyl ketone thiophene is gloomy
Copper dispersibles oil-suspending agent consumption 100g a.i./ha preventive effects 90.71%, 87.23%, and 10% fluorine thiazole pyrrole ethyl ketone dispersibles oil
Suspending agent consumption 30g a.i./ha preventive effects 81.34%, 75.89%, the gloomy copper suspension emulsion 600g a.i./ha preventive effects of 20% thiophene
74.74%th, 70.63%.It can be seen that, the 21% fluorine thiazole pyrrole gloomy copper of ethyl ketone thiophene dispersibles oil-suspending agent lifting using effect, holding effect
Phase is long, and the preventive effect to target is used alone significantly better than each single dose, meanwhile, this hair is not found in process of the test
Bright composition produces harmful effect to tomato.
Example IV：The 22% fluorine thiazole gloomy copper microcapsule suspending agent of pyrrole ethyl ketone thiophene
Following material is weight percentage：The fluorine thiazole pyrrole gloomy copper (active ingredient B) of ethyl ketone (effective constituents A) 2%, thiophene
20%th, melamine formaldehyde resin (cyst material) 8%, diethyl phthalate (solvent) 10%, maleic acid di-secondary
Dioctyl sodium sulfosuccinate (emulsifying agent) 5%, maleic acid-acrylic acid copolymer sodium salt (dispersant) 3%, organosilicon (defoamer) 1%, go
Ionized water complements to 100%.Above-mentioned active ingredient, cyst material, solvent are mixed, makes to be dissolved into homogeneous oil phase, in shearing bar
Under part, during oil phase is added to containing emulsifying agent, dispersant, the aqueous phase solution of defoamer, surplus is supplied with deionized water, through cutting
After cutting dissipates solidification, you can the 22% fluorine thiazole gloomy copper microcapsule suspending agent of pyrrole ethyl ketone thiophene is obtained.
The embodiment is used to prevent and treat eggplant bacterial wilt, and sick early period of origination carries out first time dispenser, applied for the second time after 10d
Medicine, respectively at 10d, 20 days investigation prevention eggplant bacterial wilt results after second dispenser：The 22% fluorine thiazole pyrrole gloomy copper of ethyl ketone thiophene
Microcapsule suspending agent consumption 100g a.i./ha preventive effects 90.04%, 86.29%, 10% fluorine thiazole pyrrole ethyl ketone dispersibles oil-suspending agent
Consumption 100g a.i./ha preventive effects 52.27%, 60.08%, the gloomy copper suspension emulsion 600g a.i./ha preventive effects 87.06% of 20% thiophene,
80.61%.It can be seen that, the 21% fluorine thiazole pyrrole gloomy copper of ethyl ketone thiophene dispersibles oil-suspending agent lifting using effect, and the lasting period is long, to eggplant
The preventive effect of sub- bacterial wilt is used alone significantly better than each single dose, meanwhile, the present composition pair is not found in process of the test
Eggplant produces harmful effect.
Embodiment five：22% fluorine thiazole pyrrole ethyl ketone nonylphenolsulfonate copper microcapsule suspending agent
Following material is weight percentage：Fluorine thiazole pyrrole ethyl ketone (effective constituents A) 2%, nonylphenolsulfonate copper (active ingredient B)
20%th, melamine formaldehyde resin (cyst material) 8%, Solvesso100 (solvent) 10%, polyol fatty acid ester (emulsification
Agent) 5%, sodium methylene bis-naphthalene sulfonate (dispersant) 4%, organosilicon (defoamer) 1%, deionized water complements to 100%.Will be upper
Active ingredient, cyst material, solvent mixing are stated, makes to be dissolved into homogeneous oil phase, in a shear condition, oil phase is added to and contains breast
In agent, dispersant, the aqueous phase solution of defoamer, surplus is supplied with deionized water, and two kinds of materials react in oil-water interfaces,
Form cyst wall, you can 22% fluorine thiazole pyrrole ethyl ketone nonylphenolsulfonate copper microcapsule suspending agent is obtained.
The embodiment is used to prevent and treat eggplant bacterial wilt, and sick early period of origination carries out first time dispenser, applied for the second time after 10d
Medicine, respectively at 10d, 20 days investigation prevention eggplant bacterial wilt results after second dispenser：22% fluorine thiazole pyrrole ethyl ketone nonylphenolsulfonate copper
Microcapsule suspending agent consumption 100g a.i./ha preventive effects 83.70%, 90.44%, 10% fluorine thiazole pyrrole ethyl ketone microcapsule suspending agent consumption
100g a.i./ha preventive effects 52.27%, 60.08%, 20% nonylphenolsulfonate copper microcapsule suspending agent consumption 600g a.i./ha preventive effects
71.53%th, 76.11%.It can be seen that, 22% fluorine thiazole pyrrole ethyl ketone nonylphenolsulfonate copper microcapsule suspending agent lifting using effect, the lasting period is long,
Preventive effect to eggplant bacterial wilt is used alone significantly better than each single dose, meanwhile, do not find that the present invention is combined in process of the test
Thing produces harmful effect to eggplant.
Embodiment six：22% fluorine thiazole pyrrole ethyl ketone Thiodiazole-copper microcapsule suspending agent
Following material is weight percentage：Fluorine thiazole pyrrole ethyl ketone (effective constituents A) 2%, Thiodiazole-copper (active ingredient B)
20%th, melamine formaldehyde resin (cyst material) 8%, Solvesso100 (solvent) 10%, polyol fatty acid ester (emulsification
Agent) 5%, sodium methylene bis-naphthalene sulfonate (dispersant) 4%, organosilicon (defoamer) 1%, deionized water complements to 100%.Will be upper
Active ingredient, cyst material, solvent mixing are stated, makes to be dissolved into homogeneous oil phase, in a shear condition, oil phase is added to and contains breast
In agent, dispersant, the aqueous phase solution of defoamer, surplus is supplied with deionized water, and two kinds of materials react in oil-water interfaces,
Form cyst wall, you can 22% fluorine thiazole pyrrole ethyl ketone Thiodiazole-copper microcapsule suspending agent is obtained.
The embodiment is used to prevent and treat eggplant bacterial wilt, and sick early period of origination carries out first time dispenser, applied for the second time after 10d
Medicine, respectively at 10d, 20 days investigation prevention eggplant bacterial wilt results after second dispenser：22% fluorine thiazole pyrrole ethyl ketone Thiodiazole-copper
Microcapsule suspending agent consumption 100g a.i./ha preventive effects 85.19%, 89.46%, 10% fluorine thiazole pyrrole ethyl ketone microcapsule suspending agent consumption
100g a.i./ha preventive effects 52.27%, 60.08%, 20% Thiodiazole-copper microcapsule suspending agent consumption 600g a.i./ha preventive effects
74.27%th, 79.73%.It can be seen that, 22% fluorine thiazole pyrrole ethyl ketone Thiodiazole-copper microcapsule suspending agent lifting using effect, the lasting period is long,
Preventive effect to eggplant bacterial wilt is used alone significantly better than each single dose, meanwhile, do not find that the present invention is combined in process of the test
Thing produces harmful effect to eggplant.
Embodiment seven：The 50% fluorine thiazole pyrrole gloomy copper water dispersion granula of ethyl ketone thiophene
Following material is weight percentage：The fluorine thiazole pyrrole gloomy copper (active ingredient B) of ethyl ketone (effective constituents A) 25%, thiophene
25%th, sodium butylnaphthalenesulfonate (wetting agent) 5%, PAA and the third organic copper copolymer (dispersant) 5%, poly- naphthaldehyde sulfonic acid
Sodium salt 5% (diffusant), polyvinylpyrrolidone (disintegrant) 5%, sodium carboxymethylcellulose (binding agent) 0.2%, anhydrous chlorine
Change calcium (stabilizer) 0.2%, organosiloxane (defoamer) 0.2%, mannitol (pH adjusting agent) 0.2%, diatomite (filler)
Supply 100%.By above-mentioned active ingredient, wetting agent, dispersant, diffusant, disintegrant, binding agent, stabilizer, defoamer, pH
Conditioning agent and filler are well mixed, are crushed with micro jet, through mediating, are subsequently adding in fluidized-bed granulation dryer
Row granulation, dry, screening, you can the 50% fluorine thiazole pyrrole gloomy copper water dispersion granula of ethyl ketone thiophene is obtained.
The embodiment is used to prevent and treat grapevine anthracnose, and sick early period of origination carries out first time dispenser, applied for the second time after 20d
Medicine, respectively at 10d, 20 days investigation prevention results after second dispenser：The 50% fluorine thiazole pyrrole gloomy copper water dispersion granula of ethyl ketone thiophene
Consumption 160a.i.mg/kg preventive effects 93.49%, 87.40%, 50% fluorine thiazole pyrrole ethyl ketone water dispersible granules consumption 160a.i.mg/
Kg preventive effects 81.62%, 73.88%, 50% Thiodiazole-copper water dispersible granules consumption 160a.i.mg/kg preventive effects 77.69%,
68.59%.It can be seen that, 50% fluorine thiazole pyrrole ethyl ketone Thiodiazole-copper water dispersible granules of the invention lift using effect, and the lasting period is long, right
The preventive effect of grapevine anthracnose is used alone significantly better than each single dose, meanwhile, the present composition is not found in process of the test
Harmful effect is produced to grape.
Embodiment eight：50% fluorine thiazole pyrrole ethyl ketone nonylphenolsulfonate copper water dispersible granules
Following material is weight percentage：Fluorine thiazole pyrrole ethyl ketone (effective constituents A) 25%, nonylphenolsulfonate copper (active ingredient B)
25%th, lauryl sodium sulfate (wetting agent) 5%, alkylphenol-polyethenoxy base ether phosphate (dispersant) 5%, poly- naphthaldehyde sulphur
Acid sodium-salt 5% (diffusant), sodium acid carbonate (disintegrant) 5%, glucose (binding agent) 0.2%, anhydrous calcium chloride (stabilizer)
0.2%th, organosiloxane (defoamer) 0.2%, mannitol (pH adjusting agent) 0.2%, kaolin (filler) supplies 100%.Will
Above-mentioned active ingredient, wetting agent, dispersant, diffusant, disintegrant, binding agent, stabilizer, defoamer, pH adjusting agent and filler
It is well mixed, crushed with micro jet, through mediating, be subsequently adding in fluidized-bed granulation dryer granulated, dried,
Screening, you can 50% fluorine thiazole pyrrole ethyl ketone nonylphenolsulfonate copper water dispersible granules are obtained.
The embodiment is used to prevent and treat peronophythora litchi, and sick early period of origination carries out first time dispenser, is carried out after 20d second
Dispenser, respectively at 10d, 20 days investigation prevention results after second dispenser：The 50% fluorine thiazole gloomy copper water dispersible granule of pyrrole ethyl ketone thiophene
Agent consumption 200a.i.mg/kg preventive effects 84.82%, 83.33%, 50% fluorine thiazole pyrrole ethyl ketone water dispersible granules consumption
200a.i.mg/kg preventive effects 75.12%, 70.47%, 50% nonylphenolsulfonate copper water dispersible granules consumption 200a.i.mg/kg preventive effects
71.62%th, 69.27%.It can be seen that, 50% fluorine thiazole pyrrole ethyl ketone nonylphenolsulfonate copper water dispersible granules of the invention lift using effect, hold
The effect phase is long, and the preventive effect to peronophythora litchi is used alone significantly better than each single dose, meanwhile, this is not found in process of the test
Inventive composition produces harmful effect to lichee.
Embodiment nine：50% fluorine thiazole pyrrole ethyl ketone nonylphenolsulfonate copper water dispersible granules
Following material is weight percentage：The fluorine thiazole pyrrole gloomy copper (active ingredient B) of ethyl ketone (effective constituents A) 25%, thiophene
25%th, lauryl sodium sulfate (wetting agent) 5%, alkylphenol-polyethenoxy base ether phosphate (dispersant) 5%, poly- naphthaldehyde sulphur
Acid sodium-salt 5% (diffusant), sodium acid carbonate (disintegrant) 5%, glucose (binding agent) 0.2%, anhydrous calcium chloride (stabilizer)
0.2%th, organosiloxane (defoamer) 0.2%, mannitol (pH adjusting agent) 0.2%, kaolin (filler) supplies 100%.Will
Above-mentioned active ingredient, wetting agent, dispersant, diffusant, disintegrant, binding agent, stabilizer, defoamer, pH adjusting agent and filler
It is well mixed, crushed with micro jet, through mediating, be subsequently adding in fluidized-bed granulation dryer granulated, dried,
Screening, you can 50% fluorine thiazole pyrrole ethyl ketone nonylphenolsulfonate copper water dispersible granules are obtained.
The embodiment is used to prevent and treat alternaria leaf spot of apple, and sick early period of origination carries out first time dispenser, and second is carried out after 20d
Secondary dispenser, respectively at 10d, 20 days investigation prevention results after second dispenser：The gloomy copper water dispersion of 50% fluorine thiazole pyrrole ethyl ketone thiophene
Granula consumption 80a.i.mg/kg preventive effects 86.05%, 82.31%, 50% fluorine thiazole pyrrole ethyl ketone water dispersible granules consumption
80a.i.mg/kg preventive effects 73.73%, 68.45%, 50% Thiodiazole-copper water dispersible granules consumption 80a.i.mg/kg preventive effects
70.47%th, 64.93%.It can be seen that, the gloomy copper water dispersion granula lifting using effect of 50% fluorine thiazole pyrrole ethyl ketone thiophene of the invention is held
The effect phase is long, and the preventive effect to alternaria leaf spot of apple is used alone significantly better than each single dose, meanwhile, do not find this in process of the test
The present composition produces harmful effect to apple.
Embodiment ten：62% fluorine thiazole pyrrole ethyl ketone Thiodiazole-copper wettable powder
Following material is weight percentage：Fluorine thiazole pyrrole ethyl ketone (effective constituents A) 2%, Thiodiazole-copper (active ingredient B)
60%th, alkylnaphthalene sulfonate (wetting agent) 5%, PAA and the third organic copper copolymer (dispersant) 5%, poly- naphthaldehyde sulfonic acid
Sodium salt 5% (diffusant), white carbon (filler) 5%, potter's clay (filler) supply 100%.By it is above-mentioned by active ingredient, wetting agent,
The mixing of dispersant, diffusant and filler, again through air-flow crushing after mechanical crushing, is well mixed, you can 62% fluorine thiazole pyrrole is obtained
Ethyl ketone Thiodiazole-copper wettable powder.
The embodiment is used to prevent and treat celery cabbage clubroot, and sick early period of origination carries out first time dispenser, is carried out after 20d second
Dispenser, respectively at 10d, 20 days investigation prevention results after second dispenser：The 62% fluorine thiazole gloomy copper wettable powder of pyrrole ethyl ketone thiophene
Agent consumption 200a.i.g/ha preventive effects 84.27%, 86.03%, 62% fluorine thiazole pyrrole ethyl ketone wettable powder consumption 200a.i.g/
Ha preventive effects 76.28%, 71.29%, 62% Thiodiazole-copper wettable powder consumption 200a.i.g/ha preventive effects 72.40%, 66.37%.
It can be seen that, 50% fluorine thiazole pyrrole ethyl ketone Thiodiazole-copper wettable powder of the invention lifts using effect, and the lasting period is long, to Chinese cabbage root
The preventive effect of the disease that swells is used alone significantly better than each single dose, meanwhile, do not find the present composition to great Bai in process of the test
Dish produces harmful effect.
Embodiment 11：41% fluorine thiazole pyrrole ethyl ketone nonylphenolsulfonate copper wettable powder
Following material is weight percentage：Fluorine thiazole pyrrole ethyl ketone (effective constituents A) 1%, nonylphenolsulfonate copper (active ingredient B)
40%th, alkylnaphthalene sulfonate (wetting agent) 5%, PAA and the third organic copper copolymer (dispersant) 5%, poly- naphthaldehyde sulfonic acid
Sodium salt 5% (diffusant), white carbon (filler) 5%, potter's clay (filler) supply 100%.By it is above-mentioned by active ingredient, wetting agent,
The mixing of dispersant, diffusant and filler, again through air-flow crushing after mechanical crushing, is well mixed, you can 41% fluorine thiazole pyrrole is obtained
Ethyl ketone nonylphenolsulfonate copper wettable powder.
The embodiment is used to prevent and treat watermelon grafting, and sick early period of origination carries out first time dispenser, applied for the second time after 20d
Medicine, respectively at 10d, 20 days investigation prevention results after second dispenser：41% fluorine thiazole pyrrole ethyl ketone nonylphenolsulfonate copper wettable powder
Consumption 200a.i.g/ha preventive effects 90.50%, 83.61%, 41% fluorine thiazole pyrrole ethyl ketone wettable powder consumption 200a.i.g/ha
Preventive effect 79.42%, 70.11%, 41% nonylphenolsulfonate copper wettable powder consumption 200a.i.g/ha preventive effects 67.49%, 52.03%.Can
See, 41% fluorine thiazole pyrrole ethyl ketone nonylphenolsulfonate copper wettable powder of the invention lifts using effect, the lasting period is long, to watermelon grafting
Preventive effect significantly better than each single dose be used alone, meanwhile, do not found in process of the test the present composition to watermelon produce
Harmful effect.
Embodiment 12：The 51% fluorine thiazole gloomy copper wettable powder of pyrrole ethyl ketone thiophene
Following material is weight percentage：The fluorine thiazole pyrrole gloomy copper (active ingredient B) of ethyl ketone (effective constituents A) 1%, thiophene
50%th, alkylnaphthalene sulfonate (wetting agent) 5%, PAA and the third organic copper copolymer (dispersant) 5%, poly- naphthaldehyde sulfonic acid
Sodium salt 5% (diffusant), white carbon (filler) 5%, potter's clay (filler) supply 100%.By it is above-mentioned by active ingredient, wetting agent,
The mixing of dispersant, diffusant and filler, again through air-flow crushing after mechanical crushing, is well mixed, you can 51% fluorine thiazole pyrrole is obtained
The gloomy copper wettable powder of ethyl ketone thiophene.
The embodiment is used to prevent and treat peanut sclerotium rolfsii, and sick early period of origination carries out first time dispenser, applied for the second time after 20d
Medicine, respectively at 10d, 20 days investigation prevention results after second dispenser：The 51% fluorine thiazole gloomy copper wettable powder of pyrrole ethyl ketone thiophene
Consumption 180a.i.g/ha preventive effects 96.84%, 87.20%, 51% fluorine thiazole pyrrole ethyl ketone wettable powder consumption 180a.i.g/ha
Preventive effect 82.55%, 76.47%, the gloomy copper wettable powder consumption 180a.i.g/ha preventive effects 76.41%, 70.21% of 51% thiophene.Can
See, the gloomy copper wettable powder lifting using effect of 51% fluorine thiazole pyrrole ethyl ketone thiophene of the invention, the lasting period is long, to peanut sclerotium rolfsii
Preventive effect significantly better than each single dose be used alone, meanwhile, do not found in process of the test the present composition to peanut produce
Harmful effect.
Embodiment 13：The 61% fluorine thiazole gloomy copper wettable powder of pyrrole ethyl ketone thiophene
Following material is weight percentage：The fluorine thiazole pyrrole gloomy copper (active ingredient B) of ethyl ketone (effective constituents A) 1%, thiophene
60%th, alkylnaphthalene sulfonate (wetting agent) 5%, PAA and the third organic copper copolymer (dispersant) 5%, poly- naphthaldehyde sulfonic acid
Sodium salt 5% (diffusant), white carbon (filler) 5%, potter's clay (filler) supply 100%.By it is above-mentioned by active ingredient, wetting agent,
The mixing of dispersant, diffusant and filler, again through air-flow crushing after mechanical crushing, is well mixed, you can 61% fluorine thiazole pyrrole is obtained
The gloomy copper wettable powder of ethyl ketone thiophene.
The embodiment is used to prevent and treat banyan canker, and sick early period of origination carries out first time dispenser, applied for the second time after 20d
Medicine, respectively at 20d, 40 days investigation prevention results after second dispenser：The 61% fluorine thiazole gloomy copper wettable powder of pyrrole ethyl ketone thiophene
Consumption 120a.i.g/ha preventive effects 93.04%, 96.27%, 61% fluorine thiazole pyrrole ethyl ketone wettable powder consumption 120a.i.g/ha
Preventive effect 73.44%, 80.81%, the gloomy copper wettable powder consumption 120a.i.g/ha preventive effects 81.93%, 86.04% of 61% thiophene.Can
See, the gloomy copper wettable powder lifting using effect of 61% fluorine thiazole pyrrole ethyl ketone thiophene of the invention, the lasting period is long, to peanut sclerotium rolfsii
Preventive effect significantly better than each single dose be used alone, meanwhile, do not found in process of the test the present composition to peanut produce
Harmful effect.
Embodiment 14：The Toxicity Determination examination of fluorine thiazole pyrrole ethyl ketone and Thiodiazole-copper compounding to late blight in tomato
Test
Experiment target：Late blight in tomato.
Test method：With reference to《Farm-chemical indoor determination test rule NY/T1156.14-2008》, using pot-culture method.
Statistical analysis is carried out with DPS statistical analysis softwares, the EC of each medicament is calculated50, and mixture is calculated according to the abundant methods of Sun Yun
Co-toxicity coefficient (CTC values).
Actual measurement toxicity index (ATI)=(standard agent EC50/ reagent agent EC50)×100。
Percentage composition+B the medicament toxicity index of A in theoretical toxicity index (TTI)=A medicament toxicity index × mixture × mixed
The percentage composition of B in agent.
Co-toxicity coefficient (CTC)=[mixture surveys toxicity index (ATI)/mixture theoretical toxicity index (TTI)] × 100.
The criteria for classifying is acted on according to NY/T11547.7-2006 insecticide combinations：Co-toxicity coefficient (CTC) >=120 shows as
Synergistic effect；Co-toxicity coefficient (CTC)≤80 shows as antagonism；80 ＜ co-toxicity coefficients (CTC) ＜ 120 show as being added and make
With.
The Toxicity Determination result of table 1, fluorine thiazole pyrrole ethyl ketone and Thiodiazole-copper to late blight in tomato
| Medicament title and proportioning (weight ratio) | EC50(mg/L) | ATI | TTI | CTC |
| Fluorine thiazole pyrrole ethyl ketone | 2.06 | 100.00 | -- | -- |
| Thiodiazole-copper | 23.52 | 8.76 | -- | -- |
| Fluorine thiazole pyrrole ethyl ketone：Thiodiazole-copper (1:1) | 2.85 | 72.28 | 54.38 | 132.9 |
| Fluorine thiazole pyrrole ethyl ketone：Thiodiazole-copper (1:10) | 7.27 | 28.34 | 17.05 | 166.2 |
| Fluorine thiazole pyrrole ethyl ketone：Thiodiazole-copper (1:12) | 7.84 | 26.28 | 15.78 | 166.5 |
| Fluorine thiazole pyrrole ethyl ketone：Thiodiazole-copper (1:14) | 8.29 | 24.85 | 14.84 | 167.4 |
| Fluorine thiazole pyrrole ethyl ketone：Thiodiazole-copper (1:16) | 8.58 | 24.01 | 14.13 | 170.0 |
| Fluorine thiazole pyrrole ethyl ketone：Thiodiazole-copper (1:18) | 8.51 | 24.21 | 13.56 | 178.5 |
| Fluorine thiazole pyrrole ethyl ketone：Thiodiazole-copper (1:20) | 8.36 | 24.64 | 13.10 | 188.1 |
| Fluorine thiazole pyrrole ethyl ketone：Thiodiazole-copper (1:30) | 11.09 | 18.58 | 11.70 | 158.7 |
| Fluorine thiazole pyrrole ethyl ketone：Thiodiazole-copper (1:40) | 12.05 | 17.10 | 10.98 | 155.6 |
| Fluorine thiazole pyrrole ethyl ketone：Thiodiazole-copper (1:50) | 13.63 | 15.11 | 10.55 | 143.3 |
| Fluorine thiazole pyrrole ethyl ketone：Thiodiazole-copper (1:60) | 15.14 | 13.61 | 10.25 | 132.7 |
As it can be seen from table 1 A fluorine thiazole pyrrole ethyl ketone and B Thiodiazole-coppers portfolio ratio (pressing quality) 1~1:60 co-toxicity coefficients
(CTC) 120 are all higher than, illustrate that the combination shows synergistic function to late blight in tomato, especially 1:10~
1:In the range of 20, particularly 1:20 synergistic functions are more notable.It can be seen that, fluorine thiazole pyrrole ethyl ketone and Thiodiazole-copper compounding have
Reasonability and feasibility.
Embodiment 15：The Toxicity Determination examination of fluorine thiazole pyrrole ethyl ketone and nonylphenolsulfonate copper compounding to watermelon anthrax pathogen
Test
Experiment target：Watermelon anthrax pathogen.
Test method：With reference to《Farm-chemical indoor determination test rule NY/T1156.14-2008》, using pot-culture method.
Statistical analysis is carried out with DPS statistical analysis softwares, the EC of each medicament is calculated50, and mixture is calculated according to the abundant methods of Sun Yun
Co-toxicity coefficient (CTC values).
Actual measurement toxicity index (ATI)=(standard agent EC50/ reagent agent EC50)×100。
Percentage composition+B the medicament toxicity index of A in theoretical toxicity index (TTI)=A medicament toxicity index × mixture × mixed
The percentage composition of B in agent.
Co-toxicity coefficient (CTC)=[mixture surveys toxicity index (ATI)/mixture theoretical toxicity index (TTI)] × 100.
The criteria for classifying is acted on according to NY/T11547.7-2006 insecticide combinations：Co-toxicity coefficient (CTC) >=120 shows as
Synergistic effect；Co-toxicity coefficient (CTC)≤80 shows as antagonism；80 ＜ co-toxicity coefficients (CTC) ＜ 120 show as being added and make
With.
The Toxicity Determination result of table 2, fluorine thiazole pyrrole ethyl ketone and nonylphenolsulfonate copper to watermelon anthrax pathogen
From table 2 it can be seen that fluorine thiazole pyrrole ethyl ketone and nonylphenolsulfonate copper combination ratio 1~1 (by weight):60 co-toxicity coefficients
(CTC) 120 are all higher than, synergistic function is shown to watermelon anthrax pathogen, especially 1:10~1:20 scope
It is interior, particularly 1:20, synergistic function is more notable.It can be seen that, fluorine thiazole pyrrole ethyl ketone and nonylphenolsulfonate copper compounding have reasonability and
Feasibility.
Embodiment 16：Fluorine thiazole pyrrole ethyl ketone and the gloomy copper compounding of thiophene are surveyed to the indoor virulence of apple drop point defoliation pathogen
Fixed experiment
Experiment target：Apple drop point defoliation pathogen.
Test method：With reference to《Farm-chemical indoor determination test rule NY/T1156.16-2008》, using turbidity method.
Statistical analysis is carried out with DPS statistical analysis softwares, the EC of each medicament is calculated50, and mixture is calculated according to the abundant methods of Sun Yun
Co-toxicity coefficient (CTC values).
Actual measurement toxicity index (ATI)=(standard agent EC50/ reagent agent EC50)×100。
Percentage composition+B the medicament toxicity index of A in theoretical toxicity index (TTI)=A medicament toxicity index × mixture × mixed
The percentage composition of B in agent.
Co-toxicity coefficient (CTC)=[mixture surveys toxicity index (ATI)/mixture theoretical toxicity index (TTI)] × 100.
The criteria for classifying is acted on according to NY/T11547.7-2006 insecticide combinations：Co-toxicity coefficient (CTC) >=120 shows as
Synergistic effect；Co-toxicity coefficient (CTC)≤80 shows as antagonism；80 ＜ co-toxicity coefficients (CTC) ＜ 120 show as being added and make
With.
The Toxicity Determination result of table 3, fluorine thiazole pyrrole ethyl ketone and the gloomy copper of thiophene to apple drop point defoliation pathogen
| Medicament title and proportioning (weight ratio) | EC50(mg/L) | ATI | TTI | CTC |
| Fluorine thiazole pyrrole ethyl ketone | 5.31 | 100.00 | -- | -- |
| The gloomy copper of thiophene | 22.59 | 23.51 | -- | -- |
| Fluorine thiazole pyrrole ethyl ketone：The gloomy copper (1 of thiophene:1) | 5.31 | 100.00 | 61.75 | 161.9 |
| Fluorine thiazole pyrrole ethyl ketone：The gloomy copper (1 of thiophene:10) | 10.37 | 51.21 | 30.46 | 168.1 |
| Fluorine thiazole pyrrole ethyl ketone：The gloomy copper (1 of thiophene:12) | 10.64 | 49.91 | 29.39 | 169.8 |
| Fluorine thiazole pyrrole ethyl ketone：The gloomy copper (1 of thiophene:14) | 10.83 | 49.03 | 28.61 | 171.4 |
| Fluorine thiazole pyrrole ethyl ketone：The gloomy copper (1 of thiophene:16) | 10.79 | 49.21 | 28.01 | 175.7 |
| Fluorine thiazole pyrrole ethyl ketone：The gloomy copper (1 of thiophene:18) | 10.27 | 51.70 | 27.53 | 187.8 |
| Fluorine thiazole pyrrole ethyl ketone：The gloomy copper (1 of thiophene:20) | 10.19 | 52.11 | 27.15 | 191.9 |
| Fluorine thiazole pyrrole ethyl ketone：The gloomy copper (1 of thiophene:30) | 12.84 | 41.36 | 25.97 | 159.2 |
| Fluorine thiazole pyrrole ethyl ketone：The gloomy copper (1 of thiophene:40) | 13.71 | 38.73 | 25.37 | 152.7 |
| Fluorine thiazole pyrrole ethyl ketone：The gloomy copper (1 of thiophene:50) | 14.53 | 36.55 | 25.01 | 146.1 |
| Fluorine thiazole pyrrole ethyl ketone：The gloomy copper (1 of thiophene:60) | 15.72 | 33.78 | 24.76 | 136.4 |
From table 3 it can be seen that fluorine thiazole pyrrole ethyl ketone and nonylphenolsulfonate copper combination ratio 1~1 (by weight):60 co-toxicity coefficients
(CTC) 120 are all higher than, synergistic function is shown to apple drop point defoliation pathogen, especially 1:10~1:20
In the range of, particularly 1:20, synergistic function is more notable.It can be seen that, fluorine thiazole pyrrole ethyl ketone and nonylphenolsulfonate copper compounding have rationally
Property and feasibility.
In sum, a kind of bactericidal composition containing fluorine thiazole pyrrole ethyl ketone that the present invention is provided, synergistic function shows
Write, compared with existing unitary agent, the effect of disease is significantly improved on preventing and treating crops, to Crop securify, is worth in agriculture
The upper popularization and application of industry production.
Claims (8)
1. a kind of bactericidal composition containing fluorine thiazole pyrrole ethyl ketone, it is characterised in that including two kinds of active ingredients：Effective constituents A
With active ingredient B, selected from fluorine thiazole pyrrole ethyl ketone, active ingredient B is selected from Thiodiazole-copper, nonylphenolsulfonate copper, the gloomy copper of thiophene for effective constituents A
Kind, the weight ratio of effective constituents A and B is 1:1~1:60.
2. a kind of bactericidal composition containing fluorine thiazole pyrrole ethyl ketone according to claim 1, it is characterised in that：Active ingredient
A and B gross weight percentage composition in the composition are 2%~80%.
3. a kind of bactericidal composition containing fluorine thiazole pyrrole ethyl ketone according to claim 1, it is characterised in that：Active ingredient
A and B gross weight percentage composition in the composition are 21%.
4. a kind of bactericidal composition containing fluorine thiazole pyrrole ethyl ketone according to claim 1, it is characterised in that：Active ingredient
The weight ratio of A and B is 1:10~30.
5. a kind of bactericidal composition containing fluorine thiazole pyrrole ethyl ketone according to claim 1, it is characterised in that：Active ingredient
The weight ratio of A and B is 1:20.
6. a kind of bactericidal composition containing fluorine thiazole pyrrole ethyl ketone according to claim 1, it is characterised in that：Composition
Formulation is microcapsule suspending agent, suspending agent, dispersible oil-suspending agent, the one kind in water dispersible granules, wettable powder.
7. application of a kind of bactericidal composition containing fluorine thiazole pyrrole ethyl ketone described in claim 1 in preventing and treating corps diseases.
8. a kind of bactericidal composition containing fluorine thiazole pyrrole ethyl ketone according to claim 7, it is characterised in that：Described agriculture
Crop disease is tomato late blight, cucumber downy mildew, target, eggplant bacterial wilt, grapevine anthracnose, Peronophythora Litchii
Disease, alternaria leaf spot of apple, watermelon grafting, celery cabbage clubroot, watermelon grafting, watermelon anthrax, peanut sclerotium rolfsii, banyan
Tree canker.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710051892.1A CN106719710A (en) | 2017-01-20 | 2017-01-20 | A kind of bactericidal composition containing fluorine thiazole pyrrole ethyl ketone |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710051892.1A CN106719710A (en) | 2017-01-20 | 2017-01-20 | A kind of bactericidal composition containing fluorine thiazole pyrrole ethyl ketone |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106719710A true CN106719710A (en) | 2017-05-31 |
Family
ID=58941475
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710051892.1A Withdrawn CN106719710A (en) | 2017-01-20 | 2017-01-20 | A kind of bactericidal composition containing fluorine thiazole pyrrole ethyl ketone |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106719710A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107950543A (en) * | 2017-12-10 | 2018-04-24 | 广东中迅农科股份有限公司 | A kind of bactericidal composition containing benziothiazolinone and fluorine thiazole pyrrole ethyl ketone |
| CN108142424A (en) * | 2018-02-11 | 2018-06-12 | 河北省农林科学院植物保护研究所 | The bactericidal composition of a kind of fluorine thiazole pyrrole ethyl ketone and fludioxonil and preparation and its application |
| CN108294047A (en) * | 2018-02-02 | 2018-07-20 | 深圳诺普信农化股份有限公司 | A kind of bactericidal composition containing fluorine thiazole pyrrole ethyl ketone and its application |
| CN108719308A (en) * | 2018-08-19 | 2018-11-02 | 安徽嘉联生物科技有限公司 | A kind of bactericidal composition of fluorine-containing thiazole pyrrole ethyl ketone and tiger glue adipic acid copper |
| CN109418277A (en) * | 2017-08-21 | 2019-03-05 | 浙江新农化工股份有限公司 | Composition and its preparation and application containing zinc thiazole and fluorine thiazole pyrrole ethyl ketone |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105961406A (en) * | 2016-08-03 | 2016-09-28 | 田文华 | Pesticide composition containing oxathiapiprolin and quinoline copper |
-
2017
- 2017-01-20 CN CN201710051892.1A patent/CN106719710A/en not_active Withdrawn
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105961406A (en) * | 2016-08-03 | 2016-09-28 | 田文华 | Pesticide composition containing oxathiapiprolin and quinoline copper |
Non-Patent Citations (1)
| Title |
|---|
| 无: "杜邦新一代卵菌纲病害杀菌剂上市", 《西北园艺(蔬菜)》 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109418277A (en) * | 2017-08-21 | 2019-03-05 | 浙江新农化工股份有限公司 | Composition and its preparation and application containing zinc thiazole and fluorine thiazole pyrrole ethyl ketone |
| CN107950543A (en) * | 2017-12-10 | 2018-04-24 | 广东中迅农科股份有限公司 | A kind of bactericidal composition containing benziothiazolinone and fluorine thiazole pyrrole ethyl ketone |
| CN108294047A (en) * | 2018-02-02 | 2018-07-20 | 深圳诺普信农化股份有限公司 | A kind of bactericidal composition containing fluorine thiazole pyrrole ethyl ketone and its application |
| CN108142424A (en) * | 2018-02-11 | 2018-06-12 | 河北省农林科学院植物保护研究所 | The bactericidal composition of a kind of fluorine thiazole pyrrole ethyl ketone and fludioxonil and preparation and its application |
| CN108719308A (en) * | 2018-08-19 | 2018-11-02 | 安徽嘉联生物科技有限公司 | A kind of bactericidal composition of fluorine-containing thiazole pyrrole ethyl ketone and tiger glue adipic acid copper |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106719710A (en) | A kind of bactericidal composition containing fluorine thiazole pyrrole ethyl ketone | |
| CN101595882B (en) | Pesticide composition containing methoxyl acrylic ester bactericide | |
| CN101690483B (en) | Bactericidal composition containing triazole class compounds | |
| CN101690480B (en) | Pesticide composition containing methoxy acrylic bactericide and application thereof | |
| CN103125505B (en) | Dispersible oil suspending agent containing florasulam and MCPA-isooctyl | |
| CN101647441B (en) | Sterilization combination containing azoxystrobin and application thereof | |
| CN106614599A (en) | Bactericidal composition containing quinoline copper and kasugamycin | |
| CN102630679A (en) | Pesticide composition containing orysastrobin | |
| CN101810181A (en) | Sterilizing pesticide combination, preparation method and application thereof | |
| CN101911940A (en) | Germicide compounded from azoxystrobin, difenoconazole and cyproconazole and preparation method thereof | |
| CN104115861B (en) | A kind of insecticide acaricide composition containing sulfur-phosphor and cyflumetofen | |
| CN106561698A (en) | Sterilization composition containing fenhexamid | |
| CN101779645A (en) | Azoxystrobin composite and application thereof | |
| CN101617671B (en) | Combination sterilization composition | |
| CN101617658B (en) | Combination sterilization composition | |
| CN105230642A (en) | Bactericidal composition containing isopyrazam and application thereof | |
| CN101669495A (en) | Bactericidal composition containing kresoxim-methyl phenylate | |
| CN108477189A (en) | A kind of composition pesticide containing tetramycin and isotianil | |
| CN104542611A (en) | Bactericidal composition containing mandipropamid | |
| CN104872154B (en) | Bactericidal composition containing amisulbrom and antibiotic compound | |
| CN103027075A (en) | Fungicide composition containing sulphur | |
| CN105076179B (en) | A kind of composition pesticide containing rosickyite azoles and iprodione | |
| CN104604904B (en) | A kind of containing difenodiconazole with the bactericidal composition of Mancozeb | |
| CN106719705A (en) | A kind of composition containing fenhexamid, benziothiazolinone | |
| CN107467038A (en) | A kind of bactericidal composition containing isotianil and Zhongshengmycin |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20170531 |
|
| WW01 | Invention patent application withdrawn after publication |