CN106635285A - Cold heading oil composition and application thereof - Google Patents
Cold heading oil composition and application thereof Download PDFInfo
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- CN106635285A CN106635285A CN201610834027.XA CN201610834027A CN106635285A CN 106635285 A CN106635285 A CN 106635285A CN 201610834027 A CN201610834027 A CN 201610834027A CN 106635285 A CN106635285 A CN 106635285A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/048—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
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- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/127—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids polycarboxylic
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/287—Partial esters
- C10M2207/288—Partial esters containing free carboxyl groups
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- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an alcohol or ester thereof; bound to an aldehyde, ketonic, ether, ketal or acetal radical
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- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
- C10M2209/084—Acrylate; Methacrylate
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/064—Di- and triaryl amines
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/064—Di- and triaryl amines
- C10M2215/065—Phenyl-Naphthyl amines
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
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- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
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- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
- C10M2219/022—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of hydrocarbons, e.g. olefines
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- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
- C10M2219/024—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
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- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
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- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
- C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
- C10M2219/106—Thiadiazoles
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- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/047—Thioderivatives not containing metallic elements
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- C10M2229/04—Siloxanes with specific structure
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- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
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Abstract
The invention relates to a cold heading oil composition and an application thereof. The composition mainly solves the problems in the prior art that the extreme pressure anti-wear property and copper corrosion resistance of cold heading oil cannot satisfy usage requirements of partial cold heading equipment for lubrication unified oil supply for cold heading process and equipment, galling is generated on the surface of workpiece, or transmission gear shaft is corroded. The composition comprises the following components in parts by weight: a) 100 parts of mineral base oil; b) 0.1-5.0 parts of an anti-wear reagent at extreme pressure; c) 0.01-0.5 parts of a metal passivator; d) 1.0-15.0 parts of an oiliness agent; e) 0.005-0.5 parts of an anti-foaming agent. The anti-wear reagent at extreme pressure is a mixture of sulfurized olefin and at least one of sulfurized isobutylene, phenyl sulfide, sulfurized fatty acid ester or ammonium thiophsphonate. The metal passivator is selected from at least one of triazole derivatives or thiadiazole derivatives; the oiliness agent is a mixture of sulfurized plant oil and at least one selected from fatty acid ester or high-grade fatty alcohol. The technical scheme can better solve the problem, and is used for partial cold heading equipment for lubrication unified oil supply for cold heading process and equipment.
Description
Technical field
The present invention relates to a kind of cold-heading fluid composition and application thereof.
Background technology
Cold heading technique is one of important process process in metal working process, for the fastening automobile produced in enormous quantities
Special-shaped automated production on part, motorcycle, bicycle, household electrical appliances is requisite manufacture method.It has formation of contact
Stress is high, the features such as require especially high to the extreme pressure property of cold-heading molding oil.Therefore often can be relatively large in cold-heading molding oil product
Using active sulfur additives with excellent extreme pressure property etc., but it is simultaneously higher to the corrosivity of brass.
Gear is the significant components in transmission device.Gear oil is to ensure that gear drive operating efficiency and prolongation gear are used
The important lubriation material in life-span, primarily serving in gear mechanism prevents tooth surface abrasion, take away friction produce heat and every
The absolutely flank of tooth and water, air contact, it is to avoid getting rusty, corrode etc. acts on.With cold-heading molding oil phase ratio, it is to metal (including brass)
The protecting box Corrosion Protection of metal requires higher.
During conventional cold-heading, gear box arrangement oil and cold heading technique are usually each independent lube system with oil
System, and respectively using industrial gear oil and cold-heading molding oil.But have also part cold-heading equipment in the design process by gear lubrication
System and cold-heading molding process oil system are unified, and thereby result in equipment oil and process oil uses same lubricating oil product
Use demand.
At present the requirement high to oil product extreme pressure and antiwear behavior in order to meet cold heading technique of conventional cold-heading molding oil, relatively large
Active sulfur additives with excellent extreme pressure property etc. are used, in cold heading technique and equipment lubrication the cold-heading equipment of fuel feeding has been unified
On using rear appearance or anti-copper corrosion better performances and surface of the work plucking, or workpiece reaches that standard is required and power transmission shaft is rotten
Erosion is serious.Therefore, above-mentioned conventional cold-heading oil can not meet the unified oil of using of some processes and equipment lubrication and require.
By domestic and international patent and literature query, a conventional cold-heading oil tech, such as patent CN 104403738A are found
It is related to a kind of common conventional cold-heading fluid composition, due to EP agent large usage quantity, is only applicable to common cold headers.
The content of the invention
One of the technical problem to be solved is the extreme pressure and antiwear behavior and anti-copper corrosion of prior art cold-heading oil
Performance can not simultaneously meet part cold heading technique and unify the cold-heading equipment use requirement of fuel feeding with equipment lubrication, cause surface of the work
Plucking, or the problem of driving cog axle corrosion, there is provided a kind of new cold-heading lubricates dual-purpose cold-heading fluid composition.The present invention to be solved
The two of technical problem certainly are to provide a kind of purposes of the cold-heading fluid composition.Said composition has higher extreme pressure anti-wear
With excellent anti-copper corrosion performance, it is applicable to part cold heading technique and unifies the special cold headers of fuel feeding with equipment lubrication.
To solve one of above-mentioned technical problem, the technical solution used in the present invention is as follows：A kind of cold-heading fluid composition, with weight
Amount number meter includes following component：
A) 100 parts of mineral base oils；
B) 0.1～5.0 part of extreme pressure anti-wear additives；
C) 0.01～0.5 part of metal deactivator；
D) 1.0～15.0 parts of oiliness improvers；
E) 0.005～0.5 anti-foaming agent；
The extreme pressure anti-wear additives be olefine sulfide and, selected from sulfide isobutene, phenyl sulfide, sulfide aliphatic acid ester or sulphur
For at least one mixture in the multiple ester amine salt of phosphoric acid；
At least one of the metal deactivator in benzotriazole derivative or thiadiazoles derivative；
The oiliness improver is selected from vulcanized vegetable oil and at least one mixing in fatty acid ester or higher aliphatic
Thing.
In above-mentioned technical proposal, it is preferable that in terms of parts by weight, the consumption of extreme pressure anti-wear additives is 0.5～3.0 part, metal
The consumption of passivator is 0.02～0.3 part, and the consumption of oiliness improver is 6.0～12.0 parts, and the consumption of anti-foaming agent is 0.01～0.3
Part.
In above-mentioned technical proposal, in extreme-pressure anti-wear agent composition, olefine sulfide vulcanizes with sulfide isobutene, phenyl is selected from
At least one weight ratio in the multiple ester amine salt of thing, sulfide aliphatic acid ester or D2EHDTPA is 1: (0.1～1.0)；Preferably 1:
(0.1～0.8)；More preferably 1: (0.1～0.6).
In above-mentioned technical proposal, in oiliness agent composition, vulcanized vegetable oil with fatty acid ester or higher aliphatic
At least one ratio be 1: (0.1～1.0)；Preferably 1: (0.1～0.8)；More preferably 1: (0.1～0.6).
In above-mentioned technical proposal, the benzotriazole derivative be selected from N, N- dibutyl aminomethylenes-alkyl benzotriazole or
At least one in benzotriazole, aldehyde and amine condensation product.
In above-mentioned technical proposal, the thiadiazoles derivative selected from 2,5- dimercapto-1,3,4-thiadiazole derivatives, 2,5-
At least one in dimercapto-1,3,4-thiadiazole derivative or the sulphur mixture of di-n-octyl two.
In above-mentioned technical proposal, the anti-foaming agent is selected from alkyl-silicone oil, acrylate and ether copolymer or more mixture
In at least one.
In above-mentioned technical proposal, the mineral base oil is selected from solvent refining base oil or is hydrogenated with mineral base oil extremely
Few one kind, Viscosity Index is more than 90.
In above-mentioned technical proposal, at least one in antirust agent or antioxidant is also included in the composition；With weight
Amount number meter, the consumption of antirust agent is 0.01～1.0 part, and the consumption of antioxidant is 0.05～1.2 part；Wherein, the antirust agent
At least one in calcium mahogany sulfonate, dodecenylsuccinic acid or alkenyl succinic acid half ester；The antioxidant is selected from alkyl
At least one in diphenylamines, N- PAs or phenolic antioxidant.
The preparation method of cold-heading fluid composition of the present invention is：By the desired amount of metal deactivator, antioxidant, oiliness improver,
Antirust agent, detergent-dispersant additive, anti-foaming agent are added in base oil at a temperature of 50～80 DEG C, are stirred 0.5～2 hour so as to all
Dissolving；Temperature control is added to extreme pressure anti-wear additives at 45～65 DEG C in said mixture the combination that the present invention is obtained
Thing.
To solve the two of above-mentioned technical problem, the technical solution used in the present invention is as follows：Described cold-heading fluid composition is used
Unify the lubrication of the special cold headers of fuel feeding in cold heading technique and equipment lubrication.The component of wherein described cold-heading fluid composition, weight
Amount number and preferred scope with it is identical in the technical scheme that solution one of technical problem is taken.
The present invention is evaluated using following various test methods to the performance of the cold-heading fluid composition, wherein there is profit
Lubrication prescription bearing capacity determination method (four ball method) _ resultant wear index ZMZ (GB/T3142), load carrying capacity of lubricant determination method (four
Ball) (maximum nonseizure load PB) (GB/T3142), load carrying capacity of lubricant determination method (four ball method) (sintering load PD)(GB/
T3142), the measure rotary bomb oxidation test (SH/T1093) of lubricating oil oxidation stability, lubrication oil antiwear damages performance measurement method (four balls
Machine method) (SH/T0189), inhibiting mineral oil rust prevention test method (GB/T11143 or ASTM D665) in the presence of water, oil
Product copper strip test method (GB/T5906 or ASTM D130).
Present invention employs carries out appropriately combined and screening to extreme pressure anti-wear additives, oiliness improver and metal deactivator.The pole
Pressure antiwear additive is olefine sulfide and is selected from the multiple ester amine salt of sulfide isobutene, phenyl sulfide, sulfide aliphatic acid ester or D2EHDTPA
At least one of mixture.At least one of the oiliness improver in vulcanized vegetable oil with fatty acid ester, higher aliphatic
Mixture.At least one of the metal deactivator in benzotriazole derivative or thiadiazoles derivative.Take full advantage of
The synergy of each component so that composition can have excellent extreme pressure anti-wear (to adopt load carrying capacity of lubricant determination method
(four ball method) (resultant wear index ZMZ) test is not less than 631N, (maximum using load carrying capacity of lubricant determination method (four ball method)
Without seizing load PB) test maximum nonseizure load be not less than 1000N, using load carrying capacity of lubricant determination method (four ball method)
(sintering load PD) (GB/T3142) test sintering load be not less than 6080N, using lubrication oil antiwear damage performance measurement method
(SH/T0189) wear scar diameter for determining is not more than 0.35mm), excellent corrosion resistance (copper corrosion) (adopts oil product copper
The result of piece etching test (GB/T5906 or ASTM D130) test is not more than 1)；Meanwhile, composition also has excellent resisting
Oxidation, rustless property, achieve preferable technique effect.
Below by embodiment, the invention will be further elaborated.
Specific embodiment
【Embodiment 1～6】
According to the parts by weight in table 1, weigh respectively the desired amount of metal deactivator, antioxidant, oiliness improver, antirust agent,
Detergent-dispersant additive and anti-foaming agent are added into base oil (68 viscosity grade), at 70 DEG C heating stirring to substantially uniformity, then
Reduce temperature and add extreme pressure anti-wear additives at 60 DEG C, stir to substantially uniformity and obtain the dual-purpose cold-heading oil combination of the cold-heading lubrication
Thing.The species and consumption of each component, is specifically shown in Table 1 in composition.
Wherein Rc2540 is olefine sulfide；T321 is sulfide isobutene；T307 is the multiple ester amine salt of D2EHDTPA；T404 is sulphur
Change cottonseed oil；T501 is BHT；Irganox L135 are mixed type shielding point；Irganox L57 are alkane
Base diphenylamines；T552 is benzotriazole, aldehyde and amine condensation product；T561 is 2,5- dimercapto-1,3,4-thiadiazole derivatives；
T747A is alkenyl succinic acid half ester；T922 is siliceous and non-silicon anti-foaming agent compound.
【Embodiment 7】
It is right【Embodiment 1～6】In composition extreme pressure and antiwear behavior (resultant wear index, maximum meet, burn without seizing
Knot load, wear scar diameter), corrosion resistance (copper corrosion), oxidation stability (rotary oxygen bomb value), rust-preventing characteristic (liquid phase corrosion B
Method) to be tested, result of the test is shown in Table 2.
Extreme pressure anti-wear is one of most important performance of cold-heading oil.It is right【Embodiment 1～6】In each composition carried out synthesis
Abrasion index, it is maximum without it is seizing meet, the index such as sintering load, wear scar diameter is tested.Resultant wear index, maximum nothing
It is seizing meet, sintering load, wear scar diameter it is equivalent bigger, illustrate that the oily extreme pressure and antiwear behavior of cold-heading is better；And wear scar diameter is then
The extreme pressure and antiwear behavior of less explanation oil product is better.【Embodiment 1～6】In each composition extreme pressure and antiwear behavior in resultant wear
Index is all higher than 631N, and sintering load is not less than 6080N, wear scar diameter no more than 0.35mm, and【Embodiment 4～6】In
The maximum nonseizure load value of each composition is not less than 1100N, illustrates that each composition can be while meet the spy of cold heading technique
It is different to require.Comparatively, each composition resultant wear index (ZMZ) quality is followed successively by：【Embodiment 6】＞【Embodiment 5】＞【It is real
Apply example 4】＞【Embodiment 3】=【Embodiment 2】＞【Embodiment 1】；Each composition maximum nonseizure load quality is followed successively by：【It is real
Apply example 6】＞【Embodiment 5】＞【Embodiment 4】＞【Embodiment 3】＞【Embodiment 2】=【Embodiment 1】；Each composition sintering is negative
Lotus quality is followed successively by：【Embodiment 6】＞【Embodiment 5】=【Embodiment 4】＞【Embodiment 3】=【Embodiment 2】=【Embodiment
1】；Each composition wear scar diameter quality is followed successively by：【Embodiment 5】＞【Embodiment 6】＞【Embodiment 4】＞【Embodiment 3】＞【It is real
Apply example 2】＞【Embodiment 1】.Therefore, summary evaluates 4 index situations of gear oil extreme pressure abrasion resistance, each composition
Extreme pressure property quality is followed successively by：【Embodiment 6】＞【Embodiment 5】＞【Embodiment 4】＞【Embodiment 3】＞【Embodiment 2】＞【It is real
Apply example 1】.
The anti-copper corrosion of oil product can be tested using corrosion resistance (copper corrosion) test method(s).It is general next
Say, the copper corrosion rank of oil product is less, illustrate that its anti-copper corrosion is better.It is right【Embodiment 1～6】The anti-corruption of each composition
The test data of corrosion (copper corrosion) is shown in Table 2.Each composition is can be seen that from the copper corrosion experimental data of table 2 to pass equipment
The copper part of dynamic tooth axle does not have corrosivity, can meet the particular/special requirement of cold-heading equipment gear lubrication.
Additionally, right【Embodiment 3～6】In each composition carried out non-oxidizability and rust-preventing characteristic test, as a result show each group
Non-oxidizability, the rustless property of compound can meet the particular/special requirement of cold-heading lubrication.
【Comparative example 1～4】
According in table 1【Comparative example 1～4】Parts by weight, the desired amount of metal deactivator, antioxidant, oil are weighed respectively
Property agent, antirust agent, detergent-dispersant additive and anti-foaming agent are added into base oil (68 viscosity grade), and heating stirring is to complete at 70 DEG C
It is complete uniform, then reduce temperature and add extreme pressure anti-wear additives at 60 DEG C, stir to substantially uniformity and obtain【Comparative example 1～4】It is described
Cold-heading fluid composition.【Comparative example 1～4】The species and consumption of each component, is specifically shown in Table 1 in composition.
【Comparative example 5】
It is right【Comparative example 1～4】In composition extreme pressure and antiwear behavior it is (resultant wear index (ZMZ), maximum without seizing negative
Lotus, sintering load, wear scar diameter and corrosion resistance (copper corrosion)) to be tested, result of the test is shown in Table 2.
With【Embodiment 1～6】Compare,【Comparative example 1～4】The maximum nonseizure load of each composition is respectively less than 1000N, mill
Spot diameter is all higher than 0.35mm, it is impossible to meet cold heading technique particular/special requirement；Corrosion resistance (copper corrosion) experiment of each composition
It is all higher than 1 grade, it is impossible to meet the particular/special requirement of cold-heading equipment gear lubrication.
Summary pair【Embodiment 1～6】With【Comparative example 1～4】In each composition extreme pressure anti-wear, corrosion resistance
It is (copper corrosion) and right【Embodiment 3～6】Oxidation stability (rotary bomb oxidation test), rust-preventing characteristic (liquid phase corrosion B methods) etc.
Test result, illustrates that the present composition has excellent extreme pressure anti-wear (using load carrying capacity of lubricant determination method (four balls
Method) not less than 631N, using load carrying capacity of lubricant determination method (four ball method), (maximum is without card for (resultant wear index ZMZ) test
Sting load PB) test maximum nonseizure load be not less than 1000N, using load carrying capacity of lubricant determination method (four ball method) (burn
Knot load PD) (GB/T3142) test sintering load be not less than 6080N, using lubrication oil antiwear damage performance measurement method (SH/
T0189) wear scar diameter for determining is not more than 0.35mm), excellent corrosion resistance (copper corrosion) is (rotten using oil product copper sheet
The result of corrosion test method (GB/T5906 or ASTM D130) test is not more than 1)；Meanwhile, combination also has excellent anti-oxidant
Property, resistance to rust and corrosion.
Claims (10)
1. a kind of cold-heading fluid composition, comprising following component in terms of parts by weight：
A) 100 parts of mineral base oils；
B) 0.1～5.0 part of extreme pressure anti-wear additives；
C) 0.01～0.5 part of metal deactivator；
D) 1.0～15.0 parts of oiliness improvers；
E) 0.005～0.5 anti-foaming agent；
The extreme pressure anti-wear additives be olefine sulfide and, selected from sulfide isobutene, phenyl sulfide, sulfide aliphatic acid ester or thio phosphorus
At least one mixture in the multiple ester amine salt of acid；
At least one of the metal deactivator in benzotriazole derivative or thiadiazoles derivative；
The oiliness improver is selected from vulcanized vegetable oil and at least one mixture in fatty acid ester or higher aliphatic.
2. cold-heading fluid composition according to claim 1, it is characterised in that in terms of parts by weight, the consumption of extreme pressure anti-wear additives
For 0.5～3.0 part, the consumption of metal deactivator is 0.02～0.3 part, and the consumption of oiliness improver is 6.0～12.0 parts, anti-foaming agent
Consumption is 0.01～0.3 part.
3. cold-heading fluid composition according to claim 1, it is characterised in that in extreme-pressure anti-wear agent composition, olefine sulfide with
At least one weight ratio in the multiple ester amine salt of sulfide isobutene, phenyl sulfide, sulfide aliphatic acid ester or D2EHDTPA
For 1：(0.1～1.0)；
In oiliness agent composition, vulcanized vegetable oil is 1 with least one ratio in fatty acid ester or higher aliphatic：
(0.1～1.0).
4. cold-heading fluid composition according to claim 3, it is characterised in that in extreme-pressure anti-wear agent composition, olefine sulfide with
At least one weight ratio in the multiple ester amine salt of sulfide isobutene, phenyl sulfide, sulfide aliphatic acid ester or D2EHDTPA
For 1：(0.1～0.8)；
In oiliness agent composition, vulcanized vegetable oil is 1 with least one ratio in fatty acid ester or higher aliphatic：
(0.1～0.8).
5. cold-heading fluid composition according to claim 4, it is characterised in that in extreme-pressure anti-wear agent composition, olefine sulfide with
At least one weight ratio in the multiple ester amine salt of sulfide isobutene, phenyl sulfide, sulfide aliphatic acid ester or D2EHDTPA
For 1：(0.1～0.6)；
In oiliness agent composition, vulcanized vegetable oil is 1 with least one ratio in fatty acid ester or higher aliphatic：
(0.1～0.6).
6. cold-heading fluid composition according to claim 1, it is characterised in that the benzotriazole derivative is selected from N, the fourths of N- bis-
At least one in base aminomethylene-alkyl benzotriazole or benzotriazole, aldehyde and amine condensation product；
The thiadiazoles derivative is selected from 2,5- dimercapto -1,3,4- thiadiazoles derivatives, 2,5- dimercapto -1,3,4- thiadiazoles
At least one in derivative or the sulphur mixture of di-n-octyl two.
7. cold-heading fluid composition according to claim 1, it is characterised in that the anti-foaming agent is selected from alkyl-silicone oil, acrylic acid
At least one in ester and ether copolymer or more mixture.
8. cold-heading fluid composition according to claim 1, it is characterised in that the mineral base oil is selected from solvent refining base
At least one in plinth oil or hydrogenation mineral base oil, Viscosity Index is more than 90.
9. cold-heading fluid composition according to claim 1, it is characterised in that also include selected from antirust agent in the composition
Or at least one in antioxidant；In terms of parts by weight, the consumption of antirust agent is 0.01～1.0 part, and the consumption of antioxidant is
0.05～1.2 part；Wherein, the antirust agent is in calcium mahogany sulfonate, dodecenylsuccinic acid or alkenyl succinic acid half ester
It is at least one；At least one of the antioxidant in alkylated diphenylamine, N- PAs or phenolic antioxidant.
10. the arbitrary described cold-heading fluid composition of claim 1～9 is used for cold heading technique and unifies the cold-heading of fuel feeding with equipment lubrication
The lubrication of machine.
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107603707A (en) * | 2017-09-27 | 2018-01-19 | 深圳市奥科宝特种油剂有限公司 | A kind of water-soluble cold-heading oil and preparation method thereof |
| CN108865366A (en) * | 2018-07-26 | 2018-11-23 | 中国石油化工股份有限公司 | Honing fluid composition and application thereof |
| CN109468157A (en) * | 2018-11-08 | 2019-03-15 | 希玛石油制品（镇江）有限公司 | A kind of no chlorine environmental-protecting type stainless steel molding oil and preparation method thereof |
| CN109666530A (en) * | 2017-10-13 | 2019-04-23 | 中国石油化工股份有限公司 | A kind of dedicated cold rolling fluid composition of bearing machining |
| CN110041986A (en) * | 2019-05-20 | 2019-07-23 | 上海樱花化研化工科技有限公司 | Cold-heading fluid composition and preparation method thereof |
| CN110144255A (en) * | 2019-04-30 | 2019-08-20 | 厦门加美石油集团有限公司 | A kind of easy cleaning cold-heading molding oil and preparation method thereof |
| CN110305715A (en) * | 2018-05-04 | 2019-10-08 | 嘉兴市国龙石油化工有限公司 | A kind of stainless steel drawing oil and preparation method thereof |
| CN114231344A (en) * | 2021-12-30 | 2022-03-25 | 安美科技股份有限公司 | Cold heading forming oil and preparation method thereof |
| CN115851349A (en) * | 2022-09-22 | 2023-03-28 | 广州市联诺化工科技有限公司 | Lightweight automotive aluminum alloy fastener forming oil and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006022281A (en) * | 2004-07-09 | 2006-01-26 | Sumitomo Light Metal Ind Ltd | Cold rolling lubricating oil |
| CN103740444A (en) * | 2012-09-20 | 2014-04-23 | 中国石油化工股份有限公司 | Gear oil composition and applications thereof |
| CN105238519A (en) * | 2015-10-19 | 2016-01-13 | 中国石油化工股份有限公司 | Lubricant composition and application thereof |
| CN105482873A (en) * | 2015-11-30 | 2016-04-13 | 诺泰生物科技(合肥)有限公司 | Environmentally-friendly cold heading oil with epoxidized vegetable oil as base oil, and preparation method thereof |
-
2016
- 2016-09-20 CN CN201610834027.XA patent/CN106635285B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006022281A (en) * | 2004-07-09 | 2006-01-26 | Sumitomo Light Metal Ind Ltd | Cold rolling lubricating oil |
| CN103740444A (en) * | 2012-09-20 | 2014-04-23 | 中国石油化工股份有限公司 | Gear oil composition and applications thereof |
| CN105238519A (en) * | 2015-10-19 | 2016-01-13 | 中国石油化工股份有限公司 | Lubricant composition and application thereof |
| CN105482873A (en) * | 2015-11-30 | 2016-04-13 | 诺泰生物科技(合肥)有限公司 | Environmentally-friendly cold heading oil with epoxidized vegetable oil as base oil, and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 王先会: "《工业润滑油生产与应用》", 31 January 2011, 中国石化出版社 * |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107603707A (en) * | 2017-09-27 | 2018-01-19 | 深圳市奥科宝特种油剂有限公司 | A kind of water-soluble cold-heading oil and preparation method thereof |
| CN107603707B (en) * | 2017-09-27 | 2020-09-18 | 深圳市奥科宝特种油剂有限公司 | Water-soluble cold heading oil and preparation method thereof |
| CN109666530A (en) * | 2017-10-13 | 2019-04-23 | 中国石油化工股份有限公司 | A kind of dedicated cold rolling fluid composition of bearing machining |
| CN109666530B (en) * | 2017-10-13 | 2021-11-19 | 中国石油化工股份有限公司 | Cold rolling oil composition special for bearing processing |
| CN110305715A (en) * | 2018-05-04 | 2019-10-08 | 嘉兴市国龙石油化工有限公司 | A kind of stainless steel drawing oil and preparation method thereof |
| CN108865366A (en) * | 2018-07-26 | 2018-11-23 | 中国石油化工股份有限公司 | Honing fluid composition and application thereof |
| CN109468157A (en) * | 2018-11-08 | 2019-03-15 | 希玛石油制品（镇江）有限公司 | A kind of no chlorine environmental-protecting type stainless steel molding oil and preparation method thereof |
| CN110144255A (en) * | 2019-04-30 | 2019-08-20 | 厦门加美石油集团有限公司 | A kind of easy cleaning cold-heading molding oil and preparation method thereof |
| CN110041986A (en) * | 2019-05-20 | 2019-07-23 | 上海樱花化研化工科技有限公司 | Cold-heading fluid composition and preparation method thereof |
| CN114231344A (en) * | 2021-12-30 | 2022-03-25 | 安美科技股份有限公司 | Cold heading forming oil and preparation method thereof |
| CN115851349A (en) * | 2022-09-22 | 2023-03-28 | 广州市联诺化工科技有限公司 | Lightweight automotive aluminum alloy fastener forming oil and preparation method thereof |
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