CN106666826B - A kind of melon ring additive and preparation method thereof of pair of Harm reduction techniques flavouring - Google Patents
A kind of melon ring additive and preparation method thereof of pair of Harm reduction techniques flavouring Download PDFInfo
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- CN106666826B CN106666826B CN201710104451.3A CN201710104451A CN106666826B CN 106666826 B CN106666826 B CN 106666826B CN 201710104451 A CN201710104451 A CN 201710104451A CN 106666826 B CN106666826 B CN 106666826B
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- melon ring
- melon
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/14—Use of materials for tobacco smoke filters of organic materials as additive
Abstract
The invention belongs to cigarette additive technical fields, disclose melon ring additive of a kind of pair of Harm reduction techniques flavouring and preparation method thereof: under inert gas protection, melon ring and hydroxypropyl cellulose being added in ethyl alcohol and n-hexane; the ratio between volume of the ethyl alcohol and n-hexane is 10:1 ~ 5:1; 70 ~ 118 DEG C are heated to, 1 ~ 5h is kept, alkaline solution is then added; pH value is adjusted to 10 ~ 11; after mixing evenly, it cools down, filters at room temperature; precipitating is washed with water, and is drying to obtain.Melon ring additive prepared by the present invention can make an addition in cigarette filter, effectively reduce the tar content and other harmful substances of cigarette, and will not introduce bad miscellaneous gas, while stability is high, be suitable for industrial application.
Description
Technical field
The invention belongs to the melon ring additive of cigarette additive technical field more particularly to a kind of pair of Harm reduction techniques flavouring and
Preparation method.
Background technique
Currently, with the continuous improvement of people's health consciousness, cigarette consumption person requires also to get over to the low harmful property of cigarette product
Come higher, adsorbent material is added in filter stick, come reducing tar and reducing harm is domestic in recent years using its Large ratio surface and strong adsorption capacity
Outer tobacco business passage and effective method, still, there are still many problems, examples for the filter tip produced using these adsorbent materials
Such as common inorganic adsorbing material, such as silica gel, diatomite, zeolite, porous ceramics, active carbon, hardness is larger, in filter stick and volume
In cigarette production process, it is easy to damage the blade of cutting filter stick, causes cost of equipment to rise and increases with stopping accident；Natural plant kind
Material is if any the wick grass particle of patent report, pomelo peel swelling granular etc., then quality is loose, and density is low, in filter stick formation
It is easy to be pressurized and generate dust, tar reduction effect is impacted and thus introduces miscellaneous gas；In addition, being transported there are also some adsorbent materials
It is easy to be slipped by vibration in journey to enter pipe tobacco, influences the combustibility and combustion state of cigarette, cause cigarette smoking quality unstable
It is fixed.
Therefore, for above-mentioned filter stick filtering material the shortcomings that, develops new maturation it is still necessary to select new suitable material
Technique, preparation while there is certain degree of hardness and toughness, can either reducing tar and reducing harm, and do not influence cigarette odor-absorbing, apply also for work
The filtering material that industry metaplasia produces.
Melon ring is compound emerging after cyclodextrin in recent years, with hydrophobic inner cavity and hydrophilic outer
Chamber can retain organic matter and inorganic matter, with good stability and rigid structure, and more selective and specificity.Mesh
Before be mainly used for the fields such as molecular recognition, there is no the research for applying melon ring and its derivative or compound as cigarette additive
Report.
Summary of the invention
The present invention is to solve existing additive of cigarette filter stick tar reduction effect is limited, new miscellaneous gas and production application are introduced
Unstable problem provides a kind of new adsorbent material, and selectivity and specificity are stronger, and absorption property is higher, Neng Gougeng
The tar content and other harmful substances of cigarette are effectively reduced, and new bad miscellaneous gas will not be introduced, while stability is high, is fitted
For industrial application.
To achieve the goals above, the present invention adopts the following technical scheme:
The melon ring additive of a kind of pair of Harm reduction techniques flavouring, preparation method are as follows: under inert gas protection, by melon ring with
Hydroxypropyl cellulose is added in ethyl alcohol and n-hexane, and the ratio between volume of the ethyl alcohol and n-hexane is 10:1 ~ 5:1, is heated to
70 ~ 118 DEG C, 1 ~ 5h is kept, alkaline solution is then added, pH value is adjusted to 10 ~ 11, after mixing evenly, cools down at room temperature, mistake
Filter, precipitating are washed with water, dry.
The melon ring is one of five yuan of melon rings, cucurbit(7)uril, ten yuan of melon rings, five yuan of melon rings of decamethyl.
The melon ring is preferably five yuan of melon rings of decamethyl.
The melon ring and hydroxypropyl cellulose mass ratio are 1:2 ~ 1:0.4.
The melon ring and hydroxypropyl cellulose mass ratio are preferably 1:1.
The alkaline solution is one of sodium hydroxide, potassium hydroxide, calcium hydroxide aqueous solution.
Melon ring additive prepared by the present invention, when use, are made an addition in cigarette filter.It is prepared using the method for the present invention
Melon ring additive, there is high-strength adsorption capacity, and have certain hardness without losing toughness, therefore can effectively adsorb cigarette
Tar content and other harmful substances, it is non-breakable in process, miscellaneous gas will not be introduced, property is stablized, cigarette smoking product
Matter is for a long time such as one.
It when in use in view of adsorbent, also can inevasible decrease cigarette usually while adsorbing harmful substance
Fragrance component, so that the mouthfeel of cigarette and fragrance are had some technologies to attempt to solve the problems, such as this at present by a degree of loss,
Such as fragrance extracting solution is sprayed in adsorbent material and plays the role of flavoring, but this flavoring mode only has the fragrance component of outer layer
It works, the fragrance time given is excessively of short duration, cannot be lasting.
The present invention provides a kind of preferred flavoring mode, and fragrance is mixed and crushed, and water or alcohol is added, and room temperature or heating mention
It takes, collects filtrate, be concentrated under reduced pressure, melon ring additive is then added, is stood after stirring, filter, precipitating washing makes an addition to after dry
In cigarette filter.Such flavoring mode can not only be by fragrance material in the outside of melon ring additive, more advantageously, can be by fragrance
It is loaded onto inside the cavity body structure of melon ring additive, the amount of flavorants of load is big and stablizes, and can dramatically increase the fragrance of cigarette
With inhale taste, and perfuming effect is lasting.
It is furthermore preferred that mixing and crushing peppermint, camomile, honeysuckle, cape jasmine, 5 times of waters, 80 DEG C of heating extractions are added, receive
Collect filtrate, be concentrated under reduced pressure, melon ring additive is then added, 1-2h is stood after stirring, filter, precipitating washing makes an addition to after dry
In cigarette filter.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation
Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common
Technical staff's every other embodiment obtained without making creative work belongs to the model that the present invention protects
It encloses.
Comparative example 1
Certain carbon content active is weighed, is made an addition in mouth stick with 20mg/ branch cigarette, comparative example cigarette is made.
Comparative example 2
A certain amount of five yuan of melon rings are weighed, is made an addition in mouth stick with 20mg/ branch cigarette, comparative example cigarette is made.
Embodiment 1
Under nitrogen protection, five yuan of melon rings and hydroxypropyl cellulose are added in ethyl alcohol and n-hexane, wherein ethyl alcohol with
The ratio between volume of n-hexane is 10:1, wherein five yuan of melon rings and hydroxypropyl cellulose mass ratio are 1:2, is heated to 90 DEG C, keeps
Then sodium hydroxide solution is added in 2.5h, adjust pH value to 10, after mixing evenly, cool down, filter at room temperature, precipitating is washed with water
It washs, it is dry, obtain melon ring additive.
A certain amount of melon ring additive is weighed, is made an addition in mouth stick with 10mg/ branch cigarette, filter tip is made containing additive of the present invention
Embodiment cigarette, do comparative experiments with comparative example, embodiment cigarette in addition to containing different additives, other as material auxiliary material,
Dimensions, mouth stick etc. are identical with comparative example cigarette.
Embodiment 2
Under nitrogen protection, by five yuan of melon rings of decamethyl and hydroxypropyl cellulose be added to ethyl alcohol and n-hexane (v/v=5:
1) in, wherein five yuan of melon rings of decamethyl and hydroxypropyl cellulose mass ratio are 1:1, are heated to 118 DEG C, keep 5h, are then added
Potassium hydroxide solution adjusts pH value to 11, after mixing evenly, cools down, filter at room temperature, precipitating is washed with water, and drying obtains melon ring
Additive.
A certain amount of melon ring additive is weighed, is made an addition in mouth stick with 10mg/ branch cigarette, filter tip is made containing additive of the present invention
Embodiment cigarette, do comparative experiments with comparative example, embodiment cigarette in addition to containing different additives, other as material auxiliary material,
Dimensions, mouth stick etc. are identical with comparative example cigarette.
Embodiment 3
Under nitrogen protection, ten yuan of melon rings and hydroxypropyl cellulose are added in ethyl alcohol and n-hexane, wherein ethyl alcohol with
The ratio between volume of n-hexane is 8:1, wherein ten yuan of melon rings and hydroxypropyl cellulose mass ratio are 1:0.4, is heated to 70 DEG C, keeps
Then potassium hydroxide solution is added in 1h, adjusting pH value to 10 after mixing evenly, cools down at room temperature, filters, and precipitating is washed with water,
It is dry, obtain melon ring additive.
Peppermint, camomile, honeysuckle, cape jasmine are mixed and crushed, 5 times of waters, 80 DEG C of heating extractions are added, filtrate is collected, subtracts
Pressure concentration, takes 500ml concentrate, and 20mg melon ring additive is added, 1-2h is stood after stirring, filters, precipitating washing, after dry,
It weighs 10mg/ branch to make an addition in cigarette filter tip, embodiment cigarette of the filter tip containing additive of the present invention is made, is compared with comparative example
Experiment, embodiment cigarette in addition to containing different additives, roll up with comparative example by other such as material auxiliary material, dimensions, mouth sticks
Cigarette is identical.
Embodiment cigarette and comparative example cigarette are advised with RM1 single channel smoking machine by standard GB/T/T 19609-2004
It is aspirated under the conditions of fixed standard aspiration, is required to collect flue gas sample according to different detection projects, carry out flue gas correlation harmful components
Analysis detection, while with glass fiber filter Fume collector collect total granules, according to YC/T 189 monitor cigarette smoking
Process.The total granules content that gravimetric detemination cambridge filter traps；Standard GB/T/T 19609- is pressed in tar content detection
2004 carry out；Phenolic compound is detected with High Performance Liquid Chromatography with Fluorescence Detection；HCN is detected with Continuous Flow Analysis instrument method；
CO content detects automatically in smoking machine aspiration procedure；Crotons aldehyde is detected with high performance liquid chromatography.Concrete outcome is shown in Table
1.
1 comparative example of table and embodiment cigarette smoke harmful substance testing result
10 people are asked to smoke panel test group to comparative example and implementation with YC/T138-1998 tobacco and tobacco product sensory evaluation method
Example cigarette carries out sensory evaluating smoking, scores respectively from 6 indexs such as the miscellaneous gas irritation of gloss fragrance harmony and pleasant impression, obtains total
It is allocated as the criteria of quality evaluation of cigarette smoke fragrance, concrete outcome is shown in Table 2.
2 comparative example of table and embodiment cigarette sensory evaluation scores
Claims (9)
1. the preparation method of the melon ring additive of a kind of pair of Harm reduction techniques flavouring, it is characterised in that: under inert gas protection, will
Melon ring and hydroxypropyl cellulose are added in ethyl alcohol and n-hexane, and the ratio between volume of the ethyl alcohol and n-hexane is 10:1 ~ 5:1,
70 ~ 118 DEG C are heated to, 1 ~ 5h is kept, alkaline solution is then added, adjusting pH value is after mixing evenly, cold at room temperature to 10 ~ 11
But, it filters, precipitating is washed with water, dry.
2. the preparation method of the melon ring additive of a kind of pair of Harm reduction techniques flavouring according to claim 1, it is characterised in that
The melon ring is one of five yuan of melon rings, cucurbit(7)uril, ten yuan of melon rings, five yuan of melon rings of decamethyl.
3. the preparation method of the melon ring additive of a kind of pair of Harm reduction techniques flavouring according to claim 1, it is characterised in that
The melon ring is five yuan of melon rings of decamethyl.
4. the preparation method of the melon ring additive of a kind of pair of Harm reduction techniques flavouring according to claim 1, it is characterised in that
The melon ring and hydroxypropyl cellulose mass ratio are 1:2 ~ 1:0.4.
5. the preparation method of the melon ring additive of a kind of pair of Harm reduction techniques flavouring according to claim 1, it is characterised in that
The melon ring and hydroxypropyl cellulose mass ratio are 1:1.
6. the preparation method of the melon ring additive of a kind of pair of Harm reduction techniques flavouring according to claim 1, it is characterised in that
The alkaline solution is one of sodium hydroxide, potassium hydroxide, calcium hydroxide aqueous solution.
7. the application of melon ring additive of any of claims 1-6, it is characterised in that make an addition to melon ring additive
In cigarette filter.
8. the application of melon ring additive of any of claims 1-6, it is characterised in that fragrance is mixed and crushed, is added
Enter water or alcohol, room temperature or heating extraction, collect filtrate, be concentrated under reduced pressure, melon ring additive is then added, is stood after stirring, filters,
Precipitating washing, makes an addition in cigarette filter after dry.
9. the application of melon ring additive of any of claims 1-6, it is characterised in that by peppermint, camomile, honeysuckle,
Cape jasmine mixes and crushes, and 5 times of waters, 80 DEG C of heating extractions are added, and collects filtrate, is concentrated under reduced pressure, and melon ring additive is then added,
1-2h is stood after stirring, is filtered, and precipitating washing makes an addition in cigarette filter after dry.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710104451.3A CN106666826B (en) | 2017-02-24 | 2017-02-24 | A kind of melon ring additive and preparation method thereof of pair of Harm reduction techniques flavouring |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710104451.3A CN106666826B (en) | 2017-02-24 | 2017-02-24 | A kind of melon ring additive and preparation method thereof of pair of Harm reduction techniques flavouring |
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| CN106666826A CN106666826A (en) | 2017-05-17 |
| CN106666826B true CN106666826B (en) | 2019-11-19 |
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| CN201710104451.3A Active CN106666826B (en) | 2017-02-24 | 2017-02-24 | A kind of melon ring additive and preparation method thereof of pair of Harm reduction techniques flavouring |
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| CN111480883A (en) * | 2020-03-19 | 2020-08-04 | 红塔烟草(集团)有限责任公司 | Cigarette multi-component composite filter stick without color change after smoking |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002031025A2 (en) * | 2000-10-10 | 2002-04-18 | Massachusetts Institute Of Technology | Biodegradable poly(beta-amino esters) and uses thereof |
| CN101735326A (en) * | 2009-12-23 | 2010-06-16 | 中国科学院南京土壤研究所 | Method for rapid immobilization of cucuriturils to cellulose under light of microwave electrodeless ultraviolet lamp |
| CN103352368A (en) * | 2013-06-14 | 2013-10-16 | 屠晓明 | Manufacturing method of silk used in machine-washable silk quilt |
| CN104744617A (en) * | 2015-03-25 | 2015-07-01 | 贵州大学 | [5] turil bridged acrylic polymer microsphere, preparation method and application |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4931931B2 (en) * | 2006-03-09 | 2012-05-16 | ポステック・アカデミー‐インダストリー・ファウンデーション | Tobacco added with cucurbituril and method for producing the same |
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2017
- 2017-02-24 CN CN201710104451.3A patent/CN106666826B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002031025A2 (en) * | 2000-10-10 | 2002-04-18 | Massachusetts Institute Of Technology | Biodegradable poly(beta-amino esters) and uses thereof |
| CN101735326A (en) * | 2009-12-23 | 2010-06-16 | 中国科学院南京土壤研究所 | Method for rapid immobilization of cucuriturils to cellulose under light of microwave electrodeless ultraviolet lamp |
| CN103352368A (en) * | 2013-06-14 | 2013-10-16 | 屠晓明 | Manufacturing method of silk used in machine-washable silk quilt |
| CN104744617A (en) * | 2015-03-25 | 2015-07-01 | 贵州大学 | [5] turil bridged acrylic polymer microsphere, preparation method and application |
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