CN111480883A - Cigarette multi-component composite filter stick without color change after smoking - Google Patents

Cigarette multi-component composite filter stick without color change after smoking Download PDF

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Publication number
CN111480883A
CN111480883A CN202010197727.9A CN202010197727A CN111480883A CN 111480883 A CN111480883 A CN 111480883A CN 202010197727 A CN202010197727 A CN 202010197727A CN 111480883 A CN111480883 A CN 111480883A
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section
adsorption
filter stick
composite filter
cigarette
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Inventor
马丽
舒云波
覃志宏
倪和朋
张峻松
朱远洋
李瑞丽
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Hongta Tobacco Group Co Ltd
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Hongta Tobacco Group Co Ltd
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    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/04Tobacco smoke filters characterised by their shape or structure
    • A24D3/041Tobacco smoke filters characterised by their shape or structure with adjustable means for modifying the degree of filtration of the filter

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  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)

Abstract

The invention discloses a cigarette multi-component composite filter stick without discoloration after smoking, which belongs to the technical field of tobacco filter stick manufacturing. The invention adopts a multi-element composite structure of the compact groove section and the adsorption section, the adsorption section can selectively reduce the release amount of tar in the mainstream smoke of the cigarette, adsorb harmful substances in the smoke, keep the herbal fragrance of the cigarette and reduce the harm of cigarette smoking; the smoke after selective adsorption enters the compacting groove section and enters the mouth of a consumer through the groove, so that the pollution to the filter stick is reduced, and the color of the suction end of the sucked filter stick is further prevented from changing. The test result shows that the color difference of the multi-element composite filter stick is minimum 1.33, and the appearance observation shows that the color of the multi-element composite filter stick does not change before and after the suction.

Description

Cigarette multi-component composite filter stick without color change after smoking
Technical Field
The invention relates to the technical field of tobacco filter stick manufacturing, in particular to a cigarette multi-component composite filter stick which does not discolor after being smoked.
Background
At present, the cigarette is generally adopted and is adorned the filter rod additional and alleviate the harm of smoking to the human body, but ordinary filter rod only comprises filter core and outer wrapping paper, and the process that the flue gas passes through the filter rod is comparatively unobstructed, but the filter tip is yellow after the suction, influences pleasing to the eye. Currently, with the development and progress of society, people pursue high-quality life more and more, people pay more attention to the appearance of cigarettes, and the yellowing of a filter tip after the cigarettes are smoked gradually becomes one of the focuses of people.
The filter tip which does not turn yellow after being sucked is researched and vigorously developed to become a new direction, the main reason of the color change (turning yellow) of the filter tip after being sucked is that tar in mainstream smoke is trapped by the filter tip, and a method which is commonly used is to add an adsorption material into tobacco or the filter tip. In recent years, a great deal of research is carried out on the adsorbing material added into the filter stick in the tobacco industry at home and abroad. At present, active carbon, sepiolite, molecular sieves and the like have relevant reports on tar reducing and harm reducing effects of cigarettes, but different adsorption material structures have different adsorption performances on harmful components, and the influence of the addition of the adsorption material on cigarette smoke resistance, smoke concentration and aroma amount still needs to be considered.
Therefore, the development of a cigarette filter stick which does not change color after being smoked, can reduce tar and harm and has no negative influence on the sensory quality of the cigarette is particularly necessary.
Disclosure of Invention
Aiming at the problems in the background technology, the invention provides the cigarette multi-element composite filter stick which does not change color after smoking, so that the filter stick at the mouth end does not change color after smoking the cigarette, the visual aesthetic feeling is improved, harmful substances in smoke can be selectively adsorbed, the herbal fragrance of the smoke can be reserved during smoking, and the harm of cigarette smoking is reduced.
In order to achieve the purpose, the invention adopts the following technical scheme: the color-unchanged multi-component cigarette composite filter stick after being sucked comprises a filter element and outer wrapping tipping paper, wherein the filter element comprises a pressing groove section, a common filter stick section and a first adsorption section which are sequentially butted, and grooves are uniformly formed in the outer peripheral surface of the pressing groove section.
Preferably, the compacting groove section is formed by compacting glass paper or high-permeability forming paper.
Preferably, the outer wrapping paper at the suction end of the common filter rod section is provided with vent holes in a circular array.
Preferably, the end surface of the groove is V-shaped, and the end surface of the compact groove section is in a dodecagonal star shape.
Preferably, the first adsorption section contains a cucurbituril adsorbent.
Preferably, the first adsorption section is connected with a second adsorption section at the tobacco shred end, and the second adsorption section contains an activated carbon adsorption material.
Preferably, the first adsorption section and the second adsorption section are prepared by the following steps: selecting adsorption material particles, adding essence, mixing and wetting, drying, sieving to obtain adsorption particles with the particle size of 20-50 meshes, and mixing the adsorption particles with acetate fiber tows to obtain a first adsorption section and a second adsorption section.
Preferably, the loading amounts of the cucurbituril adsorbing material and the activated carbon adsorbing material in the first adsorbing section and the second adsorbing section are both 0.5-1 mg/mm.
The invention has the beneficial effects that:
the invention adopts a multi-element composite structure of the compact groove section and the adsorption section, the adsorption section can selectively reduce the release amount of tar in the mainstream smoke of the cigarette, adsorb harmful substances in the smoke, keep the herbal fragrance of the cigarette and reduce the harm of cigarette smoking; the smoke after selective adsorption enters the compacting groove section and enters the mouth of a consumer through the groove, so that the pollution to the filter stick is reduced, and the color of the suction end of the sucked filter stick is further prevented from changing. The test result shows that the color difference of the multi-element composite filter stick is minimum 1.33, and the appearance observation shows that the color of the multi-element composite filter stick does not change before and after the suction.
Drawings
FIG. 1 is a schematic view of the present invention in example 1.
FIG. 2 is a schematic view of the present invention in example 2.
Fig. 3 is a schematic end view of a segment of a compressed groove according to the present invention.
In the figure: 1-external wrapping paper, 2-compacting groove section, 3-common filter rod section, 4-first adsorption section, 5-groove, 6-vent hole and 7-second adsorption section.
Detailed Description
In order to make the technical solution and advantages of the present invention more apparent, preferred embodiments of the present invention will be described in detail below with reference to the accompanying drawings for the convenience of the skilled person.
Example 1
As shown in fig. 1 and 3, the color-invariant multi-component composite filter stick for cigarettes after smoking comprises a filter element and an outer wrapping paper 1, wherein the filter element comprises a compact groove section 2, a common filter stick section 3 and a first adsorption section 4 which are sequentially butted, grooves 5 are uniformly arranged on the outer peripheral surface of the compact groove section 2 and are used for smoke circulation, the common filter stick section 3 is made of acetate fiber or polypropylene materials, and the first adsorption section 4 contains cucurbituril adsorption materials and can adsorb and filter harmful substances in tar in smoke. The preparation method of the first adsorption section 4 comprises the following steps: selecting adsorption material particles, adding essence, mixing and wetting, drying, sieving to obtain adsorption particles with the particle size of 20-50 meshes, mixing the adsorption particles into cellulose acetate fiber bundles to obtain a first adsorption section 4, wherein the loading capacity of the cucurbituril adsorption material is 0.5-1mg/mm, and the common filter rod section 3 plays a role in preventing the adsorption material from entering the oral cavity during suction. The tight die mould groove section 2 compresses tightly the shaping for adopting cellophane or high ventilative profiled paper, and 5 terminal surfaces of slot are the V type for the terminal surface of tight die mould groove section 2 is the twelve-pointed star, and 5 low points of slot connect dress paper 1 apart from the outsourcing to be 0.1 ~ 1mm, make tight die mould groove section 2 can effectively support outlying outsourcing and connect dress paper 1, can ensure the flue gas simultaneously and pass through efficiency. In the embodiment, the diameter of the filter stick is 8mm, the total length is 35mm, the length of the compacting groove section 2 is 10mm, the length of the common filter stick section 3 is 10mm, and the length of the first adsorption section 4 is 15 mm. And, the outsourcing of 3 suction ends of ordinary filter rod sections is opened to be circular array on the wrapping paper 1 and is had air vent 6, and air vent 6 is opened totally and has two sets ofly, and the interval is 1mm, and every quantity of group is 20, and preceding a set of air vent 5 is 1mm apart from 2 distances of compact groove section, can reduce to inhale and hinder and form cooling effect to the flue gas, promotes to inhale the taste.
Unchanged color theory after aspiration: the common filter rod section 3 and the first adsorption section 4 can adsorb and filter harmful substances such as tar in the mainstream smoke of the cigarette, reduce the release amount of tar and reduce the harm of cigarette smoking; flue gas after adsorption filtration gets into compact form groove section 2, gets into consumer's oral area through slot 5, reduces being infected with compact form groove section 2 for compact form groove section 2 terminal surface discolours after the suction, promotes cigarette suction sensory quality. The cucurbituril is easy to interact with hydrophilic substances, metal ions and the like due to the fact that the cucurbituril is provided with polar ports and hydrophobic cavities with different sizes, and hydrophobic parts or organic molecules of various molecules can be accommodated in the hydrophobic cage-shaped cavities. And the sizes of partial polycyclic aromatic hydrocarbon molecules in the smoke are matched with each other, and the tar is selectively adsorbed through the host-guest interaction. And the adsorption effect of the tar adsorbent on aroma components such as megastigmatriene containing tobacco aroma, neophytadiene and the like is not obvious, so that the tar adsorbent can ensure the tobacco aroma and selectively adsorb harmful components in tar.
Example 2
As shown in fig. 2, on the basis of embodiment 1, the first adsorption section 4 is provided with a second adsorption section 7 at the tobacco shred end, and the second adsorption section 7 contains an activated carbon adsorption material, so as to improve the release amount control of tar and the harmful substance adsorption effect in the mainstream smoke of cigarettes. In this example, the filter element comprises a pressure type groove section 2, a common filter rod section 3, a first adsorption section 4 and a second adsorption section 7, wherein the length of the pressure type groove section 2 is 10mm, the length of the common filter rod section 3 is 10mm, and the lengths of the first adsorption section 4 and the second adsorption section 7 are respectively 8mm and 7 mm. The preparation method of the second adsorption section 7 comprises the following steps: selecting adsorption material particles, adding essence, mixing and wetting, drying, sieving to obtain adsorption particles with the particle size of 20-50 meshes, mixing the adsorption particles with acetate fiber bundles to obtain a second adsorption section 7, wherein the loading capacity of the activated carbon adsorption material is 0.5-1 mg/mm.
Unchanged color theory after aspiration: through the matching of the common filter rod section 3, the first adsorption section 4 and the second adsorption section 7, harmful substances such as tar in the mainstream smoke of the cigarette can be selectively adsorbed and filtered, the tar release amount is reduced, the harm of cigarette suction is reduced, and meanwhile, the suction resistance of the filter rod can be effectively reduced and the adsorption performance of the filter rod can be enhanced by only adopting cucurbituril as an adsorption material; flue gas after the selective adsorption enters the compact type groove section 2 and enters the mouth of a consumer through the groove 5, so that the pollution to the compact type groove section 2 is reduced, the end face of the compact type groove section 2 after smoking is not discolored, and the sensory quality of cigarette smoking is further improved. Wherein, the active carbon adsorption principle carries out adsorption by two means of physics and chemistry. The physical adsorption provides a large amount of surface area through the porous structure of the activated carbon, so that the activated carbon can easily absorb impurities, and the chemical adsorption is that the activated carbon surface contains a small amount of chemically bound oxygen and hydrogen in the form of functional groups, such as carboxyl, hydroxyl, lactones and the like, and the chemically bound oxygen and hydrogen can react with adsorbed substances, so that the adsorbed substances are bound and gathered on the activated carbon surface. Has adsorption effect on aldehyde ketone, ester, acid and nitrogen heterocyclic components in the smoke, thereby achieving the purpose of selectively reducing harmful components in the tar. In addition, the activated carbon adsorption material has an unobvious adsorption effect on aroma components such as megastigmatriene containing tobacco aroma, neophytadiene and the like, so that the activated carbon adsorption material can ensure the tobacco aroma and selectively adsorb harmful components in tar.
Comparative example 1
A cigarette filter stick is a common unitary acetate fiber filter stick without a special structure.
Analysis of experiments
1) The filter sticks manufactured under the same conditions according to the examples 1 and 2 and the comparative example 1 are used as experimental samples, the experimental samples are taken before suction, blank control is taken after suction, and after an automatic smoking machine is adopted, the end faces of the filter sticks close to the mouth end are subjected to color difference analysis, and the results are shown in a table 1:
TABLE 1 color difference analysis results of filter sticks at the tip
Sample (I) dE value before and after aspiration After suction appearance
Example 1 1.51 Does not change color
Example 2 1.33 Does not change color
Comparative example 1 26.88 Yellowing of
As can be seen from table 1: the dE value of the common acetate fiber filter stick before and after suction is 26.88, and the appearance of the common acetate fiber filter stick after suction is observed to turn yellow. While the multi-component composite filter stick without the adsorbing material is prepared in example 1, the dE value before and after suction is 1.51, and the appearance after suction is observed to be unchanged, the multi-component composite filter stick with the adsorbing material is prepared in example 1, the dE value before and after suction is 1.33, and the appearance after suction is observed to be unchanged. Compared with the cigarette adopting the common acetate fiber filter stick, the multi-component composite filter stick has better adsorption effect on filter stick dyeing substances such as tar and the like, achieves the effect of no color change after smoking, and improves the smoking sensory quality of the cigarette.
2) The filter rods prepared according to examples 1 and 2 and comparative example 1 under the same conditions were used as experimental samples to perform a resistance-on-draw test on cigarettes, and the results are shown in table 2:
TABLE 2 cigarette resistance
Sample (I) Comparative example 1 Example 1 Example 2
Suction resistance (Kpa) 4.0 4.6 4.4
As can be seen from table 2: the maximum difference of the suction resistance of the common filter stick in the embodiment is 0.6Kpa, which does not affect the normal suction. Among them, example 1 has a higher absorption resistance than example 2, which is caused by the larger pore size of the activated carbon than cucurbituril.
3) The filter sticks prepared under the same conditions according to the examples 1 and 2 and the comparative example 1 are used as experimental samples, and after the filter sticks are trapped by a Cambridge filter of a smoking machine, the components of the cigarette smoke are analyzed by GC-MS, and the results are shown in Table 1:
TABLE 3 analysis results of flue gas fraction
Figure BDA0002418215380000041
Figure BDA0002418215380000051
As can be seen from table 3: the smoke components of the common filter stick cigarette are not greatly different from those of the embodiment, so that the sensory quality of the cigarette is ensured. And the embodiment 1 and the embodiment 2 have certain adsorption capacity compared with the common filter stick cigarette.
TABLE 4 sensory evaluation analysis results
Figure BDA0002418215380000061
As can be seen from Table 4, the cigarette prepared by the invention can reduce the irritation and offensive odor of the cigarette while ensuring the cigarette fragrance.
Finally, it is noted that the above-mentioned preferred embodiments illustrate rather than limit the invention, and that, although the invention has been described in detail with reference to the above-mentioned preferred embodiments, it will be understood by those skilled in the art that various changes in form and detail may be made therein without departing from the scope of the invention as defined by the appended claims.

Claims (8)

1. The utility model provides a cigarette multi-element composite filter stick that does not change colour after suction, includes filter core and outsourcing tipping paper (1), its characterized in that: the filter core is including the compact die type groove section (2), ordinary filter rod section (3) and first absorption section (4) that dock in proper order, evenly sets up slot (5) on compact die type groove section (2) outer peripheral face.
2. The multi-component composite filter stick of cigarettes not changing color after being smoked according to claim 1, characterized in that: the compacting groove section (2) is compacted and molded by adopting glass paper or high-permeability molding paper.
3. The multi-component composite filter stick for cigarettes not changing color after being smoked according to claim 1 or 2, which is characterized in that: the outer wrapping paper (1) at the suction end of the common filter rod section (3) is provided with vent holes (6) in a circular array.
4. The multi-component composite filter stick of cigarettes not changing color after being smoked according to claim 3, characterized in that: the end surface of the groove (5) is V-shaped, and the end surface of the compact groove section (2) is in a dodecagonal star shape.
5. The multi-component composite filter stick for cigarettes not changing color after being smoked according to claim 1, 2 or 4, characterized in that: the first adsorption section (4) contains cucurbituril adsorption material.
6. The multi-component composite filter stick of cigarettes not changing color after being smoked according to claim 5, characterized in that: the first adsorption section (4) is connected with a second adsorption section (7) at the tobacco shred end, and the second adsorption section (7) contains activated carbon adsorption materials.
7. The multi-component composite filter stick of cigarettes not changing color after being smoked according to claim 6, characterized in that: the preparation method of the first adsorption section (4) and the second adsorption section (7) comprises the following steps: selecting adsorption material particles, adding essence, mixing and wetting, drying, sieving to obtain adsorption particles with the particle size of 20-50 meshes, and mixing the adsorption particles with acetate fiber tows to obtain a first adsorption section (4) and a second adsorption section (7).
8. The multi-component composite filter stick of cigarettes not changing color after being smoked according to claim 6 or 7, characterized in that: the loading capacity of the cucurbituril adsorbing material and the loading capacity of the activated carbon adsorbing material in the first adsorbing section (4) and the second adsorbing section (7) are both 0.5-1 mg/mm.
CN202010197727.9A 2020-03-19 2020-03-19 Cigarette multi-component composite filter stick without color change after smoking Pending CN111480883A (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4727892A (en) * 1985-03-07 1988-03-01 Fabriques De Tabac Reunies, S.A. Ventilated cigarette
CN101433372A (en) * 2008-12-12 2009-05-20 广东中烟工业有限责任公司 Filter material of cigarette filter stick and cigarette filter stick
CN201563606U (en) * 2009-11-23 2010-09-01 牡丹江卷烟材料厂有限责任公司 Novel ternary composite filter rod
CN102423130A (en) * 2011-08-12 2012-04-25 南通烟滤嘴有限责任公司 Polynary composite filter tip and polynary composite filter stick
CN206137184U (en) * 2016-04-22 2017-05-03 浙江中烟工业有限责任公司 Cigarette is with outer slot ternary composite filter rod
CN106666826A (en) * 2017-02-24 2017-05-17 江西中烟工业有限责任公司 Cucurbituril additive for reducing harm and enhancing aroma of cigarettes and preparation method of cucurbituril additive

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4727892A (en) * 1985-03-07 1988-03-01 Fabriques De Tabac Reunies, S.A. Ventilated cigarette
CN101433372A (en) * 2008-12-12 2009-05-20 广东中烟工业有限责任公司 Filter material of cigarette filter stick and cigarette filter stick
CN201563606U (en) * 2009-11-23 2010-09-01 牡丹江卷烟材料厂有限责任公司 Novel ternary composite filter rod
CN102423130A (en) * 2011-08-12 2012-04-25 南通烟滤嘴有限责任公司 Polynary composite filter tip and polynary composite filter stick
CN206137184U (en) * 2016-04-22 2017-05-03 浙江中烟工业有限责任公司 Cigarette is with outer slot ternary composite filter rod
CN106666826A (en) * 2017-02-24 2017-05-17 江西中烟工业有限责任公司 Cucurbituril additive for reducing harm and enhancing aroma of cigarettes and preparation method of cucurbituril additive

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