CN106653585A - Triode one-side N+ diffusion layer diffusion process - Google Patents

Triode one-side N+ diffusion layer diffusion process Download PDF

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Publication number
CN106653585A
CN106653585A CN201610957522.XA CN201610957522A CN106653585A CN 106653585 A CN106653585 A CN 106653585A CN 201610957522 A CN201610957522 A CN 201610957522A CN 106653585 A CN106653585 A CN 106653585A
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China
Prior art keywords
diffusion
layer
silicon chip
audion
oxide layer
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CN201610957522.XA
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Inventor
顾晶伟
陆益
李超
刘宗帅
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Anhui Core Microelectronics Co Ltd
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Anhui Core Microelectronics Co Ltd
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Priority to CN201610957522.XA priority Critical patent/CN106653585A/en
Publication of CN106653585A publication Critical patent/CN106653585A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/22Diffusion of impurity materials, e.g. doping materials, electrode materials, into or out of a semiconductor body, or between semiconductor regions; Interactions between two or more impurities; Redistribution of impurities
    • H01L21/223Diffusion of impurity materials, e.g. doping materials, electrode materials, into or out of a semiconductor body, or between semiconductor regions; Interactions between two or more impurities; Redistribution of impurities using diffusion into or out of a solid from or into a gaseous phase

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Testing Or Measuring Of Semiconductors Or The Like (AREA)

Abstract

The invention belongs to the technical field of a semiconductor and especially relates to a triode one-side N+ diffusion layer diffusion process. The process comprises the following steps: 1, forming a double-side oxide layer by oxidizing a silicon wafer through steam; 2, corroding the oxide layer in a one-side mode; 3, performing pre-diffusion on a diffusion impurity source so as to form a pre-diffusion layer; and 4, performing re-diffusion, and carrying out junction depth advancing for certain time at a certain temperature so as to obtain a product. According to the triode one-side N+ diffusion layer diffusion process, a masking layer preventing diffusion is formed at one side of the silicon wafer, substrate diffusion is performed only at the other side of the silicon wafer, in terms of the thickness of a raw material, a quite thin silicon wafer can also be selected, and thus the production and manufacturing cost is reduced.

Description

A kind of audion one side N+The process of diffusion layer diffusion
Technical field
The invention belongs to technical field of semiconductors, more particularly to a kind of audion one side N+The technique side of diffusion layer diffusion Method.
Background technology
Need to spread through substrate in operation manufacture before triode chip at present, section is formed for N+-N--N+Structure Layer.And audion makes, one side N of chip is only needed+Layer, another side N+Layer need to remove, and typically by thinning, polishing, remove one side N+Layer, so as to realize N+-N-Making.In the method manufacture, silicon wafer is typically thicker 450-550 μm, causes the increasing of cost Plus.
The content of the invention
The present invention technical purpose be for need in above-mentioned substrate processing it is thinning, polish away one side N+The problem of layer, A kind of problem for causing cost to increase, there is provided audion one side N+The process of diffusion layer diffusion.
The technical scheme for realizing the object of the invention is:
A kind of audion one side N+The process of diffusion layer diffusion, the process include:
Step one, steam oxidation silicon chip form two sides oxide layer;
Step 2, single-sided corrosion oxide layer;
Step 3, prediffusion, diffusion impurity source form prediffusion layer;
Step 4, then spread, junction depth propulsion certain hour is carried out at a certain temperature, obtains product.
Specifically, the two sides oxide layer that the steam oxidation silicon chip is formed, is simultaneously protected using photoresist, is removed by corrosion The oxide layer of another side is gone, oxide layer simultaneously is used as the masking layer for preventing diffusion.
Further, the thickness of the silicon chip is 200-300 μm.
Specifically, the steam oxidation silicon chip of the step one, carries out Chemical cleaning including by silicon chip to be oxidized, dries, Drying;Silicon chip after drying is warming up to after uniform temperature under pure dry oxygen atmosphere, wet oxygen certain hour is passed through, dry oxygen is certain Time, cooling check oxidated layer thickness.
Preferably, oxidated layer thickness d >=1.2 μm.
Further, the single-sided corrosion oxide layer of the step 2 is that, by silicon chip one side glue, front baking, exposure, development are hard Film, and corrode in being put into corrosive liquid.
Preferably, the corrosive liquid is ammonium fluoride: Fluohydric acid.: the solution of deionized water=1.5g: 1ml: 3.5ml.
Specifically, the uniform temperature for spreading again of the step 4 is 1250 ± 20 DEG C, and junction depth propulsion certain hour is 150 ±10h。
Present invention additionally comprises a kind of manufacture method of chip, using above-mentioned audion one side N+The technique of diffusion layer diffusion Method, and base diffusion is carried out, launch site photoetching, phosphorus diffusion, mesa recess photoetching, mesa etch, mesa passivation, fairlead light Carve, middle test, evaporation of aluminum, photoetching are anti-carved, aluminium alloy, back face metalization, back side alloy, and carry out die testing.
The invention has the beneficial effects as follows:The pole pipe one side N of the present invention+The process of diffusion layer diffusion, the one of silicon chip Face forms the masking layer for preventing diffusion, substrate diffusion is only carried out in the another side of silicon chip, and masking layer thickness of thin is easily removed, made The optional relatively thin silicon wafer of material stock thickness is obtained, so as to reduce manufacturing cost.
Description of the drawings
Fig. 1 is N-type single-chip;
Fig. 2 is N in prior art+-N--N+Sectional structure chart;
Fig. 3 is N in the present invention+-N-Sectional structure chart.
Wherein, 1- masking layers.
Specific embodiment
The present invention is further illustrated below by way of specific example.
Embodiment 1
A kind of audion one side N+The process of diffusion layer diffusion, the process include:
Step one, steam oxidation silicon chip form two sides oxide layer;
Step 2, single-sided corrosion oxide layer;
Step 3, prediffusion, diffusion impurity source form prediffusion layer;
Step 4, then spread, junction depth propulsion certain hour is carried out at a certain temperature, obtains product.
It is the core content of the present invention above, the masking layer for preventing diffusion is formed in the one side of silicon chip, substrate is only spread Carry out in the another side of silicon chip.As shown in figure 3, for the present invention audion one side N+Diffusion layer sectional structure chart, can from figure To find out, masking layer 1 is defined in the one side of silicon chip, another side forms N+Diffusion layer, material stock thickness also optional relatively thin silicon Chip, so as to reduce manufacturing cost.As shown in Fig. 2 audion forms N in prior art+Diffusion layer structural representation, As can be seen from the figure form two-layer diffusion layer.
Specifically, the two sides oxide layer that the steam oxidation silicon chip is formed, is simultaneously protected using photoresist, is removed by corrosion The oxide layer of another side is gone, oxide layer simultaneously is used as the masking layer for preventing diffusion.
Further, the thickness of the silicon chip is 200-300 μm.
Specifically, the steam oxidation silicon chip of the step one, carries out Chemical cleaning including by silicon chip to be oxidized, dries, Drying;Silicon chip after drying is warming up to after uniform temperature under pure dry oxygen atmosphere, wet oxygen certain hour is passed through, dry oxygen is certain Time, cooling check oxidated layer thickness.
Preferably, oxidated layer thickness d >=1.2 μm.
Preferably, the single-sided corrosion oxide layer of the step 2 is, silicon chip one side glue, front baking, exposure are developed, Post bake, and corrode in being put into corrosive liquid.
Preferably, the corrosive liquid is ammonium fluoride: Fluohydric acid.: the solution of deionized water=1.5g: 1ml: 3.5ml.
Used as preferential, the uniform temperature for spreading again of the step 4 is 1250 ± 20 DEG C, and junction depth propulsion certain hour is 150±10h。
Embodiment 2
A kind of audion one side N+The process of diffusion layer diffusion,
Raw material:As shown in figure 1, N-type single-chip, ρ:40~45 Ω cm, piece are thick:255~265 μm;
Step one, oxidation:
Silicon chip to be oxidized is carried out Chemical cleaning by a, is dried, drying.
B is inserted in the silicon chip after drying on quartz boat, and quartz boat is pushed in the flat-temperature zone of diffusion furnace, leads in diffusion furnace Enter the pure dry oxygen of 4L/min.
C opens diffusion furnace, is heated up, was raised to T=1150 ± 20 DEG C with 5 hours.
D when temperature reach T and it is constant after, dry oxygen is changed to into wet oxygen, flow 2L/min, and calculate logical wet oxygen time, t=4 ±0.5h.After then, then the pure dry oxygen that wet oxygen is changed to 4L/min.Time t=2 ± 0.5h
E then starts cooling afterwards, drops to less than 600 DEG C with 6 ± 1h, and the quartz boat that will be equipped with silicon single crystal flake is pulled out, by silicon Single-chip removes lower loading horse, to be tested.
F checks oxidated layer thickness:Require d >=1.2 μm.
Step 2, the protection of front masking layer, remove backside oxide layer.
A fronts spin coating (ultraviolet negative photoresist), rotating speed 5000rpm, spin coating time 40sec.
B front bakings:The silicon chip of even good glue is sent into into 100 DEG C of baking ovens, and 30 ± 5min of timing, is then taken out afterwards, it is to be exposed.
C exposes:The front of spin coating is sent into litho machine carries out uv-exposure, time of exposure 10-20sec.
D develops:To be developed in silicon chip immersion negative photo developer solution after exposure.10 ± 2min of immersion, after taking-up Dry.
E post bakes:Silicon chip after development is put into into 30-40min in 140 ± 5 DEG C of baking ovens.
F corrodes:Silicon chip after post bake is put into into ammonium fluoride: hydrogen fluorine::The solution of deionized water=1.5g: 1ml: 3.5ml In, abbreviation BOE.Remove backside oxide layer, 8 ± 2min of time.
Silicon chip after corrosion is put into sulphuric acid by g:Hydrogen peroxide=1: stripping photoresist in 4.After by silicon chip extracting, deionization is used Water is rinsed more than 15 times.
Step 3, backing substrate prediffusion
The silicon chip of step 3 is carried out Chemical cleaning by a, is loaded in quartz boat, is carried out substrate prediffusion, lead to after drying, drying Enter the pure nitrogen of 4L/min.
B opens diffusion furnace, is heated up, and constant temperature T=1150 ± 20 DEG C, time t=3 ± 0.5h.
C is by diffusion impurity source (generally liquid POCl3) be carried along in diffusion furnace quartz ampoule by low discharge nitrogen, Silicon chip back side forms prediffusion layer
After d time t are arrived, less than 600 DEG C are cooled to, the quartz boat that will be equipped with silicon single crystal flake is pulled out, and silicon single crystal flake is gone down Load horse, it is to be tested.
E detects Rs=0.23-0.25.
Step 4, spread again
Spread again, in temperature T=1250 ± 20 DEG C or so, junction depth advances certain hour t=150 ± 10h, formation Product is as shown in Figure 3.
Detection junction depth:It is required that depth is 180-190 μm.
Embodiment 3
Present invention additionally comprises a kind of manufacture method of chip, using above-mentioned audion one side N+The technique of diffusion layer diffusion Method, and base diffusion is carried out, launch site photoetching, phosphorus diffusion, mesa recess photoetching, mesa etch, mesa passivation, fairlead light Carve, middle test, evaporation of aluminum, photoetching are anti-carved, aluminium alloy, back face metalization, back side alloy, and carry out die testing.
It is below 13003 chip manufacturings, early stage audion one side N+The process and 2 phase of embodiment of diffusion layer diffusion Together, i.e. raw material:As shown in figure 1, N-type single-chip, ρ:40~45 Ω cm, piece are thick:255~265 μm;Step one, oxidation:
Silicon chip to be oxidized is carried out Chemical cleaning by a, is dried, drying.
B is inserted in the silicon chip after drying on quartz boat, and quartz boat is pushed in the flat-temperature zone of diffusion furnace, leads in diffusion furnace Enter the pure dry oxygen of 4L/min.
C opens diffusion furnace, is heated up, was raised to T=1150 ± 20 DEG C with 5 hours.
D when temperature reach T and it is constant after, dry oxygen is changed to into wet oxygen, flow 2L/min, and calculate logical wet oxygen time, t=4 ±0.5h.After then, then the pure dry oxygen that wet oxygen is changed to 4L/min.Time t=2 ± 0.5h.
E then starts cooling afterwards, drops to less than 600 DEG C with 6 ± 1h, and the quartz boat that will be equipped with silicon single crystal flake is pulled out, by silicon Single-chip removes lower loading horse, to be tested.
F checks oxidated layer thickness:Require d >=1.2 μm.
Step 2, the protection of front masking layer, remove backside oxide layer.
A fronts spin coating (ultraviolet negative photoresist), rotating speed 5000rpm, spin coating time 40sec.
B front bakings:The silicon chip of even good glue is sent into into 100 DEG C of baking ovens, and 30 ± 5min of timing, is then taken out afterwards, it is to be exposed.
C exposes:The front of spin coating is sent into litho machine carries out uv-exposure, time of exposure 10-20sec.
D develops:To be developed in silicon chip immersion negative photo developer solution after exposure.10 ± 2min of immersion, after taking-up Dry.
E post bakes:Silicon chip after development is put into into 30-40min in 140 ± 5 DEG C of baking ovens.
F corrodes:Silicon chip after post bake is put into into ammonium fluoride: Fluohydric acid.: the solution of deionized water=1.5g: 1ml: 3.5ml In, abbreviation BOE.Remove backside oxide layer, 8 ± 2min of time.
Silicon chip after corrosion is put into sulphuric acid: hydrogen peroxide=1: stripping photoresist in 4 by g.After by silicon chip extracting, deionization is used Water is rinsed more than 15 times.
Step 3, backing substrate prediffusion
The silicon chip of step 3 is carried out Chemical cleaning by a, is loaded in quartz boat, is carried out substrate prediffusion, lead to after drying, drying Enter the pure nitrogen of 4L/min.
B opens diffusion furnace, is heated up, and constant temperature T=1150 ± 20 DEG C, time t=3 ± 0.5h.
C is by diffusion impurity source (generally liquid POCl3) be carried along in diffusion furnace quartz ampoule by low discharge nitrogen, Silicon chip back side forms prediffusion layer
After d time t are arrived, less than 600 DEG C are cooled to, the quartz boat that will be equipped with silicon single crystal flake is pulled out, and silicon single crystal flake is gone down Load horse, it is to be tested.
E detects Rs=0.23-0.25.
Step 4, spread again
Spread again, in temperature T=1250 ± 20 DEG C or so, junction depth propulsion certain hour t=150 ± 10h.
Detection junction depth:It is required that depth is 180-190 μm.
Step 5, base diffusion
A. boron pre-deposition
Condition:T=970 DEG C of t=60min is required:R=28-32 Ω/
B. boron spreads again
Condition:T=1250 DEG C of t=11h is required:R=48~58 Ω/, xj=26~27 μm
Step 6, launch site photoetching
Step 7, phosphorus diffusion
A phosphorus pre-deposited
T=1050 DEG C, t=80min (TongYuan), it is desirable to R=1.36~1.38 Ω/
B phosphorus spreads again
Condition:T=1195 DEG C, t=90 ± 90min requirement β:18~50 (I=0.2A)
Step 8, mesa recess photoetching
Step 9, mesa etch, mesa passivation
Require:Table top groove depth δ=60~65 μm, VCBO >=700V, VCEO >=400V
Step 10, fairlead photoetching
Step 11, middle test, it is desirable to VCBO >=700V, VCEO >=400V
Step 12, evaporation of aluminum, it is desirable to:Aluminum layer thickness δ >=4 ± 0.5 μm
Step 13, photoetching are anti-carved
Step 14, aluminium alloy, it is desirable to:VBE≤1.3V (test conditions:I=1.2A)
Step 15, back face metalization, back side alloy, it is desirable to conventional.
Step 10 six, die testing
(die-size is surveyed entirely automatically using microcomputer:1.68×1.68mm2)
1.ICBO≤20 μ A (test conditions:VCB=710V)
2.IEBO≤20 μ A (test conditions:VEB=10V)
3.BVCEO >=410V (test conditions:IC=5mA)
4.hFE=15~50 (test condition:IC=0.2A, VCE=10V)
Embodiment described above has been described in detail to technical scheme and beneficial effect, it should be understood that The specific embodiment of the present invention is the foregoing is only, the present invention is not limited to, it is all to be done in the spirit of the present invention Any modification and improvement etc., should be included within the scope of the present invention.

Claims (9)

1. a kind of audion one side N+The process of diffusion layer diffusion, it is characterised in that the process includes:
Step one, steam oxidation silicon chip form two sides oxide layer;
Step 2, single-sided corrosion oxide layer;
Step 3, prediffusion, diffusion impurity source form prediffusion layer;
Step 4, then spread, junction depth propulsion certain hour is carried out at a certain temperature, obtains product.
2. a kind of audion one side N according to claim 1+The process of diffusion layer diffusion, it is characterised in that described Steam oxidation silicon chip formed two sides oxide layer, simultaneously using photoresist protect, by corrode remove another side oxide layer, one The oxide layer in face is used as the masking layer for preventing diffusion.
3. a kind of audion one side N according to claim 1+The process of diffusion layer diffusion, it is characterised in that described The thickness of silicon chip is 200-300 μm.
4. a kind of audion one side N according to claim 1+The process of diffusion layer diffusion, it is characterised in that described The steam oxidation silicon chip of step one, carries out Chemical cleaning including by silicon chip to be oxidized, dries, drying;By the silicon chip after drying After uniform temperature is warming up under pure dry oxygen atmosphere, wet oxygen certain hour, dry oxygen certain hour, cooling, inspection oxidation are passed through Thickness degree.
5. a kind of audion one side N according to claim 1 or 4+The process of diffusion layer diffusion, it is characterised in that institute State oxidated layer thickness d >=1.2 μm.
6. a kind of audion one side N according to claim 1+The process of diffusion layer diffusion, it is characterised in that described The single-sided corrosion oxide layer of step 2 is that, by silicon chip one side glue, front baking, exposure are developed, post bake, and are put into corruption in corrosive liquid Erosion.
7. a kind of audion one side N according to claim 6+The process of diffusion layer diffusion, it is characterised in that described Corrosive liquid is ammonium fluoride: Fluohydric acid.: the solution of deionized water=1.5g: 1ml: 3.5ml.
8. a kind of audion one side N according to claim 1+The process of diffusion layer diffusion, it is characterised in that described The uniform temperature for spreading again of step 4 is 1250 ± 20 DEG C, and junction depth propulsion certain hour is 150 ± 10h.
9. a kind of manufacture method of chip, it is characterised in that usage right requires any one audion one side N described in 1-8+ The process of diffusion layer diffusion, and base diffusion is carried out, launch site photoetching, phosphorus diffusion, mesa recess photoetching, mesa etch, platform Face is passivated, fairlead photoetching, and middle test, evaporation of aluminum, photoetching are anti-carved, aluminium alloy, back face metalization, back side alloy, and are managed Core is tested.
CN201610957522.XA 2016-10-27 2016-10-27 Triode one-side N+ diffusion layer diffusion process Pending CN106653585A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107170664A (en) * 2017-05-16 2017-09-15 扬州晶新微电子有限公司 A kind of manufacturing process of substrate diffusion sheet
CN107256828A (en) * 2017-05-16 2017-10-17 扬州晶新微电子有限公司 A kind of phosphorosilicate glass annealing process for improving triode K values
CN111341650A (en) * 2020-03-13 2020-06-26 天水天光半导体有限责任公司 Bubble-emitting phosphorus diffusion process method for reducing triode reverse amplification factor
CN113053736A (en) * 2021-03-11 2021-06-29 捷捷半导体有限公司 Semiconductor device manufacturing method
CN114999914A (en) * 2022-07-01 2022-09-02 锦州辽晶电子科技有限公司 Manufacturing method of power transistor for improving secondary breakdown resistance tolerance

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57181118A (en) * 1981-04-30 1982-11-08 Nec Home Electronics Ltd Working method for substrate for semiconductor element
CN102789980A (en) * 2012-07-18 2012-11-21 启东吉莱电子有限公司 Production process of short base region structure for improving voltage
CN105374668A (en) * 2015-11-02 2016-03-02 吉林华微电子股份有限公司 Heavily doped silicon substrate high quality shielding type diffusion method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57181118A (en) * 1981-04-30 1982-11-08 Nec Home Electronics Ltd Working method for substrate for semiconductor element
CN102789980A (en) * 2012-07-18 2012-11-21 启东吉莱电子有限公司 Production process of short base region structure for improving voltage
CN105374668A (en) * 2015-11-02 2016-03-02 吉林华微电子股份有限公司 Heavily doped silicon substrate high quality shielding type diffusion method

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107170664A (en) * 2017-05-16 2017-09-15 扬州晶新微电子有限公司 A kind of manufacturing process of substrate diffusion sheet
CN107256828A (en) * 2017-05-16 2017-10-17 扬州晶新微电子有限公司 A kind of phosphorosilicate glass annealing process for improving triode K values
CN111341650A (en) * 2020-03-13 2020-06-26 天水天光半导体有限责任公司 Bubble-emitting phosphorus diffusion process method for reducing triode reverse amplification factor
CN111341650B (en) * 2020-03-13 2023-03-31 天水天光半导体有限责任公司 Bubble-emitting phosphorus diffusion process method for reducing triode reverse amplification factor
CN113053736A (en) * 2021-03-11 2021-06-29 捷捷半导体有限公司 Semiconductor device manufacturing method
CN113053736B (en) * 2021-03-11 2024-05-03 捷捷半导体有限公司 Manufacturing method of semiconductor device
CN114999914A (en) * 2022-07-01 2022-09-02 锦州辽晶电子科技有限公司 Manufacturing method of power transistor for improving secondary breakdown resistance tolerance

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