CN209300271U - A kind of ternary vinegar fibre Composite Hollow filter stick reducing Volatile phenolics in cigarette smoke - Google Patents
A kind of ternary vinegar fibre Composite Hollow filter stick reducing Volatile phenolics in cigarette smoke Download PDFInfo
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- CN209300271U CN209300271U CN201821673307.8U CN201821673307U CN209300271U CN 209300271 U CN209300271 U CN 209300271U CN 201821673307 U CN201821673307 U CN 201821673307U CN 209300271 U CN209300271 U CN 209300271U
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Abstract
The ternary vinegar fibre Composite Hollow filter sticks of Volatile phenolics in cigarette smoke can be reduced the utility model discloses one kind, which includes filter core and the interior wrapping layer and the outer casing that are wrapped on filter core；Wherein, filter core is tri compound filter core, is sequentially combined and is constituted by common acetate fiber section, chitosan oligosaccharide grafted polyacrylic acid absorbing material granules section and common acetate fiber section.The utility model is compound by three-stage, chitosan oligosaccharide grafted polyacrylic acid adsorbent material is as drop evil component, the acrylate moiety being grafted in chitosan oligosaccharide grafted polyacrylic acid absorbing material granules section contains a large amount of carboxyl, it is adsorbed with phenol and ammonia etc. by hydrogen bond action, in this way while keeping original filter stick adsorption capacity, the content of the harmful substances such as phenol and ammonia in main flume can be effectively reduced, further so as to preferably realize the purpose for reducing cigarette harmfulness, improving cigarette smoking quality.
Description
Technical field
The utility model belongs to the filter stick technical field of manufacture cigarette filter, and in particular to one kind can reduce in cigarette smoke
The ternary vinegar fibre Composite Hollow filter stick of Volatile phenolics.
Background technique
With the continuous improvement of common people's health perception, smoking has become worldwide important class with health problem at present
Topic.In recent years, to reduce cigarette harmfulness, the health of protection smoking consumer expands widely in Harm reduction techniques field
Research is a kind of more common method by adding harm reduction material or adsorbent material in tobacco or filter tip.
Phenolic compound is one kind pernicious gas biggish to health effect in cigarette mainstream flue gas, although in the prior art
Existing part is directed to the research for reducing adsorbent material used in phenolic compound in cigarette mainstream flue gas, and has obtained certain technology effect
Fruit, but for practical application, it is still necessary to the application with regard to new adsorbent material and its in cigarette is further studied, from
It and is that the stabilization of cigarette quality is improved and establishes good application foundation.
It in the prior art, is mostly single acetate fiber unitary filter stick for manufacture cigarette filter, to reduction cigarette
Although the harmful substance of main flume has a certain effect, but adsorb harmful substance when there are still non-selective, harm reduction effect compared with
For limited defect.
Some functional materials are added in filter stick to change the taste of cigarette or for reducing its tar currently, also having
Amount.But these existing filter sticks can not harmful Volatile phenolics (such as: phenol) in selectivity reducing cigarette fume
And therefore ammonia reduces the filter stick of Volatile phenolics and ammonia in cigarette smoke and still has improved necessity for existing.
Utility model content
The utility model aim is to overcome prior art defect, and phenol compounds in cigarette smoke can be reduced by providing one kind
The ternary vinegar fibre Composite Hollow filter stick of compound, can Volatile phenolics in selectivity reducing cigarette fume, the range of decrease
Reach 20%, to achieve the purpose that reduce cigarette harmfulness, improve cigarette smoking quality.
To achieve the above objectives, the present invention adopts the following technical solutions:
A kind of ternary vinegar fibre Composite Hollow filter stick reducing Volatile phenolics in cigarette smoke, the ternary vinegar are fine
Composite Hollow filter stick includes filter core and the interior wrapping layer and the outer casing that are wrapped on filter core；Wherein, filter core is tri compound filter
Core is sequentially combined by common acetate fiber section, chitosan oligosaccharide grafted polyacrylic acid absorbing material granules section and common acetate fiber section
It constitutes.
Specifically, above-mentioned ternary vinegar fibre Composite Hollow filter stick, by the common acetate fiber section of 10-12mm and 5mm chitosan oligosaccharide
Grafted polyacrylic acid absorbing material granules section and the common acetate fiber section of 10-12mm sequentially combine composition, ternary vinegar fibre compound air
Chamber filter stick overall length 25-29mm.
In order to obtain the preferable effect for reducing Volatile phenolics in cigarette smoke, chitosan oligosaccharide grafted polyacrylic acid
The size of absorbing material granules is suitable in 20-40 mesh, and it is more round better that degree of rounding of grains requires.
Further, the interior wrapping layer is forming paper.The outer casing is tipping paper.
In the present invention, chitosan oligosaccharide grafted polyacrylic acid absorbing material granules section is by chitosan oligosaccharide grafted polyacrylic acid
Adsorbent material is connect with graininess with common acetate fiber section after being directly granulated, this can be realized using this field routine techniques,
So repeating no more.Prior art preparation can be used in chitosan oligosaccharide grafted polyacrylic acid adsorbent material.Such as, chitosan oligosaccharide grafting is poly-
Acrylic acid adsorbent material can refer to a kind of Chinese patent application (application number CN201610275507.7) " chitosan oligosaccharide graft polypropylene
It is prepared by the preparation method of sour adsorbent material ".
Compared to the prior art, the utility model has the beneficial effects that
1) the utility model is compound by three-stage, and chitosan oligosaccharide grafted polyacrylic acid adsorbent material is as drop evil component, shell
The acrylate moiety being grafted in oligosaccharides grafted polyacrylic acid absorbing material granules section contains a large amount of carboxyl and phenol etc. and passes through hydrogen
Key is acted on and is adsorbed, and in this way while keeping original filter stick adsorption capacity, benzene in main flume can further be effectively reduced
The content of the harmful substances such as phenol and ammonia, so as to preferably realize the purpose for reducing cigarette harmfulness, improving cigarette smoking quality, tool
There is good application value；
2) the utility model it is found through experiment that: ternary vinegar fibre Composite Hollow filter stick can significant selectivity reducing cigarette fume
Middle Volatile phenolics such as phenol etc. decreases by 20% or more, and ammonia content reduces by 50% or more.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of ternary vinegar fibre Composite Hollow filter stick described in the utility model.
Specific embodiment
The utility model is described in further details with reference to the accompanying drawing, but the protection scope of the utility model is not limited to
This.
Embodiment 1
As shown in Figure 1, a kind of ternary vinegar fibre Composite Hollow filter stick that can reduce Volatile phenolics in cigarette smoke,
The ternary vinegar fibre Composite Hollow filter stick includes filter core 1 and the interior wrapping layer forming paper 2 being wrapped on filter core and outer casing tipping
Paper 3；Wherein, filter core 1 is the tri compound filter core of overall length 29mm, is grafted by common acetate fiber section 1a, 5mm chitosan oligosaccharide of 12mm poly-
The common acetate fiber section 1a of acrylic acid absorbing material granules section 1b and 12mm sequentially combines composition.
In order to obtain the preferable effect for reducing Volatile phenolics in cigarette smoke, chitosan oligosaccharide grafted polyacrylic acid
The size of absorbing material granules is suitable in 20-40 mesh, and it is more round better that degree of rounding of grains requires.Entire filter stick manufacturing process: will be complete
Filter stick is cut into the segment dispersed arrangement of length 24mm, and the gap 5mm is stayed in centre；Equipped with chitosan oligosaccharide grafted polyacrylic acid adsorbent material
The hopper of grain uniformly pours into a certain amount of particle in the gap 5mm, by interior wrapping layer forming paper by particle and filter stick tight,
Finally complete cutting.
Application test
To examine ternary vinegar fibre Composite Hollow filter stick provided herein ammonia and phenol etc. in reducing cigarette smoke to have
Technical effect in terms of evil substance release amount, inventor have carried out further experiment detection, have been briefly discussed below.
The cigarette of the 29mm long ternary vinegar fibre Composite Hollow filter stick prepared with embodiment 1 is experiment sample, meanwhile, in identical item
Using the cigarette of common cellulose acetate filter rod prepared by the prior art as blank control sample under part, it is with the finished cigarettes of certain brand
Example is determined the burst size of ammonia of main stream smoke of cigarette and phenol after using the suction of auto-pumping smoke machine.It is specific to survey
It is as shown in table 1 below to determine result.
Table 1, to the test result of ammonia and phenol in kinds of cigarettes main flume
| Sample | Ammonia (μ g/ branch) | Phenol (μ g/ branch) |
| Blank control sample | 5.5461 | 45.7271 |
| Embodiment 1 | 2.7219 | 35.5799 |
By upper table 1 it can be seen that being compared with using the cigarette blank control sample of common cellulose acetate filter rod, the utility model
Ternary vinegar fibre Composite Hollow filter stick has different degrees of reduction to harmful components ammonia, phenol content.Wherein, ammonia content reduces
50.92%, phenol content reduces by 22.19%.
The principles of the present invention are: in the intermediate connection chitosan oligosaccharide grafted polyacrylic acid absorption of common cellulose acetate filter rod
As evil component is dropped, these drop the acrylate moiety that is grafted in evil components and contain a large amount of carboxyl material granule section, can and benzene
Phenol etc. is adsorbed by hydrogen bond action, in this way while keeping original filter stick adsorption capacity, can further decrease mainstream smoke
The content of the harmful substances such as ammonia and phenol, improves the quality of cigarette in gas.
It should be noted last that: the technical solution of the utility model that the above embodiments are only illustrative and not limiting is appointed
What to the utility model carry out equivalent replacement and do not depart from the spirit and scope of the utility model modification or part replace,
It should cover within the scope of the utility model claims protection.
Claims (5)
1. the ternary vinegar fibre Composite Hollow filter stick that one kind can reduce Volatile phenolics in cigarette smoke, which is characterized in that
The ternary vinegar fibre Composite Hollow filter stick includes filter core and the interior wrapping layer and the outer casing that are wrapped on filter core；Wherein, filter core is
Tri compound filter core, by common acetate fiber section, chitosan oligosaccharide grafted polyacrylic acid absorbing material granules section and common acetate fiber
Duan Shunci combination is constituted.
2. the ternary vinegar fibre Composite Hollow filter stick of Volatile phenolics in cigarette smoke can be reduced as described in claim 1,
It is characterized in that, the ternary vinegar fibre Composite Hollow filter stick is by the common acetate fiber section of 10-12mm and 5mm chitosan oligosaccharide grafting poly- third
Olefin(e) acid absorbing material granules section and the common acetate fiber section of 10-12mm sequentially combine composition, and ternary vinegar fibre Composite Hollow filter stick is total
Long 25-29mm.
3. the ternary vinegar fibre Composite Hollow filter of Volatile phenolics in cigarette smoke can be reduced as claimed in claim 1 or 2
Stick, which is characterized in that the size of chitosan oligosaccharide grafted polyacrylic acid absorbing material granules is 20-40 mesh.
4. the ternary vinegar fibre Composite Hollow filter stick of Volatile phenolics in cigarette smoke can be reduced as claimed in claim 3,
It is characterized in that, the interior wrapping layer is forming paper.
5. the ternary vinegar fibre Composite Hollow filter stick of Volatile phenolics in cigarette smoke can be reduced as claimed in claim 3,
It is characterized in that, the outer casing is tipping paper.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201821673307.8U CN209300271U (en) | 2018-10-16 | 2018-10-16 | A kind of ternary vinegar fibre Composite Hollow filter stick reducing Volatile phenolics in cigarette smoke |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201821673307.8U CN209300271U (en) | 2018-10-16 | 2018-10-16 | A kind of ternary vinegar fibre Composite Hollow filter stick reducing Volatile phenolics in cigarette smoke |
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| Publication Number | Publication Date |
|---|---|
| CN209300271U true CN209300271U (en) | 2019-08-27 |
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| CN201821673307.8U Active CN209300271U (en) | 2018-10-16 | 2018-10-16 | A kind of ternary vinegar fibre Composite Hollow filter stick reducing Volatile phenolics in cigarette smoke |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111358052A (en) * | 2020-04-16 | 2020-07-03 | 江苏大亚滤嘴材料有限公司 | Ternary cavity composite filter stick containing cuprous ion-based MOFs-gel particles with CO specific adsorption capacity |
| CN112167706A (en) * | 2020-09-28 | 2021-01-05 | 江苏中烟工业有限责任公司 | Additive for cigarette filter stick for reducing ammonia in cigarette smoke and application thereof |
| CN113197344A (en) * | 2021-05-13 | 2021-08-03 | 云南中烟工业有限责任公司 | Composite acetate fiber, preparation method and application thereof |
-
2018
- 2018-10-16 CN CN201821673307.8U patent/CN209300271U/en active Active
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111358052A (en) * | 2020-04-16 | 2020-07-03 | 江苏大亚滤嘴材料有限公司 | Ternary cavity composite filter stick containing cuprous ion-based MOFs-gel particles with CO specific adsorption capacity |
| CN112167706A (en) * | 2020-09-28 | 2021-01-05 | 江苏中烟工业有限责任公司 | Additive for cigarette filter stick for reducing ammonia in cigarette smoke and application thereof |
| CN112167706B (en) * | 2020-09-28 | 2022-09-02 | 江苏中烟工业有限责任公司 | Additive for cigarette filter stick for reducing ammonia in cigarette smoke and preparation method and application thereof |
| CN113197344A (en) * | 2021-05-13 | 2021-08-03 | 云南中烟工业有限责任公司 | Composite acetate fiber, preparation method and application thereof |
| CN113197344B (en) * | 2021-05-13 | 2022-05-24 | 云南中烟工业有限责任公司 | Composite acetate fiber, preparation method and application thereof |
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