CN106675880A - Pesticide residue cleaning agent and preparation method thereof - Google Patents

Pesticide residue cleaning agent and preparation method thereof Download PDF

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Publication number
CN106675880A
CN106675880A CN201611098568.7A CN201611098568A CN106675880A CN 106675880 A CN106675880 A CN 106675880A CN 201611098568 A CN201611098568 A CN 201611098568A CN 106675880 A CN106675880 A CN 106675880A
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Prior art keywords
parts
pesticide residue
charcoal
sodium
bamboo
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CN201611098568.7A
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Chinese (zh)
Inventor
贺艺
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Qinzhou Xinghuo Planning Office
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Qinzhou Xinghuo Planning Office
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Priority to CN201611098568.7A priority Critical patent/CN106675880A/en
Publication of CN106675880A publication Critical patent/CN106675880A/en
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88Ampholytes; Electroneutral compounds
    • C11D1/94Mixtures with anionic, cationic or non-ionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/046Salts
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/10Carbonates ; Bicarbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2086Hydroxy carboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/382Vegetable products, e.g. soya meal, wood flour, sawdust
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/386Preparations containing enzymes, e.g. protease or amylase
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a pesticide residue cleaning agent and a preparation method thereof. The pesticide residue cleaning agent is composed of the following formula ingredients in parts by mass: 10-20 parts of bamboo vinegar powder, 3-5 parts of sodium citric acid, 5-6 parts of potassium hydrogen persulfate, 6-10 parts of pomegranate bark extractive, 3-5 parts of sodium hypochlorite, 1-2 parts of triethanolamine oleate, 4-8 parts of wormwood extractive, 5-7 parts of olive coal, 4-6 parts of sodium hydrogen carbonate, 6-8 parts of alkanolamide, 3-5 parts of activated carbon, 6-8 parts of bamboo carbon, 5-7 parts of ginger protease, and 6-8 parts of coconut oil. The formula of the pesticide residue cleaning agent disclosed by the invention is pollution-free, less in raw material variety and easy to obtain, simple in preparation process, low in cost, contains anion, non-ionic and ampholytic surfactant, and contains natural plant surfactant compound, and has the effects of sterilizing, complexing heavy metal ions, and moisturizing the skin at the same time, the pesticide residue on vegetables and the fruits can be effectively cleaned, the dirt on the surfaces of the vegetables and the fruits can be removed, so that the vegetables and the fruits can achieve the safe edible standard.

Description

A kind of Pesticide residue cleaner and preparation method thereof
Technical field
The present invention relates to detergent applications, in particular to a kind of Pesticide residue cleaner and preparation method thereof.
Background technology
Due to using in a large number for the various pesticide of current agricultural production, cause residual pesticide in fruit and vegerable exceeded, so as to pass through food Thing chain enters human body, damages health.Although national food safety standard --- Pesticide MRL (GB2763-2014) maximum residue limit of the Multiple Pesticides in the varieties of food items such as corn, fruit and vegerable is defined, fruit and vegerable pesticide is made With being limited, but because fruit and vegerable market handling capacity is big, circulation is more, supervision difficulty is big, testing agency is few, poor in timeliness etc. Reason, garden stuff pesticide residue cannot get effective Sources controlling, remain exceeded phenomenon still generally existing.This is accomplished by fruit and vegerable Effectively cleaned before putting on the dining table, pesticide residues are preferably minimized, to ensure safe diet.However, due to fruit and vegerable on market The reason such as detergent price is higher or specific aim is not strong, most of common people still get used to washing fruit and vegerable with clear water, hardly realize This method can not effectively wash residual pesticide.
The content of the invention
The invention provides a kind of Pesticide residue cleaner and preparation method thereof, inventive formulation is pollution-free, raw material variety Less and be easy to get, preparation process is simple is with low cost, containing anion, nonionic and amphoteric surfactant, and containing natural plant Thing surfactant compound, the effects such as have sterilization, complexation heavy metal ion, skin moistening concurrently, can effectively wash garden stuff pesticide residue, The dirt of fruit and vegetable surfaces is removed, makes fruit and vegerable reach safe edible standard.
For achieving the above object, the present invention provides following technical scheme:
A kind of Pesticide residue cleaner and preparation method thereof, is made up of following mass fraction formula components:Bamboo vinegar powder 10-20 Part, sodium citrate 3-5 parts, potassium hydrogen persulfate 5-6 parts, Pericarpium Granati extract 6-10 parts, sodium hypochlorite 3-5 parts, oleic acid triethanolamine Amine 1-2 parts, wormwood extract 4-8 part, Fructus Canarii albi charcoal 5-7 parts, sodium bicarbonate 4-6 parts, alkanolamide 6-8 parts, activated carbon 3-5 parts, Bamboo charcoal 6-8 parts, Ginger Protease 5-7 parts, Oleum Cocois 6-8 parts.
Further:It is made up of following mass fraction formula components:10 parts of bamboo vinegar powder, 3 parts of sodium citrate, potassium hydrogen persulfate 5 Part, 6 parts of Pericarpium Granati extract, 3 parts of sodium hypochlorite, 1 part of triethanolamine oleate, 4 parts of wormwood extract, 5 parts of Fructus Canarii albi charcoal, bicarbonate 4 parts of sodium, 6 parts of alkanolamide, 3 parts of activated carbon, 6 parts of bamboo charcoal, 5 parts of Ginger Protease, 6 parts of Oleum Cocois.
Further:It is made up of following mass fraction formula components:15 parts of bamboo vinegar powder, 4 parts of sodium citrate, potassium hydrogen persulfate 5.5 parts, 8 parts of Pericarpium Granati extract, 4 parts of sodium hypochlorite, 1.5 parts of triethanolamine oleate, 6 parts of wormwood extract, 6 parts of Fructus Canarii albi charcoal, 5 parts of sodium bicarbonate, 7 parts of alkanolamide, 4 parts of activated carbon, 7 parts of bamboo charcoal, 6 parts of Ginger Protease, 7 parts of Oleum Cocois.
Further:It is made up of following mass fraction formula components:20 parts of bamboo vinegar powder, 5 parts of sodium citrate, potassium hydrogen persulfate 6 Part, 10 parts of Pericarpium Granati extract, 5 parts of sodium hypochlorite, 2 parts of triethanolamine oleate, 8 parts of wormwood extract, 7 parts of Fructus Canarii albi charcoal, carbonic acid 6 parts of hydrogen sodium, 8 parts of alkanolamide, 5 parts of activated carbon, 8 parts of bamboo charcoal, 7 parts of Ginger Protease, 8 parts of Oleum Cocois.
Further:Preparation method of the present invention has following steps:
Step one, bamboo vinegar powder is dissolved in weighed water, and adds weighed hydrogen peroxide, in the case of sealing, plus To 70 DEG C, rotating speed 40r/min's heat decolourizes 1 hour, obtains solution;
Step 2, in the solution addition are pre-mixed uniform Oleum Cocois, persistently stir, and rotating speed is according to dissolving situation in real time Adjustment, treating that the former dissolves can just add completely the latter, various raw materials is not sticked in walls of beaker as far as possible during charging, 50 DEG C of temperature Stir 35-45 minutes under the conditions of degree;
Step 3, addition weighed bamboo charcoal, wormwood extract, Pericarpium Granati extract, in the case of sealing, continue to stir 5- 10 minutes;
The weighed surplus stock of step 4, addition, stirs 5 minutes under 45 DEG C of temperature conditionss, is gradually lowered rotating speed, closes Close magnetic force heating stirrer.
The invention has the beneficial effects as follows:
1st, inventive formulation is pollution-free, and raw material variety is less and is easy to get;
2nd, preparation process is simple, it is with low cost, containing anion, nonionic and amphoteric surfactant;
3rd, containing natural plants surfactant compound, the effects such as have sterilization, complexation heavy metal ion, skin moistening concurrently;
4th, garden stuff pesticide residue can be effectively washed, the dirt of fruit and vegetable surfaces is removed, makes fruit and vegerable reach safe edible standard.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, Obviously, described embodiment is only a part of embodiment of the invention, rather than the embodiment of whole.Based in the present invention Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all Belong to the scope of protection of the invention.
Embodiment one:
A kind of Pesticide residue cleaner is made up of following mass fraction formula components:Bamboo vinegar powder 10-20 parts, sodium citrate 3- 5 parts, potassium hydrogen persulfate 5-6 parts, Pericarpium Granati extract 6-10 parts, sodium hypochlorite 3-5 parts, triethanolamine oleate 1-2 parts, Folium Artemisiae Argyi carry Take thing 4-8 parts, Fructus Canarii albi charcoal 5-7 parts, sodium bicarbonate 4-6 parts, alkanolamide 6-8 parts, activated carbon 3-5 parts, bamboo charcoal 6-8 parts, Rhizoma Zingiberis Recenss Protease 5-7 parts, Oleum Cocois 6-8 parts.
Embodiment two:
A kind of Pesticide residue cleaner is made up of following mass fraction formula components:10 parts of bamboo vinegar powder, 3 parts of sodium citrate, 5 parts of potassium hydrogen persulfate, 6 parts of Pericarpium Granati extract, 3 parts of sodium hypochlorite, 1 part of triethanolamine oleate, 4 parts of wormwood extract, Fructus Canarii albi 5 parts of charcoal, 4 parts of sodium bicarbonate, 6 parts of alkanolamide, 3 parts of activated carbon, 6 parts of bamboo charcoal, 5 parts of Ginger Protease, 6 parts of Oleum Cocois.
Embodiment three:
A kind of Pesticide residue cleaner is made up of following mass fraction formula components:15 parts of bamboo vinegar powder, 4 parts of sodium citrate, 5.5 parts of potassium hydrogen persulfate, 8 parts of Pericarpium Granati extract, 4 parts of sodium hypochlorite, 1.5 parts of triethanolamine oleate, 6 parts of wormwood extract, 6 parts of Fructus Canarii albi charcoal, 5 parts of sodium bicarbonate, 7 parts of alkanolamide, 4 parts of activated carbon, 7 parts of bamboo charcoal, 6 parts of Ginger Protease, 7 parts of Oleum Cocois.
Example IV:
A kind of Pesticide residue cleaner is made up of following mass fraction formula components:20 parts of bamboo vinegar powder, 5 parts of sodium citrate, 6 parts of potassium hydrogen persulfate, 10 parts of Pericarpium Granati extract, 5 parts of sodium hypochlorite, 2 parts of triethanolamine oleate, 8 parts of wormwood extract, Fructus Canarii albi 7 parts of charcoal, 6 parts of sodium bicarbonate, 8 parts of alkanolamide, 5 parts of activated carbon, 8 parts of bamboo charcoal, 7 parts of Ginger Protease, 8 parts of Oleum Cocois.
Embodiment five:
A kind of preparation method preparation method of Pesticide residue cleaner comprises the steps:
Step one, bamboo vinegar powder is dissolved in weighed water, and adds weighed hydrogen peroxide, in the case of sealing, plus To 70 DEG C, rotating speed 40r/min's heat decolourizes 1 hour, obtains solution;
Step 2, in the solution addition are pre-mixed uniform Oleum Cocois, persistently stir, and rotating speed is according to dissolving situation in real time Adjustment, treating that the former dissolves can just add completely the latter, various raw materials is not sticked in walls of beaker as far as possible during charging, 50 DEG C of temperature Stir 35-45 minutes under the conditions of degree;
Step 3, addition weighed bamboo charcoal, wormwood extract, Pericarpium Granati extract, in the case of sealing, continue to stir 5- 10 minutes;
The weighed surplus stock of step 4, addition, stirs 5 minutes under 45 DEG C of temperature conditionss, is gradually lowered rotating speed, closes Close magnetic force heating stirrer.
Moreover, it will be appreciated that although this specification is been described by according to embodiment, not each embodiment is only wrapped Containing an independent technical scheme, this narrating mode of description is only that for clarity those skilled in the art should Using description as an entirety, the technical scheme in each embodiment can also Jing it is appropriately combined, form those skilled in the art Understandable other embodiment.

Claims (5)

1. a kind of Pesticide residue cleaner, it is characterised in that:It is made up of following mass fraction formula components:
Bamboo vinegar powder 10-20 parts, sodium citrate 3-5 parts, potassium hydrogen persulfate 5-6 parts, Pericarpium Granati extract 6-10 parts, sodium hypochlorite 3- 5 parts, triethanolamine oleate 1-2 parts, wormwood extract 4-8 part, Fructus Canarii albi charcoal 5-7 parts, sodium bicarbonate 4-6 parts, alkanolamide 6-8 Part, activated carbon 3-5 parts, bamboo charcoal 6-8 parts, Ginger Protease 5-7 parts, Oleum Cocois 6-8 parts.
2. a kind of Pesticide residue cleaner according to claim 1, it is characterised in that:By following mass fraction formula components Composition:
10 parts of bamboo vinegar powder, 3 parts of sodium citrate, 5 parts of potassium hydrogen persulfate, 6 parts of Pericarpium Granati extract, 3 parts of sodium hypochlorite, oily triethylenetetraminehexaacetic acid 1 part of hydramine, 4 parts of wormwood extract, 5 parts of Fructus Canarii albi charcoal, 4 parts of sodium bicarbonate, 6 parts of alkanolamide, 3 parts of activated carbon, 6 parts of bamboo charcoal, life 5 parts of Rhizoma Zingiberis Recens protease, 6 parts of Oleum Cocois.
3. a kind of Pesticide residue cleaner according to claim 1, it is characterised in that:By following mass fraction formula components Composition:
15 parts of bamboo vinegar powder, 4 parts of sodium citrate, 5.5 parts of potassium hydrogen persulfate, 8 parts of Pericarpium Granati extract, 4 parts of sodium hypochlorite, Oleic acid three 1.5 parts of ethanolamine, 6 parts of wormwood extract, 6 parts of Fructus Canarii albi charcoal, 5 parts of sodium bicarbonate, 7 parts of alkanolamide, 4 parts of activated carbon, bamboo charcoal 7 Part, 6 parts of Ginger Protease, 7 parts of Oleum Cocois.
4. a kind of Pesticide residue cleaner according to claim 1, it is characterised in that:By following mass fraction formula components Composition:
20 parts of bamboo vinegar powder, 5 parts of sodium citrate, 6 parts of potassium hydrogen persulfate, 10 parts of Pericarpium Granati extract, 5 parts of sodium hypochlorite, Oleic acid three 2 parts of ethanolamine, 8 parts of wormwood extract, 7 parts of Fructus Canarii albi charcoal, 6 parts of sodium bicarbonate, 8 parts of alkanolamide, 5 parts of activated carbon, 8 parts of bamboo charcoal, 7 parts of Ginger Protease, 8 parts of Oleum Cocois.
5. a kind of a kind of preparation method of Pesticide residue cleaner according to claim 1, it is characterised in that:Including as follows Step:
Step one, bamboo vinegar powder is dissolved in weighed water, and adds weighed hydrogen peroxide, in the case of sealing, be heated to 70 DEG C, rotating speed 40r/min decolourizes 1 hour, obtains solution;
Step 2, in the solution addition are pre-mixed uniform Oleum Cocois, persistently stir, and rotating speed is adjusted according to dissolving situation in real time Whole, treating that the former dissolves can just add completely the latter, various raw materials is not sticked in walls of beaker as far as possible during charging, 50 DEG C of temperature Under the conditions of stir 35-45 minutes;
Step 3, addition weighed bamboo charcoal, wormwood extract, Pericarpium Granati extract, in the case of sealing, continue to stir 5-10 point Clock;
The weighed surplus stock of step 4, addition, stirs 5 minutes under 45 DEG C of temperature conditionss, is gradually lowered rotating speed, closes magnetic Power heating stirrer.
CN201611098568.7A 2016-12-04 2016-12-04 Pesticide residue cleaning agent and preparation method thereof Pending CN106675880A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611098568.7A CN106675880A (en) 2016-12-04 2016-12-04 Pesticide residue cleaning agent and preparation method thereof

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CN201611098568.7A CN106675880A (en) 2016-12-04 2016-12-04 Pesticide residue cleaning agent and preparation method thereof

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CN106675880A true CN106675880A (en) 2017-05-17

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109897744A (en) * 2019-03-22 2019-06-18 东莞市宏裕生物科技有限公司 A kind of biological enzyme cleaning particle and its manufacture craft
CN111334382A (en) * 2020-04-17 2020-06-26 江西理工大学 Heavy metal cleaning soap based on spores and preparation method thereof
US20220145219A1 (en) * 2020-11-06 2022-05-12 Aunt Fannie Inc. Cleaning Composition

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103255007A (en) * 2012-02-16 2013-08-21 上海植晶生物科技有限公司 Pesticide residue cleaner
CN104212648A (en) * 2014-08-28 2014-12-17 青岛保利康新材料有限公司 High-efficiency pesticide residue detergent
CN105950312A (en) * 2016-05-20 2016-09-21 西安文理学院 Fruit and vegetable pesticide residue detergent and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103255007A (en) * 2012-02-16 2013-08-21 上海植晶生物科技有限公司 Pesticide residue cleaner
CN104212648A (en) * 2014-08-28 2014-12-17 青岛保利康新材料有限公司 High-efficiency pesticide residue detergent
CN105950312A (en) * 2016-05-20 2016-09-21 西安文理学院 Fruit and vegetable pesticide residue detergent and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109897744A (en) * 2019-03-22 2019-06-18 东莞市宏裕生物科技有限公司 A kind of biological enzyme cleaning particle and its manufacture craft
CN111334382A (en) * 2020-04-17 2020-06-26 江西理工大学 Heavy metal cleaning soap based on spores and preparation method thereof
US20220145219A1 (en) * 2020-11-06 2022-05-12 Aunt Fannie Inc. Cleaning Composition

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