CN106675834A - 一种羽绒服清洗液及其制备方法 - Google Patents
一种羽绒服清洗液及其制备方法 Download PDFInfo
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- CN106675834A CN106675834A CN201611220069.0A CN201611220069A CN106675834A CN 106675834 A CN106675834 A CN 106675834A CN 201611220069 A CN201611220069 A CN 201611220069A CN 106675834 A CN106675834 A CN 106675834A
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- percent
- cleanout fluid
- down jackets
- electrolyte
- amino acid
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/2086—Hydroxy carboxylic acids-salts thereof
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/06—Ether- or thioether carboxylic acids
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
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Abstract
本发明属于洗涤护理配置品技术领域，具体涉及到一种羽绒服清洗液及其制备方法，该羽绒服清洗液主要由以下质量分数的成分组成：醇醚羧酸盐9‑13％、椰油酰胺丙基甜菜碱8‑12％、氨基酸表面活性剂5‑7％、皂素1‑3％、硅酸钠0.1‑0.3％、pH缓冲剂1‑3％、羧甲基壳聚糖1‑3％、三乙醇胺2‑4％、电解质0.5‑1％和水55‑70％，该羽绒服清洗液性质温和，刺激性小，去污能力强，具有良好的抗静电、杀菌等功效，而且对羽绒蓬松度的影响小。
Description
技术领域
本发明属于洗涤护理配置品技术领域，具体涉及到一种羽绒服清洗液及其制备方法。
背景技术
羽绒是长在鹅、鸭的腹部，成芦花朵状的绒毛，能随气温变化而收缩膨胀，产生调温功能，因此被广泛的应用在保暖产品中，例如：羽绒服、羽绒被等，但是由于羽绒来源于动物，本身含有大量的蛋白、脂肪或是其他成分，容易导致细菌滋生，而且羽绒服在穿着过程中会沾染灰尘或是油渍等，但是使用一般的洗涤剂会影响羽绒服中保暖性，尤其是碱性洗涤剂会直接破坏羽绒成分。
目前常用的羽绒洗涤剂主要是中性洗涤剂，对羽绒纤维的破坏性小，但是目前的洗涤剂使用后会使之易产生静电反应，而且使用后容易破坏羽绒的蓬松度，因此，羽绒洗涤剂需要进一步的改进。
公告号为103710184B的中国专利公开了一种本发明公开了一种羽绒清洗护理剂，由如下原料制成：1-2质量份聚乙二醇，2-3质量份三聚磷酸钠，1-2质量份玫瑰精油，3-4质量份柠檬酸三丁酯，2-3质量份次亚磷酸钠，1-2质量份聚甘油单硬脂酸酯，3-4质量份月桂酸钠，3-4质量份钨酸铵，6-7质量份十二烷基苯磺酸钠，3-4质量份月桂醇硫酸钠，6-7质量份二甲基硅油，5-6质量份丙二醇，3-4质量份二异丙基萘磺酸钠，5-6质量份柠檬酸，1-2质量份月桂酰氨乙基硫酸钠，5-6质量份乙烯基三甲氧基硅烷，120质量份水，5-6质量份柔软剂，1-2质量份聚丙烯酸，该发明使用的三聚磷酸钠、亚磷酸钠会对环境造成危害，由于本身含磷，容易造成水体富营养化。
公告号为102051276B的中国专利公开了一种羽绒服清洗剂，其组分及其质量份数为：阴离子表面活性剂1-30份；非离子表面活性剂1-15份；DP-3000.1-10份；茶皂素0.1-10份；大豆乙基硫酸乙酯吗啉0.1-10份；ColtideHSi0.1-10份；香精0.1-1份；柠檬酸钠0.1-1份；去离子水13-97.4份。该发明中使用的大豆乙基硫酸乙酯吗啉是一种常见的除臭剂，主要作用是与臭味物结合、进行分解，但是在羽绒制品中，使用后会影响羽绒的品质。
发明内容
为了解决现有技术中存在的不足，本发明公开了一种羽绒服清洗液及其制备方法，本发明公开的羽绒服清洗液性质温和，刺激性小，去物流能力强，具有良好的抗静电、杀菌等功效，而且对羽绒蓬松度的影响小。
本发明具体技术方案如下所示：
一种羽绒服清洗液，主要由以下质量分数的成分组成：醇醚羧酸盐9-13％、椰油酰胺丙基甜菜碱8-12％、氨基酸表面活性剂5-7％、皂素1-3％、硅酸钠0.1-0.3％、pH缓冲剂1-3％、羧甲基壳聚糖1-3％、三乙醇胺2-4％、电解质0.5-1％和水55-70％。
醇醚羧酸盐：属于多功能阴离子表面活性剂，具有良好的去污性、润湿性、乳化性、分散性和钙皂分散力，可以改善配方的温和性，耐硬水，耐酸碱，耐电解质，具有良好的配伍性能，能与任何离子型或表面活性剂配伍，对阳离子的调理性能没有干扰，进一步，易生物降解为CO2和水。
椰油酰胺丙基甜菜碱：一种两性离子表面活性剂，在酸性及碱性条件下均具有优良的稳定性，其配伍性能良好，刺激性小，对酸碱稳定，泡沫多，去污力强，具有优良的增稠性、柔软性、杀菌性、抗静电性、抗硬水性和生物降解性，能显著提高洗涤类产品的柔软、调理和低温稳定性。
氨基酸表面活性剂：具有优良的发泡去污能力，弱酸性的氨基酸类表面活性剂，PH值与人体肌肤接近，加上氨基酸是构成蛋白质的基本物质，所以温和亲肤，能降低配方整体的刺激性，而且具有优异的杀菌抑菌性能，具有修复化学损伤特性易降解，对环境无污染。
羧甲基壳聚糖：羧甲基壳聚糖具有抗感染作用，吸附和聚沉细菌，同时穿透细胞壁进入细胞内，扰乱细菌的新陈代谢及合成而具有抗菌作用。
电解质：将电解质应用在洗涤剂中可以来增加其抗静电能力，当存在静电时电解质离子可以瞬间将电荷传导散去。
三乙醇胺：可改进油性污垢，特别是非极性皮脂的去除。
进一步的，所述的羽绒服清洗液，由以下质量分数的成分组成：醇醚羧酸盐11％、椰油酰胺丙基甜菜碱10％、氨基酸表面活性剂6％、皂素2％、硅酸钠0.2％、pH缓冲剂2％、羧甲基壳聚糖2％、三乙醇胺3％、电解质0.8％和水63％。
优选的，所述的氨基酸表面活性剂为N-酰基谷氨酸。N-酰基谷氨酸：阴离子表面活性剂，增加和保持羽绒的柔软、蓬松、光泽，性质柔和无刺激，还具有良好的抑菌效果。
进一步的，所述的电解质由醋酸钠和氯化钠按质量比1:2-3组成。
进一步的，所述的pH缓冲剂为柠檬酸。
进一步的，本发明还提供了所述的羽绒服清洗液的制备方法，步骤为，
S1：将醇醚羧酸盐、椰油酰胺丙基甜菜碱、氨基酸表面活性剂、皂素、羧甲基壳聚糖、三乙醇胺加入乳化锅中，加热至55-65℃，搅拌均匀，得乳液A；
S2：将硅酸钠、电解质加入水中至完全溶解，加入到步骤S1得到的乳液A中，搅拌均匀，得混合液B；
S3：使用pH缓冲剂调节步骤S2得到的混合液B的pH至6.0-8.0，降至室温即得。
与现有技术相比，本发明具有以下优点：
1、抗静电性：本发明使用的表面活性剂具有良好的复配型，配合使用具有良好的抗静电性，而电解质的使用，可以促进清洗液的抗静电性能。
2、温和无刺激：本发明采用成分简单，有良好的亲肤效果，同时适合机洗与手洗。
具体实施方式
下面通过实施例来介绍本发明技术方案，这些实施例仅用于说明本发明的制备方法而对本发明没有限制，本发明使用的成分均属于常规产品，其中，醇醚羧酸盐：上海发凯化工有限公司；椰油酰胺丙基甜菜碱(CAS.86438-79-1)：金锦乐化学有限公司；皂素(CAS.8047-15-2)、羧甲基壳聚糖(CAS.83512-85-0)：湖北巨胜科技有限公司。
实施例1
一种羽绒服清洗液，由以下质量分数的成分组成：醇醚羧酸盐11％、椰油酰胺丙基甜菜碱10％、氨基酸表面活性剂N-酰基谷氨酸6％、皂素2％、硅酸钠0.2％、pH缓冲剂柠檬酸2％、羧甲基壳聚糖2％、三乙醇胺3％、电解质0.8％和水63％；
所述的电解质由醋酸钠和氯化钠按质量比1:2.5组成。
所述的羽绒服清洗液的制备方法为：
S1：将醇醚羧酸盐、椰油酰胺丙基甜菜碱、氨基酸表面活性剂、皂素、羧甲基壳聚糖、三乙醇胺加入乳化锅中，加热至60℃，搅拌均匀，得乳液A；
S2：将硅酸钠、电解质加入水中至完全溶解，加入到步骤S1得到的乳液A中，搅拌均匀，得混合液B；
S3：使用pH缓冲剂调节步骤S2得到的混合液B的pH至7.0，降至室温即得。
实施例2
一种羽绒服清洗液，由以下质量分数的成分组成：醇醚羧酸盐13％、椰油酰胺丙基甜菜碱8％、氨基酸表面活性剂N-酰基谷氨酸7％、皂素1％、硅酸钠0.3％、pH缓冲剂柠檬酸1％、羧甲基壳聚糖3％、三乙醇胺2％、电解质1％和水63.7％；
所述的电解质由醋酸钠和氯化钠按质量比1:3组成。
所述的羽绒服清洗液的制备方法与实施例1类似。
实施例3
一种羽绒服清洗液，由以下质量分数的成分组成：醇醚羧酸盐9％、椰油酰胺丙基甜菜碱12％、氨基酸表面活性剂N-酰基谷氨酸5％、皂素3％、硅酸钠0.1％、pH缓冲剂柠檬酸3％、羧甲基壳聚糖1％、三乙醇胺4％、电解质0.5％和水62.4％；
所述的电解质由醋酸钠和氯化钠按质量比1:2组成。
所述的羽绒服清洗液的制备方法与实施例1类似。
对比例1
一种羽绒服清洗液，由以下质量分数的成分组成：醇醚羧酸盐11％、椰油酰胺丙基甜菜碱10％、氨基酸表面活性剂N-酰基谷氨酸6％、皂素2％、硅酸钠0.2％、pH缓冲剂柠檬酸2％、羧甲基壳聚糖2％、三乙醇胺3％和水63.8％。
与实施例1的区别是不添加电解质，增加水的含量。
所述的羽绒服清洗液的制备方法与实施例1类似。
对比例2
一种羽绒服清洗液，由以下质量分数的成分组成：醇醚羧酸盐11％、椰油酰胺丙基甜菜碱10％、氨基酸表面活性剂N-酰基谷氨酸6％、皂素4％、硅酸钠0.2％、pH缓冲剂柠檬酸2％、三乙醇胺3％、电解质0.8％和水63％；
所述的电解质由醋酸钠和氯化钠按质量比1:2.5组成。
与实施例1的区别是不添加羧甲基壳聚糖，增加皂素的含量。
所述的羽绒服清洗液的制备方法与实施例1类似。
试验例1抗静电性
试验对象：实施例1-3与对比例1制得的羽绒服清洗液。
试验方法：使用厚0.5mm的涤纶面料，大小为10×10cm，将其浸渍在1ml清洗液与1L水的混合液中，浸渍10分钟，然后捞出使用清水水洗直至水中无泡沫产生，晾干，测试清洗前后布料的表面阻抗与表面电荷量，具体结果如表1所示。
表1抗静电性能参数
从表1中可以看出，实施例1-3相比对比例1具有更好的抗静电性能。
试验例2抗菌性和抗螨试验
试验对象：实施例1-3与对比例1-2制得的羽绒服清洗液。
菌种和螨虫：金黄色葡萄球菌、大肠杆菌、屋尘螨。
1、试验方法：将0.1ml的清洗液与100ml的水混合，搅拌均匀，然后与琼脂混合制成琼脂培养基，将金黄色葡萄球菌和大肠杆菌分别接种在两个培养基上，放入37℃，恒温温箱中进行培养10小时，观察菌落数量，计算杀菌率，设置对照组，不添加清洗液，杀菌率＝菌落数量/对照组菌落数量×100％。
2、试验方法：将0.1ml的清洗液与100ml的水混合，搅拌均匀，将厚0.5mm、大小为10×10cm的涤纶面料浸泡15分钟，然后使用清水漂洗至无泡，晾干，面料上放置100只屋尘螨，计算使用前后螨虫数量变化，计算杀螨率。
具体结果如表2所示。
表2杀菌率与杀螨率结果统计
从表2中可以看出，本发明公开的羽绒服清洗液具有更好的抗菌和杀螨效果，使用后对金黄色葡萄球菌的杀菌率达到了99％以上，对大肠杆菌杀菌率达到了100％，对屋尘螨杀螨率达到了95％以上，而对比例1-2在成分上发生变化，效果也发生变化。
试验例3洗涤体验试验
试验对象：实施例1-3与对比例1制得的羽绒服清洗液。
试验方法：量取300ml蓖麻油，然后浸入30g鸭绒，30分钟后拿出，并晾干，然后放入2ml清洗液+10L水中，搅拌20分钟，搅拌速度为45r/min，然后使用清水漂洗至无泡沫，观察清洗结果，具体结果如表3所示。
表3清洗结果
从表3中可以看出，实施例1-3清洗效果更好，洗后几乎不改变羽绒的蓬松度。
综上所述，本发明实施例1-3制得的羽绒服清洗液具有良好的防静电功效，具有良好的抗菌和杀螨效果，使用后不影响羽绒的蓬松度。
Claims (6)
1.一种羽绒服清洗液，其特征在于，主要由以下质量分数的成分组成：醇醚羧酸盐9-13％、椰油酰胺丙基甜菜碱8-12％、氨基酸表面活性剂5-7％、皂素1-3％、硅酸钠0.1-0.3％、pH缓冲剂1-3％、羧甲基壳聚糖1-3％、三乙醇胺2-4％、电解质0.5-1％和水55-70％。
2.根据权利要求1所述的羽绒服清洗液，其特征在于，由以下质量分数的成分组成：醇醚羧酸盐11％、椰油酰胺丙基甜菜碱10％、氨基酸表面活性剂6％、皂素2％、硅酸钠0.2％、pH缓冲剂2％、羧甲基壳聚糖2％、三乙醇胺3％、电解质0.8％和水63％。
3.根据权利要求1或2所述的羽绒服清洗液，其特征在于，所述的氨基酸表面活性剂为N-酰基谷氨酸。
4.根据权利要求1或2所述的羽绒服清洗液，其特征在于，所述的电解质由醋酸钠和氯化钠按质量比1:2-3组成。
5.根据权利要求1或2所述的羽绒服清洗液，其特征在于，所述的pH缓冲剂为柠檬酸。
6.根据权利要求1-5任一项所述的羽绒服清洗液的制备方法，其特征在于，步骤为，
S1：将醇醚羧酸盐、椰油酰胺丙基甜菜碱、氨基酸表面活性剂、皂素、羧甲基壳聚糖、三乙醇胺加入乳化锅中，加热至55-65℃，搅拌均匀，得乳液A；
S2：将硅酸钠、电解质加入水中至完全溶解，加入到步骤S1得到的乳液A中，搅拌均匀，得混合液B；
S3：使用pH缓冲剂调节步骤S2得到的混合液B的pH至6.0-8.0，降至室温即得。
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| CN107723131A (zh) * | 2017-09-25 | 2018-02-23 | 舒城县玉龙羽绒有限公司 | 一种羽绒去油脂试剂 |
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| CN109055022A (zh) * | 2018-06-08 | 2018-12-21 | 天津燕兆蓝天环保设备有限公司 | 广谱灭菌型羽绒服清洗液及其制造方法 |
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| CN106085644A (zh) * | 2016-06-29 | 2016-11-09 | 合肥云都棉花有限公司 | 新型羽绒服清洗剂 |
| CN106190675A (zh) * | 2016-07-14 | 2016-12-07 | 湖北立天生物工程有限公司 | 一种抑菌驱避螨虫洗衣片及其制备方法 |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107502474A (zh) * | 2017-07-31 | 2017-12-22 | 名臣健康用品股份有限公司 | 一种含有醇醚羧酸盐成分的液体洗涤剂组合物 |
| CN107794139A (zh) * | 2017-09-08 | 2018-03-13 | 安徽万利达羽绒制品有限公司 | 一种鸭毛去油脂试剂及其制备方法 |
| CN107723131A (zh) * | 2017-09-25 | 2018-02-23 | 舒城县玉龙羽绒有限公司 | 一种羽绒去油脂试剂 |
| CN109055022A (zh) * | 2018-06-08 | 2018-12-21 | 天津燕兆蓝天环保设备有限公司 | 广谱灭菌型羽绒服清洗液及其制造方法 |
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