CN103571590B - Lubricating oil composition and purposes - Google Patents
Lubricating oil composition and purposes Download PDFInfo
- Publication number
- CN103571590B CN103571590B CN201210277491.5A CN201210277491A CN103571590B CN 103571590 B CN103571590 B CN 103571590B CN 201210277491 A CN201210277491 A CN 201210277491A CN 103571590 B CN103571590 B CN 103571590B
- Authority
- CN
- China
- Prior art keywords
- acid
- consumption
- lubricating oil
- rust
- ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Lubricants (AREA)
Abstract
The present invention relates to a kind of lubricating oil composition and purposes, mainly solve the base oil that use that prior art exists honing technique lubricating oil composition and have contains the components such as solar oil, safety in utilization is difficult to ensure; Some employing clorafin extreme pressure lubricants, baric rust-inhibiting additive, have the problem of certain influence to environment.The present invention comprises following component by adopting with weight parts: a) longer chain fatty acid of 0.5 ~ 6 part; B) phosphorus-containing lubricant of 0.1 ~ 4 part; C) rust-preventive agent of 0.5 ~ 5 part; D) oxidation inhibitor of 0.1 ~ 3 part; E) base oil of 86 ~ 96 parts, not containing solar oil in described base oil; Wherein, the technical scheme not containing at least one in clorafin or baric rust-preventive agent in described composition solves this problem preferably, can be used for the lubrication of metal Honing process technique, cooling and antirust.
Description
Technical field
The present invention relates to a kind of honing technique lubricating oil composition and purposes.
Background technology
Honing is a kind of conventional hole inwall fine-processing technique, is a kind of special shape in metal cutting process.It can not only remove larger process redundancy, and can improve workpiece accuracy and surface quality.Can obtain high dimensional accuracy, high form accuracy, low roughness by Honing process, and bore surface there is the workpiece of overlapping curve.In production in enormous quantities, Honing process has the advantages that cost is low, precision is high, is important component part necessary in modern manufacturing unit.
In order to ensure the low roughness on the high dimensional accuracy of metal parts after Honing process, high form accuracy and surface, need lubricant to have good oilness, in corresponding test in laboratory, show as higher last non seizure load and less wear scar diameter.Meanwhile, in workpiece hone processing course, real-time temperature is far longer than conventional cutting, and the eliminating of abrasive dust is also than difficult cutting, and heat and abrasive dust are easily assembled at process zone, therefore requires that selected honing oil possesses good cooling performance.In addition, honing oil also should possess good oxidation-resistance and resistance to rust and corrosion, corrosion does not occur to extend oil product work-ing life, proterctive equipment and workpiece as far as possible
At present, honing oil product vendor on market mainly contains SENNEN company, HOUGHTON company, CHEVRON company etc. abroad, domestic honing oil performance level is general lower, a lot of plover mill machine uses kerosene to add total loss system oil or low 2# and the 3# total loss system oil of viscosity to add a certain amount of nonactive sulfide fat oil and make honing oil, and the oilness of oil product and work-ing life are all undesirable.In addition, the additive that a lot of existing honing oil is used, as clorafin extreme pressure lubricant, baric rust-inhibiting additive etc., all has disadvantageous effect to workers ' health.
Document CN1071194 discloses a kind of lubricating composition that can be used as grinding oil of steel workpiece, and its base oil reacts obtained by refining solar oil and high-speed engine oil, and sanitas is barium mahogany sulfonate, and its content is in the composition 1 ~ 3%.
Li Jianbo has delivered " development of SH-3 honing oil " at " synthesis lubricant " magazine 2010.2, and lubricant used includes clorafin T301, particularly employs the T301 of short chain.It is reported, in November, 2000, EU Committee promulgated regulation, and restriction short chain clorafin is in the use of EU member country.Require the metalworking fluid of short chain clorafin content more than 1% and leather greasing material, must not in market sale; Before 1 day January in 2003, all use short chain clorafins must assess its risk formed health and environment through European Commission.Environmental Protection Agency is announced and is taked consecutive action to the chemical containing the 4 classes possibility health risks such as short chain clorafin and environment for 2010, finally maybe can limit these chemical inlet.
In a word, in prior art, some uses contain the base oil of the components such as solar oil, and safety in utilization is difficult to ensure; Some employing clorafin extreme pressure lubricants, baric rust-inhibiting additive, have certain influence to environment.
Summary of the invention
One of technical problem to be solved by this invention is the base oil that use that prior art exists honing technique lubricating oil composition and has contains the components such as solar oil, and safety in utilization is difficult to ensure; Some employing clorafin extreme pressure lubricants, baric rust-inhibiting additive, have the problem of certain influence to environment, provide a kind of new lubricating oil composition.Said composition not containing above-mentioned base oil and additive, and can meet Honing process processing requirement preferably.Two of technical problem to be solved by this invention is to provide a kind of purposes of the lubricating oil composition corresponding with one of technical solution problem.
For one of solving the problems of the technologies described above, the technical solution used in the present invention is as follows: a kind of lubricating oil composition, comprises following component with weight parts:
A) longer chain fatty acid of 0.5 ~ 6 part;
B) phosphorus-containing lubricant of 0.1 ~ 4 part;
C) rust-preventive agent of 0.5 ~ 5 part;
D) oxidation inhibitor of 0.1 ~ 3 part;
E) base oil of 86 ~ 96 parts, not containing solar oil in described base oil;
Wherein, at least one in clorafin or baric rust-preventive agent is not contained in described composition.
In technique scheme, with weight parts, the consumption preferable range of longer chain fatty acid is 1 ~ 5 part, and more preferably scope is 2 ~ 4 parts; The consumption preferable range of phosphorus-containing lubricant is 0.2 ~ 3.5 part, and more preferably scope is 0.4 ~ 3 part; The consumption preferable range of rust-preventive agent is 1 ~ 4 part, and more preferably scope is 1.5 ~ 3 parts; The consumption preferable range of oxidation inhibitor is 0.3 ~ 2.5 part, and more preferably scope is 0.5 ~ 2 part; The consumption preferable range of base oil is 88 ~ 94 parts, and more preferably scope is 89 ~ 93 parts.
In technique scheme, described longer chain fatty acid preferred version is for being selected from least one had in the saturated of 12 ~ 22 carbon atoms or unsaturated longer chain fatty acid; Wherein, described saturated fatty acid preferred version is be selected from least one in stearic acid, cocinic acid, oxidation rape oil or palmitinic acid, and described unsaturated fatty acids preferred version is be selected from least one in oleic acid, linolic acid, sylvic acid or dimeracid.Described phosphorus-containing lubricant preferred version is be selected from least one in phosphoric acid ester, phosphorous acid ester, phosphate amine salt, thiophosphatephosphorothioate or thiophosphate; Wherein, described phosphoric acid ester preferred version is be selected from least one in tritolyl phosphate, dibutyl phosphate, tributyl phosphate, octadecyl phosphoric acid ester, iso-octyl stearylamine phosphoric acid ester or dilauryl phosphoric acid ester; Phosphorous acid ester preferred version is be selected from least one in dibutyl phosphite, phosphorous acid di-n-octyl, tricresyl phosphite monooctyl ester or phosphorous acid two isodecyl ester.Described rust-preventive agent preferred version is be selected from least one in sulfonate, carboxylic acid group's rust-preventive agent or the ester class except barium sulfonate; Wherein, described sulfonate preferred version is that to be selected from petroleum cuts be sulfonated petro-leum or the synthesising sulfonate of raw material, comprises at least one in sodium sulfonate, sulfanilic acid, calcium sulphonate, sulfonic acid zinc, dinonylnaphthalene sulfonic acid sodium, dinonylnaphthalene sulfonic acid amine or dinonylnaphthalene sulfonic acid calcium; Carboxylic acid group's rust-preventive agent preferred version is be selected from least one in alkylbenzoic acid, nonyl benzene fluoroacetic acid or alkenyl succinic acid; Described ester class preferred version is be selected from least one in Sorbitol Powder trioleate, pentaerythritol monooleate or dodecenylsuccinic acid half ester; Described oxidation inhibitor is selected from least one in amine type, phenolic or phenol amine type oxidation inhibitor, and preferred version is be selected from least one in ditertbutylparacresol, di-tert-butylphenol, methylene radical phenol and dialkyl diphenylamine, nonox or di-t-butyl dimethylamino p-cresol.Described base oil preferred version is be selected from least one in solvent treatment base oil, hydrofining base oil or total loss system oil.
In technique scheme, with weight parts, in described composition, preferred version is also comprise the defoamer of f) 0.1 ~ 1 part or at least one g) in the sulfur-bearing extreme pressure lubricant of 0.1 ~ 4 part; Wherein, the consumption preferable range of defoamer is 0.1 ~ 0.8 part, and the consumption preferable range of sulfur-bearing extreme pressure lubricant is 0.1 ~ 2 part.Described defoamer preferred version is be selected from least one in silicone oil, methyl-silicone oil or dimethyl silicone oil; Described sulfur-bearing extreme pressure lubricant preferred version is at least one in olefine sulfide or sulfide aliphatic acid ester; Wherein, described sulfide aliphatic acid ester preferred version is be selected from least one in sulfurized lard, sulfide aliphatic acid methyl ester or sulfurized fatty acid glyceride.
The preparation method of lubricating oil composition of the present invention is as follows: first base oil is added in Mixer pot, start agitator and heater switch, heat while stir, when oil product heating temperatures to 40 ~ 50 DEG C, add rust-preventive agent and oxidation inhibitor, fully stirring more than 30 minutes to all dissolving, 35 ~ 50 DEG C time, adding longer chain fatty acid, phosphorus-containing lubricant and other auxiliary agents, stir more than 60 minutes to completely transparent, the yellow homogeneous liquid obtained is described lubricating oil composition.
For solve the problems of the technologies described above two, the technical solution used in the present invention is as follows: above-mentioned lubricating oil composition is used for the lubrication of metal Honing process technique, cooling and antirust.Identical with the technical scheme that one of technical solution problem is taked of the component of wherein said lubricating oil composition, parts by weight and preferable range.
Lubricating oil composition of the present invention be used for the lubrication of metal Honing process technique, cooling and antirust time, its using method is as follows: to clean and the honing device cooling and lubricating system of drying injects lubricating oil composition of the present invention to specifying liquid level, start the oil product recycle system of lathe, the Honing process of workpiece can be carried out.
Lubricating oil composition of the present invention, owing to wherein not containing solar oil, clorafin extreme pressure lubricant and baric rust-inhibiting additive, environmentally friendly, the security of use is guaranteed.Meanwhile, also have good oilness, smooth finish and the dimensional precision of the rear metallic surface of processing meet the requirements completely; Cooling is better, and can take away the heat produced in honing process in time, cutter life is long; Good resistance to rust and corrosion, the metallic surface of workpiece, cutter and lathe is all bright, does not have variable color and corrosion phenomenon; Honing oil property retention is steady in a long-term, and can meet the Honing process processing requirement of different diameter hydro-cylinder, achieves good technique effect.
Embodiment
[embodiment 1 ~ 6]
First base oil is added in Mixer pot, start agitator and heater switch, heat while stir, when oil product heating temperatures to 45 DEG C, add rust-preventive agent and oxidation inhibitor, fully stir 40 minutes; 40 DEG C time, add longer chain fatty acid, phosphorous extreme pressure agent and other auxiliary agents, stir 80 minutes, namely obtain yellow homogeneous liquid.Each component and content are in table 1, and its respective performances index is in table 3.
[comparative example 1 ~ 2]
Formulated according to each component about honing oil composition in document CN1071194 " a kind of lubricating composition that can be used as grinding oil of steel workpiece ", Li Jianbo " development of SH-3 honing oil ".In the product of comparative example, each component and content are in table 2, and product performance are in table 3.
Table 1
Table 2
Table 3
Note: GB/T 12583-1998 lubricant extreme pressure property assay method (four ball)
SH/T 0189-1992 lubrication oil antiwear damages performance measurement method (four-ball tester method)
SH/T 0195-1992 (2000) corrosion testing of lubricating oils method
Lubricating oil composition provided by the invention, not only not containing solar oil, clorafin extreme pressure lubricant and baric rust-inhibiting additive, environmentally friendly, the security of use is guaranteed; And there is good oilness, cooling and rust-preventing characteristic, meet the Honing process processing requirement of different diameter hydro-cylinder.
Claims (9)
1. a lubricating oil composition is used for the lubrication of metal Honing process technique, cooling and antirust, and described lubricating oil composition comprises following component with weight parts:
A) longer chain fatty acid of 0.5 ~ 6 part;
B) phosphorus-containing lubricant of 0.1 ~ 4 part;
C) rust-preventive agent of 0.5 ~ 5 part;
D) oxidation inhibitor of 0.1 ~ 3 part;
E) base oil of 86 ~ 96 parts, not containing solar oil in described base oil;
Wherein, at least one in clorafin or baric rust-preventive agent is not contained in described composition;
Described base oil is selected from least one in solvent treatment base oil, hydrofining base oil or total loss system oil.
2. the purposes of lubricating oil composition according to claim 1, it is characterized in that with weight parts, the consumption of longer chain fatty acid is 1 ~ 5 part, the consumption of phosphorus-containing lubricant is 0.2 ~ 3.5 part, the consumption of rust-preventive agent is 1 ~ 4 part, the consumption of oxidation inhibitor is 0.3 ~ 2.5 part, and the consumption of base oil is 88 ~ 94 parts.
3. the purposes of lubricating oil composition according to claim 2, it is characterized in that with weight parts, the consumption of longer chain fatty acid is 2 ~ 4 parts, the consumption of phosphorus-containing lubricant is 0.4 ~ 3 part, the consumption of rust-preventive agent is 1.5 ~ 3 parts, the consumption of oxidation inhibitor is 0.5 ~ 2 part, and the consumption of base oil is 89 ~ 93 parts.
4. the purposes of lubricating oil composition according to claim 1, is characterized in that described longer chain fatty acid is selected from least one had in the saturated of 12 ~ 22 carbon atoms or unsaturated longer chain fatty acid;
Described phosphorus-containing lubricant is selected from least one in phosphoric acid ester, phosphorous acid ester, phosphate amine salt, thiophosphatephosphorothioate or thiophosphate;
Described rust-preventive agent is selected from least one in sulfonate, carboxylic acid group's rust-preventive agent or the ester class except barium sulfonate;
Described oxidation inhibitor is selected from least one in amine type, phenolic or phenol amine type oxidation inhibitor.
5. the purposes of lubricating oil composition according to claim 4, is characterized in that described saturated fatty acid is selected from least one in stearic acid, cocinic acid, oxidation rape oil or palmitinic acid; Described unsaturated fatty acids is selected from least one in oleic acid, linolic acid, sylvic acid or dimeracid;
Described phosphoric acid ester is selected from least one in tritolyl phosphate, dibutyl phosphate, tributyl phosphate, octadecyl phosphoric acid ester, iso-octyl stearylamine phosphoric acid ester or dilauryl phosphoric acid ester; Phosphorous acid ester is selected from least one in dibutyl phosphite, phosphorous acid di-n-octyl, tricresyl phosphite monooctyl ester or phosphorous acid two isodecyl ester;
It is sulfonated petro-leum or the synthesising sulfonate of raw material that described sulfonate is selected from petroleum cuts, comprises at least one in sodium sulfonate, sulfanilic acid, calcium sulphonate, sulfonic acid zinc, dinonylnaphthalene sulfonic acid sodium, dinonylnaphthalene sulfonic acid amine or dinonylnaphthalene sulfonic acid calcium; Carboxylic acid group's rust-preventive agent is selected from least one in alkylbenzoic acid, nonyl benzene fluoroacetic acid, alkenyl succinic acid; Described ester class is selected from least one in Sorbitol Powder trioleate, pentaerythritol monooleate or dodecenylsuccinic acid half ester;
Described oxidation inhibitor is selected from least one in ditertbutylparacresol, di-tert-butylphenol, methylene radical phenol and dialkyl diphenylamine, nonox or di-t-butyl dimethylamino p-cresol.
6. the purposes of lubricating oil composition according to claim 1, is characterized in that with weight parts, also comprises the defoamer of f) 0.1 ~ 1 part or at least one g) in the sulfur-bearing extreme pressure lubricant of 0.1 ~ 4 part in described composition.
7. the purposes of lubricating oil composition according to claim 6, is characterized in that with weight parts, and the consumption of defoamer is 0.1 ~ 0.8 part, and the consumption of sulfur-bearing extreme pressure lubricant is 0.1 ~ 2 part.
8. the purposes of lubricating oil composition according to claim 6, is characterized in that described defoamer is selected from least one in silicone oil, methyl-silicone oil or dimethyl silicone oil; Described sulfur-bearing extreme pressure lubricant is selected from least one in olefine sulfide or sulfide aliphatic acid ester.
9. the purposes of lubricating oil composition according to claim 6, is characterized in that described sulfide aliphatic acid ester is selected from least one in sulfurized lard, sulfide aliphatic acid methyl ester or sulfurized fatty acid glyceride.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210277491.5A CN103571590B (en) | 2012-08-06 | 2012-08-06 | Lubricating oil composition and purposes |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210277491.5A CN103571590B (en) | 2012-08-06 | 2012-08-06 | Lubricating oil composition and purposes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103571590A CN103571590A (en) | 2014-02-12 |
| CN103571590B true CN103571590B (en) | 2015-08-19 |
Family
ID=50044306
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210277491.5A Active CN103571590B (en) | 2012-08-06 | 2012-08-06 | Lubricating oil composition and purposes |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103571590B (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104099168B (en) * | 2014-07-18 | 2016-02-03 | 苏州市凯业金属制品有限公司 | A kind of powder metallurgy lubricant |
| CN104232032A (en) * | 2014-09-29 | 2014-12-24 | 无锡康柏斯机械科技有限公司 | Lubricating agent for shaft boring machine and preparation method of lubricating agent |
| JP6405217B2 (en) * | 2014-12-09 | 2018-10-17 | シェルルブリカンツジャパン株式会社 | Lubricating oil composition for sliding guide surfaces |
| CN104845721A (en) * | 2015-05-14 | 2015-08-19 | 湖北爱国石化有限公司 | Lubricant for honing |
| CN108060001B (en) * | 2017-11-29 | 2021-02-23 | 浙江实美润滑科技有限公司 | Lubricating oil special for turbine and worm and preparation method thereof |
| CN108865366A (en) * | 2018-07-26 | 2018-11-23 | 中国石油化工股份有限公司 | Honing fluid composition and application thereof |
| CN109926874B (en) * | 2019-01-25 | 2021-03-26 | 芜湖人本轴承有限公司 | Processing technology of inner and outer rings of electroplated four-point contact ball bearing with surface coating |
| CN113773896B (en) * | 2021-09-18 | 2022-12-09 | 新乡市瑞丰新材料股份有限公司 | Extreme pressure type steam turbine oil complexing agent and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101921654A (en) * | 2010-08-18 | 2010-12-22 | 中国石油化工股份有限公司 | Oil-gas lubricating oil and production method thereof |
| CN102295977A (en) * | 2011-07-13 | 2011-12-28 | 李胜 | Novel lubricant for sewing machine and preparation method thereof |
| CN102618365A (en) * | 2012-03-09 | 2012-08-01 | 广西大学 | Lubricating-oil composition of speed reducing machine in gas turbine for ship |
-
2012
- 2012-08-06 CN CN201210277491.5A patent/CN103571590B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101921654A (en) * | 2010-08-18 | 2010-12-22 | 中国石油化工股份有限公司 | Oil-gas lubricating oil and production method thereof |
| CN102295977A (en) * | 2011-07-13 | 2011-12-28 | 李胜 | Novel lubricant for sewing machine and preparation method thereof |
| CN102618365A (en) * | 2012-03-09 | 2012-08-01 | 广西大学 | Lubricating-oil composition of speed reducing machine in gas turbine for ship |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103571590A (en) | 2014-02-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103571590B (en) | Lubricating oil composition and purposes | |
| CN103571591B (en) | Lubricating oil composition and uses thereof | |
| CN103958653B (en) | Lubricant composition | |
| CN101717684B (en) | Spray supply mode cutting oil for metal material cutting processing | |
| CN106635285B (en) | Cold heading oil composition and use thereof | |
| US3442804A (en) | Lubricating composition containing a phosphorodithioate inhibitor | |
| CN104263481A (en) | Air compressor oil and preparation method thereof | |
| CN101113383A (en) | Ester flame-proof hydraulic-oil containing nano abrasion-resistant additive and production method thereof | |
| CN107338096A (en) | A kind of environment-friendly type superfine milling oil and preparation method thereof | |
| CN107418656A (en) | A kind of low smell automotive gear oil compound additive | |
| CN102229843A (en) | Aluminum rolling oil additive composition | |
| WO2011121608A2 (en) | A broaching oil or heavy duty neat cutting oil composition | |
| CN109439419B (en) | Cutting oil with ultrahigh lubricating property and preparation method thereof | |
| CN103725365A (en) | Water-based hydraulic fluid composition | |
| CN103965997B (en) | Special lubricating oil composition for circulating system of paper machine | |
| CN105567380B (en) | A kind of lubricating oil | |
| CN101575546B (en) | Oil film bearing lubricating oil with high water separation performance | |
| CN109722330A (en) | A kind of automobile engine protective agent and preparation method | |
| CN102352276B (en) | Paper machine oil (PMO) composition and preparation method thereof | |
| EP2788461A1 (en) | Metalworking fluid composition and method for its use in the machining of compacted graphite iron | |
| CN108865366A (en) | Honing fluid composition and application thereof | |
| CN110331024A (en) | A kind of environmental protection wearproof lubricant and preparation method thereof | |
| CN103534342B (en) | Water-soluble plunger lubricant for die-casting | |
| Gulzar et al. | Chemically active oil filter to develop detergent free bio-based lubrication for diesel engine | |
| CN104726173A (en) | Lubricating grease composition produced by utilizing reclaimed oil |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |