CN106675819A - 一种防雾清洁剂及其制备方法 - Google Patents
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Abstract
本发明属于日用化工领域，具体涉及一种防雾清洁剂及其制备方法。本发明提供了一种防雾清洁剂，包括以下组分及其重量百分比：表面活性剂10‑20％、防雾剂5‑10％、原儿茶酸1‑5％、丙二醇醚25‑35％、甘油5‑10％、乙醇5‑10％、硼砂1‑5％和水5‑48％。本发明提供的防雾清洁剂不仅去污能力强，还能有效防雾。同时，本发明提供的防雾清洁剂具有杀菌、防静电、防尘、防污和防冻的作用，可保持玻璃透明光亮。
Description
技术领域
本发明属于日用化工领域，具体涉及一种防雾清洁剂及其制备方法。
背景技术
清洁剂是一种液体状态的用来洗涤衣物、清洗用具或清洁家具等东西的清洁产品。它采用多种新型表面活性剂，去污力强，漂洗容易，对皮肤无刺激，可以用于洗涤厨具，家具及水果瓜菜。作为专用型的玻璃清洁剂，属于公共事业硬表面清洁剂范围，也属于家庭清洁剂。玻璃清洁剂是一种专用在建筑物中的玻璃门窗、镜面及汽车玻璃等的清洁剂。但传统玻璃清洁剂清洁效果不好，需要多次进行清洗，且防雾效果差。
中国专利申请CN105316117A公开了一种防雾玻璃清洁剂，包括氧化胺、硅酮、椰子油烷醇酰胺、三乙醇胺、香精、十二烷基硫酸钠、冰醋酸、皂角胶、五水合硅酸钠、乙二醇丁醚和表面活性剂。该发明提供的防雾玻璃清洁剂，具有去污和防雾的作用，但其防雾效果有待提高。
中国专利申请CN104845750A公开了一种防雾玻璃清洁剂，各组分按重量份计：脂肪醇聚氧乙烯醚100份、0.5％的氨水30-40份、丙二醇单丁醚12-15份、琥珀酸烷基酯磺酸钠5-10份、丙稀酸甲酯5-10份和香橙精油0.1-2份。该发明提供的防雾玻璃清洁剂，具有去污和防雾的作用，但其防雾效果有待提高。
发明内容
为了解决现有技术中存在的问题，本发明的目的在于提供一种防雾清洁剂及其制备方法。本发明提供的防雾清洁剂不仅去污能力强，还能有效防雾。同时，本发明提供的防雾清洁剂具有杀菌、防静电、防尘、防污和防冻的作用，可保持玻璃透明光亮。
本发明提供了一种防雾清洁剂，包括以下组分及其重量百分比：
表面活性剂10-20％、防雾剂5-10％、原儿茶酸1-5％、丙二醇醚25-35％、甘油5-10％、乙醇5-10％、硼砂1-5％和水5-48％。丙二醇醚购于上海峰维化工有限公司。
本发明配伍合理科学，各组分相互作用，协同起清洁、防污的作用。同时，本发明提供的防雾清洁剂，能快速的在玻璃表面形成一种亲水纳米膜，有效防雾。
进一步地，所述的防雾清洁剂由以下组分及其重量百分比组成：
表面活性剂15％、防雾剂7.5％、原儿茶酸3％、丙二醇醚30％、甘油7.5％、乙醇7.5％、硼砂3％和水26.5％。
进一步地，所述表面活性剂由聚氧乙烯椰油酸酯、烷基酚聚氧乙烯醚和十二烷基硫酸钠按重量比2:1:2组成。聚氧乙烯椰油酸酯CAS NO：61791-29-5，烷基酚聚氧乙烯醚购于江苏省海安石化化工厂。
进一步地，所述防雾剂由丙烯酸甲酯、山梨醇酐棕榈酸酯和椰子油烷醇酰胺按重量比2:2:1组成。山梨醇酐棕榈酸酯CAS NO：26266-57-9，椰子油烷醇酰胺购于江苏泰利达集团。
同时，本发明还提供了一种防雾清洁剂的制备方法，包括以下步骤：先加入乙醇和水，边搅拌边加入丙二醇醚、表面活性剂和防雾剂，最后加入原儿茶酸、甘油和硼砂，搅拌均匀至透明，即得。
与现有技术相比，本发明提供的防雾清洁剂不仅去污能力强，还能有效防雾。同时，本发明提供的防雾清洁剂具有杀菌、防静电、防尘、防污和防冻的作用，可保持玻璃透明光亮。
具体实施方式
下面通过具体实施例对本发明进一步详细说明，这些实施例仅用于例证的目的，并不限制本发明的保护范围。
实施例1一种防雾清洁剂
所述防雾清洁剂由以下组分及其重量百分比组成：
聚氧乙烯椰油酸酯4％、烷基酚聚氧乙烯醚2％、十二烷基硫酸钠4％、丙烯酸甲酯2％、山梨醇酐棕榈酸酯2％、椰子油烷醇酰胺1％、原儿茶酸1％、丙二醇醚25％、甘油5％、乙醇5％、硼砂1％和水48％。
制备方法：先加入乙醇和水，边搅拌边加入丙二醇醚、聚氧乙烯椰油酸酯、烷基酚聚氧乙烯醚、十二烷基硫酸钠丙烯酸甲酯、山梨醇酐棕榈酸酯和椰子油烷醇酰胺，最后加入原儿茶酸、甘油和硼砂，搅拌均匀至透明，即得。
实施例2一种防雾清洁剂
所述防雾清洁剂由以下组分及其重量百分比组成：
聚氧乙烯椰油酸酯6％、烷基酚聚氧乙烯醚3％、十二烷基硫酸钠6％、丙烯酸甲酯3％、山梨醇酐棕榈酸酯3％、椰子油烷醇酰胺防雾剂1.5％、原儿茶酸3％、丙二醇醚30％、甘油7.5％、乙醇7.5％、硼砂3％和水26.5％。
制备方法与实施例1类似。
实施例3一种防雾清洁剂
所述防雾清洁剂由以下组分及其重量百分比组成：
聚氧乙烯椰油酸酯8％、烷基酚聚氧乙烯醚4％、十二烷基硫酸钠8％、丙烯酸甲酯4％、山梨醇酐棕榈酸酯4％、椰子油烷醇酰胺防雾剂2％、原儿茶酸5％、丙二醇醚35％、甘油10％、乙醇10％、硼砂5％和水5％。
制备方法与实施例1类似。
对比例1一种防雾清洁剂
所述防雾清洁剂由以下组分及其重量百分比组成：
聚氧乙烯椰油酸酯5％、烷基酚聚氧乙烯醚5％、十二烷基硫酸钠5％、丙烯酸甲酯3％、山梨醇酐棕榈酸酯3％、椰子油烷醇酰胺防雾剂1.5％、原儿茶酸3％、丙二醇醚30％、甘油7.5％、乙醇7.5％、硼砂3％和水26.5％。
制备方法与实施例1类似。
与实施例2的区别在于，将聚氧乙烯椰油酸酯、烷基酚聚氧乙烯醚和十二烷基硫酸钠的重量比2:1:2替换为1:1:1。
对比例2一种防雾清洁剂
所述防雾清洁剂由以下组分及其重量百分比组成：
聚氧乙烯椰油酸酯6％、烷基酚聚氧乙烯醚3％、十二烷基硫酸钠6％、丙烯酸甲酯2.5％、山梨醇酐棕榈酸酯2.5％、椰子油烷醇酰胺防雾剂2.5％、原儿茶酸3％、丙二醇醚30％、甘油7.5％、乙醇7.5％、硼砂3％和水26.5％。
制备方法与实施例1类似。
与实施例2的区别在于，将丙烯酸甲酯、山梨醇酐棕榈酸酯和椰子油烷醇酰胺的重量比2:2:1替换为1:1:1。
试验例一、去污效果测试
1.试验材料：实施例1-3及对比例1-2制备的防雾清洁剂。
2.试验方法：
1)试验用污垢由动物油、植物油、面粉、番茄酱、颗粒糖按重量比10:4:4:1:1组成；
2)取15cm×15cm玻璃，测重W1；将玻璃上涂覆一层约50g的污垢，于200℃下干燥1h，测重W2；
3)将5g防雾清洁剂均匀喷晒于玻璃上，室温下放置2h，然后在60℃热水流动下用海绵漂洗，烘箱烘干，测重W3；按如下公式，计算去污率。
去污率％＝(W2-W3)/(W2-W1)×100％
3.试验结果：去污效果测试结果见表1。
表1去污效果测试结果
| 组别 | 实施例1组 | 实施例2组 | 实施例3组 | 对比例1组 | 对比例2组 |
| 去污率/％ | 94.8 | 98.3 | 96.4 | 80.5 | 85.6 |
由表1知，本发明提供的防雾清洁剂的去污效果较好。而对比例1-2制备的防雾清洁剂的去污效果比实施例1-3制备的防雾清洁剂的效果差，说明本发明配伍合理科学，各组分相互作用，协同起清洁去污的作用，且当表面活性剂由聚氧乙烯椰油酸酯、烷基酚聚氧乙烯醚和十二烷基硫酸钠按重量比2:1:2组成时，去污效果最佳。
试验例二、防雾测试
1.试验材料：实施例1-3及对比例1-2制备的防雾清洁剂。
2.试验对象：冬季汽车挡风玻璃、正常浴室盥洗镜和冬季居家玻璃，各5组。
3.试验方法：
将实施例1-3及对比例1-2制备的防雾清洁剂分别均匀涂于冬季汽车挡风玻璃、正常浴室盥洗镜和冬季居家玻璃上，观察防雾效果持续有效时间，并记录。4.试验结果：防雾测试结果见表2。
表2防雾测试结果
由表2知，本发明提供的防雾清洁剂的防雾效果较好。而对比例1-2制备的防雾清洁剂的防雾效果比实施例1-3制备的防雾清洁剂的效果差，说明本发明配伍合理科学，各组分相互作用，协同起防雾的作用，且当防雾剂由丙烯酸甲酯、山梨醇酐棕榈酸酯和椰子油烷醇酰胺按重量比2:2:1组成时，防雾效果最佳。
Claims (5)
1.一种防雾清洁剂，其特征在于，包括以下组分及其重量百分比：
表面活性剂10-20％、防雾剂5-10％、原儿茶酸1-5％、丙二醇醚25-35％、甘油5-10％、乙醇5-10％、硼砂1-5％和水5-48％。
2.如权利要求1所述的雾清洁剂，其特征在于，由以下组分及其重量百分比组成：表面活性剂15％、防雾剂7.5％、原儿茶酸3％、丙二醇醚30％、甘油7.5％、乙醇7.5％、硼砂3％和水26.5％。
3.如权利要求1或2所述的防雾清洁剂，其特征在于，所述表面活性剂由聚氧乙烯椰油酸酯、烷基酚聚氧乙烯醚和十二烷基硫酸钠按重量比2:1:2组成。
4.如权利要求1或2所述的防雾清洁剂，其特征在于，所述防雾剂由丙烯酸甲酯、山梨醇酐棕榈酸酯和椰子油烷醇酰胺按重量比2:2:1组成。
5.如权利要求1-4任一所述的防雾清洁剂的制备方法，其特征在于，包括以下步骤：先加入乙醇和水，边搅拌边加入丙二醇醚、表面活性剂和防雾剂，最后加入原儿茶酸、甘油和硼砂，搅拌均匀至透明，即得。
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