CN106674417A - Acrylic foam tape composition and method for preparing acrylic foam tape composition - Google Patents
Acrylic foam tape composition and method for preparing acrylic foam tape composition Download PDFInfo
- Publication number
- CN106674417A CN106674417A CN201610816218.3A CN201610816218A CN106674417A CN 106674417 A CN106674417 A CN 106674417A CN 201610816218 A CN201610816218 A CN 201610816218A CN 106674417 A CN106674417 A CN 106674417A
- Authority
- CN
- China
- Prior art keywords
- acrylic
- agent
- foam tape
- foam
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title claims abstract description 171
- 239000006260 foam Substances 0.000 title claims abstract description 142
- 239000000203 mixture Substances 0.000 title claims abstract description 94
- 238000000034 method Methods 0.000 title claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 95
- 238000006243 chemical reaction Methods 0.000 claims abstract description 49
- 239000002390 adhesive tape Substances 0.000 claims abstract description 37
- 239000000463 material Substances 0.000 claims abstract description 28
- 239000000654 additive Substances 0.000 claims abstract description 20
- 230000000996 additive effect Effects 0.000 claims abstract description 20
- 239000000945 filler Substances 0.000 claims abstract description 20
- 239000012752 auxiliary agent Substances 0.000 claims description 55
- 230000004044 response Effects 0.000 claims description 31
- 239000000758 substrate Substances 0.000 claims description 30
- 239000000178 monomer Substances 0.000 claims description 28
- -1 nonyl ester Chemical class 0.000 claims description 23
- 239000011248 coating agent Substances 0.000 claims description 20
- 238000000576 coating method Methods 0.000 claims description 20
- 238000004026 adhesive bonding Methods 0.000 claims description 16
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 13
- 239000008267 milk Substances 0.000 claims description 11
- 210000004080 milk Anatomy 0.000 claims description 11
- 235000013336 milk Nutrition 0.000 claims description 11
- 239000002216 antistatic agent Substances 0.000 claims description 10
- 239000011521 glass Substances 0.000 claims description 10
- 229920002799 BoPET Polymers 0.000 claims description 8
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims description 8
- 238000006116 polymerization reaction Methods 0.000 claims description 8
- 150000002148 esters Chemical class 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- YFKBXYGUSOXJGS-UHFFFAOYSA-N 1,3-Diphenyl-2-propanone Chemical compound C=1C=CC=CC=1CC(=O)CC1=CC=CC=C1 YFKBXYGUSOXJGS-UHFFFAOYSA-N 0.000 claims description 4
- INQDDHNZXOAFFD-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOCCOC(=O)C=C INQDDHNZXOAFFD-UHFFFAOYSA-N 0.000 claims description 4
- VFZKVQVQOMDJEG-UHFFFAOYSA-N 2-prop-2-enoyloxypropyl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(=O)C=C VFZKVQVQOMDJEG-UHFFFAOYSA-N 0.000 claims description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 4
- LRRQSCPPOIUNGX-UHFFFAOYSA-N 2-hydroxy-1,2-bis(4-methoxyphenyl)ethanone Chemical compound C1=CC(OC)=CC=C1C(O)C(=O)C1=CC=C(OC)C=C1 LRRQSCPPOIUNGX-UHFFFAOYSA-N 0.000 claims description 3
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- 230000001458 anti-acid effect Effects 0.000 claims description 3
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical group CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 3
- 239000000975 dye Substances 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 3
- 239000011976 maleic acid Substances 0.000 claims description 3
- ANISOHQJBAQUQP-UHFFFAOYSA-N octyl prop-2-enoate Chemical compound CCCCCCCCOC(=O)C=C ANISOHQJBAQUQP-UHFFFAOYSA-N 0.000 claims description 3
- 150000002978 peroxides Chemical class 0.000 claims description 3
- 238000004017 vitrification Methods 0.000 claims description 3
- MSAHTMIQULFMRG-UHFFFAOYSA-N 1,2-diphenyl-2-propan-2-yloxyethanone Chemical compound C=1C=CC=CC=1C(OC(C)C)C(=O)C1=CC=CC=C1 MSAHTMIQULFMRG-UHFFFAOYSA-N 0.000 claims description 2
- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical compound CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 claims description 2
- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical group CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 claims description 2
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 claims description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 2
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 claims description 2
- 239000003822 epoxy resin Substances 0.000 claims description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 2
- 239000011494 foam glass Substances 0.000 claims description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims description 2
- NZIDBRBFGPQCRY-UHFFFAOYSA-N octyl 2-methylprop-2-enoate Chemical compound CCCCCCCCOC(=O)C(C)=C NZIDBRBFGPQCRY-UHFFFAOYSA-N 0.000 claims description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 2
- 239000000049 pigment Substances 0.000 claims description 2
- 229920000647 polyepoxide Polymers 0.000 claims description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 2
- 230000000475 sunscreen effect Effects 0.000 claims description 2
- 239000000516 sunscreening agent Substances 0.000 claims description 2
- 229940117958 vinyl acetate Drugs 0.000 claims description 2
- LEJBBGNFPAFPKQ-UHFFFAOYSA-N 2-(2-prop-2-enoyloxyethoxy)ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOC(=O)C=C LEJBBGNFPAFPKQ-UHFFFAOYSA-N 0.000 claims 2
- VUVPCQMETIENKA-UHFFFAOYSA-N C(C=C)(=O)O.C(C=C)(=O)O.C(C=C)(=O)O.C(C=C)(=O)O.CC(COC(C)COC(C)CO)O Chemical compound C(C=C)(=O)O.C(C=C)(=O)O.C(C=C)(=O)O.C(C=C)(=O)O.CC(COC(C)COC(C)CO)O VUVPCQMETIENKA-UHFFFAOYSA-N 0.000 claims 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 claims 1
- 235000011613 Pinus brutia Nutrition 0.000 claims 1
- 241000018646 Pinus brutia Species 0.000 claims 1
- LNCPIMCVTKXXOY-UHFFFAOYSA-N hexyl 2-methylprop-2-enoate Chemical compound CCCCCCOC(=O)C(C)=C LNCPIMCVTKXXOY-UHFFFAOYSA-N 0.000 claims 1
- 239000002304 perfume Substances 0.000 claims 1
- 235000013599 spices Nutrition 0.000 claims 1
- 238000001746 injection moulding Methods 0.000 abstract 3
- 239000012778 molding material Substances 0.000 abstract 3
- 239000002671 adjuvant Substances 0.000 abstract 2
- 239000000047 product Substances 0.000 description 24
- 239000007822 coupling agent Substances 0.000 description 12
- 239000004342 Benzoyl peroxide Substances 0.000 description 10
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 10
- 235000019400 benzoyl peroxide Nutrition 0.000 description 10
- 238000002156 mixing Methods 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 7
- 238000002347 injection Methods 0.000 description 6
- 239000007924 injection Substances 0.000 description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 5
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 4
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 4
- 230000003213 activating effect Effects 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 238000007711 solidification Methods 0.000 description 4
- 230000008023 solidification Effects 0.000 description 4
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 4
- 230000008859 change Effects 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 239000013530 defoamer Substances 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- LNMQRPPRQDGUDR-UHFFFAOYSA-N hexyl prop-2-enoate Chemical compound CCCCCCOC(=O)C=C LNMQRPPRQDGUDR-UHFFFAOYSA-N 0.000 description 2
- 238000005728 strengthening Methods 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 description 1
- VOBUAPTXJKMNCT-UHFFFAOYSA-N 1-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound CCCCCC(OC(=O)C=C)OC(=O)C=C VOBUAPTXJKMNCT-UHFFFAOYSA-N 0.000 description 1
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 1
- GENYBPRYOMJDAG-UHFFFAOYSA-N 3,4-dioctylphthalic acid Chemical compound CCCCCCCCC1=CC=C(C(O)=O)C(C(O)=O)=C1CCCCCCCC GENYBPRYOMJDAG-UHFFFAOYSA-N 0.000 description 1
- NQSLZEHVGKWKAY-UHFFFAOYSA-N 6-methylheptyl 2-methylprop-2-enoate Chemical compound CC(C)CCCCCOC(=O)C(C)=C NQSLZEHVGKWKAY-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000005662 Paraffin oil Substances 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 125000004386 diacrylate group Chemical group 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 229920001821 foam rubber Polymers 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/22—Expanded, porous or hollow particles
- C08K7/24—Expanded, porous or hollow particles inorganic
- C08K7/28—Glass
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/10—Homopolymers or copolymers of methacrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
- C09J7/24—Plastics; Metallised plastics based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
- C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
- C09J2301/124—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present on both sides of the carrier, e.g. double-sided adhesive tape
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2433/00—Presence of (meth)acrylic polymer
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2433/00—Presence of (meth)acrylic polymer
- C09J2433/006—Presence of (meth)acrylic polymer in the substrate
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesive Tapes (AREA)
Abstract
The invention provides an acrylic foam tape composition and a method for preparing the acrylic foam tape composition. The acrylic foam tape composition comprises a foam base material layer and adhesive tape layers on the upper and lower sides of the foam base material layer, wherein the foam base material layer is prepared from the following components in parts by weight: 100 parts of an acrylic mixture, 0.1 to 5 parts of a reaction adjuvant, 0.01 to 5 parts of a bridging agent, 0.1 to 10 parts of a porous filler and 1 to 10 parts of an additive; the adhesive tape layers are prepared from the following components in parts by weight: 100 parts of the acrylic mixture, 0.1 to 5 parts of the reaction adjuvant, 0.01 to 5 parts of the bridging agent, 0.1 to 10 parts of a tackifier and 1 to 10 parts of an additive. An acrylic foam tape is used for adhering an injection molding material of an automobile or an electronic product, so that the injection molding material can be permanently and fixedly adhered to an automobile body of the automobile and the electronic product; furthermore, the acrylic foam tape composition has the functions of preventing collision between the injection molding materials and preventing noise.
Description
Technical field
The present invention relates to foam tape technical field, in particular it relates to a kind of acrylic foam tape compositionss and preparation
The method of the acrylic foam tape.
Background technology
Automobile and electronic product surface would generally attach some ornaments, such as badge, plastic-injection thing etc..However, in order to
The surface energy for improving the application face of resistance to water and stain resistance, automobile and electronic product is very low, and ornament cannot be closely
Paste thereon.Therefore, all the time, before pasting ornament on automobile and electronic product, needs are located before doing on attachment surface
Reason (PRIMER process) so as to the strength adhesion strength with the durability and resistance to water for maintaining viscosity always.
The content of the invention
The invention provides a kind of acrylic foam tape compositionss and the method for preparing the acrylic foam tape, described
Acrylic system foam tape is used for automobile or the injection article of electronic product is pasted so that injection article can be sticked in permanently
On the vehicle body and electronic product of automobile, and there is the collision for preventing between injection article, prevent noise function.
Technical scheme is as follows：A kind of acrylic foam tape compositionss, including foam substrate layer and the foam
The adhesive tape layer of substrate layer upper and lower sides；The foam substrate layer includes each component of following weight portion：
The adhesive tape layer includes each component of following weight portion：
Mould release membrance is coated with the side adhesive tape layer or both sides adhesive tape layer of the acrylic foam tape.
It is preferred that in acrylic foam tape compositionss, the acrylic mixture includes 75~99 parts flexible sub- gram
Power monomer and 1~25 part of rigid acrylic monomer are mixed.
The vitrification point (Tg) of the homopolymer of the flexible acrylic monomer is less than -20 DEG C.The flexible acrylic
Monomer forms homopolymer because of polyreaction, part, partly forms copolymer with following rigid acrylic monomers.It is described flexible sub-
The polymer that gram force monomer is formed has the effect of the initial stage adhesion strength and adhesion maintenance energy for strengthening foam tape.It is described flexible sub-
When the consumption of gram force monomer is less than 75 parts, resulting acrylic foam tape adhesion strength is weaker, and during more than 99 weight portion, it is described
The weatherability of acrylic foam tape is poor, and high temperature cohesiveness is poor.Rigid acrylic monomer the containing in acrylic mixture
When amount is less than 1 part, the reduction of resulting acrylic foam tape cohesiveness, weatherability reduction, the problems such as adhesion strength is weakened, conversely,
When content is more than 25 parts, the problem of gained acrylic foam tape initial stage adhesion strength reduction.
The flexible acrylic monomer is selected from butyl acrylate, butyl methacrylate, Hexyl 2-propenoate, methacrylic acid
Own ester, 1-Octyl acrylate, n octyl methacrylate, Isooctyl acrylate monomer, 2-Propenoic acid, 2-methyl-, isooctyl ester, acrylic acid-2-ethyl
Own ester, 2-Ethylhexyl Methacrylate, vinylacetate, one kind in different nonyl ester, methacrylic acid isononyl, two kinds or two
Plant the mixture of the above.
The vitrification point (Tg) of the rigid acrylic monomer is more than 90 DEG C, and the rigid acrylic monomer leads to
Polyreaction is crossed, part forms homopolymer, partly forms copolymer with above-mentioned flexible acrylic monomer.The rigid acrylic
Monomer has the effect of the cohesiveness for strengthening foam tape.
The rigid acrylic monomer is selected from acrylic acid, methacrylic acid, maleic acid, fumaric acid, acrylamide, N- ethylene
One kind, two or more mixture in base ketopyrrolidine, N- caprolactams, acrylonitrile.
The reaction promoter is used to help the acrylic monomer polymerization, and the reaction promoter is from photoreaction auxiliary agent and warm
The mixture of reaction promoter.The polymerization efficiency of the photoreaction auxiliary agent is not enough, is used in mixed way with thermal response auxiliary agent, can adjust poly-
The molecular weight and viscosity of compound reaches required scope.
The photoreaction auxiliary agent is selected from Benzoinum methyl ether, benzoin isopropyl ether, methyl ether anisoin, Benzoinum, benzyl
One kind of base ketone or its any mixture.The thermal response auxiliary agent is selected from the peroxide system containing benzoyl peroxide, isobutyl
Base azonitrile or amine system thermal response auxiliary agent.
In acrylic foam tape compositionss, the consumption of the reaction promoter is 0.1~5 weight portion.When the reaction
When auxiliary dosage part is less than 0.1 weight portion, may result in monomer and be not polymerized, the contrary reaction promoter consumption is more than 5 weight
During part, the problem that the polymer molecular weight is reduced is likely to result in again.It is often used without when reaction is helped using this photoreaction
Reaction dissolvent.
The bridging agent is poly- by acrylic in acrylic monomer polymerization process or during adhesive tape layer performance viscous force
The effect of the initial stage adhesion strength of the bridge formation reinforcing foam tape between conjunction.The bridging agent be light bridging agent, hot bridging agent or its
Mixture.The bridging agent is diacrylate system bridge formation, triacrylate system bridging agent, aziridine system bridging agent or asphalt mixtures modified by epoxy resin
Fat system bridging agent.Specifically, the bridging agent be hexanediyl ester, glycol diacrylate, diethylene glycol dipropyl
Olefin(e) acid ester, triethylene glycol diacrylate, propylene glycol diacrylate, propylene glycol diacrylate, the propylene of tripropylene glycol two
Acid esters diacrylate system bridging agent.
In acrylic foam tape compositionss, the amount ranges of the bridging agent are 0.01~5 weight portion.The frame
When the usage amount of bridge agent is less than 0.01 weight, there is baneful influence to the acrylic foam tape cohesiveness or weatherability,
When on the contrary more than 5 weight, the acrylic foam tape can be caused to have initial stage adhesion strength and adhesion physical property to decline.
In acrylic foam tape compositionss, viscosifier amount ranges in the acrylic foam tape are
0.1~10 weight portion.When the viscosifier usage amount is less than 0.1 weight portion, the acrylic foam tape thickening effect can be caused
Fruit imperfection, when using more than 10 weight portions on the contrary, acrylic foam tape cohesiveness declines.The viscosifier are rosin series increasing
Stick, terpenic series viscosifier, one or more of mixture in Petropols system viscosifier.
The porous filler thing is hollow glass micropearl or foam glass, when the acrylic monomer is polymerized, is passed through
Heat expands the foam tape to form porous.In order that foam tape has the effect for preferably absorbing noise, the knot in the hole
Structure is spherical.In acrylic foam tape compositionss, the consumption of the porous filler thing is 0.1~10 weight portion.It is described
When porous filler thing consumption is less than 0.1 weight portion, the acrylic foam tape prevents noise result poor, on the contrary more than 10 weights
When amount part uses, the acrylic foam tape adhesion strength declines.
The additive includes couplant, and antistatic agent, interfacial agent, modified milk, dyestuff, pigment, sunscreen is antiacid
Agent etc..
The foam tape of the present invention is used for after the exterior of automobile or electronic product pastes, and experience illumination or drenches with rain, with when
Between passage, decline, and the coupling agent increased the ruggedness of the foam tape, promote the frame of acrylic monomer
Bridge, forms three-dimensional netted, shows the effect of permanent adhesion.In acrylic foam tape compositionss, the coupling
The consumption that agent is is 0.1~2 weight portion.When the couplant consumption is less than 0.1 weight portion, the frame of the foam tape can be caused
Bridge and cohesiveness are bad, when contrary usage amount is more than 2 weight portion, the foam tape adhesion strength can be caused to decline.
The antistatic agent has prevents automobile and electronic product surface from the function of electrostatic occurring.In acrylic foam rubber
In band compositionss, the antistatic agent obtains consumption for 1~5 weight portion.When the antistatic agent consumption is less than 1 weight portion, can make
Into the foam tape anti-static effect imperfection, when contrary usage amount is more than 5 weight portion, the foam tape can be caused to adhere
Power declines.
The interfacial agent is can to work as dispersant and defoamer is used, and the function of dispersant is to prevent porous filler agent
Precipitation and reduce the surface tension of foam tape, the function of defoamer is compacting bubble formation and increases acrylic monomer
Polymerization conversion ratio.In acrylic foam tape compositionss, the interfacial agent consumption is 0.05~2 weight portion.The boundary
The usage amount of face activating agent can cause the foam tape to disperse bad less than 0.05 weight portion, and entrapped air pockets, usage amount exceedes
During 2 weight portion, the foam tape cohesiveness can be caused low, poor durability.
The modified milk adds to improve tolerance to cold.In acrylic foam tape compositionss, the processing
Newborn consumption is 1~10 weight portion.When the modified milk consumption is less than 1 weight portion, it is impossible to improve the tolerance to cold of the foam tape,
When contrary usage amount is more than 10 weight portion, the ruggedness of the foam tape may be weakened.The modified milk is selected from but does not limit
In dioctyl phthalic acid system, paraffin oil, naphthalene.
In addition, acrylic foam tape compositionss of the present invention, are maintaining that in the range of its performance dyestuff, face can be added
Material, ultraviolet screening agent, antiacid agent etc..The amount of addition is can be different according to the characteristic of the final product for needing.
The method for preparing the acrylic foam tape with above-mentioned acrylic foam tape compositionss, comprises the steps：
S1) press formula and weigh the acrylic mixture, reaction promoter, bridging agent, porous filler and additive, mixing
Uniformly obtain base material mixture；
S2) gained base material mixture is coated on roasting film by coating machine, the roasting film is PET film；
S3) by S2) products therefrom continues through ultraviolet irradiation and is thermally formed foam base material；
S4) press formula and weigh the acrylic mixture, reaction promoter, bridging agent, viscosifier and additive, mixing is equal
It is even to obtain gluing agent composition；
S5) gained gluing agent composition is coated to the upper and lower surface of the foam base material；
S6) by S5) products therefrom continues through ultraviolet irradiation and heating occurs polyreaction, and in the foam base material
Both sides formed adhesive tape layer.
Be additionally included in step S6) gained adhesive tape layer on adhere to mould release membrance the step of.
Step S3) and step S6) in, the power of the ultraviolet irradiation machine that ultraviolet irradiation is used is 30W~150W,
Heating-up temperature is 60~120 DEG C.First irradiated with ultraviolet in polymerization process and be polymerized, then irradiated with ultraviolet and heated while gathering
Close.Responseless oligomer and monomer are reduced in the polymerization process, the conversion ratio of polymer reaches more than 99%.
Beneficial effects of the present invention are：Acrylic foam tape compositionss of the present invention and prepare the acrylic foam
The method of adhesive tape, the injection article for automobile or electronic product is pasted, and injection article can be allowed to paste and be permanently affixed at automobile
On vehicle body and electronic product, and with noise control sound function.
Specific embodiment
In order that the goal of the invention of the present invention, technical scheme and technique effect become more apparent, with reference to concrete reality
The present invention is described further to apply mode.It should be understood that specific embodiment described herein, is only used for explaining the present invention,
It is not intended to limit the present invention.
Embodiment 1
A kind of acrylic foam tape compositionss, including the adhesive tape layer of foam substrate layer and the foam substrate layer upper and lower sides；
The foam substrate layer includes each component of following weight portion：
The adhesive tape layer includes each component of following weight portion：
In the foam substrate layer, flexible acrylic selects acrylic acid-2-ethyl caproite in the acrylic mixture, uses
Measure as 850g, rigid acrylic selects acrylic acid, and consumption is 150g；Reaction promoter includes photoreaction auxiliary agent and thermal response auxiliary agent,
Wherein photoreaction auxiliary agent methyl ether anisoin, consumption is 10g, thermal response auxiliary agent benzoyl peroxide, and consumption is 8g；Frame
Bridge agent hexanediyl ester, consumption is 30g；The porous filler thing hollow glass micropearl K1 of 3M companies, consumption is
70g；Coupling agent agent, consumption is 5g；Modified milk, consumption is 30g.
The adhesive tape layer, flexible acrylic selects the acrylic acid-2-ethyl caproite, consumption to be in the acrylic mixture
900g, rigid acrylic selects acrylic acid, and consumption is 100g；Reaction promoter includes photoreaction auxiliary agent and thermal response auxiliary agent, wherein
Photoreaction auxiliary agent benzyl ketone, consumption is 10g, thermal response auxiliary agent benzoyl peroxide, and consumption is 8g；Bridging agent hexanediol
Diacrylate, consumption is 30g；Rosin based tackifiers 1g；Coupling agent agent, consumption is 5g, antistatic agent 20g, interfacial agent
3g。
The acrylic foam tape preparation method, comprises the steps：
S1) press formula and weigh the acrylic mixture, reaction promoter, bridging agent, porous filler and additive, mixing
Uniformly obtain base material mixture；
S2) gained base material mixture is coated on roasting film by coating machine, the roasting film is PET film, coating thickness is
900um；
S3) by S2) products therefrom continuously passed through the ultraviolet of 100W and irradiated 3 minutes, then heated with 60 degree of internal temperature
It solidify to form foam base material；
S4) press formula and weigh the acrylic mixture, reaction promoter, bridging agent, viscosifier and additive, mix homogeneously
Obtain gluing agent composition；
S5) gained gluing agent composition is coated to the upper and lower surface of the foam base material, coating thickness is 50um；S6)
By S5) products therefrom continuously passed through the ultraviolet of 100W and irradiated 3 minutes, be then heating and curing with 60 degree of internal temperature and be polymerized
Reaction, and form adhesive tape layer in the both sides of the foam base material.
Embodiment 2
A kind of acrylic foam tape compositionss, including the adhesive tape layer of foam substrate layer and the foam substrate layer upper and lower sides；
The foam substrate layer includes each component of following weight portion：
The adhesive tape layer includes each component of following weight portion：
In the foam substrate layer, flexible acrylic selects acrylic acid-2-ethyl caproite in the acrylic mixture, uses
Measure as 850g, rigid acrylic selects acrylic acid, and consumption is 150g；Reaction promoter includes photoreaction auxiliary agent and thermal response auxiliary agent,
Wherein photoreaction auxiliary agent Benzoinum methyl ether, consumption is 10g, thermal response auxiliary agent benzyl ketone, and consumption is 40g；Bridging agent is used
Hexanediyl ester, consumption is 20g；The porous filler thing hollow glass micropearl K1 of 3M companies, consumption is 10g；It is even
Connection agent agent, consumption is 50g；Modified milk, consumption is 20g.
The adhesive tape layer, flexible acrylic selects the acrylic acid-2-ethyl caproite, consumption to be in the acrylic mixture
920g, rigid acrylic selects acrylic acid, and consumption is 80g；Reaction promoter includes photoreaction auxiliary agent and thermal response auxiliary agent, wherein light
Reaction promoter Benzoinum methyl ether, consumption is 10g, thermal response auxiliary agent benzoyl peroxide, and consumption is 20g；Bridging agent is used
Hexanediyl ester, consumption is 20g；Rosin based tackifiers 5g；Coupling agent agent, consumption is 10g, antistatic agent 10g, interface
Activating agent 10g.
The acrylic foam tape preparation method, comprises the steps：
S1) press formula and weigh the acrylic mixture, reaction promoter, bridging agent, porous filler and additive, mixing
Uniformly obtain base material mixture；
S2) gained base material mixture is coated on roasting film by coating machine, the roasting film is PET film, coating thickness is
900um；
S3) by S2) products therefrom continuously passed through the ultraviolet of 90W and irradiated 3 minutes, then heated with 120 degree of internal temperature
It solidify to form foam base material；
S4) press formula and weigh the acrylic mixture, reaction promoter, bridging agent, viscosifier and additive, mix homogeneously
Obtain gluing agent composition；
S5) gained gluing agent composition is coated to the upper and lower surface of the foam base material, coating thickness is 50um；
S6) by S5) products therefrom continuously passed through the ultraviolet of 80W and irradiated 3 minutes, then heated with 100 degree of internal temperature
There is polyreaction in solidification, and form adhesive tape layer in the both sides of the foam base material.
Embodiment 3
A kind of acrylic foam tape compositionss, including the adhesive tape layer of foam substrate layer and the foam substrate layer upper and lower sides；
The foam substrate layer includes each component of following weight portion：
The adhesive tape layer includes each component of following weight portion：
In the foam substrate layer, flexible acrylic selects acrylic acid-2-ethyl caproite in the acrylic mixture, uses
Measure as 850g, rigid acrylic selects acrylic acid, and consumption is 150g；Reaction promoter includes photoreaction auxiliary agent and thermal response auxiliary agent,
Wherein photoreaction auxiliary agent Benzoinum, consumption is 10g, thermal response auxiliary agent amine system thermal response auxiliary agent, and consumption is 20g；Bridging agent
With hexanediyl ester, consumption is 10g；The porous filler thing hollow glass micropearl K1 of 3M companies, consumption is 50g；
Coupling agent agent, consumption is 5g；Modified milk, consumption is 5g.
The adhesive tape layer, flexible acrylic selects butyl methacrylate in the acrylic mixture, and consumption is 940g,
Rigid acrylic selects acrylic acid-2-ethyl caproite, and consumption is 60g；Reaction promoter includes photoreaction auxiliary agent and thermal response auxiliary agent,
Wherein photoreaction auxiliary agent Benzoinum methyl ether, consumption is 10g, thermal response auxiliary agent benzoyl peroxide, and consumption is 40g；Frame
Bridge agent hexanediyl ester, consumption is 30g；Petropols system viscosifier 10g；Coupling agent agent, consumption is 10g, is prevented quiet
Electric agent 20g, interfacial agent 30g.
The acrylic foam tape preparation method is prepared, is comprised the steps：
S1) press formula and weigh the acrylic mixture, reaction promoter, bridging agent, porous filler and additive, mixing
Uniformly obtain base material mixture；
S2) gained base material mixture is coated on roasting film by coating machine, the roasting film is PET film, coating thickness is
900um；
S3) by S2) products therefrom continuously passes through the ultraviolet of 60W and irradiates 3 minutes, then adds thermosetting with 90 degree of internal temperature
Change forms foam base material；
S4) press formula and weigh the acrylic mixture, reaction promoter, bridging agent, viscosifier and additive, mixing is equal
It is even to obtain gluing agent composition；
S5) gained gluing agent composition is coated to the upper and lower surface of the foam base material, coating thickness is 50um；
S6) by S5) products therefrom continuously passes through the ultraviolet of 30W and irradiates 3 minutes, then adds thermosetting with 60 degree of internal temperature
Change and polyreaction occurs, and adhesive tape layer is formed in the both sides of the foam base material.
Embodiment 4
A kind of acrylic foam tape compositionss, including the adhesive tape layer of foam substrate layer and the foam substrate layer upper and lower sides；
The foam substrate layer includes each component of following weight portion：
The adhesive tape layer includes each component of following weight portion：
In the foam substrate layer, flexible acrylic is from Hexyl 2-propenoate and different nonyl ester in the acrylic mixture
Mixture, consumption is 750g, and rigid acrylic selects NVP, and consumption is 250g；Reaction promoter includes that light is anti-
Answer auxiliary agent and thermal response auxiliary agent, wherein photoreaction auxiliary agent benzyl ketone, consumption is 5g, thermal response auxiliary agent benzoyl peroxide,
Consumption is 5g；Bridging agent hexanediyl ester, consumption is 0.1g；Porous filler thing is micro- with the hollow glass of 3M companies
Pearl K1, consumption is 10g；Coupling agent agent, consumption is 50g；Modified milk, consumption is 50g.
The adhesive tape layer, flexible acrylic selects the butyl methacrylate, consumption to be in the acrylic mixture
940g, rigid acrylic selects N- caprolactams, and consumption is 60g；Reaction promoter includes photoreaction auxiliary agent and thermal response
Auxiliary agent, wherein photoreaction auxiliary agent Benzoinum methyl ether, consumption is 5g, thermal response auxiliary agent benzoyl peroxide, and consumption is 5g；
Bridging agent hexanediyl ester, consumption is 0.1g；Terpenic series viscosifier 50g；Coupling agent agent, consumption is 50g, antistatic
Agent 20g, interfacial agent 30g.
The acrylic foam tape method is prepared, is comprised the steps：
S1) press formula and weigh the acrylic mixture, reaction promoter, bridging agent, porous filler and additive, mixing
Uniformly obtain base material mixture；
S2) gained base material mixture is coated on roasting film by coating machine, the roasting film is PET film, coating thickness is
900um；
S3) by S2) products therefrom continuously passed through the ultraviolet of 150W and irradiated 3 minutes, then heated with 60 degree of internal temperature
It solidify to form foam base material；
S4) press formula and weigh the acrylic mixture, reaction promoter, bridging agent, viscosifier and additive, mix homogeneously
Obtain gluing agent composition；
S5) gained gluing agent composition is coated to the upper and lower surface of the foam base material, coating thickness is 50um；
S6) by S5) products therefrom continuously passed through the ultraviolet of 120W and irradiated 3 minutes, then heated with 60 degree of internal temperature
There is polyreaction in solidification, and form adhesive tape layer in the both sides of the foam base material.
Embodiment 5
A kind of acrylic foam tape compositionss, including the adhesive tape layer of foam substrate layer and the foam substrate layer upper and lower sides；
The foam substrate layer includes each component of following weight portion：
The adhesive tape layer includes each component of following weight portion：
In the foam substrate layer, flexible acrylic selects the 1-Octyl acrylate, consumption to be in the acrylic mixture
990g, from N- caprolactams and the mixture of acrylonitrile, consumption is 10g to rigid acrylic；Reaction promoter includes light
Reaction promoter and thermal response auxiliary agent, wherein photoreaction auxiliary agent Benzoinum methyl ether, consumption is 10g, thermal response auxiliary agent peroxide
Change benzoyl, consumption is 15g；Bridging agent propylene glycol diacrylate, consumption is 40g；Porous filler thing 3M companies
Hollow glass micropearl K1, consumption is 1g；Coupling agent agent, consumption is 30g；Modified milk, consumption is 30g.
The adhesive tape layer, flexible acrylic selects the acrylic acid-2-ethyl caproite, consumption to be in the acrylic mixture
940g, rigid acrylic selects acrylic acid, and consumption is 60g；Reaction promoter includes photoreaction auxiliary agent and thermal response auxiliary agent, wherein light
Reaction promoter Benzoinum methyl ether, consumption is 15g, thermal response auxiliary agent benzoyl peroxide, and consumption is 10g；Bridging agent is used
Hexanediyl ester, consumption is 50g；Terpenic series viscosifier 100g；Coupling agent agent, consumption is 5g, antistatic agent 2g, interface
Activating agent 3g.
The acrylic foam tape method is prepared, is comprised the steps：
S1) press formula and weigh the acrylic mixture, reaction promoter, bridging agent, porous filler and additive, mixing
Uniformly obtain base material mixture；
S2) gained base material mixture is coated on roasting film by coating machine, the roasting film is PET film, coating thickness is
900um；
S3) by S2) products therefrom continuously passed through the ultraviolet of 140W and irradiated 3 minutes, then heated with 80 degree of internal temperature
It solidify to form foam base material；
S4) press formula and weigh the acrylic mixture, reaction promoter, bridging agent, viscosifier and additive, mix homogeneously
Obtain gluing agent composition；
S5) gained gluing agent composition is coated to the upper and lower surface of the foam base material, coating thickness is 50um；
S6) by S5) products therefrom continuously passed through the ultraviolet of 120W and irradiated 3 minutes, then heated with 60 degree of internal temperature
There is polyreaction in solidification, and form adhesive tape layer in the both sides of the foam base material.
Embodiment 6
A kind of acrylic foam tape compositionss, including the adhesive tape layer of foam substrate layer and the foam substrate layer upper and lower sides；
The foam substrate layer includes each component of following weight portion：
The adhesive tape layer includes each component of following weight portion：
In the foam substrate layer, flexible acrylic is from butyl acrylate and metering system in the acrylic mixture
The mixture of sour isononyl, consumption is 800g, and rigid acrylic is from acrylamide and the mixture of maleic acid, consumption
200g；Reaction promoter includes photoreaction auxiliary agent and thermal response auxiliary agent, and wherein photoreaction auxiliary agent uses the Benzoinum methyl ether, consumption to be
10g, thermal response auxiliary agent benzoyl peroxide, consumption is 30g；Bridging agent tripropylene glycol diacrylate, consumption is 25g；
The porous filler thing hollow glass micropearl K1 of 3M companies, consumption is 60g；Coupling agent agent, consumption is 5g；Modified milk, consumption
For 15g.
The adhesive tape layer, flexible acrylic selects the acrylic acid-2-ethyl caproite, consumption to be in the acrylic mixture
940g, rigid acrylic selects acrylic acid, and consumption is 60g；Reaction promoter includes photoreaction auxiliary agent and thermal response auxiliary agent, wherein light
Reaction promoter Benzoinum methyl ether, consumption is 10g, thermal response auxiliary agent benzoyl peroxide, and consumption is 5g；Bridging agent is used
Hexanediyl ester, consumption is 40g；Rosin based tackifiers 60g；Coupling agent agent, consumption is 5g, antistatic agent 20g, interface
Activating agent 25g.
The acrylic foam tape method is prepared, is comprised the steps：
S1) press formula and weigh the acrylic mixture, reaction promoter, bridging agent, porous filler and additive, mixing
Uniformly obtain base material mixture；
S2) gained base material mixture is coated on roasting film by coating machine, the roasting film is PET film, coating thickness is
900um；
S3) by S2) products therefrom continuously passed through the ultraviolet of 100W and irradiated 3 minutes, then heated with 60 degree of internal temperature
It solidify to form foam base material；
S4) press formula and weigh the acrylic mixture, reaction promoter, bridging agent, viscosifier and additive, mix homogeneously
Obtain gluing agent composition；
S5) gained gluing agent composition is coated to the upper and lower surface of the foam base material, coating thickness is 50um；
S6) by S5) products therefrom continuously passed through the ultraviolet of 130W and irradiated 3 minutes, then heated with 100 degree of internal temperature
There is polyreaction in solidification, and form adhesive tape layer in the both sides of the foam base material.
To detect the performance of acrylic foam tape of the present invention, the present inventor is to embodiment 1-3 gained acrylic bubble
Cotton tape performance is detected that detection method and result are as follows：
It is foundation in modes such as ASTM D3121-94, D3654, D3330, with 1 inch of width, with the speed of 300mm/min
Spend the power upheld by 180 degree direction and have rated adhesion strength.Adhesion unit of force is kgf/inch, as a result such as following (table 1).
The 1-3 of the present invention of table 1 gained acrylic foam tape performance detections
Above content is to combine specific preferred implementation further description made for the present invention, it is impossible to assert
The present invention be embodied as be confined to these explanations.For general technical staff of the technical field of the invention,
On the premise of present inventive concept, its framework form can be flexible and changeable, can be with subseries product.Simply make some
Simple deduction or replace, should all be considered as belonging to the scope of patent protection that the present invention is determined by the claims submitted to.
Claims (12)
1. a kind of acrylic foam tape compositionss, it is characterised in that including foam substrate layer and the foam substrate layer upper and lower sides
Adhesive tape layer；The foam substrate layer includes each component of following weight portion：
The adhesive tape layer includes each component of following weight portion：
2. acrylic foam tape compositionss as claimed in claim 1, it is characterised in that in acrylic foam tape compositionss
In, the acrylic mixture includes that 75~99 parts of flexible acrylic monomers and 1~25 part of rigid acrylic monomer are mixed.
3. acrylic foam tape compositionss as claimed in claim 2, it is characterised in that the glass of the flexible acrylic monomer
Glass temperature (Tg) is less than -20 DEG C；The flexible acrylic monomer is selected from butyl acrylate, butyl methacrylate, propylene
The own ester of acid, N-Hexyl methacrylate, 1-Octyl acrylate, n octyl methacrylate, Isooctyl acrylate monomer, methacrylic acid is different pungent
Ester, acrylic acid-2-ethyl caproite, 2-Ethylhexyl Methacrylate, vinylacetate, different nonyl ester, methacrylic acid isononyl
In one kind, two or more mixture.
4. acrylic foam tape compositionss as claimed in claim 2, it is characterised in that the rigid acrylic monomer
Vitrification point (Tg) is more than 90 DEG C；The rigid acrylic monomer is selected from acrylic acid, methacrylic acid, maleic acid, rich horse
One kind in acid, acrylamide, NVP, N- caprolactams, acrylonitrile, two or more
Mixture.
5. acrylic foam tape compositionss as described in any one of claim 1-4, it is characterised in that the reaction promoter choosing
With light reaction promoter and the mixture of thermal response auxiliary agent；The photoreaction auxiliary agent selected from Benzoinum methyl ether, benzoin isopropyl ether,
Methyl ether anisoin, Benzoinum, one kind of benzyl ketone or its any mixture；The thermal response auxiliary agent is selected from and contains peroxidating
The peroxide system of benzoyl, isobutyl group azonitrile or amine system thermal response auxiliary agent.
6. acrylic foam tape compositionss as described in any one of claim 1-4, it is characterised in that the bridging agent is two
Acrylic ester bridge formation, triacrylate system bridging agent, aziridine system bridging agent or epoxy resin bridging agent.
7. acrylic foam tape compositionss as claimed in claim 6, it is characterised in that the bridging agent is hexanediol dipropyl
Olefin(e) acid ester, glycol diacrylate, diethylene glycol diacrylate, triethylene glycol diacrylate, Propylene Glycol diacrylate
Ester, propylene glycol diacrylate, tripropylene glycol diacrylate diacrylate system bridging agent.
8. acrylic foam tape compositionss as described in any one of claim 1-4, it is characterised in that the viscosifier are pine
Perfume (or spice) system viscosifier, terpenic series viscosifier, one or more of mixture in Petropols system viscosifier.
9. acrylic foam tape compositionss as described in any one of claim 1-4, it is characterised in that the porous filler
Thing is hollow glass micropearl or foam glass.
10. acrylic foam tape compositionss as described in any one of claim 1-4, it is characterised in that the additive bag
Include couplant, antistatic agent, interfacial agent, modified milk, dyestuff, pigment, sunscreen, antiacid agent.
11. sides that acrylic foam tape is prepared with the acrylic foam tape compositionss described in any one of claim 1-10
Method, it is characterised in that comprise the steps：
S1) press formula and weigh the acrylic mixture, reaction promoter, bridging agent, porous filler and additive, mix homogeneously
Obtain base material mixture；
S2) gained base material mixture is coated on roasting film by coating machine, the roasting film is PET film；
S3) by S2) products therefrom continues through ultraviolet irradiation and is thermally formed foam base material；
S4) press formula and weigh the acrylic mixture, reaction promoter, bridging agent, viscosifier and additive, mix homogeneously is obtained
Gluing agent composition；
S5) gained gluing agent composition is coated to the upper and lower surface of the foam base material；
S6) by S5) products therefrom continues through ultraviolet irradiation and heating occurs polyreaction, and the two of the foam base material
Side forms adhesive tape layer.
12. methods for preparing acrylic foam tape as claimed in claim 11, it is characterised in that step S3) and step
Rapid S6) in, the power of the ultraviolet irradiation machine that ultraviolet irradiation is used is 30W~150W, and heating-up temperature is 60~120 DEG C.It is poly-
First irradiated with ultraviolet during conjunction and be polymerized, then polymerization simultaneously is irradiated and heated with ultraviolet.Reduce not in the polymerization process
There are the oligomer and monomer of reaction, the conversion ratio of polymer reaches more than 99%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610816218.3A CN106674417A (en) | 2016-09-10 | 2016-09-10 | Acrylic foam tape composition and method for preparing acrylic foam tape composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610816218.3A CN106674417A (en) | 2016-09-10 | 2016-09-10 | Acrylic foam tape composition and method for preparing acrylic foam tape composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106674417A true CN106674417A (en) | 2017-05-17 |
Family
ID=58839363
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610816218.3A Pending CN106674417A (en) | 2016-09-10 | 2016-09-10 | Acrylic foam tape composition and method for preparing acrylic foam tape composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106674417A (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109504299A (en) * | 2018-11-13 | 2019-03-22 | 江苏朗臣新材料科技有限公司 | A kind of preparation method of foam tape base material |
| CN109796894A (en) * | 2018-12-26 | 2019-05-24 | 张家港康得新光电材料有限公司 | A kind of foam tape and preparation method thereof |
| CN109825201A (en) * | 2018-12-26 | 2019-05-31 | 张家港康得新光电材料有限公司 | A kind of bonding structure and preparation method thereof |
| CN109825213A (en) * | 2018-12-26 | 2019-05-31 | 张家港康得新光电材料有限公司 | A kind of foam tape and preparation method thereof |
| CN110283558A (en) * | 2019-07-19 | 2019-09-27 | 厦门市垄江工业制品有限公司 | A kind of foam dust-proof cushion gum and preparation method thereof |
| CN111548754A (en) * | 2020-03-20 | 2020-08-18 | 安徽富印新材料有限公司 | Anti-staining acrylic foam adhesive tape and preparation method thereof |
| WO2020225445A1 (en) | 2019-05-08 | 2020-11-12 | Tesa Se | A prismatic battery module using aseismatic damping glue |
| CN112680139A (en) * | 2020-12-23 | 2021-04-20 | 苏州赛伍应用技术股份有限公司 | Acrylic foaming damping foam and preparation method thereof |
| CN113025242A (en) * | 2021-04-07 | 2021-06-25 | 艾利(昆山)有限公司 | Pressure-sensitive adhesive composition and acrylic foam adhesive tape with same |
| CN113429509A (en) * | 2021-07-16 | 2021-09-24 | 苏州环明电子科技有限公司 | UV acrylate foam and preparation method and application thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102702991A (en) * | 2012-06-12 | 2012-10-03 | 安徽省郎溪县阿拉法胶粘制品有限公司 | Acrylic double-faced adhesive tape and preparation method thereof |
| CN103254823A (en) * | 2012-07-10 | 2013-08-21 | 东莞市富印胶粘科技有限公司 | Foam adhesive tape and preparation method thereof |
| CN103254825A (en) * | 2012-07-10 | 2013-08-21 | 东莞市富印胶粘科技有限公司 | Non-base material adhesive tape and preparation method thereof |
| CN103635554A (en) * | 2011-07-01 | 2014-03-12 | 日东电工株式会社 | Multilayer adhesive article and adhesive sheet |
| CN104449446A (en) * | 2014-11-25 | 2015-03-25 | 东莞市富印胶粘科技有限公司 | UV curable high-transparency low-laze two-side adhesive tape and preparation method thereof |
| CN104471006A (en) * | 2012-07-10 | 2015-03-25 | 乐金华奥斯有限公司 | Flame retardant adhesive agent composition having improved gas bubble stability, and method for preparing same |
| CN105860885A (en) * | 2016-06-30 | 2016-08-17 | 潍坊富乐新材料有限公司 | Pressure-sensitive adhesive for polyacrylate foam and preparation method of pressure-sensitive adhesive |
-
2016
- 2016-09-10 CN CN201610816218.3A patent/CN106674417A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103635554A (en) * | 2011-07-01 | 2014-03-12 | 日东电工株式会社 | Multilayer adhesive article and adhesive sheet |
| CN102702991A (en) * | 2012-06-12 | 2012-10-03 | 安徽省郎溪县阿拉法胶粘制品有限公司 | Acrylic double-faced adhesive tape and preparation method thereof |
| CN103254823A (en) * | 2012-07-10 | 2013-08-21 | 东莞市富印胶粘科技有限公司 | Foam adhesive tape and preparation method thereof |
| CN103254825A (en) * | 2012-07-10 | 2013-08-21 | 东莞市富印胶粘科技有限公司 | Non-base material adhesive tape and preparation method thereof |
| CN104471006A (en) * | 2012-07-10 | 2015-03-25 | 乐金华奥斯有限公司 | Flame retardant adhesive agent composition having improved gas bubble stability, and method for preparing same |
| CN104449446A (en) * | 2014-11-25 | 2015-03-25 | 东莞市富印胶粘科技有限公司 | UV curable high-transparency low-laze two-side adhesive tape and preparation method thereof |
| CN105860885A (en) * | 2016-06-30 | 2016-08-17 | 潍坊富乐新材料有限公司 | Pressure-sensitive adhesive for polyacrylate foam and preparation method of pressure-sensitive adhesive |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109504299A (en) * | 2018-11-13 | 2019-03-22 | 江苏朗臣新材料科技有限公司 | A kind of preparation method of foam tape base material |
| CN109796894A (en) * | 2018-12-26 | 2019-05-24 | 张家港康得新光电材料有限公司 | A kind of foam tape and preparation method thereof |
| CN109825201A (en) * | 2018-12-26 | 2019-05-31 | 张家港康得新光电材料有限公司 | A kind of bonding structure and preparation method thereof |
| CN109825213A (en) * | 2018-12-26 | 2019-05-31 | 张家港康得新光电材料有限公司 | A kind of foam tape and preparation method thereof |
| CN109825213B (en) * | 2018-12-26 | 2022-02-25 | 张家港康得新光电材料有限公司 | Foam adhesive tape and preparation method thereof |
| CN109796894B (en) * | 2018-12-26 | 2023-02-28 | 张家港康得新光电材料有限公司 | Foam adhesive tape and preparation method thereof |
| WO2020225445A1 (en) | 2019-05-08 | 2020-11-12 | Tesa Se | A prismatic battery module using aseismatic damping glue |
| CN110283558A (en) * | 2019-07-19 | 2019-09-27 | 厦门市垄江工业制品有限公司 | A kind of foam dust-proof cushion gum and preparation method thereof |
| CN111548754A (en) * | 2020-03-20 | 2020-08-18 | 安徽富印新材料有限公司 | Anti-staining acrylic foam adhesive tape and preparation method thereof |
| CN112680139A (en) * | 2020-12-23 | 2021-04-20 | 苏州赛伍应用技术股份有限公司 | Acrylic foaming damping foam and preparation method thereof |
| CN113025242A (en) * | 2021-04-07 | 2021-06-25 | 艾利(昆山)有限公司 | Pressure-sensitive adhesive composition and acrylic foam adhesive tape with same |
| CN113429509A (en) * | 2021-07-16 | 2021-09-24 | 苏州环明电子科技有限公司 | UV acrylate foam and preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106674417A (en) | Acrylic foam tape composition and method for preparing acrylic foam tape composition | |
| CN105295787B (en) | A kind of solvent-free superelevation viscous force pressure sensitive adhesive of UV photocurings and preparation method thereof | |
| CN104263292B (en) | A kind of aqueous laminated adhesive stick and preparation method thereof | |
| CN103254823B (en) | Acryl foam adhesive tape and preparation method thereof | |
| CN105949984B (en) | Universal polyester film online coating fluid and preparation method thereof | |
| CN102352165B (en) | Monocomponent ultraviolet light self-crosslinking type acrylate copolymer coating, and synthetic method and application thereof | |
| CN104213465B (en) | Refreshing UV paper gloss oil of release effect, superslide and preparation method thereof is had after a kind of UV ultraviolet light polymerization | |
| CN101508759A (en) | Method of preparing epoxy modified acrylic resin emulsion | |
| CN102040930A (en) | Pressure-sensitive adhesive for PET (Polyester) adhesive tapes and preparation method thereof | |
| CN105463882A (en) | Gold print paste and preparation method thereof | |
| CN106085309A (en) | Automobile floor leather melt pressure sensitive glue composition and preparation method thereof | |
| CN107254268A (en) | A kind of acrylate pressure-sensitive adhesive and preparation method thereof | |
| CN106008792A (en) | Solvent type acrylate pressure-sensitive adhesive preparation method | |
| CN106833398A (en) | A kind of rapid curing acrylate pressure-sensitive adhesive and preparation method thereof | |
| CN103184024A (en) | Reversible bonding-debonding epoxy resin adhesive and preparation method thereof | |
| CN106432583A (en) | Heat-conducting foam tape composition and method for preparing heat-conducting foam tape from composition | |
| CN105315933B (en) | A kind of antistripping instant drying adhesive and preparation method thereof | |
| CN105440982A (en) | Packing box used and wood-leather base material used environmentally-friendly aqueous binder | |
| JPH0995600A (en) | Thermosetting composition, composition for preparing the same and thermosetting film adhesive | |
| CN108559427A (en) | A kind of high temperature resistant pressure sensitive adhesive haveing excellent performance, pressure sensitive adhesive tape and preparation method thereof | |
| CN104031591A (en) | Ultraviolet-curing composition for LED packaging | |
| WO2015096123A1 (en) | A process for die bonding in electronic products | |
| CN103254824B (en) | Heat-conductive electric appliance insulated foam adhesive tape for high temperature and preparation method thereof | |
| CN114149750B (en) | Adhesive, heat-curable adhesive tape, preparation method and use method of adhesive | |
| CN102101996A (en) | Pressure-sensitive adhesive used for cotton paper or non-woven fabrics and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170517 |