CN106665570A - Foam cleaning disinfectant containing peracetic acid and application of foam cleaning disinfectant - Google Patents
Foam cleaning disinfectant containing peracetic acid and application of foam cleaning disinfectant Download PDFInfo
- Publication number
- CN106665570A CN106665570A CN201611185724.3A CN201611185724A CN106665570A CN 106665570 A CN106665570 A CN 106665570A CN 201611185724 A CN201611185724 A CN 201611185724A CN 106665570 A CN106665570 A CN 106665570A
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- Prior art keywords
- foam
- foam cleaning
- cleaning
- peracetic acid
- sterilizing agent
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/22—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
Abstract
The invention relates to a foam cleaning disinfectant containing peracetic acid. The foam cleaning disinfectant containing the peracetic acid is characterized by being prepared from acetic acid, hydrogen peroxide, a surfactant and water. The invention also provides a use method and application of the foam cleaning disinfectant containing the peracetic acid. The foam cleaning disinfectant containing the peracetic acid has the advantages that the high-efficiency disinfection effect of the peracetic acid is utilized; by adding the cleaning and foaming surfactant, the widely applied foam cleaning disinfectant is obtained; compared with a soaking or spraying type disinfection method, the usage amount of the disinfectant is reduced by foam disinfection, and the foam cleaning disinfectant can be used for performing foam disinfection on equipment surfaces, inclined surfaces, channels, coarse grounds and the like; while the disinfection function is realized, the cleaning function is also realized, and the number of complicated steps is reduced.
Description
Technical field
The present invention relates to disinfectant field, more particularly to a kind of foam cleaning and sterilizing agent containing peracetic acid and its should
With.
Background technology
There are miscellaneous foam cleaning agent and disinfectant in the fields such as food and drink, health care.Wherein sodium hypochlorite disappears
Toxic agent is very popular, not only with Disinfection Effect and can decompose organic dirt, with cleaning performance.But the cleaning containing sodium hypochlorite
All the time stability is poor for sterile products, and 30 days contents decrease beyond 10% under suitable condition of storage;Sodium hypochlorite corrodes
Property it is strong, easily spot corrosion is caused to equipment.In recent years unitary peracetic acid is widely used as high effect disinfectantses in various occasions, is made
Peroxyacetic acid disinfectant is soaked, is rinsed, spraying article to be sterilized by the used time, operation is had high demands and disinfectant solution utilization rate is low, mistake
The cleansing power of fluoroacetic acid is limited, needs further to be cleaned using abluent before sterilization or after sterilization..
Therefore, it is necessary to provide a kind of foam cleaning and sterilizing agent, stable foam can be produced such that it is able to there is inclination
It is little that the body surface of angle or vertical object surface carry out the cleaning and sterilizing of foam coverage, disinfectant consumption, and while sterilization
Cleaning action can be played.
The content of the invention
An object of the present invention is to provide a kind of foam cleaning and sterilizing agent containing peracetic acid, and the foam cleaning disappears
Toxic agent can save disinfectant consumption, and foam wall built-up effect is good, and while sterilization cleaning action can be played.
To realize the purpose, the present invention provides a kind of foam cleaning and sterilizing agent containing peracetic acid, the foam cleaning
Disinfectant includes acetic acid, hydrogen peroxide, surfactant and water.
It is preferred that calculating according to mass percent, foam cleaning and sterilizing agent includes following components:
It is preferred that the surfactant includes oxidation amine surfactants and alkyl benzene sulphonate or its salt.
It is preferred that the oxidation amine surfactants are N- dimethyl-alkyl amine oxide, according to mass percentage
Calculate, the content of the oxidation amine surfactants is 1%~9%.
It is preferred that the alkylbenzenesulfonate is alkyl benzene sulphonate sodium salt or benzene sulfonamide acid potassium salt, according to quality percentage
Number is calculated, and the content of the alkyl benzene sulphonate or its salt is 1%~5%.
It is preferred that foam cleaning and sterilizing agent also includes stabilizer, calculate according to mass percent, the stabilizer
Content is 0~1%.
It is preferred that the stabilizer is at least one in EDTA, PAA, HEDP, EDTMP, NTA.
Another object of the present invention is providing a kind of method using foam cleaning and sterilizing agent as above, methods described bag
Include step:
(1) the foam cleaning and sterilizing agent is diluted;
(2) by dilution after the foam cleaning and sterilizing agent foaming;And
(3) the foam cleaning and sterilizing agent after foaming covers cleaning and sterilizing thing surface.
It is preferred that the using method also includes step (4):Rinse the foam on cleaning and sterilizing thing surface.
Another object of the present invention is to provide a kind of application of foam cleaning and sterilizing agent as above, and the foam is clear
Decontamination venom is applied to cleaning and sterilizing food manufacturing apparatus, factory, hospital or irrigation canals and ditches.
Prior art is compared, and the foam cleaning and sterilizing agent containing peracetic acid according to the present invention, its advantage includes:
The peracetic acid that the acetic acid and hydrogen peroxide of the present invention are generated has an efficient Disinfection Effect, surfactant plus
Entering can be so that disinfectant has foaming effect and more preferable cleaning performance.The foam cleaning disinfection liquid can produce stable bubble
Foam such that it is able to carry out the cleaning and sterilizing of foam coverage to the body surface that has angle of inclination or vertical object surface, foam disappears
Poison more saves disinfectant consumption than immersion or fountain sterilization, can be used for equipment surface, inclined plane, irrigation canals and ditches, rough earth
Deng foam disinfectant, and sterilize while can play cleaning action.
The addition that peracetic acid has strong oxidizing property, conventional surfactants is easily decomposed, and catabolic process consumes big
The peracetic acid of amount, affects the Disinfection Effect of product.Alkyl benzene sulphonate or its salt, oxidation amine surfactants resistance to oxidation, no
Easily by decomposition of peracetic acid.However, the addition of alkyl benzene sulphonate or its salt is a small amount of, less than oxidation amine surfactants
Addition so that the foam cleaning disinfection liquid is more stable.Stabilizer, stabilizer can be also added to chelate miscellaneous in the foam cleaning agent
The material of the catalysis peracetic acid reaction such as matter, unhindered amina, metal ion, further improves the stability of foam cleaning disinfection liquid.
Alkyl benzene sulphonate or its salt belong to anion surfactant, there is a good cleaning performance, and amine-oxides class surfactant can be with
Foaming, and foam can be kept more stable, the adhesive force on thing surface increases.Both compoundings had caused foam cleaning disinfection liquid both
Cleaning performance is enhanced, and with frothing function so as to new occupation mode, it is easy to execute-in-place, expand its application
Scope.
Specific embodiment
The present invention is intended to provide a kind of foam cleaning and sterilizing agent containing peracetic acid, the foam cleaning and sterilizing agent can be saved
Disinfectant consumption, foam wall built-up effect is good, and while sterilization cleaning action can be played.
The agent of foam cleaning and sterilizing includes acetic acid, hydrogen peroxide, surfactant and water, calculates according to mass percent, bubble
The agent of foam cleaning and sterilizing includes following components:
It is preferred that surfactant includes oxidation amine surfactants and alkyl benzene sulphonate or its salt.
It is preferred that oxidation amine surfactants are N- dimethyl-alkyl amine oxide, calculate according to mass percent, oxygen
The content for changing amine surfactants is 1%~9%.
It is preferred that alkylbenzenesulfonate is alkyl benzene sulphonate sodium salt or benzene sulfonamide acid potassium salt, according to mass percentage
Calculate, the content of alkyl benzene sulphonate or its salt is 1%~5%.
It is preferred that the agent of foam cleaning and sterilizing also includes stabilizer, calculate according to mass percent, the content of stabilizer is 0
~1%.
It is preferred that stabilizer is at least one in EDTA, PAA, HEDP, EDTMP, NTA.
Using the method for as above foam cleaning and sterilizing agent, method includes step:
(1) foam cleaning and sterilizing agent is diluted;
(2) the foam cleaning and sterilizing agent after dilution is foamed;
(3) the foam cleaning and sterilizing agent after foaming covers cleaning and sterilizing thing surface;And
(4) foam on cleaning and sterilizing thing surface is rinsed.
Foam cleaning disinfection liquid is applied to into cleaning and sterilizing food manufacturing apparatus, factory, hospital or irrigation canals and ditches.
The present invention is further elaborated for specific examples below, but not as a limitation of the invention.
Embodiment 1
A kind of agent of peracetic acid foam cleaning and sterilizing is made up of by weight percent following raw material, and preparation process is as follows:
7 parts of water, 1 part of acetic acid, 1 part of hydrogen peroxide is added to be uniformly mixed in plastic bottle;Add cetyl sulfonic acid
0.02 part of sodium, adds N- dimethyl-cetyl amine oxide content to be 0.2 part, adds EDTA to be 0.02 part;Add after stirring remaining
Amount water.Product is stored at room temperature 1-7 days, and peroxyacetic acid concentration is determined for 0.28% using the quick reagent paper that determines.
Embodiment 2
A kind of agent of peracetic acid foam cleaning and sterilizing is made up of by weight percent following raw material, and preparation process is as follows:
5 parts of water, 3.5 parts of acetic acid, 2 parts of hydrogen peroxide is added to be uniformly mixed in plastic bottle;Add xylene monosulfonic acid
0.05 part of sodium, adds N- dimethyl-cetyl amine oxide content to be 0.3 part, adds NTA to be 0.02 part;Add after stirring remaining
Amount water.Product is stored at room temperature 1-7 days, and peroxyacetic acid concentration is determined for 3.5% using the quick reagent paper that determines.
Embodiment 3
A kind of agent of peracetic acid foam cleaning and sterilizing is made up of by weight percent following raw material, and preparation process is as follows:
3 parts of water, 4 parts of acetic acid, 2.5 parts of hydrogen peroxide is added to be uniformly mixed in plastic bottle;Add xylene monosulfonic acid
0.05 part of sodium, adds N- dimethyl-cetyl amine oxide content to be 0.4 part, adds EDTA to be 0.04 part;Add after stirring remaining
Amount water.Product is stored at room temperature 1-7 days, and peroxyacetic acid concentration is determined for 5.4% using the quick reagent paper that determines.
Comparative example 1
A kind of peracetic acid is made up of by weight percent without alveolitoid disinfectant following raw material, and preparation process is as follows:
3 parts of water, 4 parts of acetic acid, 2.5 parts of hydrogen peroxide is added to be uniformly mixed in plastic bottle;Add xylene monosulfonic acid
0.05 part of sodium, adds EDTA to be 0.04 part;Excess water is added after stirring.Product is stored at room temperature 1-7 days, and using quick reagent paper is determined
It is 5.4% to determine peroxyacetic acid concentration.
Disinfectant solution prepared by Example 1~3 and comparative example 1 by test method according to《Disinfection technology standard》(2002 editions)
Requirement is carried out, using suspension quantitative bacteric idal experiment.
The bactericidal effect of foam cleaning and sterilizing agent
By diluted sample to peracetic acid content be 1000mg/L, disinfection time 30S-60S, experimental result such as table 1
It is shown.
The bactericidal effect of the foam cleaning disinfection liquid of table 1
As can be seen from Table 1 foam cleaning disinfection liquid of the present invention has good inhibiting effect to common pathogenic bacteria, can
Killing rate is up to 100%, and sterilizing time can be as short as 1min.The foam stabilization of embodiment 1~3, it is time of contact long with thing table, it is more right
Ratio 1 has more preferable bactericidal effect.
Foam cleaning and sterilizing agent frostproof froth n is determined
500ml peracetic acid solns (peracetic acid is diluted to 1000mg/L) are made highly to flow to same solution from 450mm
After solution surface, Roche foam meter measures at room temperature the foam volume for obtaining.
The sample foams performance test one of table 2
Sample number into spectrum | Initial foam cm | 3min foams | 10min foams |
Embodiment 1 | 68 | 52 | 33 |
Embodiment 2 | 49 | 42 | 24 |
Embodiment 3 | 36 | 28 | 18 |
Comparative example 1 | 6 | 0 | 0 |
The foam cleaning and sterilizing agent foam stabilization time
Method of testing, is foamed the sample 500g after dilution on corrosion resistant plate with foaming machine, and corrosion resistant plate area is 1 flat
Square rice, inclines 45 degree of angles, and on foam uniform fold to panel, the foam slid from stainless steel faceplate is collected in panel lower section.On time
Between weigh slide foam weight.
The sample foams performance test two of table 3
Sample number into spectrum | 1min | 2min | 5min | 10min |
Embodiment 1 | 193 | 374 | 425 | 459 |
Embodiment 2 | 247 | 396 | 432 | 470 |
Embodiment 3 | 253 | 401 | 450 | 472 |
Comparative example 1 | 442 | 468 | 472 | 473 |
Frostproof froth n is determined, the foam stabilization time two determines and illustrates simultaneously, and embodiment 1, embodiment 2, embodiment 3 has
Preferable foaming effect, foam has certain stability, it is possible to use foaming machine is normally foamed, and is capable of achieving foam disinfectant.
The foam stability extreme difference of comparative example 1, it is impossible to normally foamed using foaming machine, sample is not foamed and is directly wandered to face
Plate lower section.
Prior art is compared, and the foam cleaning and sterilizing agent containing peracetic acid according to the present invention, its advantage includes:
The peracetic acid that the acetic acid and hydrogen peroxide of the present invention are generated has an efficient Disinfection Effect, surfactant plus
Entering can be so that disinfectant has foaming effect and more preferable cleaning performance.The foam cleaning disinfection liquid can produce stable bubble
Foam such that it is able to carry out the cleaning and sterilizing of foam coverage to the body surface that has angle of inclination or vertical object surface, foam disappears
Poison more saves disinfectant consumption than immersion or fountain sterilization, can be used for equipment surface, inclined plane, irrigation canals and ditches, rough earth
Deng foam disinfectant, and sterilize while can play cleaning action.
The addition that peracetic acid has strong oxidizing property, conventional surfactants is easily decomposed, and catabolic process consumes big
The peracetic acid of amount, affects the Disinfection Effect of product.Alkyl benzene sulphonate or its salt, oxidation amine surfactants resistance to oxidation, no
Easily by decomposition of peracetic acid.However, the addition of alkyl benzene sulphonate or its salt is a small amount of, less than oxidation amine surfactants
Addition so that the foam cleaning disinfection liquid is more stable.Stabilizer, stabilizer can be also added to chelate miscellaneous in the foam cleaning agent
The material of the catalysis peracetic acid reaction such as matter, unhindered amina, metal ion, further improves the stability of foam cleaning disinfection liquid.
Alkyl benzene sulphonate or its salt belong to anion surfactant, there is a good cleaning performance, and amine-oxides class surfactant can be with
Foaming, and foam can be kept more stable, the adhesive force on thing surface increases.Both compoundings had caused foam cleaning disinfection liquid both
Cleaning performance is enhanced, and with frothing function so as to new occupation mode, it is easy to execute-in-place, expand its application
Scope.
Above disclosed is only presently preferred embodiments of the present invention, can not limit the right of the present invention with this certainly
Scope, therefore the equivalent variations made according to scope of the present invention patent, still belong to the scope that the present invention is covered.
Claims (10)
1. a kind of foam cleaning and sterilizing agent containing peracetic acid, it is characterised in that foam cleaning and sterilizing agent include acetic acid,
Hydrogen peroxide, surfactant and water.
2. the foam cleaning and sterilizing agent containing peracetic acid as claimed in claim 1, it is characterised in that according to mass percent
Calculate, foam cleaning and sterilizing agent includes following components:
3. the foam cleaning and sterilizing agent containing peracetic acid as claimed in claim 1 or 2, it is characterised in that live on the surface
Property agent include oxidation amine surfactants and alkyl benzene sulphonate or its salt.
4. the foam cleaning and sterilizing agent containing peracetic acid as claimed in claim 3, it is characterised in that the oxidation amine table
Face activating agent is N- dimethyl-alkyl amine oxide, is calculated according to mass percent, the content of the oxidation amine surfactants
For 1%~9%.
5. the foam cleaning and sterilizing agent containing peracetic acid as claimed in claim 3, it is characterised in that the alkyl benzene sulphonate
Salt is alkyl benzene sulphonate sodium salt or benzene sulfonamide acid potassium salt, according to mass percent calculating, the alkyl benzene sulphonate or its salt
Content is 1%~5%.
6. the foam cleaning and sterilizing agent containing peracetic acid as claimed in claim 1, it is characterised in that the foam cleaning disappears
Toxic agent also includes stabilizer, calculates according to mass percent, and the content of the stabilizer is 0~1%.
7. the foam cleaning and sterilizing agent containing peracetic acid as claimed in claim 6, it is characterised in that the stabilizer is
At least one in EDTA, PAA, HEDP, EDTMP, NTA.
8. a kind of method of the foam cleaning and sterilizing agent using as described in any one of claim 1~7, it is characterised in that described
Method includes step:
(1) the foam cleaning and sterilizing agent is diluted;
(2) by dilution after the foam cleaning and sterilizing agent foaming;And
(3) the foam cleaning and sterilizing agent after foaming covers cleaning and sterilizing thing surface.
9. using method as claimed in claim 8, it is characterised in that also rinse cleaning and sterilizing thing surface including step (4)
Foam.
10. a kind of application of the foam cleaning and sterilizing agent as described in any one of claim 1~7, by the foam cleaning and sterilizing
Liquid is applied to cleaning and sterilizing food manufacturing apparatus, factory, hospital or irrigation canals and ditches.
Priority Applications (1)
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CN201611185724.3A CN106665570B (en) | 2016-12-20 | 2016-12-20 | A kind of agent of foam cleaning and sterilizing and its application containing Peracetic acid |
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CN201611185724.3A CN106665570B (en) | 2016-12-20 | 2016-12-20 | A kind of agent of foam cleaning and sterilizing and its application containing Peracetic acid |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108047113A (en) * | 2017-12-14 | 2018-05-18 | 广州中冠动物药业有限公司 | A kind of synthesis technology of Peracetic acid |
CN111165478A (en) * | 2020-02-11 | 2020-05-19 | 南通大学 | Foam type sterilization, disinfection and air purification agent and preparation method and application thereof |
CN111264555A (en) * | 2020-03-06 | 2020-06-12 | 吉林云飞医药有限公司 | Hydrogen peroxide disinfectant and preparation method and application thereof |
CN112956475A (en) * | 2021-01-25 | 2021-06-15 | 海韵一剑大卫生科技有限公司 | Foam type peroxyacetic acid disinfectant, and preparation method and use method thereof |
CN111494870B (en) * | 2020-03-18 | 2021-11-19 | 中国人民解放军陆军防化学院 | Disinfection method |
CN115486445A (en) * | 2021-11-02 | 2022-12-20 | 上海柯珑清洁技术有限公司 | Cleaning disinfectant and preparation method thereof |
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US4263177A (en) * | 1979-06-27 | 1981-04-21 | Sherex Chemical Company, Inc. | Amine oxide foam stabilizers for alkyl benzene sulfonate foaming agents |
CN1711845A (en) * | 2004-06-25 | 2005-12-28 | 殷生章 | Disinfectant for killing coronary virus |
CN101507430A (en) * | 2009-03-31 | 2009-08-19 | 中国检验检疫科学研究院 | Freezeproof foam disinfectant and preparation method thereof |
CN102090393A (en) * | 2010-12-29 | 2011-06-15 | 广东环凯微生物科技有限公司 | Stable peroxyacetic acid disinfectant |
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2016
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Publication number | Priority date | Publication date | Assignee | Title |
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US4263177A (en) * | 1979-06-27 | 1981-04-21 | Sherex Chemical Company, Inc. | Amine oxide foam stabilizers for alkyl benzene sulfonate foaming agents |
CN1711845A (en) * | 2004-06-25 | 2005-12-28 | 殷生章 | Disinfectant for killing coronary virus |
CN101507430A (en) * | 2009-03-31 | 2009-08-19 | 中国检验检疫科学研究院 | Freezeproof foam disinfectant and preparation method thereof |
CN102090393A (en) * | 2010-12-29 | 2011-06-15 | 广东环凯微生物科技有限公司 | Stable peroxyacetic acid disinfectant |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108047113A (en) * | 2017-12-14 | 2018-05-18 | 广州中冠动物药业有限公司 | A kind of synthesis technology of Peracetic acid |
CN111165478A (en) * | 2020-02-11 | 2020-05-19 | 南通大学 | Foam type sterilization, disinfection and air purification agent and preparation method and application thereof |
CN111264555A (en) * | 2020-03-06 | 2020-06-12 | 吉林云飞医药有限公司 | Hydrogen peroxide disinfectant and preparation method and application thereof |
CN111494870B (en) * | 2020-03-18 | 2021-11-19 | 中国人民解放军陆军防化学院 | Disinfection method |
CN112956475A (en) * | 2021-01-25 | 2021-06-15 | 海韵一剑大卫生科技有限公司 | Foam type peroxyacetic acid disinfectant, and preparation method and use method thereof |
CN115486445A (en) * | 2021-11-02 | 2022-12-20 | 上海柯珑清洁技术有限公司 | Cleaning disinfectant and preparation method thereof |
CN115486445B (en) * | 2021-11-02 | 2024-03-26 | 上海柯珑清洁技术有限公司 | Cleaning disinfectant and preparation method thereof |
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