CN106711378B - The continuous lamination production line of three diaphragms for lithium battery manufacture - Google Patents
The continuous lamination production line of three diaphragms for lithium battery manufacture Download PDFInfo
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- CN106711378B CN106711378B CN201611109105.6A CN201611109105A CN106711378B CN 106711378 B CN106711378 B CN 106711378B CN 201611109105 A CN201611109105 A CN 201611109105A CN 106711378 B CN106711378 B CN 106711378B
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- diaphragm
- negative electrode
- releasing
- electrode tab
- positive plate
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/005—Devices for making primary cells
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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- Chemical Kinetics & Catalysis (AREA)
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- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Secondary Cells (AREA)
Abstract
The invention discloses a kind of continuous lamination production lines of three diaphragms for lithium battery manufacture, it includes belt-type dragger, and set gradually from front to back along belt-type dragger: the first diaphragm machine for releasing, first positive plate discharges manipulator, second diaphragm machine for releasing, the second diaphragm machine for releasing are identical as the first diaphragm machine for releasing;First negative electrode tab discharges manipulator, and the first negative electrode tab release manipulator is identical as the first positive plate robot manipulator structure, for discharging negative electrode tab;Third diaphragm machine for releasing, the third diaphragm machine for releasing are identical as the second diaphragm machine for releasing;Heat-sealing machine, counter, cutting device, the severing for diaphragm;Folding device, the second positive plate discharges manipulator, and arranges platform, the arrangement for lamination.Lamination high degree of automation of the present invention, whole process are all automatically performed by machine, are not necessarily to human intervention, improve the automatic level of production, and efficiency improves.
Description
Technical field
The invention is related to lithium battery lamination production technical field, specifically a kind of continuous lamination production line of three diaphragms.
Background technique
Soft pack cell (also known as " polymer battery core "), is widely present in some small digital products.
The structure of current soft pack cell includes laminated structure and two kinds of wound form structure.
It is to form positive plate, diaphragm, negative electrode tab composition superposition, septation is disconnected in common laminated structure
It opens, the lamination of this structure, diaphragm is usually cut into the thin slice slightly larger than pole piece, is then successively superimposed,
There are problems that lithium ion in the surrounding of diaphragm around diaphragm, is affected to the charge-discharge performance of battery core.
In common wound form structure, positive plate, diaphragm and negative electrode tab be continuous strip, three superposition, then around
One center is wound, and forms a flat structure, the canoe of this structure, there are reel stress, prolonged applications
In the process, it may appear that arch camber, buckling phenomena, the generation of this phenomenon are due to the tensioning between winding layer each in winding process
Caused by dynamics is inconsistent.
All there is certain technical advantage and technological deficiency in both the above mode, idea of the invention is that providing one kind more
Add outstanding scheme.
Summary of the invention
In order to solve the deficiencies in the prior art, the present invention provides a kind of three diaphragms continuous lamination production line, is used for rectangular lithium
The lamination of battery makes, and provides a kind of manufacture craft of new way, more convenient, more efficient, effect is more preferable, and soft
The isolation effect of packet lithium cell, puncture-resistant effect are more preferable.
The technical solution adopted by the present invention to solve the technical problems are as follows:
The continuous lamination production line of three diaphragms for lithium battery manufacture, which is characterized in that including belt-type dragger, and
It is set gradually from front to back along belt-type dragger:
First diaphragm machine for releasing,
Let off roll, idler roller and nip rolls are provided in the first diaphragm machine for releasing, wherein the let off roll is electronic
Traction roller,
First positive plate discharges manipulator,
It includes rotating disk and fixed disk that first positive plate, which discharges mechanical hand, and the rotate the outside of the disc of eight prism-shapeds is eight
Sucker is provided with a rectangular recess in each sucker, and four corners in groove are provided with gas nozzle, and in rotating disk
It is internally provided with the gas circuit with gas nozzle perforation, gas circuit is attached by fixed disk and positive and negative gas source, the side of the rotating disk
Gas circuit port, each gas circuit are correspondingly arranged with fixed disk one by one for setting, and a negative pressure gas circuit is provided in the fixed disk,
Negative pressure gas circuit is slidably matched by branch gas circuit and the gas circuit port of top and front side in the rotating disk, in fixation
A positive pressure gas circuit is provided on disk, positive pressure gas circuit is slidably matched with the gas circuit port below rotating disk, passes through positive pressure gas
Road controls the absorption gas nozzle in underlying groove;The rotating disk is mounted in a shaft, and wherein shaft is in driving electricity
Machine is rotated by,
Second diaphragm machine for releasing, the second diaphragm machine for releasing are identical as the first diaphragm machine for releasing;
Incude the sensor of positive plate position, is located at after the second diaphragm machine for releasing;
First negative electrode tab discharges manipulator, and the first negative electrode tab release manipulator is identical as the first positive plate robot manipulator structure,
For discharging negative electrode tab;
Third diaphragm machine for releasing, the third diaphragm machine for releasing are identical as the second diaphragm machine for releasing;
Heat-sealing machine,
The heat-sealing machine includes cutter, quadrilateral connecting rod mechanism and the first cylinder, wherein cutter is a rectangle frame, heat
It shares the cutter to be fixed in a heat seal frame, there is electrical heating elements, installation one on the upside of the heat seal frame in heat seal frame
One end of parallelogram linkage, parallelogram linkage extends outwardly and hinged with rack, and described
First cylinder is installed between parallelogram mechanism and rack;
Counter,
Cutting device, the severing for diaphragm;
Folding device, the folding machine include riser, connecting rod and electric linear push rod, wherein riser lower end is articulated in folding
On stacking device, the middle part of the riser connects connecting rod by hinged mode respectively with top, and electric linear push rod drives riser
It swings;
Second positive plate discharges manipulator, and it includes cabinet, bottom plate, raising plate, jack that the positive plate, which discharges mechanical hand,
Structure and ejecting mechanism, wherein the cabinet is rectangular ceramic case, and in the longitudinal direction, the length of the cabinets cavity is less than negative
2 millimeters of pole piece length, equal in width direction, after negative electrode tab is put into, negative electrode tab (B) is micro- with one in the longitudinal direction
The trend of microprotrusion,
In cabinet upper end, open-mouth is provided with a pair of of card slot, and two card slots are oppositely arranged and are fixed on the upper edge of cabinet
Place, the two sides negative electrode tab (B) are free to slide along card slot;
In the upper end of cabinet, one top plate is set, the lower surface of the top plate be the arcwall face being recessed upwards, and radian and
The radian of raising plate is identical,
It is provided with the first notch avoided to the electrode outlet in negative electrode tab in a wherein card slot, while
The second notch avoided to positive electrode extension is provided on cabinet;
The raising plate is arc panel, the upper surface of arc panel is provided with soft copper layer, downside is guide post, guide post two
Side setting is with teeth;
One bottom plate is installed at the lower open mouth of cabinet by way of articulated connection, bottom plate can open and close, open state
Under, negative electrode tab (B) is filled to box house, under closed state, the jacking for positive plate;It is arranged in the centre position of bottom plate
Have a circular hole, the guide post passes through circular hole, another symmetrically arranged gear is installed on the downside of bottom plate, the gear with
Tooth in guide post is engaged, and two gears pass through a pair of oppositely arranged angular wheel respectively and driven by first servo motor
It is dynamic;
On front side of cabinet card slot and rear side is respectively arranged with first guide plate and the second guide plate, second guiding
Ejecting mechanism is installed, wherein ejecting mechanism includes cylinder, head board and connection frame on plate, wherein the head board be thickness with
The equal alloy sheets of negative electrode tab or ceramic wafer, the release front edge of board are inserted into card slot, and rear end passes through connection frame and cylinder
Piston be attached, cylinder push head board move back and forth;
Second negative electrode tab discharges manipulator and the mechanical palmistry of the second positive plate release is same, in the front and rear sides of folding device point
Not She Zhi second negative electrode tab discharge manipulator and the second positive plate discharges manipulator, to folding position filling negative electrode tab and just
Pole piece;
With arrange platform, arrangement for lamination.
The belt-type dragger includes upper traction roller and lower traction belts, and annular lower traction belts are in power motor
It can be moved under driving, and the end of upper traction roller and lower traction belts carries out contact and drives diaphragm along belt direction of travel
Advance.
It is additionally provided between negative electrode tab release manipulator and third diaphragm machine for releasing whole to the progress of positive plate spacing
The electronic partition of reason.
The electronic partition includes partition and control motor, guide post, the thickness setting of the partition in the electronic partition
It is 2 millimeters, the partition, which has in the case where controlling motor driven along guide post, to be moved up and down.
The beneficial effects of the present invention are:
1, lamination high degree of automation, whole process are all automatically performed by machine, are not necessarily to human intervention, are improved production
Automatic level, efficiency improve.
2, due to using Z-fold mode, reel stress, good product consistency, the operation mode of pipeline system is not present
It is better than traditional lamination process consistency.
3, high-efficient, the release of whole process diaphragm, positive plate release, heat seal, negative electrode tab release, by once, efficiency mentions
It is high by 50%.
4, using dedicated pole piece machine for releasing tool hand, positive and negative plate rate of release is fast, and not damaged, can satisfy actual
It needs.
Detailed description of the invention
Fig. 1 is lamination effect picture.
Fig. 2 is monolithic positive plate (negative electrode tab) perspective view.
Fig. 3 is lamination schematic diagram.
Fig. 4 is one of lamination process.
Fig. 5 is lamination manufacturing process simulation drawing.
Fig. 6 is lamination production-line arrangement figure.
Fig. 7 is membrane unwinding roll end schematic diagram.
Fig. 8 is the perspective view that the first positive plate discharges rotating disk in manipulator.
Fig. 9 is that the first positive plate discharges manipulator partial sectional view.
Figure 10 is the perspective view of heat device.
Figure 11 is the perspective view of Scissoring device.
Figure 12 is the main view of Scissoring device.
Figure 13 is the perspective view of folding machine.
Figure 14 is the perspective view 1 of continous way pole piece release device.
Figure 15 is the perspective view 2 of continous way pole piece release device.
Figure 16 is the perspective view 3 of continous way pole piece release device.
Figure 17 is the cross-sectional view of continous way pole piece release device.
Figure 18 is the working principle diagram of continous way pole piece release device.
Figure 19 is that storage arranges platform schematic diagram.
Figure 20 is lamination process flow chart.
Figure 21 is the schematic diagram of zero air fliud flushing device of electrolyte.
Figure 22 is the structure chart that soft-package battery accommodates and shakes mechanism.
Figure 23 is soft-package battery cored structure schematic diagram.
In figure: 1 diaphragm release part, 11 first diaphragm machine for releasing, 111 let off roll, 1111 nylon jackets, 113 nip rolls, 12
Second diaphragm machine for releasing, 11 ' first diaphragms, 12 ' second diaphragms, 13 third diaphragm machine for releasing, 13 ' third diaphragms, 2 first anodes
Piece release manipulator, 2 ' second positive plates release manipulator, 3 heat sealed portions, 31 cutters, 32 quadrilateral connecting rod mechanisms, 33 first
Cylinder, 34 heat seal frames, 35 hinge joints, 4 first negative electrode tabs discharge manipulator, and 4 ' second negative electrode tabs discharge manipulator, 5 arrangement portions
Point, 6 reduce part, 61 gantry type frames, 62 cut-off knives, 63 second cylinders, 64 counters, 65 sheet metals, 66 sheet rubbers, 67 knives
Slot, 71 lower traction belts, traction roller on 711,72 electronic partitions, 73 folding machines, 731 risers, 732 connecting rods, 733 electric linears push away
Bar, 8 storages arrange platform, 81 supporting plates, 82 elevating mechanisms, 83 assistant cylinders, 84 finishing plates, 91 cabinets, 911 card slots, 912 tops
Plate, 913 first notches, 913 ' second notches, 92 bottom plates, 921 gears, 923 angular wheels, 922 first servo motors, 93 jackings
Plate, 94 lifting bodies, 95 ejecting mechanisms, 951 cylinders, 952 head boards, 953 connection frames, 901 first guide plates, 902 second lead
To plate, 101 electric pumps, 102 electrolyte storage tanks, 103 filters, the aid of 104 soft-package batteries and concussion mechanism, 1041 vibrations are flat
Platform, 1042 left and right reciprocal aid plates, 1043 rocker arms, 1,044 first eccentric wheels, 1045 Damper Braces bars, 1046 mandrils, 1,047
Two eccentric wheels, 100 Soft Rolls.
Specific embodiment
Due to the difference of each manufacturer's production technology, polymer lithium electricity currently on the market is divided into takeup type (Sony, Toshiba
To represent), stacked (TCL, ATL are representative) two kinds of different structures.
Existing laminating machine and lamination principle are all layer-by-layer disks, that is, use a continuous diaphragm, diaphragm is used folded
Piece machine carries out Z-shaped bending, and positive plate and being implanted in diaphragm interlayer for negative electrode tab interval are formed lamination, and this mode works
Although inefficiency, the degree of automation can be improved, but be still difficult to meet efficient production.
Common mentality of designing is to improve the feeding efficiency of diaphragm, that is, using continuous, high speed continuous film feeding, is mentioned
High production capacity.
But traditional method is defective, problem is, after film feeding speed reaches 1 meter per second, since diaphragm has
Certain elasticity, high-speed coiling certainly exist restoring force in the process, cause stress, that is, the lamination after winding, electrode can be wrapped up in
Tightly, buckling phenomena is caused.
For existing defect, protection theme of the invention is as follows:
Exploitation is a kind of soft pack cell and the continuous lamination production line of three diaphragms, and theoretically, efficiency raising should be list
Four times or more of the layer continuous lamination of diaphragm.
Exploitation is a kind of Soft Roll shell lithium cell, positive plate and the completely isolated encapsulation of negative electrode tab, and in metal shell
The cushion space of insulating coating and foam material is arranged in surface, improves encapsulation quality.
Be introduced below by its manufacture craft, referring to figs. 1 to Figure 20, basic principle is, using three layers every
The mode that film is superimposed simultaneously, positive plate therein is superimposed in advance between first, second layer of diaphragm, is then again folded negative electrode tab
Close between second and third layer diaphragm, and positive/negative plate overlaps each other, and is only staggered at tab position, then by heat seal into
The preliminary encapsulation of row, is then folded over, is implanted into a negative electrode tab and positive plate again in folding process, forms compound lamination effect
Fruit will form lamination after arrangement, the lamination of formation is packaged with metal shell again, welding electrode.Due to before folding
Preliminary compound, 3 times of folding efficiency raising or more is carried out, and since diaphragm does not have the pretightning force of tensioner, quality is more preferable.
While folding, heat sealing can be carried out to the diaphragm overlapped for the first time and be mentioned so that positive/negative plate is isolated from each other
High isolation effect between the two.
It is directed to the lamination speed of high speed simultaneously, traditional sucking disc type mechanical hand can not adapt to quick, continuous positive plate
Or the supply of negative electrode tab, the carrying part of electrode slice is redesigned, to achieve the purpose that global optimization.
It is provided by the invention that a kind of secondary lithium cell automatic laminating production line is provided based on the description above: such as Fig. 1 to figure
Shown in 20,
Manipulator 4, heat seal portion are discharged including diaphragm release part 1, the first positive plate release manipulator 2, the first negative electrode tab
Divide the 3, second positive plate release manipulator 2 ', the second negative electrode tab release manipulator 4 ', finishing part 5, reduce part 6 and delivery section
Point.
Diaphragm discharges part 1 and includes the first diaphragm machine for releasing 11, the second diaphragm machine for releasing 12, third diaphragm machine for releasing 13,
The effect of diaphragm release part be with one after another rational sequence and speed coiled diaphragm discharged, flattened, tiled.
Let off roll 111, idler roller 112 and nip rolls 113 wherein are provided in the first diaphragm machine for releasing 11, wherein are unreeled
Roller be electric traction roller, by motor traction realize slowly unreel, idler roller for diaphragm tensioning, and avoid it is fully relaxed,
Nip rolls guarantees that diaphragm is in flat, and third, the second diaphragm machine for releasing are identical as the first diaphragm machine for releasing.
Wherein the first diaphragm machine for releasing 11 first discharges the first diaphragm 11 ', after tiling, then discharges positive plate, then discharges
Two diaphragms 12 ', positive plate A is encapsulated between two layers of diaphragm, and is positioned, and heat seal is finally carried out, and is formed intermittent, uniform
Spaced positive plate, the spacing between two of them positive plate are arranged at 2 millimeters or so, which is to pass through
What electronic partition was realized.
Membrane unwinding roller 111, which uses, determines torque buffer technology, that is, the driving motor of let off roll 111 is servo digitalization electricity
Machine can carry out Digital Control, buffered between let off roll 111 and motor power axis using determining moment device, determine power
Moment device structure includes: inside and outside two be nested with nylon jacket 1111, determines torque by the damping force realization between setting nylon jacket
Transmission, under normal circumstances, keeps friction law between nylon jacket, opposing stationary, when driving torque is more than setting torque, realizes
It skids, prevents from being excessively driven and excessively be torn caused by diaphragm, with reference to Fig. 7.
Idler roller is using flexible tensioner technology, that is, idler roller is a composite roll, and intermediate mandrel is steel shaft, outside steel shaft
Surface is set as rubber material, and mandrel both ends are mounted on the rack by bearing.
As a kind of replaceable scheme, above-mentioned idler roller is the composition of flexible axle and rubber sleeve, and in the appearance of flexible axle
Face covers rubber sleeve, wherein diaphragm is unclamped by rotating at R2 meters, prevent tension by the curvature control of idler roller.It is installing
In the process, flexible axle keeps both ends to keep certain angle.
Further, above-mentioned idler roller uses eccentric structure, that is, the idler roller sheet is as an eccentric rollers, partially
Rate control realizes the purpose of relaxation by eccentric transfer regularity at 1 centimetre, wherein installs a tooth in one end of idler roller
Wheel, gear is directly driven by a motor, and the electrode at this place is run with the movement of pulsed, and idler roller is driven intermittent to open with one
Stop shake movement, achievees the purpose that uncoiling, with reference to Fig. 8.
After uncoiling, the first diaphragm 11 ' being laid in lower traction belts is in free flat, and there is no rebounds
Stress.
Nip rolls 113 is super smooth roll, and roller surface fineness therein reaches R1.6 (roughness), and diameter is not less than 1 meter,
Realize that cladding angle is not less than 90 degree, for smoothly turning to for diaphragm.
Second diaphragm machine for releasing 12 is identical as the first diaphragm machine for releasing, is used for the release of the second diaphragm 12 ', one in front and one in back cloth
It sets, the first positive plate is set in the middle position of two diaphragm relieving mechanisms and discharges manipulator 2 and pneumatic barrier.
First positive plate discharges manipulator 2 using structure described in Fig. 8, and main body is the rotating disk 21 of an octahedral shape,
It is eight suckers 22 on eight faces of rotating disk, a groove 23 is provided in each sucker, groove 23 is rectangle, recessed
Four corners in slot are provided with gas nozzle 24, and are internally provided with gas circuit 25 in rotating disk 21, gas circuit by fixed disk with just,
Angrily source is attached, and forms a kind of gas circuit conversion air valve, when being connect with positive pressure gas source, generation blowing force at above-mentioned sucker,
For discharging pole piece therein.When connecting with negative pressure gas source, above-mentioned sucker generates adsorption capacity, for grabbing positive plate.
Above-mentioned conversion air valve structure refers to Fig. 9, and 16 gas circuit ports are arranged in the side of above-mentioned rotating disk, each
A gas circuit is correspondingly arranged with fixed disk 26, is provided with a negative pressure gas circuit 261 in fixed disk, negative pressure gas circuit by branch gas circuit with
The gas circuit port of top and front side in above-mentioned rotating disk is slidably matched, and is located above by the control of negative pressure gas circuit,
Absorption gas nozzle in the groove in front and front side orientation.
A positive pressure gas circuit 262 is provided in fixed disk 26, the gas circuit port below positive pressure gas circuit and rotating disk carries out
It is slidably matched, by positive pressure gas circuit control bit in the absorption gas nozzle in the groove of lower section.
The edge of groove is provided with an electrode evacuation notch 231, the electrode of two adjacent suckers avoids notch
Between about boundary be symmetrical arranged, the positive plate placed in two adjacent grooves is symmetrically arranged.
Above-mentioned rotating disk 21 is mounted in a shaft, wherein shaft being rotated by driving motor,
Third diaphragm machine for releasing 13 is identical as the second diaphragm machine for releasing, is used for the release of third diaphragm 13 ', one in front and one in back cloth
It sets, the first negative electrode tab is set in the middle position of two diaphragm relieving mechanisms and discharges manipulator, the first negative electrode tab discharges manipulator
It is identical as the first positive plate robot manipulator structure, for discharging negative electrode tab.
First negative electrode tab discharges manipulator 4, which discharges manipulator and discharge 2 phase of manipulator with the first positive plate
Together, the difference is that internal place is negative electrode tab.Negative electrode tab a positive and a negative in the first negative electrode tab release manipulator cabinet
It is staggeredly placed.
Negative electrode tab release position lower traction belts 71 above be arranged an Electronic control electronic partition 72, it is electronic every
Plate includes partition and control motor, guide post, and the thickness of the partition in electronic partition is set as 2 millimeters, there is no obtuse angle structure,
Partition is fastened between two adjacent pole pieces, so that (positive and negative) pole piece forms spacing positioning, guarantees that the spacing of two pole pieces is equal
It is even consistent.Electronic partition 72 has up and down action process, and specific structure can refer to cut-off knife mechanism, is planer type structure, will wherein
Cutter change certain thickness partition into, details are not described herein again.
Specifically used method is, positive plate in place after, diaphragm pause first falls in partition on the second diaphragm, and will under
The positive plate of side is kept apart, and then close to partition and is placed on negative electrode tab on the second diaphragm, and after the completion, partition lifts, every
Film continuation is run backward.
Heat sealed portion 3 is set on rear side of third diaphragm machine for releasing 13, and heat sealed portion 3 is the heat seal of electric heating heat seal mode
Machine, the heat-sealing machine include cutter 31, quadrilateral connecting rod mechanism 32 and the first cylinder 33, wherein and cutter 31 is a rectangle frame, on
It states heat seal to be fixed in a heat seal frame 34 with cutter, there are electrical heating elements in heat seal frame, cutter can be heated to 200 and taken the photograph
Family name's degree, it is sufficient to diaphragm be formed into partial melting, heat seal is formed, install a parallelogram linkage on the upside of heat seal frame 34
32, an end of parallelogram linkage extends outwardly and, i.e. hinge joint 35 in Fig. 9 hinged with rack, this is parallel
Quadrangular mechanism has a movement waved under the action of the first cylinder 33, and during waving, heat seal frame 34 is always
In horizontality.
Heat seal cutter carries out heat seal simultaneously to two adjacent three-layer membranes simultaneously, so that positive and negative plate is fixed, heat seal
The structure chart of mechanism is with reference to shown in Fig. 9 and Figure 10.
Heat seal frame can use the structure with buffer technology, and buffer spring is inlaid in heat seal frame in sight, realize automatic
Buffering.
After heat seal, the diaphragm strip C that inner clamps hold positive plate is formed, diaphragm strip C refers to, is pressed from both sides by continuous three-layer membrane
Positive and negative plate composition is held, wherein positive plate is equidistantly uniformly arranged, and the negative electrode tab on top, lower part are positive plate, shape
At several continuous laminations.
It is belt-type dragger in the downside of heat seal cutter, diaphragm machine for releasing, above-mentioned belt-type dragger includes above leading
Pick-up roll 711 and lower traction belts 71, lower traction belts can be moved under the driving of power motor, drive the diaphragm of top
It is moved, with reference to Fig. 6.
Upper traction roller 711 is driven using stepper motor, and upper traction roller surface is rubber cladding, and is set on the surface of rubber rollers
It is equipped with decorative pattern, improves traction dynamics.
It is provided on rear side of pull roll assembly and cuts part 6, which is pneumatic type Scissoring device, which includes
Cut-off knife 62 is arranged in gantry type frame 61 on gantry type frame, and gantry frame can open and close up and down under the effect of the second cylinder 63,
Complete cutting movement, for example, each battery core is made of 50 positive/negative plates, then each 50 pole pieces carry out severing, for
A counter 64 is arranged in the front side of Scissoring device or rear side in total number, and the preferred magnetic strength counter of counter passes through induction
The quantity of pole piece counts, for controlling the thickness of lamination.
It is cut for cooperation cut-off knife, a cutter groove 67 is provided on the platform immediately below cut-off knife, flexible rubber mat is placed in cutter groove,
It improves and cuts uniformity, and protect cut-off knife.
A sheet metal 65 is provided on rear side of Scissoring device, the rear side of sheet metal is bonded a sheet rubber 66 flexible,
Sheet rubber 66 is in hang under self-acting, and sagging length is the half of pole piece width, with reference to Figure 11 and Figure 12.
A storage, which is placed with, in the end of the belt-type dragger of the side-lower position of 66 rear side of sheet rubber arranges platform
8, storage arranges platform and has function of auto-lift, including supporting plate 81, elevating mechanism 82, detection switch, wherein elevating mechanism position
In the downside of supporting plate 81, for the raising and lowering of supporting plate 81, detection switch is used to detect the quantity of the diaphragm strip on supporting plate, and
Control system is fed back to, for controlling the decline of supporting plate, often falls next lamination, supporting plate declines the height of a lamination thickness automatically
Degree, gradually declines.It is respectively arranged with a baffle in the left and right sides of supporting plate 81, baffle is for limiting lamination in left and right orientation
Position, since lamination is continuously, so slightly being limited in the lateral direction.
8 front and rear sides of platform are arranged in storage and are provided with an assistant cylinder 83, install one on the piston rod of assistant cylinder
A finishing plate 84 being vertically arranged, when lamination in place after, by the reciprocal vibration of two assistant cylinders, to diaphragm lamination from front and back
Two sides carry out concussion arrangement, improve neat degree, wherein assistant cylinder from vibration frequency control on 50 left sides per minute
It is right.
In the front and rear sides that storage arranges platform, one the second negative electrode tab release manipulator 4 and the second positive plate are respectively set
Manipulator is discharged, after above-mentioned special-purpose machinery, robot manipulator structure is discharged to close to mode separation strapping positive plate by the first negative electrode tab
Negative electrode tab is inserted at the folding of side, and manipulator is discharged by positive plate and is inserted at the folding of mode separation strapping negative electrode tab side
Negative electrode tab adsorbs a piece of pole piece every time, realizes operating and filling.
Second negative electrode tab release manipulator 4 ' is identical as the second positive plate release manipulator 2 ', two before and after folding device
The second negative electrode tab release manipulator and the second positive plate release manipulator is respectively set in side, inserts negative electrode tab to position is folded
And positive plate;
Second positive plate discharges manipulator 2 ', carries a positive plate A every time, and positive plate A is placed on the first diaphragm
On 11 ', the right setting intersected with each other of above-mentioned one the first from left of positive plate, wherein left positive plate is different with the position of right positive plate, one just
One anti-placement realizes the folded symmetrical of positive plate, with reference to Fig. 4 convenient for the extraction of anode ear A1.Traditional sucked type is mechanical
There are two problems for hand tool, and first problem is that transporting velocity is slow, need to inhale, carry, three movements of release, pneumatic system is needed to match
It closes, it is difficult to it quickly finishes, Second Problem is, due to the very thin thickness of positive plate, generally 0.1 millimeter of thickness to 0.3 milli
The aluminium foil of rice, is easy to produce adhesion, once carries two panels, cause maloperation.
Second positive plate discharges manipulator 2 ', and structure includes cabinet 91, bottom plate 92, raising plate 93, lifting body 94 and pushes away
Mechanism 95 out, referring now to figs. 14 through Figure 16, wherein above-mentioned cabinet 91 is that rectangular box can be prevented using clean ceramic case
Positive plate A therein is polluted, in the longitudinal direction, the length of cabinets cavity is less than positive 2 millimeters of leaf length, width side
Equal upwards, when positive plate is put into after, positive plate A has a pico- raised trend in the longitudinal direction, with reference to Figure 18,
Since positive plate itself has certain elasticity, the screen resilience with a tensioner, after positive plate is put into, in lower part raising plate
Under the action of, positive plate raises upward.
91 upper end open-mouth of cabinet is provided with the card slot 911 of a pair of of plastic material, two card slots are oppositely arranged, are fixed on
At the upper edge of cabinet, the two sides positive plate A can be free to slide in card slot 911.
The position of card slot 911 can satisfy moving freely for a positive plate just, that is, one positive plate of conveying every time,
Due to the limitation of card slot local width, the case where being not in multi-disc.
One top plate 912 is set in the upper end of cabinet 91, the lower surface of top plate 912 is the arcwall face being recessed upwards, and arc
Degree is identical as the radian of raising plate 93, this region is the recovery region of positive plate, in this area, positive plate A expansion, after flattening
The two sides positive plate A are inserted into slot.
The first notch 913 avoided to the electrode outlet on positive plate is provided in a wherein card slot 911,
The second notch 913 ' avoided to electrode lead-out part point is provided on cabinet 91 simultaneously, for the extraction of electrode, wherein
The quantity of second notch is two, realizes that positive plate a positive and a negative in positive plate release manipulator cabinet is staggeredly placed.
Raising plate 93 is the arc panel of a metal material, and the upper surface of arc panel 93 is provided with soft copper layer, arc panel
Lower surface is provided with the reinforcing rib of a transverse direction, draws a columned guide post 931, guide post two sides on reinforcing rib downwards
It is arranged with teeth 932.
One bottom plate 92 is installed at the lower open mouth of cabinet 91 by way of articulated connection, bottom plate can open and close, opening
Under state, positive plate A, under closed state, the jacking for positive plate are filled to box house.
The centre position of bottom plate 92 is provided with a circular hole, above-mentioned guide post passes through circular hole, in the downside of bottom plate
It is provided with another symmetrically arranged gear 921, gear 921 is engaged with the tooth 932 in guide post, forms transmission.Two teeth
Wheel is driven by a pair of of angular wheel 923 by first servo motor 922 respectively.
On front side of 91 card slot of cabinet and rear side is respectively arranged with first guide plate 901 and the second guide plate 901, and first
The effect of guide plate 901 is for positive plate to be delivered at purpose, and a positive pressure is provided on the downside of the first guide plate
The air inlet of sealed gas chamber, sealed gas chamber is attached by an electromagnetic valve of gas circuit with positive pressure gas bag, and electromagnetic valve of gas circuit is passed through
With the make-up gas into sealed gas chamber, it is provided with inside and outside nozzle mounting hole in the first guide plate, in nozzle mounting hole
Nozzle is installed, nozzle is not known uniformly in the first guide plate, and the pressure control of sealed gas chamber passes through gas in 0.2 megapascal or so
Body brushes, and for balancing pole piece self weight, mitigates the frictional resistance of pole piece and the first guide plate, guarantees that pole piece quality is in excellent
Etc. ranks.
The effect of second guide plate 902 is installation ejecting mechanism 95, and wherein ejecting mechanism includes cylinder 951, head board
952 and connection frame 953, wherein head board 952 is the thickness alloy sheets or ceramic wafer equal with positive plate, release front edge of board
It is inserted into card slot 911, rear end is attached by connection frame 953 and the piston of cylinder.It is pushed and is released by the movement of cylinder
The reciprocating motion of plate.
Further, there are two extreme positions for above-mentioned head board 952 tool, and initial threshold position is located at the effective of positive plate
Other than region, final position is located at the release region of positive plate.
The negative electrode tab orientation of above-mentioned the first negative electrode tab release manipulator release is identical, and positive plate orientation is identical, so that folding
The lamination of poststack meets the requirement of positive and negative tab welding, with reference to Fig. 1.
A folding machine 73 is provided on front side of the sheet rubber below Scissoring device, folding machine 73 includes riser 731, connecting rod
732 and electric linear push rod 733, wherein 731 lower end of riser is articulated on chassis equipment, the middle part of riser 731 and top difference
Connecting rod is connected by hinged mode, parallelogram mechanism is formed, and lift to the formation of the sheet rubber on top, avoids sheet rubber
Out of control, electric linear push rod 733 directly drives riser swing, and completes the folding of mode separation strapping.When the diaphragm strip of vertical state arrives
Behind position, folding machine 73 is acted, and carries out the deflecting and folding of lamination, is realized and is folded 90 degree, while folding, realizes front and rear sides
The insertion of positive and negative plate, it is every to fold once, a positive and negative plate is inserted into from the left and right sides.
Above-mentioned folding machine can be substituted using horizontally disposed cylinder, and cylinder is fixed in equipment, then pass through cylinder
Lamination is carried out the superposition of intermittent by piston, forms lamination.
The course of work is such that
Firstly, the first diaphragm machine for releasing first discharges the first diaphragm with reference to Fig. 5, the first diaphragm after release is with naturally side
Formula is laid in lower traction belts, then the first diaphragm discharges positive plate, 2 are kept between positive plate and positive plate without expanding force
The spacing of millimeter or so, then, the second diaphragm is discharged by the second diaphragm relieving mechanism, after the second diaphragm relieving mechanism
The sensor of a detection positive plate is arranged in side, when positive plate in place after, then the pause of lower traction belts is pressed under pneumatic barrier
In interval region between two positive plates, meanwhile, negative electrode tab discharges manipulator and discharges negative electrode tab, so that pole piece between adjacent
For Separation control at 2 millimeters, the interval between 2 millimeters of the pole piece is realized by pneumatic barrier, then discharges third diaphragm,
Positive plate, negative electrode tab are encapsulated between three-layer membrane by third diaphragm without expanding force, finally carry out heat seal, and heat seal point is located at pole
The edge of piece, and avoid electrode section, forms intermittent, spaced (positive or negative) pole piece, two of them positive plate it
Between spacing be arranged at 2 millimeters or so, form fixed mode separation strapping, the pole piece in mode separation strapping is independent of one another and interval setting
, and the tab position between positive plate and negative electrode tab offsets one from another.
Then riser is swung in the form of a pulse in folding machine, every to swing a lamination mode separation strapping folding once, and
While folding, it is implanted into a negative electrode tab and a negative electrode tab simultaneously from front and rear sides, forms lamination, in lamination, anode ear
Position overlaps each other, and the position of negative electrode lug overlaps each other, finally by the shape of arrangement formation rule.
Soft-packaging lithium battery cores and its manufacture craft
The above-mentioned lamination folded is subjected to electrode welding and forms one, welding uses Pressure Welding, and it is firm to weld, then will be upper
It states and is put into after lamination is wrapped up using diaphragm in a soft bag, then carry out electrolyte injection, be finally packaged, encapsulation process
In electrode area increase electrode insulation set, formed soft-package battery.The soft-package battery has the following structure:
Positive plate and the setting of negative electrode tab interval, and it is provided with one layer of diaphragm between the two, it is formed after diaphragm heat seal, positive plate
With the electrode of negative electrode tab independently bunchy, and outside is led to, Soft Roll band is the macromolecule resin material with insulation performance.
Soft package lithium battery manufacture craft,
Step 1, it is stand-by by being coated with, cutting obtained positive plate and negative electrode tab,
Step 2, preparation width be positive plate, 1.2 times of cathode leaf length of diaphragm, for use
Above-mentioned first diaphragm is laid in the lower traction belts that one continuously moves, while positive plate being occupied by step 3
In be uniformly placed on the first diaphragm, by by hand or it is mechanical in the way of above-mentioned positive plate uniform intervals are arranged,
Compartment is away from being maintained at 2 millimeters or so, and every side reserves 2 millimeters of surplus,
Second diaphragm is uniformly covered on the first diaphragm by step 4, while negative electrode tab being uniformly placed between two parties
On second diaphragm, above-mentioned negative electrode tab and above-mentioned positive plate are overlapped in the way of manual or mechanical, and makes
The tab of positive/negative plate is staggered,
Third diaphragm is uniformly covered on the second diaphragm by step 5, and using heat seal cutter to positive and negative plate surrounding
Three-layer membrane carry out heat seal, heat seal process avoids electrode area, forms continuous mode separation strapping after heat seal, the shape in mode separation strapping
The pole piece group arranged at interval,
Above-mentioned mode separation strapping is folded according to Z-shaped mode, and inserts positive and negative plate during folding by step 5,
In above-mentioned negative electrode tab electrode superposition, the electrode superposition on positive plate forms appearance as shown in Figure 1,
Step 6 is bundled after arranging lamination using diaphragm, and formation is rectangular, and is put into a soft bag,
Soft bag is put into filling machine and carries out pressing arrangement by step 7, formation rule shape, and carries out electrolyte
It is filling,
Step 8 carries out heat seal encapsulation after static 1 to 2 hour, pass through the row of exhausting-gas hole on Soft Roll band after heat seal encapsulation
Except internal air is finally packaged gas vent by multiple continuous fliud flushing, drain, the completely air inside exclusion.
A kind of zero air charging device of electrolyte, with reference to Figure 21, which is comprised the following structure:
Electric pump 101, electrolyte storage tank 102, filter 103, soft-package battery aid and concussion mechanism 104, wherein electric pump
101 be the topping-up pump of the model E2-R20B of UBA (excellent despot) brand, and electrolyte is extracted into soft-package battery, passed through by electric pump
Filter 103 filters, and filter is double parallel constructions, with one for one, wherein soft-package battery aid includes that vibration is flat with concussion mechanism
Platform 1041, left and right reciprocal aid plate 1042, driving motor, above-mentioned shock platforms 1041 are arranged with through a rocker arm
1043, the upper end of rocker arm is mounted in the middle part of shock platforms, and lower end is mounted on first eccentric wheel 1044, meanwhile, it is shaking
Four corners of platform are provided with Damper Braces bar 1045, and Damper Braces bar refers to be stretched with telescopicing performance and elastic
Bar, above-mentioned first eccentric wheel is controlled by a driving motor, and under the rotation of the first eccentric wheel, above-mentioned shock platforms are in shake
Dynamic state.
Rotary cylinder simultaneously operation at left and right sides of while fluid injection, rotary cylinder drive the second eccentric wheel 1047, the
Two eccentric wheels are sprung back under the action of pressure spring by driving mandril 1046, mandril, and Soft Roll progress is back and forth clamped in release, this
Process is conducive to driving out of for the bubble in Soft Roll 100, with reference to Figure 22.
It should ensure that one circulation of maintenance during entire filling, at least guarantee that there is no bubbles to be forced out.
Then the exhaust outlet of Soft Roll is blocked, closure mode is heat seal, forms permanent block.
One reinforced sealing is set in the outside of Soft Roll heat seal position, the soft-package battery core of formation is with reference to shown in Figure 23
Structure.
The above-described embodiments are merely illustrative of preferred embodiments of the present invention, not to model of the invention
It encloses and is defined, without departing from the spirit of the design of the present invention, relevant technical staff in the field is to various changes of the invention
Shape and improvement should all expand in the protection scope as determined by claims of the present invention.
Claims (4)
1. the continuous lamination production line of three diaphragms for lithium battery manufacture, which is characterized in that including belt-type dragger, Yi Jiyan
Belt-type dragger is set gradually from front to back: the first diaphragm machine for releasing, the first positive plate release manipulator, the second diaphragm are released
It puts machine, sensor, the first negative electrode tab release manipulator, third diaphragm machine for releasing, heat-sealing machine, counter, cutting device, fold dress
It sets, the second positive plate release manipulator, the second negative electrode tab discharge manipulator and arrange platform, wherein
First diaphragm machine for releasing,
Let off roll (111), idler roller (112) and nip rolls (113) are provided in the first diaphragm machine for releasing (11), wherein
The let off roll is electric traction roller,
First positive plate discharges manipulator,
It includes rotating disk (21) and fixed disk that first positive plate, which discharges manipulator (2), and the rotate the outside of the disc of eight prism-shapeds is
Eight suckers (22) are provided with a rectangular recess (23) in each sucker, and four corners in groove are provided with gas
Mouth (24), and it is internally provided with the gas circuit (25) with gas nozzle perforation in rotating disk (21), gas circuit passes through fixed disk and positive and negative gas source
It is attached, multiple a gas circuit ports are arranged in the side of the rotating disk, each gas circuit is correspondingly arranged with fixed disk (26), institute
State and be provided with a negative pressure gas circuit (261) in fixed disk, negative pressure gas circuit by top in branch gas circuit and the rotating disk and
The gas circuit port of front side is slidably matched, and is provided with a positive pressure gas circuit (262) on fixed disk (26), positive pressure gas circuit with
Gas circuit port below rotating disk is slidably matched, by positive pressure gas circuit control bit in the absorption gas nozzle in the groove of lower section;
The rotating disk (21) is mounted in a shaft, wherein shaft being rotated by driving motor,
Second diaphragm machine for releasing (12), the second diaphragm machine for releasing (12) are identical as first diaphragm machine for releasing (11);
Incude the sensor of positive plate position, is located at after the second diaphragm machine for releasing;
First negative electrode tab discharges manipulator, and the first negative electrode tab release manipulator is identical as the first positive plate robot manipulator structure, is used for
Discharge negative electrode tab;
Third diaphragm machine for releasing, the third diaphragm machine for releasing are identical as the second diaphragm machine for releasing;
Heat-sealing machine,
The heat-sealing machine includes cutter (31), quadrilateral connecting rod mechanism (32) and the first cylinder (33), wherein cutter (31) is one
A rectangle frame, heat seal are fixed in a heat seal frame (34) with the cutter, have electrical heating elements, the heat seal in heat seal frame
One parallelogram linkage (32) is installed, an end of parallelogram linkage extends outwardly on the upside of frame (34)
And it is hinged with rack, and the first cylinder (33) are installed between the parallelogram mechanism and rack;
Counter (64), for being counted to heat seal quantity,
Cutting device, the severing for diaphragm;
Folding device, the folding device (73) include riser (731), connecting rod (732) and electric linear push rod (733), wherein
Riser (731) lower end is articulated in folding device, and the middle part of the riser (731) is connected by hinged mode respectively with top
Connecting rod, electric linear push rod drive riser to swing;
Second positive plate discharges manipulator (2 '), and it includes cabinet (91), bottom plate (92), top that second positive plate, which discharges mechanical hand,
Lift slab (93), lifting body (94) and ejecting mechanism (95), wherein the cabinet (91) is rectangular ceramic case, in length direction
On, the length of the cabinets cavity is equal in width direction less than 2 millimeters of cathode leaf length, after negative electrode tab is put into, bears
Trend of the pole piece (B) in the longitudinal direction with a pico- protrusion,
In cabinet (91) upper end, open-mouth is provided with a pair of of card slot (911), and two card slots are oppositely arranged and are fixed on the upper of cabinet
Edge, the negative electrode tab two sides (B) are free to slide along card slot (911);
One top plate (912) is set in the upper end of cabinet (91), the lower surface of the top plate (912) is the arc being recessed upwards
Face, and radian is identical as the radian of raising plate (93),
It is provided with the first notch (913) avoided to the electrode outlet in negative electrode tab in a card slot (911) wherein,
The second notch (913 ') avoided to positive electrode extension is provided on cabinet (91) simultaneously;
The raising plate (93) is arc panel, the upper surface of arc panel is provided with soft copper layer, downside is guide post (931), is led
To column two sides, (932) with teeth are set;
One bottom plate (92) is installed at the lower open mouth of cabinet (91) by way of articulated connection, bottom plate can open and close, opening
Under state, negative electrode tab (B) is filled to box house, under closed state, the jacking for positive plate;Centre in bottom plate (92)
Position is provided with a circular hole, and the guide post passes through circular hole, and in the downside of bottom plate, there are two symmetrically arranged gears for installation
(921), the gear (921) is engaged with the tooth (932) in guide post, and two gears pass through a pair of oppositely arranged respectively
Angular wheel (923) is driven by first servo motor (922);
On front side of cabinet (91) card slot and rear side is respectively arranged with first guide plate (901) and the second guide plate (902), institute
Installation ejecting mechanism (95) on the second guide plate (902) is stated, wherein ejecting mechanism includes cylinder (951), head board (952) and connects
Connect frame (953), wherein the head board (952) is the thickness alloy sheets or ceramic wafer equal with negative electrode tab, the head board
Front end is inserted into card slot (911), and rear end is attached by connection frame (953) and the piston of cylinder, and cylinder pushes head board
It moves back and forth;
Second negative electrode tab release manipulator (4 ') is identical as the second positive plate release manipulator (2 '), two before and after folding device
The second negative electrode tab release manipulator and the second positive plate release manipulator is respectively set in side, inserts negative electrode tab to position is folded
And positive plate;
Arrange platform, the arrangement for lamination.
2. the three diaphragms continuous lamination production line according to claim 1 for lithium battery manufacture, which is characterized in that institute
Stating belt-type dragger includes upper traction roller (711) and lower traction belts (71), and annular lower traction belts are in power motor
It can be moved under driving, and the end of upper traction roller (711) and lower traction belts carries out contact and diaphragm is driven to transport along belt
Line direction advances.
3. the three diaphragms continuous lamination production line according to claim 1 for lithium battery manufacture, which is characterized in that
Be additionally provided between negative electrode tab release manipulator and third diaphragm machine for releasing to positive plate spacing arranged it is electronic every
Plate.
4. the three diaphragms continuous lamination production line according to claim 3 for lithium battery manufacture, which is characterized in that institute
Stating electronic partition includes partition and control motor, guide post, and the thickness of the partition in the electronic partition is set as 2 millimeters, institute
Stating partition (72) has up and down action along guide post in the case where controlling motor driven.
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CN108448171B (en) * | 2018-03-19 | 2023-08-08 | 广东新宇智能装备有限公司 | Battery cell lamination machine and use method thereof |
CN109301331A (en) * | 2018-08-03 | 2019-02-01 | 深圳市山木新能源科技股份有限公司 | A kind of graphene lithium battery manufacture equipment |
CN111816931B (en) * | 2019-11-29 | 2022-09-13 | 合肥国轩高科动力能源有限公司 | Continuous production device for laminated batteries |
CN110890586A (en) * | 2019-12-02 | 2020-03-17 | 天津昊宸智能科技有限公司 | Battery pole piece lamination device and lamination method |
CN113422113B (en) * | 2021-06-04 | 2022-07-05 | 深圳赛骄阳能源科技股份有限公司 | Method for manufacturing special-shaped lithium ion battery |
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JP2013179035A (en) * | 2012-01-31 | 2013-09-09 | Nissan Motor Co Ltd | Method and apparatus for manufacturing non-bipolar battery |
CN102751538A (en) * | 2012-07-16 | 2012-10-24 | 深圳邦凯新能源股份有限公司 | Winding laminating machine and laminating method thereof |
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