CN106675875A - Wax removing cleaning agent for ceramics and preparation method of wax removing cleaning agent - Google Patents
Wax removing cleaning agent for ceramics and preparation method of wax removing cleaning agent Download PDFInfo
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- CN106675875A CN106675875A CN201510753831.0A CN201510753831A CN106675875A CN 106675875 A CN106675875 A CN 106675875A CN 201510753831 A CN201510753831 A CN 201510753831A CN 106675875 A CN106675875 A CN 106675875A
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- cleaning agent
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- paraffin removal
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- removal cleaning
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Abstract
The invention firstly aims to provide a wax removing cleaning agent for ceramics. Raw materials of the wax removing cleaning agent for the ceramics comprise the following components: potassium oleate, isopropylbenzenesulfonic acid sodium salt, triethanolamine, glycerinum, diethanol amine, glycol ether and deionized water. Various components in the formula of the wax removing cleaning agent for the ceramics provided by the invention are easily obtained; the whole formula is low in cost; according to the wax removing cleaning agent for the ceramics, the isopropylbenzenesulfonic acid sodium salt serves as a surfactant and a solubilizer, and the wax removing property of the potassium oleate is combined, so that a good cleaning effect on wax containing various components is achieved; the whole formula forms a water-emulsion type cleaning agent, and is environment-friendly and pollution-free. The invention secondly aims to provide a preparation method of the wax removing cleaning agent for the ceramics; the process steps are simple; process parameters are controlled easily; the preparation method is suitable for industrial production.
Description
Technical field
The present invention relates to ceramic processing technique field, especially, is related to a kind of ceramics paraffin removal cleaning agent and its preparation side
Method.
Background technology
When ceramic product is processed by shot blasting in process to its surface, because product cannot be entered using clamp tool to it
Row positioning, need to be fixed using sticky wax mode to product, and ceramic surface remains wax material after polishing, therefore, need
The wax of surface of ceramic products residual is removed, to reach the purpose of clean surface.
Cleaning agent of the prior art is as follows：
The patent application of Application No. 201310728732.8 discloses a kind of Environmental Safety scale removal wax removing agent, and the scale removal is removed
Cerate is constituted according to percentage by weight：Glycerine 10-20%, urea 1-2%, coconut acid diethanolamide 10-15%, monoethanolamine
2.5-3%, hydrogen peroxide 10-20%, hydrochloric acid 5-10%, sodium metasilicate 2-9% and deionized water.This formula has brighter to scale removal
Aobvious effect, and to paraffin removal effect be not it is particularly evident, it is more unobvious to the paraffin removal effect of ceramics.
The patent application of Application No. 201210395298.1 discloses a kind of paraffin removal cleaning method, comprises the following steps：
(1) using the cleaning agent being made up of following weight percent composition：7.6-10.3% OPEOs, 3.5-6.7%
Salicylic acid, 1.5-5.2% acetamides, 2.6-7.8%2- HPAAs, 4.1-8.3% sodium metasilicate, 3.7-5.8% Portugals
Grape sodium saccharate, 5.1-9.2% ethanol, 1.3-4.0% isopropanols, 5.5-9.8% trichloro ethylenes, balance of deionized water；(2) first
The cloth of cleaning is immersed in cleaning agent, then body surface is wiped with the cloth, until body surface wax is removed totally.The present invention
Paraffin removal method is not suitable for ceramic product, easily produces damage to product.
The patent application of Application No. 99115440.1 discloses a kind of Wax removal water, the percentage by weight of constituent content
It is：Coconut oil diethanol amide phosphate 18-25%, coconut oil diethanol amide 5-12%, AEO 1-
3%, NPE 1-3%, thermally coupled distillation columns 1-5%, MEA 3-5%, water 56-63%
Composition.The polishing paraffin removal of suitable metallic article, is not suitable for ceramic product.
In sum, paraffin removal formula of the prior art is not suitable for ceramic product, therefore, be badly in need of in industry it is a kind of into
This low, paraffin removal effect is good and paraffin removal cleaning agent suitable for ceramic product.
The content of the invention
The first object of the present invention is to provide that a kind of low cost, paraffin removal effect be good and ceramics use suitable for ceramic product
Paraffin removal cleaning agent, concrete technical scheme is as follows：
A kind of ceramics use paraffin removal cleaning agent, and raw material includes following components in terms of mass fraction：
Potassium oleate 12-13 part sodium cumene sulfonate 0.4-0.8 part triethanolamine 10.5-11.5 parts
Glycerine 2.5-3.5 part diethanol amine 1.0-1.5 part ethylene glycol ethyl ether 4.0-4.5 parts
Deionized water 65-68 part.
Preferred in above technical scheme, raw material includes following components in terms of mass fraction：
12 parts of potassium oleate, 0.4 part of sodium cumene sulfonate, 10.5 parts of triethanolamine
2.5 parts of glycerine, 1.0 parts of diethanol amine, 4.0 parts of ethylene glycol ethyl ether
67 parts of deionized water.
Preferred in above technical scheme, raw material includes following components in terms of mass fraction：
12.5 parts of potassium oleate, 0.6 part of sodium cumene sulfonate, 11 parts of triethanolamine
3 parts of glycerine, 1.2 parts of diethanol amine, 4.2 parts of ethylene glycol ethyl ether
67 parts of deionized water.
Preferred in above technical scheme, raw material includes following components in terms of mass fraction：
13 parts of potassium oleate, 0.8 part of sodium cumene sulfonate, 11.5 parts of triethanolamine
3.5 parts of glycerine, 1.5 parts of diethanol amine, 4.5 parts of ethylene glycol ethyl ether
68 parts of deionized water.
Using the ceramics paraffin removal cleaning agent of the present invention, have the advantages that：The ceramics of the present invention are cleaned with paraffin removal
Agent includes potassium oleate, sodium cumene sulfonate, triethanolamine, glycerine, diethanol amine, ethylene glycol ethyl ether and deionized water, matches somebody with somebody
Each component is readily available in side, the low cost of whole formula.The present invention adopts sodium cumene sulfonate, has the effect that：a、
As anion surfactant, emulsion is formed with water, have excellent solvability, cleaning performance to rosin, organic compound
It is good；B, as solubilizer, itself there is excellent emulsification and dispersive property, stability is strong in acid and alkaline medium；Oil
Sour potassium has very strong paraffin removal, and in the hydrophobic grouping of oleic acid acid molecule, active larger double bond, dissolubility is good, for
Greasy dirt, the wax of various compositions all has good cleaning performance；Whole formula constitutes emulsion type cleaning agent, environmentally friendly,
It is pollution-free.
The second object of the present invention is to provide a kind of preparation method of above-mentioned ceramics paraffin removal cleaning agent, comprising following step
Suddenly：
First weigh deionized water in the ratio for designing and be added in agitator, turn on agitator；Successively will be corresponding
The potassium oleate of ratio, sodium cumene sulfonate, triethanolamine, diethanol amine, six kinds of material difference of ethylene glycol ethyl ether and glycerine
Fed, the charging process includes addition raw material and two steps that stir.
It is preferred in above technical scheme, it is described stir during：Stir speed (S.S.) is 2000 rpms, stirring temperature
Spend for 22 degrees Celsius -27 degrees Celsius.
Preparation method processing step of the present invention is simplified, and technological parameter is easily controlled, and is adapted to industrialized production.
In addition to objects, features and advantages described above, the present invention also has other objects, features and advantages.
Below with reference to specific embodiment, the present invention is further detailed explanation.
Specific embodiment
Technical solution of the present invention is described in detail with reference to embodiments, but the present invention can be according to claim
The multitude of different ways for limiting and covering is implemented.
Embodiment 1：
A kind of ceramics use paraffin removal cleaning agent, comprising following components：
12 kilograms of potassium oleate, 0.4 kilogram of sodium cumene sulfonate, 10.5 kilograms of triethanolamine
2.5 kilograms of glycerine, 1.0 kilograms of diethanol amine, 4.0 kilograms of ethylene glycol ethyl ether
67 kilograms of deionized water.
The above-mentioned ceramics preparation method of paraffin removal cleaning agent, comprises the steps of：
Step one：First the deionized water for weighing is added in agitator, turn on agitator；
Step 2：The potassium oleate for weighing is added and is stirred in agitator uniformly, obtain the first mixture；
Step 3：The sodium cumene sulfonate for weighing is added and is stirred in the first mixture in agitator
It is even, obtain the second mixture；
Step 4：The triethanolamine for weighing is added and is stirred uniformly in the second mixture in agitator, obtained
3rd mixture；
Step 5：The diethanol amine for weighing is added and is stirred uniformly in the 3rd mixture in agitator, obtained
4th mixture；
Step 6：The ethylene glycol ethyl ether for weighing is added and is stirred uniformly in the 4th mixture in agitator, obtained
To the 5th mixture；
Step 7：The glycerine for weighing is added and is stirred uniformly in the 5th mixture in agitator, obtain this
Bright ceramics paraffin removal cleaning agent, is labeled as MK1.
Into step 7, the stir speed (S.S.) of agitator is set in 2000 rpms to above-mentioned steps two, and whipping temp is arranged
At 25 degrees Celsius.
Embodiment 2：
Difference from Example 1 is：Ceramics include following components with paraffin removal cleaning agent：
12.5 kilograms of potassium oleate, 0.6 kilogram of sodium cumene sulfonate, 11 kilograms of triethanolamine
3 kilograms of glycerine, 1.2 kilograms of diethanol amine, 4.2 kilograms of ethylene glycol ethyl ether
67 kilograms of deionized water.
The ceramics paraffin removal cleaning agent that the present embodiment is obtained is labeled as into MK2.
Embodiment 3：
Difference from Example 1 is：Ceramics include following components with paraffin removal cleaning agent：
13 kilograms of potassium oleate, 0.8 kilogram of sodium cumene sulfonate, 11.5 kilograms of triethanolamine
3.5 kilograms of glycerine, 1.5 kilograms of diethanol amine, 4.5 kilograms of ethylene glycol ethyl ether
68 kilograms of deionized water.
The ceramics paraffin removal cleaning agent that the present embodiment is obtained is labeled as into MK3.
Comparative example 1：
Difference from Example 1 is：Ceramics include following components with paraffin removal cleaning agent：
13 kilograms of potassium oleate, 11.5 kilograms of triethanolamine, 4.5 kilograms of ethylene glycol ethyl ether
3.5 kilograms of glycerine, 1.5 kilograms of diethanol amine, 68 kilograms of deionized water.
The above-mentioned ceramics preparation method of paraffin removal cleaning agent, comprises the steps of：
Step one：First the deionized water for weighing is added in agitator, turn on agitator；
Step 2：The potassium oleate for weighing is added and is stirred in agitator uniformly, obtain the first mixture；
Step 3：The triethanolamine for weighing is added and is stirred uniformly in the first mixture in agitator, obtained
The second ' mixture；
Step 4：The diethanol amine for weighing is added and is stirred uniformly in the second ' mixture in agitator, obtained
3rd ' mixture；
Step 5：The ethylene glycol ethyl ether for weighing is added and is stirred uniformly in the 3rd ' mixture in agitator, obtained
To the 4th ' mixture；
Step 6：The glycerine for weighing is added and is stirred uniformly in the 4th ' mixture in agitator, obtain this right
Than the ceramics of embodiment paraffin removal cleaning agent, DMK1 is labeled as.
Into step 7, the stir speed (S.S.) of agitator is set in 2000 rpms to above-mentioned steps two, and whipping temp is arranged
At 25 degrees Celsius.
Comparative example 2：
Difference from Example 1 is：Ceramics include following components with paraffin removal cleaning agent：
13 kilograms of potassium oleate, 0.05 kilogram of sodium cumene sulfonate, 11.5 kilograms of triethanolamine
3.5 kilograms of glycerine, 1.5 kilograms of diethanol amine, 4.5 kilograms of ethylene glycol ethyl ether
68 kilograms of deionized water.
The ceramics paraffin removal cleaning agent that the present embodiment is obtained is labeled as into DMK2.
Comparative example 3：
Difference from Example 1 is：Ceramics include following components with paraffin removal cleaning agent：
13 kilograms of potassium oleate, 0.2 kilogram of sodium cumene sulfonate, 11.5 kilograms of triethanolamine
3.5 kilograms of glycerine, 1.5 kilograms of diethanol amine, 4.5 kilograms of ethylene glycol ethyl ether
68 kilograms of deionized water.
The ceramics paraffin removal cleaning agent that the present embodiment is obtained is labeled as into DMK3.
Comparative example 4：
Difference from Example 1 is：Ceramics include following components with paraffin removal cleaning agent：
13 kilograms of potassium oleate, 1.0 kilograms of sodium cumene sulfonate, 11.5 kilograms of triethanolamine
3.5 kilograms of glycerine, 1.5 kilograms of diethanol amine, 4.5 kilograms of ethylene glycol ethyl ether
68 kilograms of deionized water.
The ceramics paraffin removal cleaning agent that the present embodiment is obtained is labeled as into DMK4.
Comparative example 5：
Difference from Example 1 is：Ceramics include following components with paraffin removal cleaning agent：
13 kilograms of potassium oleate, 1.2 kilograms of sodium cumene sulfonate, 11.5 kilograms of triethanolamine
3.5 kilograms of glycerine, 1.5 kilograms of diethanol amine, 4.5 kilograms of ethylene glycol ethyl ether
68 kilograms of deionized water.
The ceramics paraffin removal cleaning agent that the present embodiment is obtained is labeled as into DMK5.
Using following methods to obtained by embodiment 1, embodiment 2, embodiment 3 and comparative example 1-5 totally eight kinds it is clear
Lotion is tested, and effect refers to table 1.
Test method：To be per component according to 10 with a collection of pending ceramic product (yellow wax after surface adhesion solidification)
8 groups；Respectively eight kinds of paraffin removal cleaning agents of measured amounts, add into rinse bath, rise high-temperature to 75 ± 5 DEG C, open ultrasonic wave,
Ultrasonic wave current strength is set to 2.5 amperes, and ultrasonic frequency is set to 28 KHzs, and scavenging period is set to 180 seconds.
The result of the test of the embodiment 1 of table 1, embodiment 2, embodiment 3 and comparative example's 1-5 products obtained therefroms
When as known from Table 1, without when sodium cumene sulfonate (comparative example 1) with addition sodium cumene sulfonate
(embodiment 1-3) compares, and the consumption for adding the paraffin removal cleaning agent of sodium cumene sulfonate is significantly reduced, and paraffin removal effect has
Significantly improve；As sodium cumene sulfonate consumption very few (comparative example 2 and comparative example 3), the use of paraffin removal cleaning agent
Amount or than larger, but the wax of surface of ceramic products can be completely removed；When sodium cumene sulfonate consumption is excessive, (contrast is implemented
Example 4 and comparative example 5) when, the consumption of paraffin removal cleaning agent is not significantly reduced, and paraffin removal effect is basically unchanged.Therefore, adopt
With the ceramics of inventive formulation paraffin removal cleaning agent, consumption is appropriate on the premise of paraffin removal effect is ensured, practical.
The preferred embodiments of the present invention are the foregoing is only, the present invention is not limited to, for the skill of this area
For art personnel, the present invention can have various modifications and variations.It is all within the spirit and principles in the present invention, made any repair
Change, equivalent, improvement etc., should be included within the scope of the present invention.
Claims (6)
1. a kind of ceramics use paraffin removal cleaning agent, it is characterised in that：Raw material includes following components in terms of mass fraction：
2. ceramics paraffin removal cleaning agent according to claim 1, it is characterised in that：Raw material is comprising following in terms of mass fraction
Component：
3. ceramics paraffin removal cleaning agent according to claim 1, it is characterised in that：Raw material is comprising following in terms of mass fraction
Component：
4. ceramics paraffin removal cleaning agent according to claim 1, it is characterised in that：Raw material is comprising following in terms of mass fraction
Component：
5. a kind of ceramics as described in claim 1-4 any one preparation method of paraffin removal cleaning agent, it is characterised in that：Bag
Containing following steps：
First weigh deionized water in the ratio for designing and be added in agitator, turn on agitator；Successively by corresponding proportion
Potassium oleate, sodium cumene sulfonate, triethanolamine, diethanol amine, six kinds of materials of ethylene glycol ethyl ether and glycerine carry out respectively
Charging, the charging process includes addition raw material and two steps that stir.
6. the ceramics preparation method of paraffin removal cleaning agent according to claim 5, it is characterised in that：It is described to stir
Cheng Zhong：Stir speed (S.S.) is 2000 rpms, and whipping temp is 22 degrees Celsius -27 degrees Celsius.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510753831.0A CN106675875B (en) | 2015-11-06 | 2015-11-06 | A kind of ceramics paraffin removal cleaning agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510753831.0A CN106675875B (en) | 2015-11-06 | 2015-11-06 | A kind of ceramics paraffin removal cleaning agent and preparation method thereof |
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| CN106675875A true CN106675875A (en) | 2017-05-17 |
| CN106675875B CN106675875B (en) | 2019-01-22 |
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Cited By (3)
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| CN107326372A (en) * | 2017-06-17 | 2017-11-07 | 常州市玉宇化工有限公司 | A kind of preparation method of wax removing agent |
| JP2021522083A (en) * | 2018-04-20 | 2021-08-30 | ポストプロセス テクノロジーズ インク | Finishing medium and finishing suspension |
| CN114574291A (en) * | 2022-03-02 | 2022-06-03 | 南充三环电子有限公司 | Wax removal composition and preparation method and application thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107326372A (en) * | 2017-06-17 | 2017-11-07 | 常州市玉宇化工有限公司 | A kind of preparation method of wax removing agent |
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| JP2021522083A (en) * | 2018-04-20 | 2021-08-30 | ポストプロセス テクノロジーズ インク | Finishing medium and finishing suspension |
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| CN114574291A (en) * | 2022-03-02 | 2022-06-03 | 南充三环电子有限公司 | Wax removal composition and preparation method and application thereof |
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| CN106675875B (en) | 2019-01-22 |
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