CN105463882A - Gold print paste and preparation method thereof - Google Patents
Gold print paste and preparation method thereof Download PDFInfo
- Publication number
- CN105463882A CN105463882A CN201511027842.7A CN201511027842A CN105463882A CN 105463882 A CN105463882 A CN 105463882A CN 201511027842 A CN201511027842 A CN 201511027842A CN 105463882 A CN105463882 A CN 105463882A
- Authority
- CN
- China
- Prior art keywords
- parts
- monomer
- gold stamping
- acrylic
- emulsion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
- D06P1/5271—Polyesters; Polycarbonates; Alkyd resins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
- D06P1/5278—Polyamides; Polyimides; Polylactames; Polyalkyleneimines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
- D06P1/5285—Polyurethanes; Polyurea; Polyguanides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
Abstract
The invention provides gold print paste and a preparation method thereof. The gold print paste is prepared from, by weight, acrylic emulsion, hot melting powder, a curing agent, a thickening agent and a defoaming agent; the acrylic emulsion is mainly prepared from, by weight, 0.8-1.8 parts of emulsifying agent, 60-70 parts of soft monomer, 20-35 parts of hard monomer, 0.5-3 parts of cross-linking monomer, 3-5 parts of functional monomer, 0.15-0.4 part of initiating agent, 0.3-1.4 part of neutralizing agent, 0.3-0.5 part of pH buffering agent, 0-2.4 parts of adipic acid dihydrazide and 88-115 parts of deionized water. The gold print paste can serve as an adhesive between gold print foil and any cloth, the print making process is easy to implement, prints are not tacky, printing temperature is low, printed textile made through the gold print paste has super-high washable performance, achieves a mirror surface effect and is soft in hand feeling, and the gold print paste has good application prospects in the field of textile and paper products.
Description
Technical field
The invention belongs to printing technique field, particularly relate to a kind of gold stamping slurry and preparation method thereof.
Background technology
Gold stamping stamp is beautiful in colour due to it, the advantage such as to glitter and obtain the favor of textile industry, but yet there is a lot of problem simultaneously, mainly concentrates on washing fastness, environmental protection, flatness, pliability, high-temperature discoloration etc.
Current solution washing fastness has main following several method: in gold stamping slurry, add glittering powder, adopt thermal fusing powder and adopt chloride emulsion or chloride auxiliary agent.
CN1769069A discloses a kind of washable, soft, glittering costume bronzing technique, and described technique mainly comprises: print gold stamping slurry, naturally dry, hot pressing is gold stamping, high temperature bakes, and it adds the glittering powder of 5-20% for bottoming in the gold stamping slurry of softness printed; The gold stamping slurry of high-strength adhesion strength is used for capping; Bake and coldly tear golden paper afterwards.This patent have employed glittering powder, to its object is to after gold stamping slurry film forming with glittering powder, fills up orange cold foil and to drop part, but adds due to glittering powder the flatness that membership affects film forming matter, and then affects mirror effect.
CN102718921A discloses gold stamping printing paste adhesive agent emulsion of a kind of environment-friendlytextile textile and preparation method thereof, this emulsion is made up of the component of following weight percentage: emulsifying agent 0.5% ~ 3%, soft monomer 30% ~ 50%, hard monomer 6% ~ 15%, functional monomer 2% ~ 5%, initator 0.1% ~ 0.3%, deionized water 40% ~ 60%, neutralizer 0.5% ~ 2%.Its feature is can obtain gold stamping stamp without the need to high temperature thermoprint, solve high-temperature discoloration problem, but its emulsion does not adopt the means such as any cross-linking system or thermal fusing powder, can be relatively poor in wash water fastness.
CN103255646B discloses a kind of gold stamping slurry and preparation method thereof, and this gold stamping slurry is made up of the raw material comprising following parts by weight: acrylic acid ester emulsion 60 ~ 80, deionized water 2 ~ 6, solvent 3 ~ 10, stabilizing agent 1 ~ 5, EVA hot-melt adhesive powder 10 ~ 20, silica 0.5 ~ 3, polyurethane defoamer 0.2 ~ 0.5, pH adjusting agent 0.1 ~ 0.5, preservative agent 0.1 ~ 0.2 and emulsification wetting agent 0.3 ~ 1, thickener 0.4 ~ 2.Its feature is that employing EVA thermal fusing powder increases fastness, but the resistance to water of EVA material is general, so be of limited application.
Summary of the invention
For prior art Problems existing, the object of the present invention is to provide a kind of gold stamping slurry and preparation method thereof, described gold stamping slurry can as the sticker between orange cold foil and any cloth, making stamp process is easy to operate, stamp is not clamminess, blocking point is low, with the printing textile that it is made, there is superelevation wash durability, repeatedly wash and do not fade, do not lose mirror effect and soft, in weaving, paper product field, there is good application prospect.
For reaching this object, the present invention by the following technical solutions:
An object of the present invention is to provide a kind of gold stamping slurry, described gold stamping slurry is by weight by 55.8 ~ 92.2 parts of acrylic emulsions, 5 ~ 40 parts of thermal fusing powders, 0.3 ~ 0.8 part of curing agent, 1.5 ~ 3 parts of thickeners and 0.1 ~ 0.4 part of defoamer prepare, and the parts by weight sum of described acrylic emulsion, thermal fusing powder, curing agent, thickener and defoamer is 100 parts; Wherein, described acrylic emulsion prepares primarily of following raw material by weight:
Described cross-linking monomer is methacrylic acid ethyl acetoacetate (AAEM) or diacetone acrylamide, and when cross-linking monomer is methacrylic acid ethyl acetoacetate, the parts by weight of adipic dihydrazide are 0.Use AAEM or ketone hydrazine cross-linking system, effectively can improve the self-crosslinking speed of glued membrane, the anodized aluminium of its carbonyl and orange cold foil produces bonding and gives the better fastness of Printing and elasticity simultaneously.
Described gold stamping slurry is by weight by 55.8 ~ 92.2 parts of acrylic emulsions, 5 ~ 40 parts of thermal fusing powders, 0.3 ~ 0.8 part of curing agent, 1.5 ~ 3 parts of thickeners and 0.1 ~ 0.4 part of defoamer prepare, if acrylic emulsion is 56 parts, 57 parts, 60 parts, 62 parts, 65 parts, 68 parts, 70 parts, 75 parts, 80 parts, 85 parts, 90 parts or 91 parts etc.; Thermal fusing powder is 6 parts, 8 parts, 10 parts, 12 parts, 15 parts, 20 parts, 25 parts, 30 parts or 35 parts; Curing agent is 0.4 part, 0.5 part, 0.6 part or 0.7 part etc.; Thickener is 1.6 parts, 1.8 parts, 2.0 parts, 2.2 parts, 2.5 parts or 2.8 parts etc.; Defoamer is 0.2 part or 0.3 part etc.The parts by weight sum of described acrylic emulsion, thermal fusing powder, curing agent, thickener and defoamer is 100 parts, as acrylic emulsion 60 parts, thermal fusing powder 37.3 parts, 0.5 part, curing agent, thickener 2 parts and defoamer 0.2 part; Acrylic emulsion 65 parts, thermal fusing powder 32.1 parts, 0.4 part, curing agent, thickener 2.2 parts and defoamer 0.3 part; Acrylic emulsion 70 parts, thermal fusing powder 26.8 parts, 0.6 part, curing agent, thickener 2.5 parts and defoamer 0.1 part; Acrylic emulsion 75 parts, thermal fusing powder 21.3 parts, 0.7 part, curing agent, thickener 2.8 parts and defoamer 0.2 part; Acrylic emulsion 80 parts, thermal fusing powder 16.8 parts, 0.5 part, curing agent, thickener 2.5 parts and defoamer 0.2 part; Acrylic emulsion 86 parts, thermal fusing powder 10.5 parts, 0.5 part, curing agent, thickener 2.7 parts and defoamer 0.3 part.
Described acrylic emulsion prepares primarily of following raw material by weight: emulsifying agent 0.8 ~ 1.8 part, as 0.9 part, 1.0 parts, 1.2 parts, 1.3 parts, 1.4 parts or 1.6 parts etc.; Soft monomer 60 ~ 70 parts, as 61 parts, 62 parts, 63 parts, 65 parts, 67 parts or 69 parts etc.; Hard monomer 20 ~ 35 parts, as 22 parts, 25 parts, 28 parts, 30 parts, 32 parts or 34 parts etc.; Cross-linking monomer 0.5 ~ 3 part, as 0.8 part, 1.0 parts, 1.5 parts, 1.8 parts, 2.0 parts, 2.3 parts, 2.5 parts or 2.8 parts etc.; Function monomer 3 ~ 5 parts, as 3.2 parts, 3.5 parts, 3.8 parts, 4.0 parts, 4.2 parts, 4.5 parts or 4.8 parts etc.; Initator 0.15 ~ 0.4 part, as 0.2 part, 0.23 part, 0.25 part, 0.28 part, 0.30 part, 0.35 part or 0.38 part etc.; Neutralizer 0.3 ~ 1.4 part, as 0.4 part, 0.5 part, 0.6 part, 0.7 part, 0.8 part, 0.9 part, 1.0 parts, 1.2 parts or 1.3 parts etc.; PH buffer 0.3 ~ 0.5 part, as 0.32,0.35,0.38,0.40,0.42,0.45 or 0.48 etc.; Adipic dihydrazide 0 ~ 2.4 part, as 0.1 part, 0.3 part, 0.5 part, 0.8 part, 1.0 parts, 1.2 parts, 1.5 parts, 1.8 parts, 2.0 parts or 2.2 parts etc.; Deionized water 88 ~ 115 parts, as 90 parts, 95 parts, 98 parts, 100 parts, 105 parts, 108 parts, 110 parts or 112 parts etc.
As preferred technical scheme, described acrylic emulsion prepares primarily of following raw material by weight:
Described cross-linking monomer is methacrylic acid ethyl acetoacetate or diacetone acrylamide, and when cross-linking monomer is methacrylic acid ethyl acetoacetate, the parts by weight of adipic dihydrazide are 0.
Described emulsifying agent is phosphoric acid esters wedding agents and reactive emulsifier.Reactive emulsifier can reduce micromolecular migration, strengthens its resistance to water; And phosphoric acid esters wedding agents can improve the adhesive force between glued membrane and orange cold foil.
Preferably, described phosphoric acid ester emulsifying agent is aliphatic alcohol polyoxyvinethene phosphate, as sub-RS610 and/or RS710 in sieve ground.
Preferably, described reactive emulsifier is molecular formula is CH
2=CHCH
2oCH
2cH (ROCH
2) (OCH
2cH
2)
nat least one in the surfactant of OX, wherein R is alkyl, and as methyl, ethyl, propyl group, butyl or amyl group etc., n is 10 ~ 30, and as 12,13,15,18,20,22,25 or 28 etc., X is H or SO
3nH
4.
Described soft monomer is the mixture of a kind of and butyl acrylate in ethyl acrylate or Isooctyl acrylate monomer.Typical but non-limiting mixture is: the mixture of ethyl acrylate and butyl acrylate, Isooctyl acrylate monomer and butyl acrylate mixture.
Preferably, described hard monomer is the mixture of any one or at least two kinds in methyl methacrylate, styrene and acrylonitrile.Typical but non-limiting mixture is: methyl methacrylate and styrene, styrene and acrylonitrile, methyl methacrylate, styrene and acrylonitrile, methyl methacrylate and acrylonitrile.
Preferably, described function monomer is acrylic monomers containing circulus and/or carboxy-containing acid group's acrylic monomers.
Preferably, the described acrylic monomers containing circulus is the methacrylate-based monomer of glycidyl methacrylate and/or band urea heterocyclic group, and the methacrylate-based monomer of described band urea heterocyclic group is as SIPOMERWAM-II and/or SIPOMERWAM-III.Acrylic monomers containing circulus can improve wet adhesion, makes gold stamping pulp-water can't be washed off look.
Preferably, described carboxy-containing acid group's acrylic monomers is the mixture of any one or at least two kinds in acrylic acid, methacrylic acid and β-propyloic acrylic ester.Typical but non-limiting mixture is: acrylic acid and methacrylic acid, acrylic acid and β-propyloic acrylic ester, methacrylic acid and β-propyloic acrylic ester, acrylic acid, methacrylic acid and β-propyloic acrylic ester.
Described initator is ammonium persulfate and/or potassium peroxydisulfate.
Preferably, described neutralizer is the mixture of a kind of in ammoniacal liquor, ethylenediamine and diethanol amine or at least two kinds.Typical but non-limiting mixture is: ammoniacal liquor and ethylenediamine, ammoniacal liquor and diethanol amine, ethylenediamine and diethanol amine, ammoniacal liquor, ethylenediamine and diethanol amine.
Preferably, described pH buffer is sodium bicarbonate.
Described thermal fusing powder is the mixture of any one or at least two kinds in Silon, polyester powder and polyurethane powder.
Preferably, the particle diameter of described thermal fusing powder is 0 ~ 80 μm.
It is a phase that described thermal fusing powder melts with glued membrane after hot melt at a certain temperature, has both added glued membrane fastness, makes again glued membrane smooth and then make gold stamping stamp have mirror effect; Use the collocation of dissimilar thermal fusing powder, its fastness adjustable and pliability simultaneously.
Described curing agent is 3-(2,3-epoxy third oxygen) propyl trimethoxy silicane.
Preferably, described thickener is association type polyurethane.
Preferably, described defoamer is polysiloxanes.
Two of object of the present invention is the preparation method providing a kind of gold stamping slurry as above, described preparation method is: the emulsifying agent of formula ratio, soft monomer, hard monomer, cross-linking monomer, function monomer, initator, neutralizer, pH buffer, adipic dihydrazide and deionized water are dripped technique continuously through pre-emulsification and makes pre-emulsion, backward pre-emulsion in add the thermal fusing powder of formula ratio, curing agent, thickener and defoamer, gold stamping slurry can be obtained.
As preferred technical scheme, the preparation method of described gold stamping slurry comprises the steps:
(1) by acrylate soft monomer 60 ~ 70 parts, hard monomer 20 ~ 35 parts, function monomer 3 ~ 5 parts, emulsifying agent 0.5 ~ 1 part and deionized water 40 ~ 50 parts, stir after mixing and be prepared into pre-emulsion;
(2) 0.1 ~ 0.3 part of initator is dissolved in the deionized water of 5 ~ 10 parts, is mixed with initiator solution;
(3) in a kettle., add 40 ~ 50 parts of deionized waters, 0.05 ~ 0.1 part of initiator solution, 0.3 ~ 0.8 part of emulsifying agent and 0.3 ~ 0.5 part of pH buffer, stir; Then add pre-emulsion 5 ~ 8 parts under agitation, be warming up to 88 ~ 90 DEG C and react, occur after blue light until emulsion; In reactor, drip 112 ~ 120 parts of pre-emulsions and 4 ~ 5 parts of initiator solutions, drip 3h continuously and add; Again cross-linking monomer 0.5 ~ 3 part is dissolved in the solution obtained in 3 ~ 5 parts of deionized waters to drip together with 28 ~ 30 parts of pre-emulsions, drips 0.5h continuously and add; Be warmed up to 92 ~ 93 DEG C and insulation reaction 1 ~ 1.5h; Finally cool the temperature to less than 40 DEG C, adjust ph to 6.5 ~ 7.0, add the neutralizer of 0.3 ~ 1.4 part and the adipic dihydrazide of 0 ~ 2.4 part, after warp thread net filtration, obtain acrylic emulsion;
(4) in acrylic emulsion, add the thermal fusing powder of 5 ~ 40 parts successively, 0.3 ~ 0.8 part of curing agent, 1.5 ~ 3 parts of thickeners and 0.1 ~ 0.4 part of defoamer, obtain gold stamping slurry.
Step (1) the described pre-emulsified time is 20 ~ 30min, as 22min, 23min, 25min, 26min, 27min or 29min etc.
Preferably, the order number of step (3) described gauze is 120 ~ 180 orders, as 130 orders, 140 orders, 150 orders, 160 orders or 170 orders etc.
Step (4) described cross-linking monomer is methacrylic acid ethyl acetoacetate (AAEM) or diacetone acrylamide, and when cross-linking monomer is methacrylic acid ethyl acetoacetate, the parts by weight of adipic dihydrazide are 0.
Preferably, step (4) described thermal fusing powder adds in pre-emulsion under high-speed stirred condition.
Preferably, the speed of described stirring is 2000 ~ 3000r/min, as 2200r/min, 2500r/min, 2800r/min or 2900r/min etc.
Preferably, the viscosity of step (4) described acrylic emulsion is 12000 ~ 15000mPas, as 12500mPas, 13000mPas, 13500mPas, 14000mPas or 14500mPas etc.
Compared with prior art, beneficial effect of the present invention is:
(1) gold stamping slurry provided by the invention has selected Polymerizable Emulsifier and phosphoric acid ester emulsifying agent, and its Polymerizable Emulsifier can reduce micromolecular migration, strengthens its resistance to water; And phosphoric acid ester emulsifying agent can improve the adhesive force between glued membrane and orange cold foil;
(2) ring-type function monomer selected by gold stamping slurry provided by the invention, and Main Function is to improve wet adhesion, makes gold stamping pulp-water can't be washed off look;
(3) gold stamping slurry provided by the invention selects methacrylic acid ethyl acetoacetate (AAEM) or ketone hydrazine cross-linking system, effectively can improve the self-crosslinking speed of glued membrane, the anodized aluminium of its carbonyl and orange cold foil produces bonding and gives the better fastness of Printing and elasticity simultaneously;
(4) gold stamping slurry provided by the invention uses thermal fusing powder, being a phase, both having added glued membrane fastness because melting with glued membrane after thermal fusing powder hot melt at a certain temperature, makes again glued membrane smooth and then make gold stamping stamp have mirror effect; Use the collocation of dissimilar thermal fusing powder, its fastness adjustable and pliability simultaneously.
Described gold stamping slurry can as the sticker between orange cold foil and any cloth, make easy to operate in stamp process, printed surface is not clamminess, blocking point is low, blocking point is 130 ~ 140 DEG C, the printing textile made can be washed for resistance to 60 DEG C, 2.5 hours, at least 3 washings are not faded, do not lose mirror effect and soft not easy-to-draw quick-fried, in weaving, paper product field, there is good application prospect.
Detailed description of the invention
Technical scheme of the present invention is further illustrated below by detailed description of the invention.
Embodiment 1
A kind of gold stamping slurry, described gold stamping slurry by weight array prepares primarily of following raw material:
Described thermal fusing powder is Silon; The particle diameter of described thermal fusing powder is 0 ~ 80 μm, does not comprise 0;
Described curing agent is 3-(2,3-epoxy third oxygen) propyl trimethoxy silicane; Described thickener is association type polyurethane; Described defoamer is polysiloxanes.
Described acrylic emulsion prepares primarily of following raw material by weight:
Described cross-linking monomer is diacetone acrylamide.
Described emulsifying agent is phosphoric acid esters wedding agents and reactive emulsifier, and described phosphoric acid ester emulsifying agent is aliphatic alcohol polyoxyvinethene phosphate, and described reactive emulsifier is molecular formula is CH
2=CHCH
2oCH
2cH (ROCH
2) (OCH
2cH
2)
nthe surfactant of OX, wherein R is methyl, and n is 30, X is H.
Described function monomer is the acrylic monomers containing circulus, and the described acrylic monomers containing circulus is glycidyl methacrylate.
Described soft monomer is the mixture of ethyl acrylate and butyl acrylate.
Described hard monomer is methyl methacrylate.
Described initator is ammonium persulfate.
Described neutralizer is ammoniacal liquor.
Described pH buffer is sodium bicarbonate.
The preparation method of described gold stamping slurry comprises the steps:
(1) by acrylate soft monomer 70 parts, hard monomer 20 parts, function monomer 3 parts, stir after emulsifying agent 0.5 part and deionized water 40 parts mix and be prepared into pre-emulsion;
(2) 0.1 part of initator is dissolved in the deionized water of 5 parts, is mixed with initiator solution;
(3) in a kettle., add 40 parts of deionized waters, 0.05 part of initiator solution, 0.3 part of emulsifying agent and 0.5 part of pH buffer, stir; Then add the pre-emulsion 5 parts in step (1) under agitation, be warming up to 88 DEG C and react; Occur after blue light until emulsion, in reactor, drip 112 parts of pre-emulsions and 4 parts of initiator solutions, drip 3h continuously and add; Again the solution that cross-linking monomer 3 parts is dissolved in 3 parts of deionized waters is dripped together with 28 parts of pre-emulsions, drip 0.5h continuously and add; Be warmed up to 92 DEG C and insulation reaction 1.5h; Finally cool the temperature to less than 40 DEG C, adjust ph to 6.5, add the adipic dihydrazide of 2.4 parts and the neutralizer of 0.3 part, after 180 object gauzes filter, obtain the acrylic emulsion that viscosity is 12000mPas;
(4) 92.2 parts of acrylic emulsions are added thermal fusing powder 5 parts, 0.8 part, curing agent, thickener 1.6 parts and defoamer 0.4 part successively under the stirring of 2000r/min, obtain gold stamping slurry.
Embodiment 2
A kind of gold stamping slurry, described gold stamping slurry by weight array prepares primarily of following raw material:
Described thermal fusing powder is polyester powder and polyurethane powder; The particle diameter of described thermal fusing powder is 0 ~ 80 μm, does not comprise 0;
Described curing agent is 3-(2,3-epoxy third oxygen) propyl trimethoxy silicane; Described thickener is association type polyurethane; Described defoamer is polysiloxanes.
Described acrylic emulsion prepares primarily of following raw material by weight:
Described cross-linking monomer is methacrylic acid ethyl acetoacetate.
Described emulsifying agent is phosphoric acid esters wedding agents and reactive emulsifier, and described phosphoric acid ester emulsifying agent is aliphatic alcohol polyoxyvinethene phosphate, and described reactive emulsifier is molecular formula is CH
2=CHCH
2oCH
2cH (ROCH
2) (OCH
2cH
2)
nthe surfactant of OX, wherein R is amyl group, and n is 10, X is SO
3nH
4.
Described function monomer is carboxy-containing acid group's acrylic monomers, and described carboxy-containing acid group's acrylic monomers is acrylic acid.
Described soft monomer is the mixture of ethyl acrylate and butyl acrylate.
Described hard monomer is acrylonitrile.
Described initator is potassium peroxydisulfate.
Described neutralizer is diethanol amine.
Described pH buffer is sodium bicarbonate.
The preparation method of described gold stamping slurry comprises the steps:
(1) by acrylate soft monomer 60 parts, hard monomer 35 parts, function monomer 5 parts, stir after emulsifying agent 1 part and deionized water 50 parts mix and be prepared into pre-emulsion;
(2) 0.15 parts by mass initator is dissolved in the deionized water of 10 parts by mass, is mixed with initiator solution;
(3) in a kettle., add 50 parts of deionized waters, 0.1 part of initiator solution, 0.8 part of emulsifying agent and 0.3 part of pH buffer, stir; Then add the pre-emulsion 8 parts in step (1) under agitation, be warming up to 90 DEG C and react; Occur after blue light until emulsion, in reactor, drip 112 parts of pre-emulsions and 5 parts of initiator solutions, drip 3h continuously and add; Again the solution that cross-linking monomer 0.5 part is dissolved in 5 parts of deionized waters is dripped together with 30 parts of pre-emulsions, drip 0.5h continuously and add; Be warmed up to 92 ~ 93 DEG C and insulation reaction 1h; Finally cool the temperature to less than 40 DEG C, adjust ph to 7.0, add the neutralizer of 1.4 parts, after 120 object gauzes filter, obtain the acrylic emulsion that viscosity is 15000mPas;
(4) 55.8 parts of acrylic emulsions are added thermal fusing powder 40 parts, 0.8 part, curing agent, thickener 3 parts and defoamer 0.4 part successively under the stirring of 3000r/min, obtain gold stamping slurry.
Embodiment 3
A kind of gold stamping slurry, described gold stamping slurry by weight array prepares primarily of following raw material:
Described thermal fusing powder is the mixture of Silon, polyester powder and polyurethane powder; The particle diameter of described thermal fusing powder is 0 ~ 80 μm, does not comprise 0;
Described curing agent is 3-(2,3-epoxy third oxygen) propyl trimethoxy silicane; Described thickener is association type polyurethane; Described defoamer is polysiloxanes.
Described acrylic emulsion prepares primarily of following raw material by weight:
Described cross-linking monomer is diacetone acrylamide.
Described emulsifying agent is phosphoric acid esters wedding agents and reactive emulsifier, and described phosphoric acid ester emulsifying agent is aliphatic alcohol polyoxyvinethene phosphate, and described reactive emulsifier is molecular formula is CH
2=CHCH
2oCH
2cH (ROCH
2) (OCH
2cH
2)
nthe surfactant of OX, wherein R is alkyl, and n is 15, X is H.
Described function monomer is acrylic monomers containing circulus and carboxy-containing acid group's acrylic monomers.The described acrylic monomers containing circulus is the methacrylate-based monomer of glycidyl methacrylate and band urea heterocyclic group; Described carboxy-containing acid group's acrylic monomers is the mixture of acrylic acid, methacrylic acid and β-propyloic acrylic ester.
Described soft monomer is the mixture of ethyl acrylate and butyl acrylate.
Described hard monomer is the mixture of methyl methacrylate, styrene and acrylonitrile.
Described initator is ammonium persulfate and potassium peroxydisulfate.
Described neutralizer is the mixture of ammoniacal liquor, ethylenediamine and diethanol amine.
Described pH buffer is sodium bicarbonate.
The preparation method of described gold stamping slurry comprises the steps:
(1) by acrylate soft monomer 65 parts, hard monomer 30 parts, function monomer 4 parts, stir after emulsifying agent 0.6 part and deionized water 45 parts mix and be prepared into pre-emulsion;
(2) 0.3 part of initator is dissolved in 6 parts of deionized waters, is mixed with initiator solution;
(3) in a kettle., add 45 parts of deionized waters, 0.08 part of initiator solution, 0.4 part of emulsifying agent and 0.4 part of pH buffer, stir; Then add the pre-emulsion 7 parts in step (1) under agitation, be warming up to 89 DEG C and react; Occur after blue light until emulsion, in reactor, drip 120 parts of pre-emulsions and 4.5 parts of initiator solutions, drip 3h continuously and add; Again the solution that cross-linking monomer 2 parts is dissolved in 4 parts of deionized waters is dripped together with 29 parts of pre-emulsions, drip 0.5h continuously and add; Be warmed up to 92.5 DEG C and insulation reaction 1.8h; Finally cool the temperature to less than 40 DEG C, adjust ph to 6.8, add the adipic dihydrazide of 1.2 parts and the neutralizer of 1.0 parts, after 150 object gauzes filter, obtain the acrylic emulsion that viscosity is 14500mPas;
(4) 78.1 parts of acrylic emulsions are added thermal fusing powder 20 parts, 0.3 part, curing agent, thickener 1.5 parts and defoamer 0.1 part successively under the stirring of 2500r/min, obtain gold stamping slurry.
Embodiment 4
A kind of gold stamping slurry, described gold stamping slurry by weight array prepares primarily of following raw material:
Described thermal fusing powder is Silon; The particle diameter of described thermal fusing powder is 0 ~ 80 μm, does not comprise 0;
Described curing agent is 3-(2,3-epoxy third oxygen) propyl trimethoxy silicane; Described thickener is association type polyurethane; Described defoamer is polysiloxanes.
Described acrylic emulsion prepares primarily of following raw material by weight:
Described cross-linking monomer is diacetone acrylamide.
Described emulsifying agent is phosphoric acid esters wedding agents and reactive emulsifier, and described phosphoric acid ester emulsifying agent is aliphatic alcohol polyoxyvinethene phosphate, and described reactive emulsifier is molecular formula is CH
2=CHCH
2oCH
2cH (ROCH
2) (OCH
2cH
2)
nat least one in the surfactant of OX, wherein R is propyl group, and n is 20, X is SO
3nH
4.
Described function monomer is acrylic monomers containing circulus and carboxy-containing acid group's acrylic monomers.The described acrylic monomers containing circulus is the methacrylate-based monomer of glycidyl methacrylate and band urea heterocyclic group; Described carboxy-containing acid group's acrylic monomers is acrylic acid.
Described soft monomer is the mixture of Isooctyl acrylate monomer and butyl acrylate.
Described hard monomer is the mixture of methyl methacrylate, styrene and acrylonitrile.
Described initator is potassium peroxydisulfate.
Described neutralizer is the mixture of ethylenediamine and diethanol amine.
Described pH buffer is sodium bicarbonate.
The preparation method of described gold stamping slurry comprises the steps:
(1) by acrylate soft monomer 68 parts, hard monomer 25 parts, function monomer 3 parts, stir after emulsifying agent 0.5 part and deionized water 40 parts mix and be prepared into pre-emulsion;
(2) 0.3 part of initator is dissolved in 5 parts of deionized waters, is mixed with initiator solution;
(3) in a kettle., add 40 parts of deionized waters, 0.08 part of initiator solution, 0.5 part of emulsifying agent and 0.4 part of pH buffer, stir; Then add the pre-emulsion 8 parts in step (1) under agitation, be warming up to 90 DEG C and react; Occur after blue light until emulsion, in reactor, drip 115 parts of pre-emulsions and 5 parts of initiator solutions, drip 3h continuously and add; Again the solution that cross-linking monomer 2 parts is dissolved in 5 parts of deionized waters is dripped together with 30 parts of pre-emulsions, drip 0.5h continuously and add; Be warmed up to 92 DEG C and insulation reaction 1.5h; Finally cool the temperature to less than 40 DEG C, adjust ph to 7.0, add the adipic dihydrazide of 2 parts and the neutralizer of 0.5 part, after 150 object gauzes filter, obtain the acrylic emulsion that viscosity is 14000mPas;
(4) 66.7 parts of acrylic emulsions are added thermal fusing powder 30 parts, 0.6 part, curing agent, thickener 2.5 parts and defoamer 0.2 part successively under the stirring of 2600r/min, obtain gold stamping slurry.
Embodiment 5
A kind of gold stamping slurry, described gold stamping slurry by weight array prepares primarily of following raw material:
Described thermal fusing powder is polyurethane powder; The particle diameter of described thermal fusing powder is 0 ~ 80 μm, does not comprise 0;
Described curing agent is 3-(2,3-epoxy third oxygen) propyl trimethoxy silicane; Described thickener is association type polyurethane; Described defoamer is polysiloxanes.
Described acrylic emulsion prepares primarily of following raw material by weight:
Described cross-linking monomer is methacrylic acid ethyl acetoacetate.
Described emulsifying agent is phosphoric acid esters wedding agents and reactive emulsifier, and described phosphoric acid ester emulsifying agent is aliphatic alcohol polyoxyvinethene phosphate, and described reactive emulsifier is molecular formula is CH
2=CHCH
2oCH
2cH (ROCH
2) (OCH
2cH
2)
nat least one in the surfactant of OX, wherein R is alkyl, and n is 25, X is SO
3nH
4.
Described function monomer is the acrylic monomers containing circulus.The described acrylic monomers containing circulus is the methacrylate-based monomer of band urea heterocyclic group; Described carboxy-containing acid group's acrylic monomers is β-propyloic acrylic ester.
Described soft monomer is the mixture of ethyl acrylate and butyl acrylate.
Described hard monomer is methyl methacrylate.
Described initator is potassium peroxydisulfate.
Described neutralizer is ammoniacal liquor.
Described pH buffer is sodium bicarbonate.
The preparation method of described gold stamping slurry comprises the steps:
(1) by acrylate soft monomer 62 parts, hard monomer 30 parts, function monomer 4 parts, stir after emulsifying agent 0.8 part and deionized water 47 parts mix and be prepared into pre-emulsion;
(2) 0.2 part of initator is dissolved in 10 parts of deionized waters, is mixed with initiator solution;
(3) in a kettle., add 50 parts of deionized waters, 0.08 part of initiator solution, 0.7 part of emulsifying agent and 0.3 part of pH buffer, stir; Then add the pre-emulsion 8 parts in step (1) under agitation, be warming up to 88 DEG C and react; Occur after blue light until emulsion, in reactor, drip 118 parts of pre-emulsions and 5 parts of initiator solutions, drip 3h continuously and add; Again the solution that cross-linking monomer 1 part is dissolved in 3 parts of deionized waters is dripped together with 30 parts of pre-emulsions, drip 0.5h continuously and add; Be warmed up to 93 DEG C and insulation reaction 1h; Finally cool the temperature to less than 40 DEG C, adjust ph to 6.5, add the neutralizer of 1.0 parts, after 180 object gauzes filter, obtain the acrylic emulsion that viscosity is 13000mPas;
(4) 77.2 parts of acrylic emulsions are added thermal fusing powder 20 parts, 0.5 part, curing agent, thickener 2 parts and defoamer 0.3 part successively under the stirring of 3000r/min, obtain gold stamping slurry.
Comparative example 1
Do not contain except diacetone acrylamide and adipic dihydrazide except in the raw material of acrylic emulsion, described comparative example 1 is identical with embodiment 4.
Comparative example 2
Do not contain except methacrylic acid ethyl acetoacetate (AAEM) except in the raw material of acrylic emulsion, described comparative example 2 is identical with embodiment 5.
Comparative example 3
Except the emulsifying agent in acrylic emulsion is phosphoric acid esters wedding agents, described comparative example 3 is identical with embodiment 4.
Comparative example 4
Except the emulsifying agent in acrylic emulsion is reactive emulsifier, described comparative example 4 is identical with embodiment 4.
Comparative example 5
Except the emulsifying agent in acrylic emulsion is reactive emulsifier, and not containing outside diacetone acrylamide, methacrylic acid ethyl acetoacetate and adipic dihydrazide in the raw material of acrylic emulsion, described comparative example 5 is identical with embodiment 4.
Gold stamping slurry obtained with comparative example 1 ~ 5 for embodiment 1 ~ 5 is carried out performance test, and test result is as shown in table 1.
Table 1
Note: wash water fastness is tested: soap water washes 2.5 hours;
Mirror effect is evaluated: 0 grade: mirror effect, have reflecting effect; 1-2 level: surfacing, but mirror effect is not given prominence to; 3-4 level: there is little noise on surface, no-reflection effect; 5 grades: rough surface out-of-flatness.
Applicant states; the foregoing is only the specific embodiment of the present invention; but protection scope of the present invention is not limited thereto; person of ordinary skill in the field should understand; anyly belong to those skilled in the art in the technical scope that the present invention discloses; the change that can expect easily or replacement, all drop within protection scope of the present invention and open scope.
Claims (10)
1. a gold stamping slurry, it is characterized in that, described gold stamping slurry is by weight by 55.8 ~ 92.2 parts of acrylic emulsions, 5 ~ 40 parts of thermal fusing powders, 0.3 ~ 0.8 part of curing agent, 1.5 ~ 3 parts of thickeners and 0.1 ~ 0.4 part of defoamer prepare, and the parts by weight sum of described acrylic emulsion, thermal fusing powder, curing agent, thickener and defoamer is 100 parts; Wherein, described acrylic emulsion prepares primarily of following raw material by weight:
Described cross-linking monomer is methacrylic acid ethyl acetoacetate or diacetone acrylamide, and when cross-linking monomer is methacrylic acid ethyl acetoacetate, the parts by weight of adipic dihydrazide are 0.
2. gold stamping slurry according to claim 1, is characterized in that, described acrylic emulsion prepares primarily of following raw material by weight:
Described cross-linking monomer is methacrylic acid ethyl acetoacetate or diacetone acrylamide, and when cross-linking monomer is methacrylic acid ethyl acetoacetate, the parts by weight of adipic dihydrazide are 0.
3. gold stamping slurry according to claim 1 and 2, is characterized in that, described emulsifying agent is phosphoric acid esters wedding agents and reactive emulsifier;
Preferably, described phosphoric acid ester emulsifying agent is aliphatic alcohol polyoxyvinethene phosphate;
Preferably, described reactive emulsifier is molecular formula is CH
2=CHCH
2oCH
2cH (ROCH
2) (OCH
2cH
2)
nat least one in the surfactant of OX, wherein R is alkyl, and n is 10 ~ 30, X is H or SO
3nH
4.
4. according to the gold stamping slurry one of claim 1-3 Suo Shu, it is characterized in that, described soft monomer is the mixture of a kind of and butyl acrylate in ethyl acrylate or Isooctyl acrylate monomer;
Preferably, described hard monomer is the mixture of any one or at least two kinds in methyl methacrylate, styrene and acrylonitrile;
Preferably, described function monomer is acrylic monomers containing circulus and/or carboxy-containing acid group's acrylic monomers;
Preferably, the described acrylic monomers containing circulus is the methacrylate-based monomer of glycidyl methacrylate and/or band urea heterocyclic group;
Preferably, described carboxy-containing acid group's acrylic monomers is the mixture of any one or at least two kinds in acrylic acid, methacrylic acid and β-propyloic acrylic ester.
5. according to the gold stamping slurry one of claim 1-3 Suo Shu, it is characterized in that, described initator is ammonium persulfate and/or potassium peroxydisulfate;
Preferably, described neutralizer is the mixture of a kind of in ammoniacal liquor, ethylenediamine, diethanol amine or at least two kinds;
Preferably, described pH buffer is sodium bicarbonate.
6. according to the gold stamping slurry one of claim 1-5 Suo Shu, it is characterized in that, described thermal fusing powder is the mixture of any one or at least two kinds in Silon, polyester powder and polyurethane powder;
Preferably, the particle diameter of described thermal fusing powder is 0 ~ 80 μm.
7. according to the gold stamping slurry one of claim 1-6 Suo Shu, it is characterized in that, described curing agent is 3-(2,3-epoxy third oxygen) propyl trimethoxy silicane;
Preferably, described thickener is association type polyurethane;
Preferably, described defoamer is polysiloxanes.
8. according to the preparation method of the gold stamping slurry one of claim 1-7 Suo Shu, it is characterized in that, described preparation method is: the emulsifying agent of formula ratio, soft monomer, hard monomer, cross-linking monomer, function monomer, initator, neutralizer, pH buffer, adipic dihydrazide and deionized water are dripped technique continuously through pre-emulsification and makes acrylic emulsion, in acrylic emulsion, add the thermal fusing powder of formula ratio, curing agent, thickener and defoamer again, gold stamping slurry can be obtained.
9. preparation method according to claim 8, is characterized in that, described preparation method comprises the steps:
(1) by acrylate soft monomer 60 ~ 70 parts, hard monomer 20 ~ 35 parts, function monomer 3 ~ 5 parts, emulsifying agent 0.5 ~ 1 part and deionized water 40 ~ 50 parts, stir after mixing and be prepared into pre-emulsion;
(2) 0.1 ~ 0.3 part of initator is dissolved in the deionized water of 5 ~ 10 parts, is mixed with initiator solution;
(3) in a kettle., add 40 ~ 50 parts of deionized waters, 0.05 ~ 0.1 part of initiator solution, 0.3 ~ 0.8 part of emulsifying agent and 0.3 ~ 0.5 part of pH buffer, stir; Then add pre-emulsion 5 ~ 8 parts under agitation, be warming up to 88 ~ 90 DEG C and react, occur after blue light until emulsion; In reactor, drip 112 ~ 120 parts of pre-emulsions and 4 ~ 5 parts of initiator solutions, drip 3h continuously and add; Again cross-linking monomer 0.5 ~ 3 part is dissolved in the solution obtained in 3 ~ 5 parts of deionized waters to drip together with 28 ~ 30 parts of pre-emulsions, drips 0.5h continuously and add; Be warmed up to 92 ~ 93 DEG C and insulation reaction 1 ~ 1.5h; Finally cool the temperature to less than 40 DEG C, adjust ph to 6.5 ~ 7.0, add the neutralizer of 0.3 ~ 1.4 part and the adipic dihydrazide of 0 ~ 2.4 part, after warp thread net filtration, obtain acrylic emulsion;
(4) in acrylic emulsion, add the thermal fusing powder of 5 ~ 40 parts, 0.3 ~ 0.8 part of curing agent, 1.5 ~ 3 parts of thickeners and 0.1 ~ 0.4 part of defoamer successively, obtain gold stamping slurry.
10. preparation method according to claim 8 or claim 9, it is characterized in that, step (1) the described pre-emulsified time is 20 ~ 30min;
Preferably, the order number of step (3) described gauze is 120 ~ 180 orders;
Preferably, step (4) described thermal fusing powder adds in pre-emulsion under high-speed stirred condition;
Preferably, the speed of described stirring is 2000 ~ 3000r/min;
Preferably, the viscosity of step (4) described acrylic emulsion is 12000 ~ 15000mPas.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511027842.7A CN105463882B (en) | 2015-12-30 | 2015-12-30 | A kind of gold stamping slurry and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511027842.7A CN105463882B (en) | 2015-12-30 | 2015-12-30 | A kind of gold stamping slurry and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105463882A true CN105463882A (en) | 2016-04-06 |
| CN105463882B CN105463882B (en) | 2018-02-16 |
Family
ID=55602006
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201511027842.7A Active CN105463882B (en) | 2015-12-30 | 2015-12-30 | A kind of gold stamping slurry and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105463882B (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105859940A (en) * | 2016-05-04 | 2016-08-17 | 合肥聚合辐化技术有限公司 | Mucilage resin for producing mucilage and preparing method thereof |
| CN107083701A (en) * | 2017-04-10 | 2017-08-22 | 江苏新瑞贝科技股份有限公司 | A kind of environmental protection typed gold green onion slurry and preparation method thereof |
| CN107880208A (en) * | 2017-12-12 | 2018-04-06 | 杭州龙驹合成材料有限公司 | A kind of gold stamping slurry emulsion and preparation method thereof |
| CN108360273A (en) * | 2018-02-05 | 2018-08-03 | 山东黄河三角洲纺织科技研究院有限公司 | A kind of processing method of metallic Chinese flax fabric |
| CN108411651A (en) * | 2018-03-20 | 2018-08-17 | 惠州长联新材料科技有限公司 | A kind of gold stamping slurry and its preparation method and application |
| CN108442141A (en) * | 2018-03-20 | 2018-08-24 | 东莞长联新材料科技股份有限公司 | A kind of environment-friendly type printing and dyeing special-purpose high temperature foaming slurry and preparation method thereof |
| CN109651559A (en) * | 2018-12-11 | 2019-04-19 | 上海绘兰材料科技有限公司 | A kind of release-free scalds cloth anodized aluminium acrylic resin and its preparation method and application |
| CN110396290A (en) * | 2019-07-19 | 2019-11-01 | 安徽聚合辐化化工有限公司 | A kind of thermal fusing powder modified aqueous polyurethane resin and preparation method thereof |
| CN111254725A (en) * | 2020-02-25 | 2020-06-09 | 东莞威冠服饰工艺有限公司 | Bronzing-imitating paste and manufacturing method thereof |
| CN113832750A (en) * | 2021-11-11 | 2021-12-24 | 东莞长联新材料科技股份有限公司 | Gold stamping paste and preparation method and application thereof |
| CN117229448A (en) * | 2023-10-16 | 2023-12-15 | 波司登羽绒服装有限公司 | Aqueous acrylic emulsion for gold stamping |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62102861A (en) * | 1985-10-26 | 1987-05-13 | Takashi Nishihira | Bronze-tone resin finishing method |
| CN102229789A (en) * | 2011-05-17 | 2011-11-02 | 北京高盟新材料股份有限公司 | Aqueous laminating adhesive for gold and silver cards and preparation method thereof |
| CN102848762A (en) * | 2012-09-12 | 2013-01-02 | 昆山杰明纺织品有限公司 | Gold printing process for clothing |
| CN104628933A (en) * | 2015-02-10 | 2015-05-20 | 东莞长联新材料科技股份有限公司 | Environment-friendly anti-oxidation printing adhesive for glitter paste and gold and silver power and preparation method thereof |
-
2015
- 2015-12-30 CN CN201511027842.7A patent/CN105463882B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62102861A (en) * | 1985-10-26 | 1987-05-13 | Takashi Nishihira | Bronze-tone resin finishing method |
| CN102229789A (en) * | 2011-05-17 | 2011-11-02 | 北京高盟新材料股份有限公司 | Aqueous laminating adhesive for gold and silver cards and preparation method thereof |
| CN102848762A (en) * | 2012-09-12 | 2013-01-02 | 昆山杰明纺织品有限公司 | Gold printing process for clothing |
| CN104628933A (en) * | 2015-02-10 | 2015-05-20 | 东莞长联新材料科技股份有限公司 | Environment-friendly anti-oxidation printing adhesive for glitter paste and gold and silver power and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 李怀贵: "烫金浆的分类与应用", 《丝网印刷》 * |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105859940A (en) * | 2016-05-04 | 2016-08-17 | 合肥聚合辐化技术有限公司 | Mucilage resin for producing mucilage and preparing method thereof |
| CN107083701A (en) * | 2017-04-10 | 2017-08-22 | 江苏新瑞贝科技股份有限公司 | A kind of environmental protection typed gold green onion slurry and preparation method thereof |
| CN107880208A (en) * | 2017-12-12 | 2018-04-06 | 杭州龙驹合成材料有限公司 | A kind of gold stamping slurry emulsion and preparation method thereof |
| CN108360273A (en) * | 2018-02-05 | 2018-08-03 | 山东黄河三角洲纺织科技研究院有限公司 | A kind of processing method of metallic Chinese flax fabric |
| CN108411651B (en) * | 2018-03-20 | 2020-09-11 | 惠州长联新材料科技有限公司 | Slurry for gold stamping and preparation method and application thereof |
| CN108442141A (en) * | 2018-03-20 | 2018-08-24 | 东莞长联新材料科技股份有限公司 | A kind of environment-friendly type printing and dyeing special-purpose high temperature foaming slurry and preparation method thereof |
| CN108411651A (en) * | 2018-03-20 | 2018-08-17 | 惠州长联新材料科技有限公司 | A kind of gold stamping slurry and its preparation method and application |
| CN109651559A (en) * | 2018-12-11 | 2019-04-19 | 上海绘兰材料科技有限公司 | A kind of release-free scalds cloth anodized aluminium acrylic resin and its preparation method and application |
| CN109651559B (en) * | 2018-12-11 | 2021-11-09 | 上海绘兰材料科技有限公司 | Acrylic resin for release-free ironing cloth electrochemical aluminum and preparation method and application thereof |
| CN110396290A (en) * | 2019-07-19 | 2019-11-01 | 安徽聚合辐化化工有限公司 | A kind of thermal fusing powder modified aqueous polyurethane resin and preparation method thereof |
| CN111254725A (en) * | 2020-02-25 | 2020-06-09 | 东莞威冠服饰工艺有限公司 | Bronzing-imitating paste and manufacturing method thereof |
| CN113832750A (en) * | 2021-11-11 | 2021-12-24 | 东莞长联新材料科技股份有限公司 | Gold stamping paste and preparation method and application thereof |
| CN113832750B (en) * | 2021-11-11 | 2023-11-17 | 东莞长联新材料科技股份有限公司 | Gold stamping paste and preparation method and application thereof |
| CN117229448A (en) * | 2023-10-16 | 2023-12-15 | 波司登羽绒服装有限公司 | Aqueous acrylic emulsion for gold stamping |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105463882B (en) | 2018-02-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105463882A (en) | Gold print paste and preparation method thereof | |
| CN102718930B (en) | Organic silicon modified acrylate emulsion and preparation method thereof | |
| CN101220563B (en) | Environment protection type pigment resin printing adhesive agent capable of self crosslinking at low-temperature, and preparation thereof | |
| CN101423734B (en) | Method for preparing organosilicon modified acrylic ester binding agent | |
| CN104628933B (en) | A kind of environment-friendly type antioxidation gold Herba Alii fistulosi slurry and gold silver slurry printing adhesive and preparation method thereof | |
| CN102391411A (en) | Low-temperature self-crosslinking polyacrylate pigment printing binding agent and preparation method thereof | |
| CN101864025B (en) | Preparation method of polyacrylate microgel emulsion and application thereof | |
| CN108411651B (en) | Slurry for gold stamping and preparation method and application thereof | |
| CN107964060A (en) | A kind of gradient type polyacrylate stamp lotion and preparation method thereof | |
| CN108977134A (en) | A kind of environment-friendly water-based Laminating adhesive and preparation method thereof that cohesive force is strong | |
| CN101492594A (en) | Chloroprene rubber latex adhesive, preparation and uses thereof | |
| CN105111363B (en) | A kind of function performed polymer and preparation method and application | |
| CN105602490A (en) | Dual-component emulsion polyacrylate pressure-sensitive adhesive and preparation method and application thereof | |
| CN104910319A (en) | Polyacrylate emulsion capable of postponing dye transfer and preparation method thereof | |
| CN111620983A (en) | Acrylate emulsion for moisture-resistant rubbing water-based ink and preparation method thereof | |
| CN104045761B (en) | Dumb light damage resistant water-base resin and its preparation method | |
| CN108442141B (en) | Environment-friendly high-temperature foaming slurry special for printing and dyeing and preparation method thereof | |
| CN102260479B (en) | Crylic acid grafted nano material aqueous pressure-sensitive adhesive for electronic-grade protective film | |
| CN102108110A (en) | Method for preparing acrylate printing adhesive | |
| CN103233364B (en) | Self-cross-linking type waterborne polyacrylate powder-free base slurry for clothing fusible interlining | |
| CN104211852A (en) | Preparation method of acrylate emulsion for waterborne printing ink | |
| CN104610512A (en) | Preparation method of super-soft IPN (interpenetrating polymer network) pigment printing binder | |
| CN112851882B (en) | Preparation method of epoxy resin modified styrene-acrylic emulsion for plastic ink | |
| CN110437360A (en) | A kind of skirting, door sleeve apply mud high viscosity emulsion adhesive and preparation method thereof | |
| CN113321678B (en) | Silane coupling agent, water-based acrylate laminating adhesive emulsion and water-based acrylate laminating adhesive |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CP02 | Change in the address of a patent holder |
Address after: 523400 Building 1, No. 733, Liaobu section, Shida Road, Liaobu Town, Dongguan City, Guangdong Province Patentee after: DONGGUAN CTL NEW MATERIAL TECHNOLOGY Co.,Ltd. Address before: 523419 Guangdong province Dongguan city Liaobu Town Village loose sand Industrial Zone Road Patentee before: DONGGUAN CTL NEW MATERIAL TECHNOLOGY Co.,Ltd. |
|
| CP02 | Change in the address of a patent holder |